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Laminar Static Mixer Introduction In static mixers, also called motionless or in-line mixers, a fluid is pumped through a pipe containing stationary blades. This mixing technique is particularly well suited for laminar flow mixing because it generates only small pressure losses in this flow regime. This example studies the flow in a twisted-blade static mixer. It evaluates the mixing performance by calculating the concentration s standard deviation. Model Definition This model studies the mixing of one species dissolved in water at room temperature. The geometry consists of a tube with three twisted blades of alternating rotations (Figure 1). Figure 1: Depiction of a laminar static mixer containing three blades with alternating rotations. The tube s radius, R, is 6 mm; the length is 14R, and the length of each blade is 3R. The inlet flow is laminar and fully developed with an average velocity of 1 cm/s. At the outlet, the model specifies a constant reference pressure of 0 Pa. The equations for the momentum transport are the stationary Navier-Stokes equations in 3D: 2011 COMSOL 1 LAMINAR STATIC MIXER

u u = pi + u + u T u = 0 (1) Here denotes the dynamic viscosity (kg/(m s)), u is the velocity (m/s), represents the fluid density (kg/m 3 ), and p denotes the pressure (Pa). The fluid s properties are not affected by the change in concentration of the dissolved species. The model studies the mixing performance by assuming a discontinuous concentration profile at the mixer s inlet. The inlet concentration is defined as c c 0 x 0 inlet = 0 x 0 (2) with the line x = 0 separating the two inlet sides. Diffusion and convection contribute to the mass flux, and the resulting mass transport equation is: D c+ cu = 0 (3) Here D denotes the diffusion coefficient (m 2 /s), and c is the concentration (mol/m 3 ). At the outlet, the mass transport is mainly driven by convection. That is, the transport by diffusion is neglected in the normal direction of the pipe s cross section. Because the convective term leads to instabilities in the solution, you need a fine mesh to obtain a stable solution for the concentration field. The low Reynolds numbers, in the mixer implies that the Navier-Stokes equations do not require a particularly dense mesh. You can therefore first solve the Navier-Stokes equations on a coarse mesh and then map the solution onto a finer mesh. In the last solution step you use this mapped velocity field in the convective mass-transport term. Results Figure 2 shows a slice plot of the concentration in the mixer. The slice at the bottom shows the lighter and darker halves of the fluid with and without the dissolved species, respectively. As the fluid flows upward through the system, the two solutions are mixed and an almost constant concentration is obtained at the outlet. 2 LAMINAR STATIC MIXER 2011 COMSOL

Figure 2: Slice plot of the concentration at different distances from the inlet. 2011 COMSOL 3 LAMINAR STATIC MIXER

Figure 3 shows the flow field responsible for the mixing. The streamlines clearly reveal the twisting motion in the fluid that is induced by the mixer blades. Figure 3: Slice plots of the velocity magnitude field inside the mixer. The streamlines show the flow direction. You can also visualize the mixing through a series of cross-section plots. Figure 4 contains such a series of plots showing the concentration in the mixer s cross section 4 LAMINAR STATIC MIXER 2011 COMSOL

along the direction of the flow. The results show that most of the mixing takes place where the blades change rotational direction (the three middle figures). Figure 4: Cross-sectional plots of the concentration at different distances from the inlet. The nine plots shows the concentration at z =- 2 mm to z = 30 mm in steps of 4 mm. References 1. R. Perry and D. Green, Perry s Chemical Engineering Handbook, 7th ed., McGraw-Hill, 1997. 2. J.M. Coulson and J.F. Richardson, Chemical Engineering, vol. 1, 4th ed., Pergamon Press, 1990. Model Library path: Chemical_Reaction_Engineering_Module/Mixing/ laminar_static_mixer 2011 COMSOL 5 LAMINAR STATIC MIXER

Modeling Instructions MODEL WIZARD 1 Go to the Model Wizard window. 2 Click Next. 3 In the Add physics tree, select Fluid Flow>Single-Phase Flow>Laminar Flow (spf). 4 Click Add Selected. 5 In the Add physics tree, select Chemical Species Transport>Transport of Diluted Species (chds). 6 Click Add Selected. 7 Click Next. 8 In the Studies tree, select Preset Studies for Selected Physics>Stationary. 9 Click Finish. GLOBAL DEFINITIONS Parameters 1 In the Model Builder window, right-click Global Definitions and choose Parameters. 2 Go to the Settings window for Parameters. 3 Locate the Parameters section. In the Parameters table, enter the following settings: NAME EXPRESSION DESCRIPTION ra 3[mm] Tube radius u_mean 10[mm/s] Mean inlet velocity c0 5[mol/m^3] Inlet concentration D 5e-8[m^2/s] Diffusion coefficient Step 1 1 In the Model Builder window, right-click Global Definitions and choose Functions>Step. 2 Go to the Settings window for Step. 3 Locate the Parameters section. In the To edit field, type 5. 4 Click to expand the Smoothing section. 5 Select the Size of transition zone check box. 6 In the associated edit field, type 3e-4. 6 LAMINAR STATIC MIXER 2011 COMSOL

GEOMETRY 1 1 In the Model Builder window, click Model 1>Geometry 1. 2 Go to the Settings window for Geometry. 3 Locate the Units section. From the Length unit list, select mm. 4 Right-click Model 1>Geometry 1 and choose Work Plane. Rectangle 1 1 In the Model Builder window, right-click Geometry and choose Rectangle. 2 Go to the Settings window for Rectangle. 3 Locate the Size section. In the Width edit field, type 2.4*3. 4 In the Height edit field, type 3/8. 5 Locate the Position section. From the Base list, select Center. 6 Click the Build Selected button. Extrude 1 1 In the Model Builder window, right-click Work Plane 1 and choose Extrude. 2 Go to the Settings window for Extrude. 3 Locate the Distances from Work Plane section. In the associated table, enter the following settings: DISTANCES (MM) 1.5 4 Locate the Twist Angles section. In the associated table, enter the following settings: TWIST ANGLES (DEG) 30 Copy 1 1 In the Model Builder window, right-click Geometry 1 and choose Transforms>Copy. 2 Select the object ext1 only. 3 Go to the Settings window for Copy. 4 Locate the Displacement section. In the z edit field, type 1.5. 2011 COMSOL 7 LAMINAR STATIC MIXER

Rotate 1 1 In the Model Builder window, right-click Geometry 1 and choose Transforms>Rotate. 2 Select the object copy1 only. 3 Go to the Settings window for Rotate. 4 Locate the Rotation Angle section. In the Rotation edit field, type -30. Copy 2 1 In the Model Builder window, right-click Geometry 1 and choose Transforms>Copy. 2 Select the objects ext1 and rot1 only. 3 Go to the Settings window for Copy. 4 Locate the Displacement section. In the z edit field, type 3. Rotate 2 1 In the Model Builder window, right-click Geometry 1 and choose Transforms>Rotate. 2 Select the objects copy2(1) and copy2(2) only. 3 Go to the Settings window for Rotate. 4 Locate the Rotation Angle section. In the Rotation edit field, type -60. Copy 3 1 In the Model Builder window, right-click Geometry 1 and choose Transforms>Copy. 2 Select the objects ext1 and rot1 only. 3 Go to the Settings window for Copy. 4 Locate the Displacement section. In the z edit field, type 6. Rotate 3 1 In the Model Builder window, right-click Geometry 1 and choose Transforms>Rotate. 2 Go to the Settings window for Rotate. 3 Locate the Rotation Angle section. In the Rotation edit field, type -120. 4 Select the objects copy3(1) and copy3(2) only. 8 LAMINAR STATIC MIXER 2011 COMSOL

Copy 4 1 In the Model Builder window, right-click Geometry 1 and choose Transforms>Copy. 2 Select the objects ext1, rot1, rot2(1), rot2(2), rot3(1), and rot3(2) only. 3 Go to the Settings window for Copy. 4 Locate the Displacement section. In the z edit field, type 9. Scale 1 1 In the Model Builder window, right-click Geometry 1 and choose Transforms>Scale. 2 Select the objects copy4(4), copy4(5), copy4(2), copy4(3), copy4(6), and copy4(1) only. 3 Go to the Settings window for Scale. 4 Locate the Scale Factor section. From the Scaling list, select Anisotropic. 5 In the x edit field, type -1. 6 Click the Build Selected button. Rotate 4 1 In the Model Builder window, right-click Geometry 1 and choose Transforms>Rotate. 2 Select the objects sca1(2), sca1(3), sca1(1), sca1(6), sca1(4), and sca1(5) only. 3 Go to the Settings window for Rotate. 4 Locate the Rotation Angle section. In the Rotation edit field, type 90. Copy 5 1 In the Model Builder window, right-click Geometry 1 and choose Transforms>Copy. 2 Select the objects ext1, rot1, rot2(1), rot2(2), rot3(1), and rot3(2) only. 3 Go to the Settings window for Copy. 4 Locate the Displacement section. In the z edit field, type 18. Cylinder 1 1 In the Model Builder window, right-click Geometry 1 and choose Cylinder. 2 Go to the Settings window for Cylinder. 3 Locate the Size and Shape section. In the Radius edit field, type 3. 4 In the Height edit field, type 42. 5 Locate the Position section. In the z edit field, type -6. 2011 COMSOL 9 LAMINAR STATIC MIXER

6 Locate the Rotation Angle section. In the Rotation edit field, type 15. 7 Click the Build Selected button. Union 1 1 In the Model Builder window, right-click Geometry 1 and choose Boolean Operations>Union. 2 Select the objects copy5(6), rot4(1), rot4(4), rot4(5), rot4(2), rot4(3), rot4(6), ext1, rot1, copy5(3), rot2(1), copy5(2), copy5(5), copy5(4), rot2(2), rot3(1), copy5(1), and rot3(2) only. 3 Click the Build Selected button. Difference 1 1 In the Model Builder window, right-click Geometry 1 and choose Boolean Operations>Difference. 2 Go to the Settings window for Difference. 3 Locate the Difference section. Under Objects to add, click Activate Selection. 4 Select the object cyl1 only to add it to the Objects to add list in the previous instruction. 5 Under Objects to subtract, click Activate Selection. 6 Select the object uni1 only. 7 Click the Build Selected button. 8 Click the Zoom Extents button on the Graphics toolbar. MATERIALS 1 In the Model Builder window, right-click Model 1>Materials and choose Open Material Browser. 2 Go to the Material Browser window. 3 Locate the Materials section. In the Materials tree, select Built-In>Water, liquid. 4 Right-click and choose Add Material to Model from the menu. The first material you add applies to all domains by default, so you do not need to change any settings. 10 LAMINAR STATIC MIXER 2011 COMSOL

LAMINAR FLOW Initial Values 1 1 In the Model Builder window, expand the Model 1>Laminar Flow node, then click Initial Values 1. 2 Go to the Settings window for Initial Values. 3 Locate the Initial Values section. Specify the u vector as 0 x 0 y u_mean Inlet 1 z 1 In the Model Builder window, right-click Laminar Flow and choose Inlet. 2 Select Boundary 20 only. 3 Go to the Settings window for Inlet. 4 Locate the Velocity section. In the U 0 edit field, type 2*(1-(x^2+y^2)/ ra^2)*u_mean. This gives a parabolic inlet velocity profile appropriate for fully developed laminar flow with mean velocity u_mean. Outlet 1 1 In the Model Builder window, right-click Laminar Flow and choose Outlet. 2 Select Boundary 23 only. TRANSPORT OF DILUTED SPECIES Convection and Diffusion 1 1 In the Model Builder window, expand the Model 1>Transport of Diluted Species node, then click Convection and Diffusion 1. 2 Go to the Settings window for Convection and Diffusion. 3 Locate the Diffusion section. In the D i edit field, type D. 4 Locate the Model Inputs section. From the u list, select Velocity field (spf/fp1). Inflow 1 1 In the Model Builder window, right-click Transport of Diluted Species and choose Inflow. 2 Go to the Settings window for Inflow. 2011 COMSOL 11 LAMINAR STATIC MIXER

3 Locate the Concentration section. In the c 0,c edit field, type step1(x[1/mm]). 4 Select Boundary 20 only. Outflow 1 1 In the Model Builder window, right-click Transport of Diluted Species and choose Outflow. 2 Select Boundary 23 only. MESH 1 In the Model Builder window, right-click Model 1>Mesh 1 and choose Free Tetrahedral. Size 1 In the Model Builder window, click Size. 2 Go to the Settings window for Size. 3 Locate the Element Size section. From the Predefined list, select Extra fine. 4 Click the Build All button. MESH 2 1 In the Model Builder window, right-click Model 1 and choose Mesh. 2 Right-click Model 1>Meshes>Mesh 2 and choose Free Tetrahedral. Size 1 In the Model Builder window, click Size. 2 Go to the Settings window for Size. 3 Locate the Element Size section. Click the Custom button. 4 Locate the Element Size Parameters section. In the Maximum element size edit field, type 0.7. 5 In the Minimum element size edit field, type 0.35. 6 Click the Build All button. STUDY 1 Step 1: Stationary 1 In the Model Builder window, right-click Study 1 and choose Study Steps>Stationary. 2 Go to the Settings window for Stationary. 12 LAMINAR STATIC MIXER 2011 COMSOL

3 Locate the Physics Selection section. In the associated table, enter the following settings: PHYSICS INTERFACE Transport of diluted species (chds) USE Step 2: Stationary 2 1 In the Model Builder window, click Study 1>Step 2: Stationary 2. 2 Go to the Settings window for Stationary. 3 Locate the Physics Selection section. In the associated table, enter the following settings: PHYSICS INTERFACE USE Laminar flow (spf) 4 In the Model Builder window, right-click Study 1 and choose Compute. RESULTS To reproduce plot in Figure 3 that visualizes the velocity field, follow these steps. Concentration (chds) 1 In the Model Builder window, expand the Results>Concentration (chds) node, then click Slice 1. 2 Go to the Settings window for Slice. 3 Locate the Plane Data section. From the Plane list, select xy-planes. 4 In the Planes edit field, type 8. 5 Click the Plot button. Velocity (spf) 1 In the Model Builder window, expand the Results>Velocity (spf) node, then click Slice 1. 2 Go to the Settings window for Slice. 3 Locate the Plane Data section. From the Plane list, select xy-planes. 4 In the Planes edit field, type 8. 5 Locate the Expression section. From the Unit list, select mm/s. 6 In the Model Builder window, right-click Velocity (spf) and choose Streamline. 7 Go to the Settings window for Streamline. 2011 COMSOL 13 LAMINAR STATIC MIXER

8 Locate the Streamline Positioning section. From the Positioning list, select Magnitude controlled. 9 In the Min distance edit field, type 0.025. 10 In the Max distance edit field, type 0.1. 11 Locate the Coloring and Style section. From the Line type list, select Tube. 12 In the Tube radius expression edit field, type 0.05. 13 From the Color list, select Yellow. 14 Select the Radius scale factor check box. 15 In the associated edit field, type 2. 16 Click the Plot button. Finally, reproduce the series of cross-sectional concentration plots for different z-coordinates shown in Figure 4 with the following steps. Data Sets 1 In the Model Builder window, right-click Results>Data Sets and choose Cut Plane. 2 Go to the Settings window for Cut Plane. 3 Locate the Plane Data section. From the Plane list, select xy-planes. 4 In the z-coordinate edit field, type -2. 2D Plot Group 5 1 In the Model Builder window, right-click Results and choose 2D Plot Group. 2 Go to the Settings window for 2D Plot Group. 3 Locate the Data section. From the Data set list, select Cut Plane 3D 1. 4 Right-click 2D Plot Group 5 and choose Surface. 5 Go to the Settings window for Surface. 6 In the upper-right corner of the Expression section, click Replace Expression. 7 From the menu, choose Concentration (c). 8 Locate the Coloring and Style section. Clear the Color legend check box. 9 Click the Plot button. 10 Click the Zoom Extents button on the Graphics toolbar. Data Sets 1 In the Model Builder window, click Results>Data Sets>Cut Plane 1. 2 Go to the Settings window for Cut Plane. 14 LAMINAR STATIC MIXER 2011 COMSOL

3 Locate the Plane Data section. In the z-coordinate edit field, type 2. 4 Right-click 2D Plot Group 5. Repeat these steps for z-coordinate 6, 10, 14, 18, 22, 26, and 30 to reproduce the remaining plots in Figure 4. 2011 COMSOL 15 LAMINAR STATIC MIXER

16 LAMINAR STATIC MIXER 2011 COMSOL