DATA REPOSITORY. G. Di Vincenzo, A. Grande, F. Rossetti CONTENTS

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DATA REPOSITORY Paleozoic siliciclastic rocks from northern Victoria Land (Antarctica): provenance, timing of deformation and implications for the Antarctica/Australia connection G. Di Vincenzo, A. Grande, F. Rossetti CONTENTS APPENDIX Experimental Methods TABLES Table DR1. Geochemical and isotope whole-rock data Table DR2. Electron microprobe analyses of detrital white micas Table DR3. White mica single-grain total fusion 40 Ar 39 Ar data Table DR4. In-situ 40 Ar 39 Ar data on rock chips Table DR5. Step-heating 40 Ar 39 Ar data on whole-rock samples FIGURES Figure DR1. Chemical composition of metsediments from the Bowers and the Robertson Bay Terranes, plotted in the classification scheme of sandstones based on major elements (Herron, 1988) (A) and in the discrimination diagrams for tectonic setting based on Phanerozic graywackes (Bathia and Crook, 1986) (B and C). Figure DR2. Th/Yb vs. Ta/Yb plot (after Pearce, 1983) for Cambrian mafic (meta)volcanic rocks of the Lachlan orogen and for mafic igneous rocks with variable metamorphic overprint from the Bowers Terrane and the eastern Wilson Terrane. Source of data: Stawell Zone (Eastern Lachlan orogeny), Squire et al. (2006); Heathcote and Mount Wellington Belts (Western and Central Lachlan orogen), Foster et al. (2009); Bowers Terrane, Rocchi et al. (2011); Wilson Terrane, Di Vincenzo et al. (1997) and Palmeri et al. (2012). REFERENCES CITED

Experimental Methods Major and trace elements, including Sm and Nd concentrations, were determined by ICP-AES and ICP-MS at the Actlabs (Ontario, Canada) on whole-rock powders dissolved through the lithium metaborate and lithium tetraborate fusion method. Nd isotopic compositions were determined by Thermal Ionization Mass Spectrometry at the IGG CNR of Pisa (Italy), using a Finngan MAT 262 multicollector mass-spectrometer running in dynamic mode. Measured 143 Nd/ 144 Nd were normalized to 146 Nd/ 144 Nd = 0.7219. ε Nd notation was calculated using a 147 Sm/ 144 Nd ratio of 0.1976 and a 143 Nd/ 144 Nd ratio of 0.512638 as starting values in the chondritic mantle reference. The Nd model ages relative to a quadratic depleted mantle evolution (T DM ) were calculated following DePaolo et al. (1991). During the collection of the isotopic data, four analyses of the JNdi-1 standard (Tanaka et al., 2000) yielded an average value of 0.512102±0.000010 (±2SD). Data are listed in Table DR1. Petrographical and microstructural investigation were carried out on polished thin sections using optical microscopy and back-scattered electron (BSE) imaging. BSE images were acquired at the Dipartimento di Scienze della Terra of Siena (Italy) using a Philips XL30 scanning electron microscope (SEM), operating at an accelerating voltage of 20 kv. Electron microprobe (EMP) analyses of detrital white micas were performed at the Dipartimento di Scienze della Terra of Milano (Italy), by a JEOL 8200 Super Probe, operating at an accelerating voltage of 15 kv, sample current of 5 na and using a beam of 5 µm. Natural standards were used for calibration. The full set of data is available as supplementary material (Table DR2). Sample preparation and 40 Ar 39 Ar analyses were also completed at IGG CNR, using different laser extraction techniques, namely: (1) single-grain total fusion analysis of detrital white micas (20 to 35 flakes; grain size of 180 250µm), separated through standard separation techniques and careful handpicking under a stereomicroscope; (2) insitu analysis on rock chips ~9.0 mm in diameter, drilled from double-polished thick sections (~300 µm thick), previously investigated by BSE imaging; (3) step-heating analysis of a few (4 6) whole-rock grains, handpicked under a stereomicroscope from the 250 360 µm grain size and investigated by SEM prior to 40 Ar 39 Ar analysis. White mica concentrates, rock chips and whole-rock grains were cleaned ultrasonically by alternating methanol and deionized water. Samples were wrapped in aluminium foil and irradiated for 80 h in the core of the TRIGA reactor at the University of Pavia (Italy) along with the dating standard Fish Canyon sanidine (FCs). Single-grain total fusion analyses were completed on individual detrital white mica using a continuous-wave (CW) diode-pumped Nd:YAG (neodymium-doped yttrium aluminium garnet) infrared laser. In situ laser 40 Ar 39 Ar analyses were carried out by either the Nd:YAG infrared laser connected to an external computer-controlled shutter or a pulsed Nd:YAG ultraviolet laser (frequency quadrupled and Q-switched). Single infrared laser shots (lasting 10 ms) of the infrared laser (operating at 12 W) were focused to produce melt pits ~100 µm in diameter. The ultraviolet laser, operating at 20 Hz and 1 mj per pulse, was focused to ~10 µm and repeatedly rastered by a computer-controlled x y stage over areas of ~(100 x 100) µm 2 to produce pits a few tens of micrometers deep. Laser step-heating experiments were performed using the infrared laser beam defocused to a ~2 mm spot size and homogenized by a beam-homogenizer lens which produces a flat power distribution. Steps were carried out at increasing laser power until complete melting occurred. More details on the analytical procedures are also given in Di Vincenzo and Skála (2009). Data corrected for post-irradiation decay, mass discrimination effects, isotope derived from interfering neutron reactions and blank are listed in Tables DR3, DR4 and DR5. Errors on single runs are 2σ analytical uncertainties, including in-run statistics and uncertainties in the discrimination factor, interference corrections and procedural blanks. Uncertainties on total gas ages, on error-weighted mean ages and on single run when used for intersample comparison, also include the

uncertainty in the fluence monitor (2σ internal errors). Ages were calculated using the IUGS recommended constants (Steiger and Jäger, 1977) and an age of 28.03 Ma for FCs (Jourdan and Renne, 2007).

TABLE DR1. WHOLE-ROCK GEOCHEMICAL AND ISOTOPIC (ND) ANALYSES sample 31-12-89 GO7 23-01-89 RG4 12-12-94 GO6 12-12-94 GO9 04-01-90 M1 27-01-02 CR2 13-01-02 CR6 01-02-02 CR2 10-01-02 CR2 26-12-93 GM6 12-01-02 CR3 [2] [4] [5] [6] [7] [8] [9] [10] [11] [12] [13] major elements (wt%) SiO 2 62.93 69.70 70.33 73.64 66.76 68.11 64.88 67.06 71.99 63.83 62.12 TiO 2 0.70 0.53 0.60 0.57 0.69 0.62 0.63 0.47 0.61 0.69 0.63 Al 2 O 3 15.22 10.67 12.34 11.62 13.78 13.99 14.82 9.20 9.22 13.76 14.75 Fe 2 O 3 (T) 6.58 3.75 4.86 4.05 5.37 5.33 6.21 4.16 4.14 5.90 6.22 MnO 0.07 0.08 0.05 0.05 0.16 0.05 0.05 0.11 0.08 0.15 0.09 MgO 4.34 2.33 2.43 2.10 2.58 2.95 3.58 1.98 1.66 2.96 3.17 CaO 0.71 3.69 1.13 0.98 0.77 0.86 1.10 6.59 4.25 2.55 1.73 Na 2 O 1.60 2.01 1.87 2.29 1.93 2.70 1.78 0.97 1.68 1.36 1.03 K 2 O 3.68 2.13 2.73 2.39 2.82 2.48 3.15 2.13 1.91 3.30 3.88 P 2 O 5 0.14 0.17 0.18 0.17 0.19 0.16 0.14 0.13 0.21 0.18 0.14 LOI 4.40 5.26 3.87 2.52 3.41 3.35 4.01 7.94 4.77 4.99 5.23 Total 100.37 100.32 100.39 100.37 98.46 100.60 100.35 100.74 100.52 99.67 98.99 trace elements (ppm) and isotopic data Be 3 2 2 2 3 2 3 2 2 3 3 Sc 16 8 10 10 13 13 14 8 8 13 14 V 110 61 68 67 99 83 94 51 47 91 94 Cr 190 100 100 130 70 110 540 580 1170 110 550 Co 20 11 11 10 14 12 17 10 9 15 12 Ni 90 30 40 40 30 40 60 30 40 40 30 Cu 30 30 20 10 50 20 30 50 10 10 40 Zn 120 70 80 80 110 90 110 70 60 110 90 Ga 23 14 17 16 20 19 22 13 13 20 21 Rb 175 96 130 118 140 118 153 105 92 160 180 Sr 48 113 99 139 74 102 101 319 235 55 109 Y 29.3 30.6 28.8 29.8 29.7 29.8 27.9 37.6 33.7 40.1 30.6 Zr 121 184 164 257 184 169 115 112 420 168 131 Nb 12.6 9.2 10.6 9.8 12.2 10.7 11.4 9.2 11 12 11.4 Sb 2.3 2.5 2.5 2.2 3.0 1.2 3.7 1.6 3.4 2.7 2.6 Cs 9.1 4.9 7.2 7.0 7.3 5.9 7.4 4.6 4.5 8.0 12.1 Ba 348 318 410 423 583 519 683 322 347 535 611 La 37 38.1 37.1 41.9 44.4 38.8 36.9 28.8 45.8 39.8 36 Ce 81.4 80.8 79.8 86.1 92.9 83.3 79.3 63 98.6 85.7 77.8 Pr 8.74 8.72 8.63 9.61 9.92 8.99 8.53 6.97 10.5 9.35 8.34 Nd 31.4 32.5 31.6 34.1 35 32.1 30.7 26 37.9 34.7 30.3 Sm 6.13 6.26 6.35 6.32 6.38 6.28 5.9 5.44 7.06 6.75 5.88 Eu 1.42 1.33 1.46 1.34 1.27 1.37 1.22 1.23 1.36 1.44 1.34 Gd 5.78 5.86 6.22 5.92 5.82 5.68 5.25 5.62 6.55 6.68 5.79 Tb 0.93 0.93 0.96 0.93 0.92 0.93 0.86 1.00 1.01 1.15 0.93 Dy 5.12 5.27 5.09 5.05 4.99 5.23 4.76 5.93 5.73 6.73 5.3 Ho 1.01 1.01 0.94 0.96 0.95 0.99 0.9 1.21 1.1 1.3 1.02 Er 2.96 3 2.78 2.91 2.9 2.94 2.68 3.66 3.31 3.88 3.01 Tm 0.429 0.445 0.409 0.435 0.441 0.442 0.417 0.55 0.507 0.608 0.456 Yb 2.77 2.85 2.68 2.85 2.81 2.86 2.67 3.61 3.39 3.99 2.94 Lu 0.410 0.426 0.403 0.430 0.442 0.416 0.407 0.548 0.535 0.603 0.436 Hf 3.5 5.1 4.5 6.8 5.1 4.7 3.2 3.1 11.2 4.8 3.6 Ta 1.37 1.00 1.13 1.15 1.39 1.20 1.18 0.97 1.14 1.27 1.19 W 2.3 1.5 1.9 1.7 3.3 2.2 2.4 1.6 1.5 2.1 2.1 Tl 1.0 0.56 0.71 0.69 0.87 0.59 0.84 0.51 0.61 0.88 0.97 Pb 59 16 11 11 21 13 31 50 6 30 21 Th 17.2 14.6 14.8 16.8 20 15.1 16.1 11.3 18.3 15.4 14.7 U 2.99 2.53 2.35 2.66 3.81 2.84 1.83 1.71 2.65 2.33 1.88 147 Sm/ 144 Nd 0.116 0.118 0.121 0.112 0.110 0.118 0.116 0.126 0.113 0.118 0.117 143 Nd/ 144 Nd 0.511886 0.511826 0.511891 0.511868 0.511779 0.511874 0.511834 0.511922 0.511939 0.511925 0.511894 ±2σ m 0.000006 0.000009 0.000008 0.000008 0.000006 0.000006 0.000011 0.000008 0.000008 0.000008 0.000004 ε Nd(0) -14.7-15.8-14.6-15.0-16.8-14.9-15.7-14.0-13.6-13.9-14.5 T DM 1.81 1.94 1.90 1.76 1.86 1.89 1.89 1.96 1.66 1.77 1.81

Table DR 2. Electron microprobe analyses of detrital white micas. Structural formulae were calculated on the basis of 11 oxigens. Wilson Terrane [1] Sample 31 01 89PR51 1 2 3a 3b 4a 4b 5 6 7 8 9 10a 10b 11a 11b 12 13 14 15a 15b core core core rim core rim core core core core core core rim core rim core core core core rim SiO 2 46.42 47.02 47.34 47.14 47.47 47.22 46.54 46.15 46.94 46.99 47.14 47.16 46.93 45.98 46.57 46.35 45.94 46.77 47.17 47.20 TiO 2 0.60 0.56 0.25 0.45 0.59 0.63 0.54 1.02 0.06 0.36 0.39 0.67 0.45 0.41 0.46 0.98 0.82 0.46 0.18 0.19 Al 2 O 3 35.76 35.12 31.96 32.33 34.03 33.45 35.83 35.78 35.05 34.37 33.95 34.16 34.85 36.26 35.11 36.05 34.91 35.49 35.73 36.16 FeO 1.22 0.95 3.07 2.73 1.55 1.68 0.99 1.12 1.71 2.43 2.52 2.28 2.29 0.95 1.23 0.66 1.45 1.33 0.94 0.89 MnO bdl bdl bdl 0.04 bdl bdl 0.02 0.07 0.00 bdl bdl bdl 0.03 bdl 0.06 0.03 bdl 0.01 0.03 bdl MgO 0.56 0.83 1.80 1.65 1.39 1.52 0.52 0.52 0.91 0.74 0.91 1.26 1.01 0.46 0.72 0.59 0.72 0.77 0.80 0.79 CaO 0.02 0.01 0.04 0.05 bdl 0.05 0.10 0.08 0.03 0.10 0.01 0.04 0.04 0.02 0.06 0.02 0.11 0.01 0.06 0.04 Na 2 O 0.65 1.48 0.27 0.28 0.27 0.28 0.63 1.03 0.43 0.29 0.42 1.50 1.60 1.07 1.09 0.86 0.31 0.73 0.43 0.34 K 2 O 10.37 9.18 10.86 10.86 11.25 11.05 10.48 9.82 10.78 11.00 10.70 9.15 9.09 9.71 9.46 10.39 10.93 10.28 10.77 10.69 Cr 2 O 3 0.03 0.09 0.04 bdl 0.03 0.04 bdl 0.15 bdl 0.03 bdl 0.01 0.00 0.06 0.08 0.28 0.03 0.08 0.09 0.03 NiO 0.03 0.02 0.00 bdl bdl bdl bdl bdl 0.03 bdl bdl 0.05 bdl bdl bdl 0.00 0.07 bdl bdl bdl Cl 0.01 0.01 0.02 bdl 0.00 0.00 0.01 0.01 bdl 0.00 0.00 bdl 0.01 0.01 0.01 0.00 0.01 0.00 bdl 0.01 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 95.66 95.28 95.66 95.53 96.57 95.93 95.67 95.74 95.94 96.31 96.04 96.29 96.30 94.93 94.84 96.22 95.30 95.94 96.20 96.35 Si 3.073 3.108 3.173 3.159 3.130 3.136 3.079 3.051 3.109 3.116 3.131 3.108 3.091 3.056 3.099 3.05 3.07 3.088 3.102 3.095 Ti 0.030 0.028 0.013 0.023 0.029 0.032 0.027 0.051 0.003 0.018 0.019 0.033 0.022 0.021 0.023 0.049 0.041 0.023 0.009 0.010 Al 2.791 2.736 2.525 2.554 2.645 2.618 2.794 2.788 2.737 2.687 2.658 2.654 2.706 2.841 2.754 2.795 2.750 2.761 2.770 2.794 Fe 2+ 0.067 0.053 0.172 0.153 0.086 0.093 0.055 0.062 0.095 0.135 0.140 0.126 0.126 0.053 0.068 0.036 0.081 0.073 0.052 0.049 Mn bdl bdl bdl 0.002 bdl bdl 0.001 0.004 0.000 bdl bdl bdl 0.001 bdl 0.003 0.002 bdl 0.001 0.002 bdl Mg 0.055 0.082 0.180 0.165 0.136 0.151 0.052 0.052 0.089 0.073 0.090 0.124 0.100 0.046 0.071 0.058 0.072 0.076 0.078 0.077 Ca 0.001 0.001 0.003 0.004 bdl 0.003 0.007 0.005 0.002 0.007 0.001 0.003 0.003 0.002 0.005 0.002 0.008 0.001 0.004 0.003 Na 0.084 0.190 0.035 0.037 0.035 0.037 0.081 0.132 0.055 0.037 0.054 0.192 0.204 0.138 0.141 0.109 0.040 0.094 0.055 0.044 K 0.876 0.774 0.929 0.928 0.946 0.937 0.884 0.828 0.911 0.931 0.907 0.769 0.764 0.823 0.803 0.872 0.932 0.866 0.904 0.894 Cr 0.002 0.005 0.002 bdl 0.002 0.002 bdl 0.008 bdl 0.001 bdl 0.001 0.000 0.003 0.004 0.015 0.002 0.004 0.005 0.001 Ni 0.002 0.001 0.000 bdl bdl bdl bdl bdl 0.002 bdl bdl 0.002 bdl bdl bdl 0.000 0.004 bdl bdl bdl Cl 0.001 0.002 0.002 bdl bdl 0.001 0.001 0.001 bdl 0.000 0.000 bdl 0.001 0.001 0.001 0.000 0.001 0.000 bdl 0.001 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 6.981 6.979 7.035 7.024 7.009 7.009 6.981 6.981 7.003 7.006 7.000 7.013 7.019 6.983 6.972 6.988 7.000 6.986 6.980 6.968 Na+K+Ca 0.961 0.965 0.967 0.968 0.981 0.977 0.972 0.966 0.968 0.975 0.962 0.964 0.971 0.962 0.948 0.983 0.980 0.960 0.963 0.941 Na/(Na+K) 0.087 0.197 0.036 0.038 0.035 0.037 0.083 0.138 0.057 0.039 0.056 0.200 0.211 0.143 0.149 0.111 0.041 0.098 0.057 0.047

Wilson Terrane Table DR 2. Continued Bowers Terrane [1] Sample 31 01 89PR51 [2] Sample 31 12 89GO7 16 17 18 19 20 21 22 1 2 3 4 5 6 7 8 9 10 11 12 core core core core core core core core core core core rim core rim core core core core core SiO 2 46.48 46.20 46.39 46.47 46.75 47.64 46.29 46.32 46.40 46.93 46.15 48.01 44.83 45.93 47.28 47.54 48.83 47.18 46.33 TiO 2 0.52 0.95 0.93 0.80 0.90 0.18 0.41 0.73 0.69 0.11 0.21 0.41 1.18 0.37 0.63 0.72 0.35 0.63 0.02 Al 2 O 3 35.93 35.94 34.68 36.51 36.30 31.97 34.03 36.35 36.00 30.32 35.40 33.45 28.71 31.47 34.02 34.90 29.50 32.95 38.89 FeO 1.35 1.12 1.77 0.94 0.89 3.28 2.91 1.30 1.33 5.54 1.53 2.28 6.91 4.72 1.74 1.33 4.60 3.63 0.62 MnO 0.03 0.00 bdl bdl 0.02 0.06 0.11 0.00 bdl 0.05 0.00 0.03 0.09 0.06 bdl 0.03 0.04 0.04 0.04 MgO 0.69 0.59 0.62 0.52 0.54 1.88 0.74 0.54 0.60 1.59 0.75 1.51 4.40 2.06 1.14 1.11 1.71 1.57 0.06 CaO 0.02 0.01 0.02 0.04 0.02 0.07 0.02 0.02 0.02 0.05 0.05 0.05 0.07 0.05 0.02 0.00 0.25 0.08 0.08 Na 2 O 0.61 0.44 0.55 1.03 0.88 0.22 0.45 0.59 0.51 0.27 0.85 0.62 0.32 0.34 0.44 0.30 1.66 0.58 0.53 K 2 O 10.18 10.76 10.38 9.78 9.61 11.02 10.76 10.56 10.68 10.43 9.53 9.95 8.18 10.49 10.44 10.87 9.10 10.06 10.73 Cr 2 O 3 0.05 0.01 0.02 0.06 0.03 bdl 0.01 bdl 0.04 bdl 0.02 0.07 0.03 bdl 0.05 bdl bdl 0.04 0.06 NiO 0.03 0.04 0.02 0.06 0.04 0.01 bdl 0.03 bdl 0.03 0.04 bdl 0.08 0.03 0.02 bdl bdl bdl 0.03 Cl 0.00 0.00 0.01 0.01 0.01 0.01 0.01 0.02 0.02 bdl 0.00 bdl 0.03 0.02 0.02 0.02 0.02 0.03 0.03 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 95.88 96.08 95.39 96.21 96.01 96.34 95.73 96.47 96.30 95.32 94.54 96.38 94.84 95.55 95.80 96.82 96.06 96.78 97.43 Si 3.068 3.051 3.09 3.049 3.067 3.176 3.099 3.046 3.059 3.193 3.084 3.162 3.076 3.114 3.133 3.115 3.266 3.125 3.004 Ti 0.026 0.047 0.047 0.040 0.044 0.009 0.021 0.036 0.034 0.006 0.010 0.020 0.061 0.019 0.032 0.036 0.018 0.031 0.001 Al 2.796 2.798 2.723 2.823 2.807 2.513 2.685 2.818 2.797 2.431 2.788 2.596 2.322 2.515 2.657 2.695 2.326 2.572 2.972 Fe 2+ 0.074 0.062 0.098 0.051 0.049 0.183 0.163 0.072 0.073 0.315 0.086 0.125 0.396 0.267 0.097 0.073 0.257 0.201 0.034 Mn 0.001 0.000 bdl bdl 0.001 0.003 0.006 0.000 bdl 0.003 0.000 0.002 0.005 0.003 bdl 0.001 0.002 0.002 0.002 Mg 0.068 0.058 0.061 0.051 0.053 0.187 0.074 0.053 0.059 0.161 0.075 0.148 0.450 0.209 0.113 0.109 0.171 0.155 0.006 Ca 0.001 0.001 0.001 0.003 0.002 0.005 0.002 0.002 0.002 0.003 0.003 0.003 0.005 0.004 0.001 0.000 0.018 0.006 0.006 Na 0.078 0.057 0.071 0.131 0.112 0.029 0.058 0.076 0.065 0.036 0.111 0.080 0.043 0.045 0.057 0.038 0.215 0.074 0.066 K 0.858 0.906 0.882 0.819 0.804 0.937 0.919 0.886 0.899 0.906 0.812 0.836 0.716 0.908 0.882 0.909 0.776 0.850 0.888 Cr 0.002 0.001 0.001 0.003 0.002 bdl 0.001 bdl 0.002 bdl 0.001 0.004 0.002 bdl 0.002 bdl bdl 0.002 0.003 Ni 0.002 0.002 0.001 0.003 0.002 0.000 bdl 0.002 0.000 0.002 0.002 bdl 0.005 0.002 0.001 bdl bdl bdl 0.002 Cl 0.000 0.000 0.001 0.001 0.001 0.001 0.001 0.002 0.002 bdl 0.000 bdl 0.004 0.003 0.002 0.002 0.002 0.003 0.004 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 6.974 6.983 6.977 6.974 6.944 7.044 7.028 6.993 6.993 7.056 6.974 6.976 7.085 7.088 6.977 6.978 7.051 7.022 6.987 Na+K+Ca 0.937 0.964 0.954 0.953 0.918 0.971 0.978 0.963 0.966 0.946 0.926 0.919 0.764 0.957 0.940 0.947 1.009 0.930 0.960 Na/(Na+K) 0.083 0.059 0.074 0.138 0.123 0.030 0.059 0.079 0.068 0.039 0.120 0.087 0.057 0.047 0.061 0.040 0.217 0.080 0.069

Table DR 2. Continued Bowers Terrane [2] Sample 31 12 89GO7 [3] Sample 23 01 DS7 13 14 15 16 17 1 2 3 4a 4b 5a 5b 6a 6b 7a 7b 8a 8b 9a core core core core core core core core core rim core rim core rim core rim core rim core SiO 2 51.18 49.81 45.34 46.78 46.88 47.09 47.72 47.03 46.93 46.67 47.85 47.55 47.16 47.08 47.20 46.56 47.34 46.62 47.33 TiO 2 0.12 0.36 0.21 0.72 0.15 0.97 0.67 0.75 0.19 0.20 0.69 0.60 0.41 0.42 0.08 0.13 0.35 0.15 0.83 Al 2 O 3 29.68 30.95 29.73 34.55 36.10 29.97 29.15 35.84 32.17 32.43 32.12 31.58 36.59 36.53 35.04 35.32 36.69 36.52 34.50 FeO 2.11 2.40 4.00 3.50 1.90 5.78 4.89 1.13 4.44 4.44 3.18 3.28 1.17 1.16 1.73 1.67 0.61 0.71 2.19 MnO 0.05 0.06 0.06 0.01 bdl 0.08 0.14 0.01 0.28 0.29 bdl 0.02 0.02 bdl bdl 0.01 0.01 bdl 0.03 MgO 3.08 2.47 1.43 0.89 0.91 1.49 2.03 0.90 0.62 0.48 1.85 2.02 0.56 0.64 1.08 0.96 1.11 1.07 0.84 CaO 0.04 0.02 0.04 0.06 0.02 bdl 0.01 bdl 0.09 0.04 0.02 0.02 0.01 bdl 0.02 0.01 bdl 0.02 0.02 Na 2 O 0.31 0.37 0.30 0.81 0.84 0.31 0.32 1.32 0.26 0.26 0.50 0.41 0.47 0.42 0.37 0.43 0.28 0.31 0.38 K 2 O 10.76 10.16 10.95 10.16 10.08 11.02 10.63 9.38 10.40 10.53 10.77 10.74 10.71 10.87 10.45 10.63 11.06 11.04 10.88 Cr 2 O 3 0.01 bdl bdl 0.01 bdl 0.02 bdl 0.02 0.02 0.05 0.05 0.03 bdl bdl 0.10 0.09 bdl 0.05 bdl NiO bdl bdl bdl bdl 0.04 0.01 bdl 0.05 0.03 bdl bdl bdl 0.01 0.01 bdl bdl 0.05 bdl 0.03 Cl 0.02 0.02 0.01 0.01 0.02 0.01 0.02 bdl 0.01 0.01 0.01 0.01 0.02 0.01 0.02 0.01 bdl 0.01 0.01 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 97.35 96.63 92.06 97.50 96.94 96.74 95.59 96.43 95.43 95.40 97.04 96.26 97.13 97.14 96.08 95.82 97.51 96.50 97.04 Si 3.339 3.271 3.189 3.075 3.068 3.176 3.234 3.076 3.168 3.155 3.164 3.172 3.074 3.071 3.115 3.087 3.070 3.059 3.111 Ti 0.006 0.018 0.011 0.036 0.007 0.049 0.034 0.037 0.010 0.010 0.035 0.030 0.020 0.020 0.004 0.007 0.017 0.008 0.041 Al 2.282 2.396 2.465 2.677 2.785 2.383 2.328 2.763 2.561 2.584 2.503 2.483 2.811 2.808 2.725 2.760 2.805 2.825 2.673 Fe 2+ 0.115 0.132 0.235 0.192 0.104 0.326 0.277 0.062 0.251 0.251 0.176 0.183 0.064 0.063 0.095 0.093 0.033 0.039 0.120 Mn 0.003 0.004 0.004 0.000 bdl 0.004 0.008 0.001 0.016 0.017 bdl 0.001 0.001 bdl bdl 0.001 0.001 bdl 0.002 Mg 0.299 0.242 0.150 0.087 0.088 0.150 0.205 0.088 0.063 0.048 0.182 0.201 0.055 0.063 0.106 0.095 0.107 0.105 0.082 Ca 0.002 0.001 0.003 0.005 0.002 bdl 0.001 bdl 0.007 0.003 0.001 0.001 0.001 bdl 0.001 0.001 bdl 0.002 0.001 Na 0.039 0.048 0.040 0.104 0.107 0.041 0.042 0.167 0.034 0.034 0.064 0.053 0.059 0.053 0.048 0.055 0.035 0.039 0.049 K 0.896 0.851 0.983 0.852 0.842 0.948 0.919 0.783 0.896 0.908 0.909 0.914 0.891 0.905 0.880 0.899 0.915 0.924 0.913 Cr 0.000 bdl bdl 0.000 0.000 0.001 bdl 0.001 0.001 0.003 0.003 0.002 bdl bdl 0.005 0.005 bdl 0.003 bdl Ni bdl bdl bdl bdl 0.002 0.000 bdl 0.003 0.002 bdl bdl bdl 0.000 0.001 bdl bdl 0.003 bdl 0.002 Cl 0.002 0.002 0.001 0.001 0.002 0.002 0.003 0.000 0.001 0.001 0.001 0.001 0.003 0.001 0.002 0.001 bdl 0.001 0.001 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 6.984 6.964 7.081 7.029 7.008 7.080 7.051 6.980 7.008 7.014 7.038 7.042 6.979 6.985 6.981 7.002 6.986 7.003 6.994 Na+K+Ca 0.938 0.900 1.026 0.960 0.951 0.989 0.962 0.950 0.936 0.945 0.975 0.968 0.951 0.958 0.929 0.955 0.950 0.965 0.963 Na/(Na+K) 0.042 0.053 0.039 0.109 0.113 0.041 0.044 0.176 0.036 0.036 0.066 0.055 0.062 0.055 0.051 0.058 0.037 0.040 0.051

Table DR 2. Continued Bowers Terrane [3] Sample 23 01 DS7 [4] Sample 23 01 89RG4 9b 10 11 12 13a 13b 14a 14b 15 16 17 18 19 1a 1b 2 3 4 5 rim core core core core rim rim core core core core core core core rim core core core core SiO 2 47.56 46.08 45.78 46.87 48.48 47.77 48.13 47.31 46.17 46.54 47.23 47.64 48.26 47.53 48.58 48.71 47.25 47.59 46.69 TiO 2 0.94 0.63 0.68 1.29 0.46 0.10 0.59 0.68 0.01 0.99 0.48 1.06 0.80 0.43 0.38 0.93 0.69 0.35 0.53 Al 2 O 3 34.01 32.36 32.81 30.52 31.67 33.12 35.80 35.38 35.48 30.31 31.35 28.07 30.50 29.97 30.08 29.18 35.44 29.55 35.54 FeO 2.22 4.62 4.67 5.03 2.63 2.96 1.48 1.53 4.09 6.37 5.37 6.69 3.76 4.43 4.34 3.27 0.76 2.54 1.04 MnO 0.03 bdl 0.05 0.07 bdl 0.06 0.02 0.02 0.00 0.00 0.02 0.07 0.02 0.03 0.05 0.00 0.02 0.01 bdl MgO 0.95 1.12 1.07 1.64 2.25 2.01 1.03 1.08 0.02 1.04 1.24 2.23 2.10 1.45 1.59 2.44 1.32 2.02 0.90 CaO 0.01 0.00 0.07 0.01 bdl 0.01 0.03 0.01 0.01 0.00 0.02 0.02 0.01 0.00 0.01 0.02 0.01 0.01 0.03 Na 2 O 0.33 0.43 0.44 0.40 0.19 0.27 0.47 0.55 0.44 0.23 0.27 0.23 0.47 0.17 0.17 0.23 0.48 0.19 1.41 K 2 O 10.85 10.61 10.61 10.67 11.20 11.10 10.65 10.69 10.66 10.81 10.75 10.64 10.53 10.87 10.83 10.76 10.50 10.77 9.00 Cr 2 O 3 0.01 0.09 0.07 bdl 0.04 0.03 bdl 0.03 bdl 0.04 bdl 0.04 0.05 0.05 bdl 0.06 0.02 0.06 bdl NiO 0.08 0.02 0.01 bdl bdl bdl 0.02 bdl bdl bdl 0.01 bdl bdl bdl bdl 0.05 bdl bdl 0.00 Cl 0.02 0.03 0.02 0.01 0.01 0.02 0.02 0.02 0.01 0.01 0.01 0.00 0.01 0.01 bdl bdl 0.01 bdl 0.01 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 97.02 96.00 96.27 96.52 96.93 97.44 98.23 97.29 96.88 96.36 96.73 96.69 96.50 94.96 96.02 95.65 96.50 93.08 95.15 Si 3.127 3.107 3.080 3.152 3.201 3.144 3.105 3.088 3.064 3.156 3.166 3.224 3.214 3.232 3.258 3.267 3.094 3.267 3.087 Ti 0.046 0.032 0.034 0.065 0.023 0.005 0.029 0.034 0.001 0.051 0.024 0.054 0.040 0.022 0.019 0.047 0.034 0.018 0.026 Al 2.636 2.571 2.602 2.419 2.465 2.569 2.722 2.723 2.775 2.423 2.477 2.239 2.394 2.402 2.378 2.307 2.735 2.392 2.770 Fe 2+ 0.122 0.260 0.263 0.283 0.145 0.163 0.080 0.084 0.227 0.361 0.301 0.379 0.210 0.252 0.243 0.184 0.042 0.146 0.057 Mn 0.002 bdl 0.003 0.004 bdl 0.003 0.001 0.001 0.000 0.000 0.001 0.004 0.001 0.002 0.003 0.000 0.001 0.001 bdl Mg 0.093 0.113 0.107 0.164 0.222 0.197 0.099 0.105 0.002 0.106 0.124 0.225 0.209 0.147 0.159 0.244 0.128 0.207 0.089 Ca 0.001 0.000 0.005 0.001 bdl 0.001 0.002 0.001 0.000 0.000 0.001 0.001 0.001 0.000 0.001 0.001 0.001 0.001 0.002 Na 0.042 0.057 0.058 0.053 0.024 0.034 0.059 0.070 0.056 0.030 0.035 0.030 0.061 0.022 0.022 0.030 0.061 0.025 0.181 K 0.910 0.912 0.911 0.915 0.944 0.932 0.876 0.890 0.903 0.935 0.919 0.918 0.894 0.943 0.926 0.921 0.877 0.943 0.759 Cr 0.001 0.005 0.004 bdl 0.002 0.001 bdl 0.001 bdl 0.002 bdl 0.002 0.002 0.003 bdl 0.003 0.001 0.003 bdl Ni 0.005 0.001 0.000 bdl bdl bdl 0.001 bdl bdl bdl 0.000 bdl bdl bdl bdl 0.003 bdl bdl 0.000 Cl 0.002 0.003 0.003 0.002 0.001 0.002 0.002 0.002 0.001 0.001 0.001 0.000 0.001 0.002 bdl bdl 0.001 bdl 0.001 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 6.986 7.061 7.069 7.058 7.027 7.051 6.975 6.998 7.029 7.065 7.048 7.077 7.027 7.027 7.008 7.008 6.975 7.003 6.973 Na+K+Ca 0.953 0.969 0.973 0.969 0.968 0.967 0.937 0.960 0.960 0.965 0.955 0.949 0.955 0.966 0.949 0.953 0.939 0.969 0.942 Na/(Na+K) 0.044 0.059 0.059 0.054 0.025 0.035 0.063 0.073 0.058 0.031 0.036 0.031 0.063 0.023 0.023 0.032 0.065 0.026 0.193

Table DR 2. Continued Bowers Terrane [4] Sample 23 01 89RG4 6 7 9 10a 10b 11 12a 12b 13 14 15 16 17 18a 18b 19a 19b 20 core core core core rim core core rim core core core core core core rim core rim core SiO 2 46.41 48.13 49.00 49.17 47.48 47.13 45.63 45.66 46.72 47.53 47.94 49.58 46.64 46.15 45.91 46.56 46.27 46.60 TiO 2 0.95 1.08 1.37 1.42 0.84 0.71 1.50 1.44 0.08 0.27 0.67 0.34 0.65 0.84 0.85 0.33 0.48 0.56 Al 2 O 3 35.45 27.16 30.37 30.42 32.65 32.94 31.94 31.74 35.30 35.46 30.24 28.80 36.20 31.25 31.18 36.00 35.79 34.01 FeO 1.08 5.18 1.73 1.44 3.13 2.79 4.18 4.38 2.86 2.10 4.14 3.71 1.37 5.03 5.10 1.38 1.34 3.55 MnO bdl 0.01 0.02 0.02 0.00 bdl 0.01 0.02 0.11 0.05 0.02 0.05 0.06 0.03 bdl bdl 0.01 0.03 MgO 1.13 2.86 2.99 2.86 1.43 1.20 0.92 1.13 1.33 0.69 2.29 2.38 0.84 1.37 1.36 0.82 0.80 0.50 CaO 0.01 bdl 0.05 0.01 bdl bdl 0.01 bdl 0.03 0.05 0.00 0.04 0.02 0.01 0.05 bdl bdl 0.02 Na 2 O 0.53 0.21 0.34 0.29 0.52 0.55 0.42 0.36 0.31 0.46 0.31 0.18 0.63 0.34 0.31 0.42 0.39 0.48 K 2 O 10.43 10.92 10.52 10.75 10.30 10.54 10.54 10.55 10.30 10.61 10.37 10.89 10.28 10.60 10.48 10.72 10.80 10.53 Cr 2 O 3 0.01 bdl bdl 0.03 0.01 0.03 bdl 0.02 0.01 bdl bdl 0.01 0.02 0.05 0.02 bdl 0.04 bdl NiO 0.04 0.01 bdl bdl 0.04 0.00 bdl bdl 0.02 bdl 0.01 bdl bdl 0.04 bdl 0.07 bdl 0.03 Cl 0.01 0.01 0.00 bdl bdl bdl 0.01 0.00 0.01 0.02 0.02 0.01 0.01 0.01 0.00 0.01 bdl 0.01 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 96.05 95.57 96.40 96.42 96.41 95.90 95.15 95.31 97.08 97.24 96.01 95.99 96.72 95.71 95.26 96.31 95.93 96.33 Si 3.062 3.274 3.232 3.240 3.150 3.142 3.098 3.099 3.070 3.107 3.212 3.317 3.055 3.128 3.126 3.068 3.063 3.104 Ti 0.047 0.055 0.068 0.070 0.042 0.036 0.076 0.074 0.004 0.013 0.034 0.017 0.032 0.043 0.043 0.017 0.024 0.028 Al 2.757 2.178 2.361 2.363 2.553 2.588 2.556 2.539 2.734 2.733 2.388 2.270 2.795 2.497 2.502 2.796 2.792 2.670 Fe 2+ 0.060 0.295 0.095 0.079 0.174 0.156 0.238 0.248 0.157 0.115 0.232 0.208 0.075 0.285 0.290 0.076 0.074 0.198 Mn bdl 0.000 0.001 0.001 0.000 bdl 0.001 0.001 0.006 0.003 0.001 0.003 0.003 0.002 0.000 0.000 0.001 0.002 Mg 0.111 0.290 0.294 0.281 0.142 0.119 0.093 0.115 0.131 0.067 0.229 0.237 0.082 0.138 0.139 0.081 0.079 0.050 Ca 0.000 bdl 0.004 0.001 bdl bdl 0.001 bdl 0.002 0.003 0.000 0.003 0.002 0.001 0.003 bdl bdl 0.001 Na 0.068 0.028 0.043 0.038 0.067 0.071 0.055 0.048 0.039 0.058 0.041 0.023 0.080 0.045 0.041 0.053 0.050 0.063 K 0.878 0.948 0.885 0.903 0.872 0.897 0.913 0.914 0.864 0.885 0.887 0.930 0.859 0.916 0.910 0.901 0.912 0.895 Cr 0.001 bdl bdl 0.002 0.001 0.002 bdl 0.001 0.001 bdl bdl 0.000 0.001 0.002 0.001 bdl 0.002 bdl Ni 0.002 0.000 bdl bdl 0.002 0.000 bdl bdl 0.001 bdl 0.001 bdl bdl 0.002 bdl 0.004 bdl 0.002 Cl 0.001 0.002 0.000 bdl bdl bdl 0.001 0.001 0.001 0.002 0.002 0.002 0.001 0.001 0.000 0.002 bdl 0.001 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 6.987 7.071 6.984 6.978 7.002 7.011 7.032 7.038 7.009 6.987 7.026 7.010 6.985 7.060 7.055 6.997 6.997 7.013 Na+K+Ca 0.947 0.976 0.932 0.942 0.939 0.968 0.968 0.962 0.905 0.946 0.928 0.956 0.941 0.961 0.954 0.954 0.962 0.959 Na/(Na+K) 0.072 0.029 0.047 0.040 0.071 0.073 0.057 0.049 0.043 0.062 0.044 0.024 0.085 0.047 0.043 0.056 0.052 0.065

Table DR 1. Continued Robertson Bay Terrane [6] Sample 12 12 94GO9 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 core core core core core core core core core core core core core core core core core core core core SiO 2 48.49 47.77 45.66 45.93 47.57 46.95 48.86 48.24 47.57 49.00 47.18 47.72 47.10 45.90 45.23 46.37 46.77 46.58 47.05 45.97 TiO 2 0.59 0.62 0.10 0.06 0.60 0.35 0.24 0.31 0.86 0.36 0.44 1.04 0.98 0.55 0.22 0.63 0.95 0.35 0.37 0.81 Al 2 O 3 33.21 32.81 37.26 37.28 36.48 33.41 33.78 33.13 28.39 31.83 35.81 32.07 30.07 33.44 33.67 33.43 35.19 33.53 35.12 36.75 FeO 1.78 1.88 1.10 1.14 1.09 2.66 0.99 1.21 5.48 2.59 1.47 3.46 3.77 3.93 4.05 3.88 2.76 3.43 1.91 1.10 MnO 0.05 0.04 bdl bdl bdl 0.03 bdl bdl 0.03 0.05 bdl 0.01 0.04 0.08 0.03 0.03 0.04 0.04 bdl 0.00 MgO 1.95 1.93 0.29 0.35 0.76 1.26 1.90 1.87 1.95 1.90 0.88 1.37 1.84 1.29 0.63 0.88 0.81 0.68 0.76 0.36 CaO bdl bdl 0.03 0.01 0.02 0.02 bdl bdl 0.01 0.10 0.05 0.01 0.28 0.02 0.03 bdl 0.03 0.03 0.00 0.02 Na 2 O 0.37 0.42 0.55 0.51 1.02 0.59 0.31 0.21 0.15 0.84 1.22 0.40 0.30 0.58 0.42 0.34 1.17 0.47 0.48 0.60 K 2 O 10.87 10.80 10.45 10.47 9.87 10.16 9.44 9.55 10.65 9.46 9.33 10.72 10.67 10.40 10.76 10.94 9.71 10.58 10.78 10.37 Cr 2 O 3 0.06 0.00 bdl 0.05 0.02 0.00 0.03 0.01 0.05 0.03 0.07 bdl 0.04 0.09 bdl bdl 0.06 bdl 0.13 0.02 NiO bdl bdl 0.02 0.04 bdl bdl bdl 0.01 0.00 0.05 0.07 bdl 0.04 bdl 0.01 bdl bdl 0.06 0.01 bdl Cl 0.01 0.02 0.02 0.00 0.00 0.00 bdl bdl 0.04 0.00 0.03 0.02 0.01 bdl 0.02 0.01 0.00 bdl 0.02 0.01 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 97.38 96.30 95.48 95.84 97.43 95.44 95.55 94.54 95.19 96.20 96.55 96.81 95.15 96.27 95.07 96.51 97.49 95.76 96.63 96.01 Si 3.168 3.160 3.027 3.032 3.079 3.136 3.203 3.204 3.247 3.230 3.085 3.165 3.193 3.072 3.071 3.097 3.059 3.121 3.099 3.031 Ti 0.029 0.031 0.005 0.003 0.029 0.018 0.012 0.016 0.044 0.018 0.022 0.052 0.050 0.028 0.011 0.032 0.047 0.018 0.019 0.040 Al 2.557 2.558 2.911 2.901 2.784 2.630 2.609 2.593 2.284 2.473 2.761 2.506 2.403 2.638 2.695 2.632 2.713 2.648 2.727 2.856 Fe 2+ 0.097 0.104 0.061 0.063 0.059 0.148 0.054 0.067 0.313 0.143 0.080 0.192 0.214 0.220 0.230 0.217 0.151 0.192 0.105 0.061 Mn 0.003 0.002 bdl bdl bdl 0.002 bdl bdl 0.002 0.003 bdl 0.000 0.002 0.005 0.002 0.002 0.002 0.002 bdl bdl Mg 0.190 0.191 0.029 0.034 0.073 0.125 0.186 0.185 0.199 0.186 0.085 0.135 0.186 0.129 0.064 0.088 0.079 0.068 0.075 0.035 Ca bdl bdl 0.002 0.001 0.002 0.002 bdl bdl 0.001 0.007 0.004 0.001 0.020 0.001 0.003 bdl 0.002 0.002 bdl 0.002 Na 0.047 0.055 0.071 0.066 0.128 0.076 0.040 0.027 0.020 0.107 0.155 0.051 0.040 0.076 0.055 0.044 0.148 0.062 0.062 0.076 K 0.906 0.912 0.883 0.882 0.815 0.866 0.789 0.809 0.927 0.795 0.779 0.907 0.923 0.888 0.932 0.932 0.811 0.905 0.906 0.872 Cr 0.003 bdl bdl 0.002 0.001 bdl 0.002 0.001 0.003 0.002 0.004 bdl 0.002 0.005 bdl bdl 0.003 bdl 0.007 0.001 Ni bdl bdl 0.001 0.002 bdl bdl bdl 0.001 0.000 0.003 0.004 bdl 0.002 bdl 0.001 bdl bdl 0.003 0.000 bdl Cl 0.001 0.002 0.003 0.000 0.000 0.000 bdl bdl 0.005 0.000 0.003 0.002 0.002 bdl 0.002 0.001 0.000 bdl 0.002 0.001 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 7.001 7.015 6.992 6.987 6.970 7.003 6.895 6.901 7.044 6.966 6.981 7.012 7.038 7.060 7.065 7.044 7.016 7.021 7.001 6.975 Na+K+Ca 0.953 0.967 0.956 0.949 0.945 0.944 0.829 0.836 0.948 0.909 0.938 0.959 0.983 0.965 0.989 0.976 0.961 0.969 0.968 0.950 Na/(Na+K) 0.049 0.056 0.074 0.069 0.136 0.081 0.048 0.032 0.021 0.119 0.166 0.053 0.042 0.079 0.055 0.045 0.154 0.064 0.064 0.080

Table DR 1. Continued Robertson Bay Terrane [6] Sample 12 12 94GO9 [9] Sample 13 01 02CR6 21 22 23 24 25 1 2 3 4 6 7 10 11 12 13 14 15 16 17 core core core core core core core core core core core core core core core core core core core SiO 2 50.47 49.61 47.00 49.15 50.11 47.77 50.19 45.86 46.79 49.14 49.49 50.76 48.47 46.84 46.43 46.88 46.65 46.73 46.32 TiO 2 0.32 0.63 1.03 1.29 0.09 0.40 0.19 0.06 0.24 0.89 0.70 0.42 0.32 1.01 1.22 0.58 0.60 1.16 0.94 Al 2 O 3 27.62 32.55 33.83 26.46 26.57 33.28 27.37 35.85 30.65 30.86 30.50 25.91 29.06 30.29 30.54 35.27 35.04 28.82 34.00 FeO 3.91 2.46 2.58 4.08 4.95 1.71 4.22 1.50 3.94 0.80 1.11 3.18 3.31 4.01 4.06 0.94 1.35 4.79 1.18 MnO 0.00 0.04 0.02 0.05 0.03 0.00 0.03 0.03 0.03 0.02 0.01 bdl bdl bdl 0.03 0.02 0.01 0.02 0.01 MgO 2.83 1.67 1.06 2.84 3.42 1.37 2.26 0.71 2.83 3.58 3.54 3.44 2.91 1.58 1.64 0.81 1.11 1.95 1.86 CaO 0.02 0.02 0.01 1.04 0.04 0.07 bdl 0.02 0.01 0.01 0.00 bdl bdl bdl bdl 0.03 0.01 0.01 0.01 Na 2 O 0.07 0.38 0.47 0.09 0.06 0.80 0.29 0.43 0.32 0.33 0.30 0.13 0.12 0.17 0.21 1.10 1.08 0.28 0.47 K 2 O 10.88 10.64 10.71 10.19 10.38 9.87 10.48 10.51 9.73 10.72 10.57 10.81 10.71 10.79 10.74 9.54 9.49 10.77 10.14 Cr 2 O 3 0.04 0.06 bdl 0.04 0.06 0.02 0.02 0.07 bdl bdl 0.00 0.08 bdl 0.04 0.01 0.02 0.02 bdl 0.10 NiO bdl 0.03 0.01 bdl 0.06 0.02 0.02 bdl bdl bdl bdl bdl 0.02 0.04 0.03 0.05 0.08 bdl 0.00 Cl 0.01 0.01 bdl 0.00 0.01 0.01 0.02 0.00 0.01 0.01 0.01 0.02 0.01 bdl bdl 0.01 0.01 0.00 0.01 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 96.16 98.09 96.73 95.24 95.79 95.31 95.09 95.04 94.54 96.37 96.23 94.75 94.94 94.76 94.91 95.25 95.45 94.52 95.03 Si 3.369 3.218 3.107 3.328 3.373 3.173 3.387 3.062 3.174 3.230 3.256 3.428 3.273 3.189 3.160 3.102 3.089 3.208 3.088 Ti 0.016 0.031 0.051 0.066 0.005 0.020 0.010 0.003 0.012 0.044 0.035 0.021 0.016 0.052 0.063 0.029 0.030 0.060 0.047 Al 2.173 2.489 2.635 2.112 2.108 2.605 2.177 2.821 2.450 2.390 2.365 2.063 2.313 2.431 2.450 2.751 2.735 2.332 2.672 Fe 2+ 0.218 0.133 0.143 0.231 0.279 0.095 0.238 0.084 0.223 0.044 0.061 0.179 0.187 0.228 0.231 0.052 0.075 0.275 0.066 Mn bdl 0.002 0.001 0.003 0.002 bdl 0.002 0.002 0.002 0.001 0.001 bdl bdl bdl 0.002 0.001 0.000 0.001 0.001 Mg 0.281 0.162 0.105 0.287 0.343 0.135 0.228 0.071 0.286 0.350 0.347 0.346 0.293 0.160 0.167 0.080 0.110 0.200 0.185 Ca 0.001 0.001 0.001 0.076 0.003 0.005 bdl 0.002 0.001 0.001 0.000 bdl bdl bdl bdl 0.002 0.001 0.001 0.000 Na 0.009 0.047 0.061 0.012 0.008 0.103 0.038 0.055 0.042 0.042 0.038 0.017 0.016 0.022 0.028 0.142 0.138 0.037 0.061 K 0.927 0.881 0.903 0.880 0.891 0.836 0.902 0.895 0.842 0.899 0.887 0.931 0.923 0.937 0.932 0.806 0.801 0.943 0.862 Cr 0.002 0.003 bdl 0.002 0.003 0.001 0.001 0.004 bdl bdl 0.000 0.004 bdl 0.002 0.000 0.001 0.001 bdl 0.005 Ni bdl 0.001 0.001 bdl 0.003 0.001 0.001 bdl bdl bdl bdl bdl 0.001 0.002 0.002 0.003 0.004 bdl bdl Cl 0.001 0.001 bdl 0.001 0.001 0.001 0.002 0.001 0.001 0.002 0.001 0.002 0.001 bdl bdl 0.001 0.002 0.000 0.001 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 6.997 6.970 7.007 6.997 7.019 6.975 6.986 6.999 7.032 7.003 6.991 6.992 7.024 7.023 7.034 6.969 6.986 7.057 6.988 Na+K+Ca 0.937 0.929 0.965 0.967 0.902 0.943 0.940 0.952 0.884 0.942 0.925 0.948 0.939 0.959 0.960 0.950 0.940 0.980 0.923 Na/(Na+K) 0.009 0.051 0.063 0.013 0.009 0.109 0.041 0.058 0.047 0.045 0.041 0.018 0.017 0.023 0.029 0.149 0.147 0.037 0.066

Table DR 1. Continued Robertson Bay Terrane [9] Sample 13 01 02CR6 [10] Sample 01 02 02CR2 18 19 21 22 23 24 1 2 3a 3b 4 5 6 7 8 9 10 11 12 core core core core core core rim core core rim core core core core core core core core core SiO 2 48.31 47.09 46.60 47.14 46.58 45.87 46.59 46.32 47.56 47.24 48.79 47.37 47.71 50.06 49.43 51.27 47.83 48.18 46.59 TiO 2 0.34 0.54 0.82 1.06 0.89 0.93 0.71 0.72 0.29 0.26 0.42 0.73 0.53 0.43 0.30 0.43 0.21 0.60 0.38 Al 2 O 3 30.02 33.04 36.42 31.16 34.11 27.63 34.84 34.29 35.10 35.18 31.22 35.18 36.10 29.97 31.06 28.01 34.89 31.56 35.02 FeO 3.65 2.37 0.67 2.42 1.81 6.18 2.56 3.13 1.67 1.58 2.30 1.37 1.19 3.14 2.48 2.63 1.61 2.75 2.25 MnO 0.01 bdl 0.01 0.04 0.05 0.06 bdl 0.03 0.03 0.00 bdl 0.04 0.04 bdl 0.04 bdl bdl 0.02 bdl MgO 2.05 1.48 0.79 1.77 1.30 3.65 0.83 0.60 0.88 0.94 2.02 1.07 1.00 2.48 2.06 3.22 1.08 2.06 0.92 CaO bdl bdl 0.01 bdl bdl bdl bdl 0.01 0.01 0.00 0.01 0.00 0.01 bdl bdl bdl 0.01 0.00 bdl Na 2 O 0.23 0.34 0.49 0.36 0.37 0.22 0.47 0.59 0.77 0.60 0.76 0.38 0.31 0.44 0.44 0.18 1.08 0.28 0.34 K 2 O 10.80 10.53 10.71 10.79 10.67 9.74 10.59 10.39 10.20 10.40 9.86 11.10 11.00 10.19 10.46 10.35 9.59 10.57 11.11 Cr 2 O 3 0.02 0.07 0.06 0.03 bdl 0.04 bdl bdl 0.06 bdl 0.05 0.07 0.00 0.04 0.04 0.01 0.03 0.07 0.02 NiO bdl bdl bdl bdl 0.03 0.02 0.04 bdl bdl bdl bdl bdl 0.02 bdl bdl 0.05 0.10 0.04 bdl Cl 0.01 0.01 0.02 0.01 0.02 0.04 0.02 0.01 0.01 bdl bdl 0.01 0.01 0.00 0.02 0.01 bdl 0.02 bdl F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 95.43 95.47 96.60 94.78 95.84 94.37 96.65 96.09 96.59 96.21 95.43 97.32 97.93 96.75 96.32 96.16 96.42 96.14 96.63 Si 3.251 3.145 3.052 3.183 3.096 3.171 3.079 3.086 3.119 3.111 3.244 3.095 3.089 3.296 3.265 3.386 3.134 3.201 3.081 Ti 0.017 0.027 0.041 0.054 0.045 0.048 0.035 0.036 0.014 0.013 0.021 0.036 0.026 0.021 0.015 0.021 0.010 0.030 0.019 Al 2.381 2.600 2.811 2.480 2.672 2.251 2.713 2.693 2.714 2.731 2.447 2.710 2.754 2.326 2.418 2.181 2.694 2.471 2.729 Fe 2+ 0.205 0.133 0.037 0.136 0.100 0.357 0.141 0.174 0.092 0.087 0.128 0.075 0.065 0.173 0.137 0.145 0.088 0.153 0.124 Mn 0.001 bdl 0.001 0.003 0.003 0.004 bdl 0.002 0.002 0.000 bdl 0.002 0.002 bdl 0.002 bdl bdl 0.001 bdl Mg 0.205 0.147 0.077 0.178 0.129 0.376 0.081 0.060 0.087 0.092 0.200 0.104 0.097 0.244 0.203 0.317 0.106 0.204 0.091 Ca bdl bdl 0.001 bdl bdl bdl bdl 0.001 0.001 0.000 0.001 0.000 0.001 bdl bdl bdl 0.001 0.000 bdl Na 0.030 0.044 0.062 0.047 0.048 0.029 0.061 0.077 0.098 0.076 0.098 0.049 0.039 0.056 0.056 0.023 0.137 0.036 0.044 K 0.927 0.897 0.895 0.929 0.905 0.859 0.893 0.883 0.854 0.874 0.837 0.926 0.908 0.856 0.882 0.872 0.802 0.896 0.937 Cr 0.001 0.004 0.003 0.002 bdl 0.002 bdl bdl 0.003 bdl 0.002 0.004 0.000 0.002 0.002 0.000 0.002 0.004 0.001 Ni bdl bdl bdl bdl 0.002 0.001 0.002 bdl bdl bdl bdl bdl 0.001 bdl bdl 0.003 0.005 0.002 bdl Cl 0.001 0.001 0.002 0.001 0.002 0.004 0.002 0.001 0.001 bdl bdl 0.001 0.001 0.000 0.002 0.001 bdl 0.002 bdl F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 7.018 6.998 6.981 7.012 7.001 7.102 7.007 7.012 6.984 6.985 6.978 7.002 6.983 6.975 6.982 6.950 6.978 7.000 7.026 Na+K+Ca 0.957 0.941 0.958 0.976 0.953 0.888 0.954 0.960 0.953 0.950 0.935 0.975 0.948 0.912 0.938 0.895 0.939 0.932 0.981 Na/(Na+K) 0.031 0.047 0.064 0.048 0.050 0.033 0.064 0.080 0.103 0.080 0.104 0.050 0.041 0.062 0.059 0.026 0.146 0.039 0.044

Table DR 1. Continued Robertson Bay Terrane [10] Sample 01 02 02CR2 [8] Sample 27 01 02CR2 13 14 15 16 17 18 19 20 21 1 2 3 4a 4b 5a 5b 6 7a 7b beam size 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm core core core core core core core core core core core core core rim core rim core core rim SiO 2 47.17 48.65 47.76 47.94 45.85 48.66 47.64 47.01 49.66 48.86 46.39 46.88 45.47 45.74 49.96 48.90 47.23 46.58 46.48 TiO 2 0.57 0.93 1.10 0.83 1.21 0.50 0.22 0.78 0.38 0.21 1.31 1.53 0.35 0.30 0.38 0.27 1.14 0.78 0.80 Al 2 O 3 33.19 30.35 34.72 35.28 34.67 32.77 36.55 34.34 29.20 26.87 27.38 27.51 33.34 33.24 26.50 27.30 26.81 30.60 29.30 FeO 3.27 3.52 1.53 1.27 2.31 2.14 1.30 1.54 3.07 3.32 5.10 4.57 2.69 2.75 2.87 2.98 4.20 4.17 4.31 MnO 0.01 0.02 0.00 0.05 bdl 0.04 0.01 0.02 0.01 0.04 0.04 bdl 0.02 bdl 0.04 0.07 0.02 0.08 0.02 MgO 1.43 1.68 1.31 1.31 0.62 1.64 0.64 1.07 2.58 3.27 2.93 2.78 0.89 0.86 3.24 2.85 3.01 1.20 1.98 CaO bdl bdl 0.01 0.02 0.00 bdl bdl 0.02 bdl bdl 0.01 bdl 0.02 0.04 0.02 0.04 0.03 0.01 0.02 Na 2 O 0.36 0.35 0.43 0.97 0.62 0.49 0.96 0.25 0.23 0.09 0.15 0.14 0.39 0.37 0.07 0.11 0.19 0.48 0.18 K 2 O 10.71 10.84 10.63 10.00 10.49 10.46 9.95 11.01 10.60 11.02 10.62 11.00 10.65 10.77 10.77 10.74 10.95 10.55 10.81 Cr 2 O 3 0.03 0.00 0.05 0.04 0.06 bdl bdl 0.13 0.04 bdl 0.04 bdl bdl bdl 0.02 0.05 0.04 0.04 bdl NiO bdl bdl 0.00 bdl 0.01 0.02 bdl 0.00 0.01 0.11 0.04 0.04 0.03 bdl 0.03 bdl bdl 0.01 0.02 Cl 0.00 0.01 0.02 0.02 0.01 0.00 bdl 0.00 0.00 bdl 0.01 0.01 bdl bdl 0.01 0.00 0.01 0.00 0.01 F nd nd nd nd nd nd nd nd nd bdl bdl bdl bdl bdl 0.01 bdl bdl bdl bdl Total 96.74 96.35 97.57 97.72 95.85 96.72 97.27 96.17 95.78 93.79 94.03 94.46 93.85 94.08 93.92 93.31 93.61 94.51 93.92 Si 3.126 3.242 3.107 3.103 3.056 3.197 3.091 3.111 3.311 3.350 3.212 3.226 3.102 3.114 3.400 3.355 3.271 3.182 3.202 Ti 0.028 0.047 0.054 0.040 0.061 0.025 0.011 0.039 0.019 0.011 0.068 0.079 0.018 0.016 0.019 0.014 0.059 0.040 0.042 Al 2.593 2.384 2.662 2.691 2.724 2.538 2.795 2.678 2.295 2.172 2.235 2.231 2.681 2.668 2.126 2.208 2.189 2.464 2.380 Fe 2+ 0.181 0.196 0.083 0.069 0.128 0.118 0.071 0.085 0.171 0.190 0.296 0.263 0.154 0.156 0.163 0.171 0.243 0.238 0.248 Mn 0.001 0.001 0.000 0.003 bdl 0.002 0.001 0.001 0.001 0.002 0.003 bdl 0.001 bdl 0.002 0.004 0.001 0.005 0.001 Mg 0.142 0.167 0.127 0.127 0.062 0.161 0.062 0.106 0.256 0.335 0.303 0.285 0.091 0.088 0.329 0.292 0.311 0.122 0.203 Ca bdl bdl 0.001 0.001 0.000 bdl bdl 0.001 bdl bdl 0.001 bdl 0.001 0.003 0.002 0.003 0.002 0.001 0.002 Na 0.046 0.045 0.054 0.122 0.080 0.062 0.121 0.032 0.029 0.012 0.020 0.019 0.052 0.048 0.009 0.014 0.026 0.064 0.024 K 0.906 0.921 0.882 0.826 0.892 0.876 0.823 0.929 0.901 0.965 0.939 0.966 0.927 0.936 0.935 0.940 0.968 0.920 0.950 Cr 0.001 0.000 0.003 0.002 0.003 bdl bdl 0.007 0.002 bdl 0.002 bdl bdl bdl 0.001 0.003 0.002 0.002 bdl Ni bdl bdl 0.000 bdl 0.001 0.001 bdl 0.000 0.001 0.006 0.002 0.002 0.002 bdl 0.002 bdl bdl 0.000 0.001 Cl 0.001 0.002 0.002 0.002 0.001 0.000 bdl 0.000 0.000 bdl 0.001 0.001 bdl bdl 0.001 0.000 0.001 0.000 0.002 F nd nd nd nd nd nd nd nd nd bdl bdl bdl bdl bdl 0.002 bdl bdl bdl bdl Total 7.025 7.004 6.975 6.986 7.007 6.980 6.974 6.989 6.986 7.042 7.081 7.073 7.029 7.028 6.992 7.004 7.072 7.037 7.055 Na+K+Ca 0.952 0.966 0.937 0.949 0.972 0.938 0.944 0.962 0.930 0.976 0.960 0.985 0.980 0.988 0.946 0.958 0.996 0.985 0.976 Na/(Na+K) 0.048 0.046 0.058 0.129 0.082 0.066 0.128 0.033 0.031 0.012 0.020 0.020 0.053 0.049 0.010 0.015 0.026 0.065 0.025

Table DR 2. Continued Robertson Bay Terrane [8] Sample 27 01 02CR2 8a 8b 9a 9b 10a 10b 11a 11b 12 13a 13b 14a 14b 15a 15b 16a 16b 17a 17b 18a core rim core rim core rim core rim core core rim core rim core rim core rim core rim core SiO 2 44.88 45.08 44.98 45.53 47.20 46.81 45.03 46.11 48.65 47.97 47.75 47.18 47.71 46.10 45.48 45.23 46.34 46.32 46.47 45.37 TiO 2 0.99 1.06 0.36 0.44 0.54 0.56 1.12 0.63 0.33 0.25 0.30 0.54 0.42 0.32 0.17 1.05 1.17 1.02 1.09 0.76 Al 2 O 3 33.77 34.12 33.17 32.60 31.36 31.10 34.81 34.37 25.44 27.70 28.62 25.53 25.13 33.46 34.79 27.96 28.16 28.14 27.88 32.71 FeO 1.91 1.83 3.22 2.41 1.75 1.65 1.11 1.40 4.48 3.55 3.82 5.19 5.01 1.82 1.70 6.30 6.15 5.87 5.91 2.73 MnO bdl 0.04 0.00 0.02 bdl 0.05 bdl 0.04 0.02 0.04 0.05 0.04 0.09 bdl 0.01 0.09 0.07 0.13 0.04 0.01 MgO 0.85 0.83 0.91 0.96 1.68 1.76 0.57 0.88 3.19 2.77 2.44 2.98 2.87 0.84 0.59 2.06 2.12 2.16 2.09 0.90 CaO 0.01 0.00 bdl 0.02 0.03 0.03 bdl 0.02 bdl 0.02 0.00 0.01 bdl 0.00 0.01 0.04 0.02 0.00 0.02 0.01 Na 2 O 0.75 0.70 0.45 0.44 0.92 0.84 0.88 0.84 0.14 0.18 0.20 0.14 0.13 0.40 0.43 0.31 0.22 0.27 0.23 0.50 K 2 O 10.25 10.30 10.37 10.62 9.50 9.78 10.08 10.13 10.88 10.96 10.95 10.95 10.95 10.41 10.53 10.57 10.68 10.86 10.60 10.53 Cr 2 O 3 0.03 0.05 bdl 0.03 0.05 0.02 0.00 0.06 0.02 bdl bdl 0.02 0.04 0.04 bdl bdl bdl bdl bdl 0.03 NiO bdl bdl bdl bdl bdl bdl 0.01 bdl 0.02 0.05 0.05 bdl 0.06 0.00 bdl 0.00 bdl 0.05 0.00 bdl Cl 0.01 bdl bdl 0.01 0.03 0.02 0.00 0.01 0.01 0.01 bdl 0.01 0.01 0.01 bdl bdl 0.00 0.01 0.02 bdl F bdl bdl bdl bdl bdl bdl bdl bdl 0.01 bdl bdl bdl bdl bdl bdl bdl bdl bdl bdl bdl Total 93.45 94.01 93.46 93.09 93.07 92.61 93.62 94.47 93.21 93.49 94.19 92.56 92.41 93.39 93.72 93.60 94.94 94.81 94.35 93.53 Si 3.064 3.057 3.087 3.128 3.211 3.206 3.050 3.096 3.378 3.305 3.270 3.321 3.359 3.136 3.085 3.170 3.193 3.197 3.215 3.108 Ti 0.051 0.054 0.019 0.023 0.028 0.029 0.057 0.032 0.017 0.013 0.016 0.028 0.022 0.016 0.009 0.055 0.060 0.053 0.057 0.039 Al 2.718 2.727 2.684 2.640 2.515 2.511 2.780 2.720 2.082 2.249 2.310 2.118 2.086 2.683 2.781 2.309 2.287 2.289 2.274 2.641 Fe 2+ 0.109 0.104 0.185 0.139 0.100 0.095 0.063 0.079 0.260 0.205 0.219 0.305 0.295 0.103 0.097 0.369 0.355 0.339 0.342 0.156 Mn bdl 0.003 0.000 0.001 bdl 0.003 bdl 0.002 0.002 0.002 0.003 0.002 0.005 bdl 0.001 0.005 0.004 0.007 0.003 0.000 Mg 0.087 0.084 0.093 0.099 0.171 0.180 0.058 0.088 0.330 0.284 0.249 0.313 0.302 0.085 0.060 0.215 0.217 0.222 0.216 0.092 Ca 0.000 0.000 bdl 0.002 0.003 0.002 bdl 0.001 bdl 0.001 0.000 0.001 bdl 0.000 0.001 0.003 0.001 0.000 0.001 0.001 Na 0.099 0.092 0.060 0.058 0.121 0.111 0.116 0.110 0.019 0.024 0.027 0.019 0.017 0.052 0.056 0.042 0.030 0.037 0.031 0.066 K 0.893 0.891 0.908 0.931 0.825 0.855 0.871 0.868 0.964 0.964 0.956 0.983 0.983 0.903 0.911 0.945 0.939 0.956 0.936 0.920 Cr 0.002 0.003 bdl 0.002 0.003 0.001 0.000 0.003 0.001 bdl bdl 0.001 0.002 0.002 bdl bdl bdl bdl bdl 0.001 Ni bdl bdl bdl bdl bdl bdl 0.001 bdl 0.001 0.003 0.003 bdl 0.004 0.000 bdl 0.000 bdl 0.003 0.000 bdl Cl 0.001 bdl bdl 0.001 0.003 0.002 0.000 0.001 0.001 0.001 bdl 0.002 0.002 0.001 bdl 0.000 bdl 0.001 0.002 bdl F bdl bdl bdl bdl bdl bdl bdl bdl 0.002 bdl bdl bdl bdl bdl bdl bdl bdl bdl bdl bdl Total 7.022 7.015 7.036 7.024 6.978 6.994 6.996 7.000 7.058 7.052 7.052 7.093 7.077 6.984 7.000 7.114 7.087 7.104 7.076 7.025 Na+K+Ca 0.993 0.983 0.968 0.991 0.949 0.968 0.987 0.979 0.983 0.989 0.983 1.002 1.000 0.956 0.968 0.990 0.970 0.993 0.968 0.986 Na/(Na+K) 0.100 0.093 0.062 0.059 0.128 0.115 0.118 0.112 0.020 0.024 0.027 0.018 0.017 0.055 0.058 0.043 0.031 0.037 0.032 0.067 Table DR 2. Continued

Robertson Bay Unit [8] Sample 27 01 02CR2 [5] Sample 12 12 94GO6 18b 19a 19b 1 2 3 4 5 6 7 8 10 11 12 13 14 15 16 17 rim core rim core core core core core core core core core core core core core core core core SiO 2 45.25 44.00 45.03 47.96 46.17 48.39 46.88 47.21 47.26 46.76 47.52 46.96 47.29 50.22 50.06 46.79 50.17 46.81 47.44 TiO 2 0.69 0.74 0.14 0.87 0.47 0.43 0.29 0.16 0.80 1.12 0.98 1.17 0.89 0.40 0.39 0.26 0.86 0.30 0.00 Al 2 O 3 33.41 31.71 31.79 31.08 34.90 32.06 36.09 35.51 35.85 32.87 32.73 32.95 33.37 29.39 30.18 36.19 27.52 34.69 36.66 FeO 3.01 3.91 3.70 2.82 3.20 3.17 1.77 1.93 1.36 2.36 2.34 2.32 2.31 2.39 2.38 1.68 4.71 2.73 1.32 MnO 0.06 0.03 bdl 0.04 0.01 bdl 0.04 0.04 0.01 bdl bdl 0.02 bdl 0.06 bdl 0.03 0.01 bdl 0.01 MgO 0.75 1.67 1.34 1.86 0.79 1.27 0.50 0.70 0.75 1.20 1.35 1.29 1.35 2.87 2.87 0.65 2.32 0.82 0.76 CaO bdl 0.04 0.02 bdl 0.00 bdl bdl bdl 0.01 0.02 0.01 0.02 0.00 0.01 0.01 0.00 bdl 0.01 0.01 Na 2 O 0.68 0.34 0.28 0.27 0.95 0.72 0.39 0.36 1.10 0.42 0.33 0.50 0.42 0.26 0.39 0.60 0.10 1.29 0.48 K 2 O 10.25 10.39 10.53 11.03 9.88 9.90 10.78 10.96 9.86 10.71 10.73 10.67 10.89 10.72 10.58 10.54 11.06 9.40 10.70 Cr 2 O 3 0.01 bdl bdl 0.04 0.03 bdl bdl bdl bdl bdl 0.00 0.07 0.06 0.05 0.03 0.01 bdl 0.01 0.09 NiO bdl bdl bdl 0.03 bdl 0.06 bdl 0.01 0.01 bdl bdl bdl bdl bdl 0.12 0.06 bdl 0.05 0.05 Cl 0.00 0.04 0.01 0.00 0.00 0.01 0.01 0.01 0.00 0.01 0.00 0.01 0.00 0.00 0.00 0.00 0.00 0.00 0.01 F bdl bdl bdl nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 94.12 92.86 92.83 96.00 96.40 96.01 96.76 96.90 97.01 95.47 95.99 95.99 96.58 96.36 97.01 96.82 96.76 96.11 97.53 Si 3.082 3.064 3.124 3.203 3.062 3.212 3.078 3.100 3.081 3.130 3.158 3.126 3.128 3.318 3.286 3.069 3.348 3.098 3.081 Ti 0.035 0.039 0.007 0.044 0.024 0.022 0.014 0.008 0.039 0.056 0.049 0.059 0.044 0.020 0.019 0.013 0.043 0.015 0.000 Al 2.682 2.603 2.599 2.447 2.728 2.508 2.793 2.749 2.754 2.593 2.564 2.586 2.602 2.289 2.335 2.798 2.164 2.706 2.806 Fe 2+ 0.172 0.228 0.215 0.157 0.178 0.176 0.097 0.106 0.074 0.132 0.130 0.129 0.128 0.132 0.131 0.092 0.263 0.151 0.072 Mn 0.003 0.002 bdl 0.003 0.000 bdl 0.002 0.002 0.001 bdl bdl 0.001 bdl 0.003 bdl 0.002 0.001 bdl 0.001 Mg 0.076 0.174 0.138 0.185 0.078 0.126 0.049 0.069 0.073 0.120 0.133 0.129 0.133 0.283 0.281 0.064 0.231 0.081 0.073 Ca bdl 0.003 0.001 bdl 0.000 bdl bdl bdl 0.001 0.001 0.001 0.002 0.000 0.001 0.001 0.000 bdl 0.001 0.001 Na 0.090 0.045 0.037 0.034 0.122 0.092 0.050 0.046 0.139 0.055 0.043 0.064 0.054 0.034 0.049 0.077 0.014 0.165 0.060 K 0.891 0.923 0.932 0.939 0.836 0.838 0.903 0.918 0.820 0.914 0.909 0.907 0.919 0.904 0.886 0.882 0.941 0.794 0.886 Cr 0.001 bdl bdl 0.002 0.002 bdl bdl bdl bdl bdl 0.000 0.004 0.003 0.002 0.002 0.001 bdl 0.001 0.005 Ni bdl bdl bdl 0.002 0.000 0.003 0.000 0.001 0.001 bdl bdl bdl bdl bdl 0.007 0.003 bdl 0.003 0.003 Cl 0.000 0.004 0.001 0.000 0.001 0.001 0.001 0.001 0.000 0.001 0.000 0.001 0.000 0.000 0.001 0.000 0.000 0.000 0.001 F bdl bdl bdl nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 7.032 7.084 7.055 7.015 7.030 6.978 6.988 7.000 6.982 7.002 6.987 7.007 7.012 6.986 6.997 7.000 7.005 7.014 6.989 Na+K+Ca 0.981 0.971 0.971 0.973 0.958 0.930 0.953 0.964 0.960 0.970 0.952 0.973 0.973 0.938 0.936 0.959 0.955 0.960 0.947 Na/(Na+K) 0.092 0.047 0.038 0.035 0.127 0.099 0.052 0.048 0.145 0.057 0.045 0.066 0.055 0.036 0.053 0.080 0.014 0.172 0.064

[5] Sample 12 12 94GO6 Table DR 2. Continued Robertson Bay Terrane [11] Sample 10 01 02CR3 13 14 15 16 17 18 19 20 1 2 3 4 5 6 7 8 9 10 11 core core core core core core core core core core core core core core core core core core core SiO 2 49.04 47.20 50.20 47.11 50.25 47.16 47.54 49.61 50.88 52.08 48.15 48.12 49.86 51.17 49.31 47.95 47.05 47.25 47.67 TiO 2 0.50 0.65 0.78 0.72 0.27 0.75 1.00 0.71 0.43 0.33 0.86 0.80 0.41 0.36 0.39 0.81 0.25 0.29 0.22 Al 2 O 3 32.06 34.04 30.85 35.83 29.83 33.29 32.08 26.59 26.92 27.31 31.53 31.33 27.75 27.84 28.40 31.39 36.21 36.35 34.28 FeO 1.74 2.59 0.47 1.36 3.45 2.90 4.89 4.63 2.15 3.37 2.71 2.34 3.31 3.14 3.75 3.13 1.29 1.16 1.63 MnO 0.00 bdl 0.01 0.02 0.05 0.03 bdl 0.05 0.00 0.01 0.03 bdl 0.01 bdl 0.00 bdl 0.05 0.09 0.04 MgO 1.92 1.10 3.37 0.73 2.41 0.96 1.54 3.88 3.91 3.27 1.88 1.76 2.83 2.93 2.77 1.75 0.60 0.48 1.12 CaO 0.01 0.03 bdl 0.01 0.01 bdl bdl 0.03 0.02 0.01 0.01 0.03 0.04 0.04 0.02 bdl 0.02 0.01 bdl Na 2 O 0.36 0.66 0.14 0.76 0.32 0.26 0.26 0.11 0.20 0.17 0.42 0.41 0.09 0.08 0.17 0.30 0.40 0.49 0.57 K 2 O 10.71 10.31 11.40 10.49 10.77 11.06 11.00 10.93 10.22 10.69 10.84 10.80 10.68 10.79 10.73 10.96 11.00 10.74 10.57 Cr 2 O 3 bdl 0.06 0.07 bdl bdl 0.01 bdl bdl 0.01 0.00 0.04 0.01 0.12 0.08 0.01 0.01 bdl bdl 0.01 NiO 0.02 bdl 0.02 bdl 0.01 0.03 0.09 bdl bdl bdl 0.05 0.08 bdl bdl bdl bdl 0.07 0.08 bdl Cl 0.01 0.02 0.00 0.01 0.01 0.01 0.00 0.01 bdl 0.02 0.01 0.01 0.00 0.01 0.01 0.01 0.01 0.02 bdl F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 96.39 96.66 97.31 97.04 97.38 96.45 98.40 96.54 94.76 97.27 96.53 95.69 95.10 96.44 95.57 96.32 96.96 96.97 96.12 Si 3.229 3.115 3.266 3.079 3.303 3.134 3.131 3.325 3.404 3.417 3.193 3.212 3.355 3.386 3.313 3.194 3.080 3.087 3.146 Ti 0.025 0.032 0.038 0.035 0.013 0.038 0.049 0.036 0.022 0.016 0.043 0.040 0.021 0.018 0.020 0.041 0.012 0.014 0.011 Al 2.489 2.648 2.366 2.760 2.311 2.608 2.490 2.101 2.123 2.112 2.465 2.465 2.201 2.172 2.249 2.464 2.795 2.799 2.667 Fe 2+ 0.096 0.143 0.026 0.074 0.190 0.161 0.269 0.259 0.121 0.185 0.150 0.131 0.186 0.174 0.211 0.175 0.071 0.064 0.090 Mn 0.000 bdl 0.001 0.001 0.003 0.001 bdl 0.003 0.000 0.001 0.002 bdl 0.000 bdl 0.000 bdl 0.003 0.005 0.002 Mg 0.188 0.108 0.327 0.071 0.236 0.095 0.152 0.388 0.390 0.320 0.186 0.175 0.284 0.289 0.277 0.174 0.059 0.047 0.110 Ca 0.001 0.002 bdl 0.001 0.001 bdl bdl 0.002 0.001 0.001 0.001 0.002 0.003 0.003 0.002 bdl 0.002 0.001 bdl Na 0.047 0.085 0.018 0.096 0.041 0.033 0.033 0.015 0.027 0.022 0.054 0.053 0.011 0.011 0.022 0.039 0.051 0.062 0.073 K 0.900 0.868 0.947 0.875 0.903 0.938 0.924 0.934 0.873 0.895 0.917 0.920 0.917 0.911 0.920 0.931 0.918 0.895 0.890 Cr bdl 0.003 0.003 bdl bdl 0.000 bdl bdl 0.001 0.000 0.002 0.001 0.006 0.004 0.001 0.001 bdl bdl 0.001 Ni 0.001 bdl 0.001 0.000 0.001 0.002 0.005 bdl bdl bdl 0.003 0.005 bdl bdl bdl bdl 0.004 0.004 bdl Cl 0.001 0.002 0.000 0.001 0.001 0.001 0.000 0.001 0.000 0.002 0.001 0.002 0.000 0.001 0.001 0.002 0.001 0.002 0.000 F nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd Total 6.977 7.006 6.993 6.993 7.003 7.011 7.053 7.063 6.962 6.971 7.016 7.004 6.985 6.968 7.016 7.020 6.995 6.980 6.991 Na+K+Ca 0.948 0.955 0.965 0.972 0.945 0.971 0.957 0.951 0.901 0.918 0.972 0.975 0.931 0.924 0.944 0.970 0.970 0.958 0.963 Na/(Na+K) 0.049 0.089 0.019 0.099 0.043 0.034 0.034 0.016 0.030 0.024 0.056 0.054 0.012 0.012 0.024 0.040 0.052 0.065 0.076