S5P HCHO Product Verification Using the IUP-UB Verification Algorithm

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Institute of Environmental Physics and Remote Sensing IUP/IFE-UB Department 1 Physics/Electrical Engineering S5P HCHO Product Verification Using the IUP-UB Verification Algorithm S5p Second Products Release Workshop September 28, 2018 Kezia Lange, Andreas Richter, Leonardo Alvarado, Kai-Uwe Eichmann and John P. Burrows Institute of Environmental Physics and Institute of Remote Sensing University of Bremen

Executive Summary S5P V1.1 HCHO Slant Columns are in good shape* *but perfect they are not 2

Approach to Verification Some self-consistency checks of S5P HCHO products Comparison of S5P OFFL HCHO slant columns with IUP-UB S5P results Comparison of S5P OFFL HCHO vertical columns with IUP-UB S5P results 3

Details of Verification (read later) IUP-UB HCHO fitting for S5P: 323.5 361 nm NO 2, 2xO 3, 2xO 3 Pukite, O 4, BrO, HCHO, Ring, linear offset Linearised DOAS fit, polynomial degree 5 Daily Pacific radiance background Reference sector correction Adding of model SC over reference region OMI LER AMF based on daily TM4-ECPL model run for 2017 (!) No cloud correction, just screening 4

HCHO coverage NRTI OFFL HCHO OFFL data have systematic gaps over the Pacific HCHO NRTI have less gaps IUP-UB product based on OFFL lv1 data has even more data IUP-UB 5

HCHO QA-value QA value should be low over snow and ice but is high over Greenland Not all clear cloud patterns appear to be flagged by low QA value There is a funny pattern of QA values getting good again at SZA > 75 6

HCHO cloud top dependence There is a clear dependence of HCHO tropospheric vertical columns on cloud top pressure The effect is much reduced but not removed if only data with QA > 0.75 are used The remaining effect appears to come from the SC as it shows a similar pattern as the quality assured VC 7

Content of lv2 HCHO files Variable time_utc is empty Attribute time_coverage_start is missing Z at the end Attribute time_coverage_end is missing Z at the end Attribute time_reference is missing Z at the end Values of attributes should be homogenized between products: processing_status = Nominal product_version = 1.1 references = https://atmos.eoc.dlr.de/tropomi title = TROPOMI/S5P Tropospheric Formaldehyde HCHO HCHO processing_status = OFFL-processing nominal product product_version = 1.0.0 references = http://www.tropomi.eu/data-products/nitrogen-dioxide title = TROPOMI/S5P NO2 1-Orbit L2 Swath 7x3.5km NO2 8

Comparison to IUP-UB: SC Overall good agreement in pattern OFFL S5P HCHO SC is larger in USA, South America, Africa, Asia, Siberia and smaller in Europe More negative values in IUP-UB product 9

Comparison to IUP-UB: VC Overall good agreement in pattern Higher background values in IUP-UB product Higher values in Canada, US, Siberia => difference in data selection includes more high HCHO events 10

Summary & Conclusions S5P HCHO product looks reasonable QA values do not appear to be doing what one would expect Some small things in the files need to be fixed Comparison with IUP-UB SCs shows qualitatively good agreement Comparison with IUP-UB VCs shows qualitatively good agreement, some marked differences which can in part be understood from data selection Only small things need to be fixed prior to release of HCHO product 11