a ae (Chemi m cal bon o d)
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- Dinah Jackson
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1 a ae (Chemical bond)
2 å å å a a ooo i o i a ao e e e a ao a a
3 å å å å o æ e и å o e u и 2 ae o æ e и å o e u ( a å o u å o ooo ) æ a ao a a ao e e a a ooo i æ e и a å o e u æ a a o e æ a å a æ o o
4 å å å å ooo i i ooo æ a ooo ooo æ a ooo o å u å å u å å å u å e и o ooo æ a ooo o å u å e и o ooo æ a ooo o å u
5 å e и o ooo æ a ooo å e и o ooo æ a ooo и e u oa o å e и æ a å o å o o å ooo i o o å ooo i a å a å e i å a o ooo i a o ooo i a i å a å o å ooo i a i å a å o å ooo i
6 å å å å å e i a ao e e e e i o a ao e e e e å e и æ a å o å o å a o o å a o
7 å å a ae и ae и a å a ae и a å a ae и a å å a å a a a å å a å a a
8 a aoo ie o e e иo æ a å a a å o e u Co Valent
9 å o e u å a o o e u o e e å o å å å
10 *. a a ooo i (Ionic Bond).* oæ и e i å a u å (+) æ a (-) e å å a æ ae и å и e i å å ooo i (Ionic Compound) å oo i e i å o a Valence - electron æ oo a a и e åa o a и å IE1 å æ oo a и å EN e NaCl 11Na = 1s 2 2s 2 2p 6 3p Cl = 1s 2 2s 2 2p 6 3s 2 3p 5
11 11Na + = + 17 Cl - = [Na + ][Cl - ] 1s 2 2s 2 2p 6 1s 2 2s 2 2p 6 3s 2 3p 6 å ooo i e i å a a ooo i 20Ca = 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 S = 1s 2 2s 2 2p 6 3s 2 3p 4 16S = Ca Ca 16 S 2- ae åe oo a å e æ aoo a a e a и å a e o o æ å a å u 8 и a ae и и a ae и (Octate s rule)
12 å ooo i e i å a a ooo i He = 2 = 1s 2 Ne = 1s 2 2s 2 2p 6 Ar = 1s 2 2s 2 2p 6 3s 2 3p 6 Kr = 1s 2 2s 2 2p 6 3s 2 4p 6 Xe = 1s 2 2s 2 2p 6 3s 2 5p 6
13 å o å o å NaCl å и ooo o Na + o ooo o Cl - 6 o u å e и a ooo o Cl - o Na + 6 o u å e a å ooo i NaCl и e и e oa å a å ooo (Na + ) æ a ooo (Cl - ) и o o å å o 1 : 1 и o e u æ a CaF Ca o F 8 o u å F o Ca 4 o u å oa å 1 : 2 = Ca : F
14 ooo æ a ooo o å u å å u å å Li + H + N 3- O 2- F- Na + Mg 2+ H - Al 3+ P 3- S 2- Cl - K + Ca 2+ o aæ i a oå Ga 3+ As 3- Se 2- Br - e i ooo å å 1 Rb + Sr 2+ i e Cr 2+ In, 3+ Sn 2+ Sb 3- Te 2- I - Cr 3+, Mn 2+, Mn 3+ Sn, 4+ Cs + Ba 2+ Fe 2+, Fe 3+, Co 2+, Tl 3+ Pb 2+ Bi 3+ Co 3+, Cu +, Cu 3+ Pb 4+
15 å e и o ooo æ a ooo o å u ooo ooo 1 + ooo 2 + ooo 3 + H + o e ooo Mg 2+ æ иe и ooo Al 3+ oa ie и ooo Na + o e и ooo Ca 2+ æ e и ooo Cr 3+ o e и (III) ooo K + o æ e и ooo Fe 2+ o oo (I) ooo Fe 3+ o oo (III) ooo Cu + o e o (I) ooo Cu 2+ o e o (II) ooo Hg + (Hg 2 2+ ) e o i и(i) ooo Hg 2+ e o i и(ii) ooo Ag + i e o ooo Pb 2+ e (II) ooo
16 ooo ooo 1 _ ooo 2 _ ooo 3 _ H - o ooo O 2- oo ooo N 3- oooo CL - o ooo S 2- a ooo P 3- o ooo Br - o ooo Se 2- и и ooo I - ooo ooo Te 2- e ooo
17 å e и o ooo æ a ooo и e u oa o ooo o ooo o NH 4 + æo o e и ooo OH - o ooo CN - å ooo MnO 4 - e o æ åe ooo NO - ooo NO - e ooo 2 3 HCO 3 - o e å oe ooo CO 3 2- å oe ooo HSO 4 - o e a e ooo SO 4 2- a e ooo S 2 O 3 2- oo a e ooo HPO 4 2- o e o e ooo PO 4 3- H 2 PO 4- o e o e ooo o e ooo
18 NO - 2 = (Nitrite) NO - 3 N 3- SO 3 SO 2-4 SO 2- S 2- = e (Nitrate) = (Nitride) = a ooo (Sulphite Sulphite) = a e ooo ( Sulphate) = a (Sulphide)
19 å e и o å ooo i å a u å o o a (e и e åo a e и e åo a) и и a u å+ e и oa å a u å- o å å.... ( o a o a ) Na + a Cl - oa å 1 : 1 NaCl (Sodium Chloride) Ca 2 + a Br - oa å 1 : 2 CaBr 2 (Calcium bromide) Al 3 + a I - oa å 1 : 3 AlI 3 (Aluminium iodide) K + a O 2 - oa å 2 : 1 K 2 O (Potassium oxide)
20 å o å o o å o a å oo ae и å å e e и _ide (- o o ) и и o a и a u å å å и и o a и a u å å å 1 å o e и e o a å a æ e åo å o å e å åoa e Fe 2 + a O 2 - oa å 1 : 1 FeO (Iron(II)oxide) Fe 3 + a O 2 - oa å 2 : 3 Fe 2 O 3 (Iron(III)oxide) Cu + a S 2 - oa å 2 : 1 Cu 2 S (Cupper(I)sulphide) Cu 2 + a S 2 - oa å 1 : 1 CuS (Cupper(II)sulphide)
21 SnCl 2 SnCl 4 o å å Stannum (II) chloride o å å Stannum (IV) chloride Fe 3 O 4 o å å Iron (II) /(III) oxide e i å å o FeO + Fe 2 O 3
22 Ca 2 + a SO 2-4 oa å 1 : 1 CaSO 4 (Calciumsulphate) Cr 2 + a SO 2-4 oa å 1 : 1 CrSO 4 (Chromium(II)sulphate) Cr 3 + a SO 2-4 oa å 2 : 3 Cr(SO 4 ) 3 (Chromium Chromium(III III)sulphate sulphate) Pb 2 + a NO 3- oa å 1 : 2 Pb(NO 3 ) 2 (Lead(II)nitrate) Ni 2+ a H 2 PO 4- oa å 1 : 2 Ni(H 2 PO 4 ) 2 (Nickel(II)dihidrogenphosphate)
23 Ni 2 + a HPO 2-4 oa å 1 : 1 NiHPO 4 (Nickel (II) hidrogen phosphate) Ni 2 + a PO 3-4 oa å 3 : 2 Ni 3 (PO 4 ) 2 (Nickel (II) phosphate) Ni 3 + a HCO 3- oa å 1 : 3 Ni(HCO ) 3 3 (Nickel (III) hydrogen carbonate) Ni 3 + a CO 3- oa å 2 : 3 Ni 2 (CO 3 ) 3 (Nickel (III) carbonate)
24 H 3 PO 4 = o o i Na 2 HPO 4 = o e и o e o e NaH 2 PO 4 = o e и o e o e Na 3 PO 4 = o e и o e FeHPO 4 = Iron(II)hydrogenphosphate Fe 2 (HPO 4 ) 3 = Iron(III)hydrogenphosphate FePO 4 = Iron(III)phosphate Fe(H 2 PO 4 ) 2 = Iron(II)dihydrogenphosphate Fe(H 2 PO 4 ) 3 = Iron(III)dihydrogenphosphate
25 H 3 PO 4 H 2 PO - 4 H + + H 2 PO - 4 H + + HPO 2-4 HPO H + + PO 3-4
26 a å a å e i å a o ooo i NaCl Na(s) Na(g) Na(g) a å å ae i ae i (Sublimation energy) (Ionization energy) 1 2 Na + (g) + e - a å ooo e a Cl 2 (g) Cl(g) Bond dissociation å å a a Cl(g) + e- Cl(g) å a å e - (Election affinity) EA Na+(g) + Cl - (g) NaCl(s) å Lattice energy ( a å å o a å å o )
27 a i å a å o å ooo i 1. и å ae o æ e 2. å a å å å a å a o å å 3. åe o æ a o å å o e a å å e e и a 4. и o e u æ и e и e oa å a å ooo æ a o å å
28 *. a ao e e (Co Co-valent bond).* o æ e и и e i å oo a a oo a å Valent electron electron å a (Shair) IV (C, Si) Share 4 VA (N, P, AS, Sb) Shair 3 VIA (O, S, Se) Shair 3 VIIA (H, F, CL, Br, I) Shair 1
29 å e i a ao e e å a a и e i å oo a a oo a å Valence-electron electron a (share) e o å oo a a и å IE1 å e и e - å æ a и å EN e - и å ioa o o oo a a и a å a - e ooa o e å å a o o i e и a e - o eo æ a e - o oи oa o å e i o e u и å a å å e i å e и e o e u o e e e å e i o e u H 2
30 a o % e/% H2
31 i o a ao e e æ å å e i a a 3 ae a ae и (Single bond) o a a и oo a Val e - e и 1 e - a a (Double bond) o a a и oo a Val e - e и 2 e - a a å (Triple bond) o a a и oo a Val e - e и 3 e -
32 å å e и o å a ao e e o Gillbert Newton Lewis å oe i a å 2 a a å æ u æ a æ e 1. æ u a a (.) 0, x æ e - å a a o e - o e и 2. æ e a a e a e e æ a ae и e æ a a e æ a a å
33 a o å e 17 Cl = 2, 8, 7 å a o
34 "Single Bond" e H 2 O, H = 1 8 O -2 = 2, 6 æ e H-O-H æ u
35 "Double Bond" e O 2, 8 O = 2, 6 æ e æ u
36 "Triple Bond" e O 2, 8 O = 2, 6 æ u æ e
37 oo e e å e i å a o Co Vent и oa o o oo a å å a 8
38 3. o e u o e e и e å oo e a и å o e e и и å e i a a Co-Vent æ e å ooo e å e å и a a (Unstable) e BeCl 2, 4Be = 2, 2 17Cl = 2, 8, 7 (Be share = 4 e - )
39 BCl 3, 5B = 2, 3 17Cl = 2, 8, 7 (B share = 6 e - )
40 PCl 5 15P P = 2, 8, 5 17Cl = 2, 8, 7 (P share = 10 e - )
41 SF 6 16S S = 2, 8, 6 9F = 2, 7
42 XeF 4 54Xe = 2, 8, 18, 18, 8 9F = 2, 7
43 å e и æ a å o å o å a o Co-Valent å u å e и å Co-Val åe å å å u o oo a o å oa å o å u a e 4 7 oa å 1 : 4 e Cl 4, CCl 4, SiF 4, SiBr 4,CN oa å 1 : 3 e NH 3, NCl 3, PBr 3, PI oa å 1 : 2 e SCl 2, OF 2, OH 2 = H 2 O 7 7 oa å 1 : 2 e H 2, Cl 2 F 2, Br 2 I 2 (H 2 и å EN å H 2 O)
44 4 6 oa å 2 : 4 = 1 : 2 e CO 2, CS 2, SiO oa å 2 : 3 e N 2 O 3, P 2 O oa å 1 : 1 e O 2, S 8, Se oa å 2 : 1 e
45 å o å o å a o o e e å u и a a и o å ooo a a å o æ o å oo a a a o a a ue a å å и ( a i a i ) oo a o a æ e и å å e e и o (-ide)
46 å å и å oa o o o (mono) 1 (di) 2 (tri) 3 e a (tetra) 4 e a (penta) 5 e a (hexa) 6 e a (hepta) 7 oo a (octa) 8 o a (nona) 9 e a (deca) 10
47 e CO o å å o o o oo Carbon mono oxide CO 2 o å Carbondioxide PCl 3 o å Phosphoroustrichloride PBr 3 o å Phosphorouspentabromide
48 BeCl 2 o å Beryliumdichloride BF 3 o å Borontrifluoride PCl 5 o å Phosphorouspentachloride SF 6 o å Sulpherhexafluoride XeF 4 o å Kenontetrafluoride
49 e N 2 O o å Dinitrogenmonooxide NO o å Mononitrogen N 2 O 3 o å Nitrogentrioxide N 2 O 4 (NO 2 ) o å Nitrogentetraoxide N 2 O 5 o å Nitrogenpentaoxide
50 H 2 O (water) NH 3 (Ammonia) o å a PH 3 (Phosphine)
51 å å a ae и (Average Bond Length) å å a a a å i e и o oa o å u å a a (Co-valent) e å e i o e u o H 2 å и å å å a å i e и o H oa o a 2 a å a 74 pm. å å å å a a o å u и и å å 2 oa o e H 2 O å å a a a å O-H 2 oa o å e å a a и å å 2.9 å 123
52 å å å a a a å O-H å a o и å a a и å å a a e å a и å å å o å å a a å å åe и a a å å a a o O-H и å a å 97 pm. å å a a и e i å i o a a и å a å и e å å и a ae и å o å u e и æ i o a a å a a и å å a a e å a e å å å 2.10 o C æ a C
53 C-C å å a a= 154 pm C=C å å a a = 134 pm C C å å a a= 120 pm
54 å å å o a a å u e и a o a ae и å å a a a a å å a a å e åa иæ å å i e и å a e i æ и å
55 a å a ae и (Average Bond energy) o a å и o å a a o o e u o e e e H 2 (g)(o e u o e u ) KJ/mol 2H(g)( H(g)(oa o ) a å a å 436 KJ/mol 2H(g) H(g)(oa o ) H 2 (g)(o e u o e u ) KJ/mol å a å 436 KJ/mol o a å и å a a å o a å и å a a o e e å a å a a и e i å o e u и иoa o å å 2 oa o e CH4 (Methane gas)
56 å åe и = 1652/4 = 413 å a å a a a å C-H a å 413 KJ/mol CH 4 (g) C(g) + 4H(g) oa o (C(s) + 2H 2 (g) o e u a å C-H = 413 x 4 = 1652 KJ/mol a a C(g) + 4H (g) CH 4 (g) å a å = 1652 KJ/mol
57 a a å a å å e åa share a 3 a å e o a a e å a e o å a a o å a a a a å e å o o a å å a ae и o å a a o å a a å å å a ( å å 2.11)
58 C-C å a a = 348 pm C=C å a a = 614 pm C C å a a = 839 pm
59 ** i o a a (e и e и,, å ) æ a å a å å a a a aæ æ a a a a å a a a a å a a **
60 a å å a å a a 1.. o e и i i i å ( å å ) и o å å o a u å 2. e и o e u o å (o e e ) e o å æ e 3. æ å a å a å a a o å и e i i i i å å æ a i a u å
61 4. a å и å a å o å a o å å a a ( a å a å ) E1 KJ æ a a å o i a o å å a a å a a( å a å å a å ) E2 KJ å o a å = E, ( H ) a a E, ( H ) = E1 + E2 å E 1 > E 2 и å (+)... e i i i å a å å E 1 < E 2 и å (-)... e i i i å å a å
62 a o å å e å o å иe (CH 4 ) 1 mol a и å å a å и io
63 Hydrocarbon = и o e a å o e o a o æ 3 å e å æ
64 o e å e o e å e (Aliphatic) и 3 i å a a 1.Alhana (C n H n+2 ) å n = 1 å n = 2 å n = 3 CH 4 иe (Methane) 4 C 2 H 5 oиe (Ethane) C 3 H 8 o e (Propane) å n = 4 C 4 H 10 i e (Butane)
65 2. Alkene (C n H 2n ) a a a a [n e i a æ 2] å n = 2 C 2 H 4 (Ethane) å a Ethylene gas å n = 3 C 3 H 8 (Propane) 3. Alkyne (C n H 2n-2 ) a a å a a å [n >1] å n = 2 C 2 H 2 (Ethyne, Acetylene gas) å n = 3 C 3 H 4 (Propyne)
66 i и å CH 4 (g) + 2O 2 (g) CO 2 (g) +2H 2 O (g) = 4 x (498) 2 x (463) = = 2648 KJ å = 3460 KJ a a å å o = = 812 KJ/mol
67 E = E1 - E2 = = -812 KJ a a å a å 812 KJ
68 Ent 46 i i i å å e и C2H2 å æ e i i i i å 2 a o a и a o и 1 2C(æ æ ) 2C (g) å o o å å e o = 717 KJ/mol a o и 2 2C(g) + H2 (g) H-C C-H i i i å и å o å o и io /o o å
69 i и å 2C(s) 2C(g) KJ/mol a å 2C(g) H2(g) H-C C-H 2C(g) + H2(g) H-C C-H (2 x 717) = (2 x 414) = = = 1870 = 1665 å i i i å и a å = = 205 KJ
70 Ent 48 A e å u 6 å 2 æ a B e å u 7 å 2 A 2 (g) + B 2 (g) å a o A æ a B a å 60 KJ å a å a a A - B o KJ/ mol å a å a a A A æ a B B e å a 500 æ a 160 KJ/mol å å a
71 i и å A 2 (g) + 2B 2 (g) (A=A) + 2(B-B) 2AB 2 (g) 2(B-A-B) x x 2x x 820 4x
72 820-4x = 60 4x = 760 x = 180 a å o A-B AB 2 и å 190 KJ/mol
73 a aoo ie o e e (Co Co ordinate ordinate Co-Valent Valent) ( a a a a ) o a ao e e o и e - a a å å oa o oa o e å a e NH 4+, NH 3-, BCl 3, H 3 O +, PH + 4
74 a o å NH 3 NH 3 + HCl (g) NH 4 Cl (g) + H-Cl
75 a o å NH+BCl
76 a o å OH + HCl
77 a o å PH + HCl
78 иo æ (Resonance Resonance) e i å a ao e e и å и a a a a ae и o и e- å a ao e e å i e- oи ae o å a å oa o a 3 e O3 (Ozone)
79 e SO 2, CO 2-3, NO 3-, SO 2-4, PO 3-4, C 6 H 6 (Benzene - a å a å oi и ) o oo ie e- å å oa o e и иo æ и a ae и
80 a å a a C 3 H 8 ( a ae и a ae и ) 3C(g) + 8 H(g) a å å и u C 3 H 6 ( a a a a ) 3C(g) + 6H(g) C 3 H 4 ( a a å a a å ) 3C(g) + 4 H(g) a å o и u
81 æ 2 ae å o e u Co Valent 1. o e u Co-Valent и oa o å и e - o e и a и a и 5 æ 1.) e BeCl 2, AB 2 2.) å e и æ å BF 3, AB 3 3.) и å CH 4, AB 4 4.) и a i å å e и PCl 5, AB 5 5.) æ å SF 6, AB 6
82 2. o e u Co- Valent и oa o å и e- o e и a иæ å a и e o å e- o e и o oa o å æ aoa o å e и и å æ a a a e e u e i å o e u и å a æ aæ o o e u a å a å æ å o V S E P R ( Valent Shell Electron Pair Repulsion Model) a o AB x E y
83 AB x E y o и A æ oa o å B æ oa o å e и E æ e- o e и o oa o å X æ å oa o å e и Y æ å e- o e и o oa o å
84 a и å å и æ å a å e- o e и a a a a и e - o e и e - o e и e - a a oa o å oa o å oa o å a > a > a e - o e и e - a a e - a a oa o å e и oa o å e и oa o å e и
85 å å 2.12 å o e u o e e и oa o å и e- o e и
86 å å 2.13 a o å å o e u o e e и oa o å и e- o e и
87 å o e u e 3 oa o AB 2 = BeCl 2, CO 2, H 2 Be å e и æ å 4 oa o AB 3 = BF 3, BCl 3, NH 3 3 oa o e H 2 O, H 2 S e o E 2 = u o 4 oa o e NH 3 e o E = и a i å å e и 3 e 3 oa o AB 2 E 3 e XeF 2, I - 3 AB2 e BeCl 2, CO 2, H 2 Be u o AB 2 E 2 e H 2 O, H 2 S, Cl 2 O, OF 3 AB 2 E e O 3, SO 2 ( иo æ иo æ ) и a
88 4 oa o å e и æ å AB 3 e BF 3, BCl 3, BI 3 (CO 2-3 ), (NO 3- ) SbI 3, (H 3 O + ) и a i å å e и AB 3 E e NH 3, PH 3, AsH 3, a и AB E e ClF, ClBr oa o и å AB 4 e CH 4, SiCl 4 TeF 4 (seesaw) и å i e и AB 4 E e SF 4, SeF 4, ( a å ) и e и æ å AB 4 E 2 e XeF 4
89 6 oa o и a i å å e и AB 5 e PCl 5, AsF 5, SbCl 5 и a i å и e и AB 5 E e XeOF 4, IF 5 7 oa o æ å AB6 e SF 6, TeF 6, SeF 6
90 å a o o e u o e e a a o Co Valent - a a и a - a a и a å o e u Co Valent -o e u Co Valent и a -o e u Co-Valent и a
91 1. a a o Co Valent - a a и a å oa o å a a и å i a ( a å u a å u) e CO, HCl * å и å EN å e (-) å и å EN o e (+) e H-2, Cl 3 Cl > H o å å и N e- (delta S-,S+) æ EN
92 å EN o S+ å EN å S- æ a и a å e o - a a и и a å oa o å a ae o a e H 2, O 2, CL 2, F 2 o åe oa o o å å и a u åe o a a a å a e a a и a
93 2. å o e u o e e - o e u Co-Valent и a o o e u и e i å oa o å и e- o e и a eo e u o, и a i å å e и o å и a и e и oa o å и e- e o 3 e и å - å e и æ å и oa o å e o 3 e и å T-shape - и å и oa oo å e o 1 2 e и å a å, seesaw, и e и æ å - и a i å å e и и oa o å e oo 1 e и å и a i å и e и
94 o e u o e e и a å o Co-Valent oa o e - и e, å e и æ å, и a i å å e и æ a æ å u o e H 2 O и a i å å e и e NH 3 * æ i å o a u o o e u o e e и и a æ e и å и å
95 a o å o e u Co Val и a e ( и i å и i å )
96 a a и a o e u и a * o e u a oa o H 2 = 2 x 1.66 x g H a 1.66 x æ e и a å o e u o e e a a o e H e F, O, N
97 å o å å å (Network Structure) - e o e u и å e i å å u и 4 (C Si æ a O) C e o a o o i и и i C и o (oa ) и å a 2 o å o e,æ ( å å, e å) - и å a oa o å o e u и æ å a
98 1. e Diamond ( a a a a, e o a a ) и a a 6 e и u o å и å å a a 154 pm. [C-C] C] и å a e o æ e e i eo å i å å o æ a æ a å o и и å a a o oa o o e- e 6 e и e- u oa o a share a ae и и å å a ae 154 pm. и u o æ å o å å e e å u и æ и u å a e e o a a o e o a a, e åao a å
99
100 2. æ (Graphite) e i eo å i e a æ и a a i e o e C a share a eo e- a ae и e и 3 oie o ae o e- oи 1 o u å i o oa o a å e и a å å a a o e- a å 140 pm. æ a å a a å 340 pm. a и
101
102 a i o æ 1. å a Electrode e o å 2. å i o å o æ å a 3. e e å o o a 4. и å e o i и o i e o
103 3. Silica o SiO 2 и å e æ и å u O (oo ie oo ie ) a a å Si æ a и H.P. = 1730 o åe e и ao и i o å e a u i åæ a o å a o å i å æ åæ o å o å å å e æ i i å æ a и SiC ( å o a å o a ) и HP = 2700 o å e e и åe o o i a и
104 References e i å o i å å æ ae o o и, å a. a oe и å a å e и å æ ae i e i e и e 1. u e : o i u u å å å, e i å o i å å æ ae o o и, å a. o å a å e и å æ a e i e i e и e 1. u e : o i u u å å å, å å u. e и.4 e 1. u e : i a å a i.. a å å a, 2547 u a i, e и.4 e 1. u e : i a e a i i å a,2546
105 Thank you Miss Panida Natthevanit Major of chemistry Department of science St. Louis College Chachoengsao
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