Innovative Photon Management for Smart Control of Light. Shawn-Yu Lin Device Thrust Leader RPI Constellation Professor (The Future-Chips)

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Innovative Photon Management for Smart Control of Light Shawn-Yu Lin Device Thrust Leader RPI Constellation Professor (The Future-Chips) 1

Light, Visual Experience & Innovation Sun light Vacuumtube technology Bio-imaging (Nucleus) Human eye Semiconductorchip technology Lighting & health Color Display- Polarization (Summer Davos 09, photonic revolution, opening remark-1/2, Dr. SY Lin-RPI, USA)

What are the most innovative contributions? the New Science of LED - tailoring the emitter-photon interaction - E photons E // photons photons photons photons emitter photons n=1 n=2.6 emitter emitter Micro-cavity C ex >80-100%** Guided modes eliminate Rad. pattern- (Δθ<10 o ) Guided/ trapped light (4%) Rad. pattern- Lambertian Un-polarized- θ~0 o η int >90%*** Cavity modes Emitter-photon- coupled (**source: Laser & Photonics Rev. 1, 307-333, 2007, ***Nature 425, 268, 2003)

On-Chip Control of the Nature of Light Pattern Polarization E,// color λ Color temperature

Under This ERC, We Have Identified 4 Areas as our Device Focus for Year 2-3. DP: Device Project SP: System Project (from Art Sanderson Nov. 09)

We Have Formulated a Preliminary List of Device Performance Matrix As our Near-Term Objectives. 1. Wavelength bandwidth (variable/tunable/δλ 30/10nm) 2. Brightness (C ex, η, droop effect ) 3. Uniformity (0.25mm 2, 5mm 2, 50mm 2 ) 4. Directionality /emission θ ( 30/20/10 0 ) 5. Polarization selectivity (2:1/10:1/50:1) 6. Phosphor lifetime (100ns/10ns/1nsec) new device design Broadband green Narrowband red 7. Color mixing (spectral uniformity) 8. Thermal management 9. Fabrication technology (70nm over 625mm 2 ) What are the tradeoffs in optimizing for system performance?

The key performance attributes and characteristics- (I) extraction and radiation pattern Approach Principle C (extraction) Source Device Grand Challenge a. Surface texture +thin film-reflector b. Photonic crystal +thin film-reflector c. Nano LED*** d. Nano LED*** +thin film-reflector a Optical scattering; FP cavity Bloch scattering; FP cavity Single-mode or few modes Single-mode; FP cavity External efficiency: 46% 68-78% (total) -1mA 50-70% (one-side) Expect: >80-90% (total) b photons APL 63, 2174, 93 APL 79, 2315, 01 Nature Photonics 3, 163, 2009 photons photons photonic crystal emitter reflector MQW 700nm reflector

Engineering the Basic Optical Mode : LED Light Extraction and Pattern Control Wavelength imaging spectrometer slit d Nano LED Sapphire x100 objective MQW Frequency (a/λ) 1.2 1 0.8 0.6 0.4 0.2 0 Radiation mode λ=455nm Guided mode 0 0.5 1 1.5 2 K z (2π/a) d=200nm/ 82 modes d=100nm/ 5 modes d=50nm/ 1 modes LN 2 -CCD η int (%) 1 0.8 0.6 0.4 0.2 0 0.1 1 10 d (μm) (data to be published)

Nano Engineering of the Basic Mode Also Allows Us to Tailor an LED s Radiation Pattern. 90 90 90 120 60 120 60 120 60 150 30 150 30 150 30 180 0180 180 0 0 d=50nm Sapphire d=2μm d=8μm S P a d Next: 2D Array d=100nm d=200nm d=2,000nm

Beam Shaping for Lighting and Communication (Smart Lighting ERC/BU Dr. T Little)

Polarized LED for Display Application Polarizer Liquid crystal CCFL Polarizer High-power LED Backlighting/ Edge injection/ Waveguiding Smart features : Reduced motion blur by impulse driving Color filter-less LCD by sequential driving

The key performance attributes, characteristics- (II) polarization. LED Device Grand Challenge a Approach a. External Reflector b. Metallic grating c. strain engineering** d. Metallic/ plasmonic photonic crystal** External reflector Principle Critical angle Metallic loss VB degeneracy Plasmonic coupling c Polar. ratio 2:1 2:1 2:1 (522nm) 5:1 (588nm) 10:1 (expect) VB Strain Engineering Comments Bulky; Emis. angle dependent Growth intensive; High In-concentration; Metal loss at visible Light focusing at corners EL Intensity (arb.u) 160 120 80 40 505 nm E c-axis 491 nm E//c-axis Source Op. Express 15, 11213, 09 APL 93, 23111, 08 JJAP 47, 7854, 2008 m-plane MQW LED 20 ma Imax Imin ρ = = 0.77 I + I 0 350 400 450 500 550 600 650 700 max Wavelength (nm) (from C. Wetzel et al.) min

For Bio-Imaging Applications, There is a Need for Wavelength and Intensity Control. Intensity Photo-toxicity Absorp.-1 Absorp.-2 300 400 Wavelength (nm) 500 600 Hg Spectrum (λ=300-600nm) --- Alexa 488 antibody --- Rhodamine LED Advantages: λ-selective Photo-toxicity Compact, low cost Full spectral Polarization

Approach for Bandwidth-Control and Wavelength-Tuning. LED Device Grand Challenges (Bio-imaging) Photonic crystal (PC) Match LED-λ to fluorophore Δλ=30nm(desired), Δλ=10nm (ideal) Dynamic λ-tuning Polarized LED Collimated emission DBR Cr/Au AuSn Si Lu, IEEE PTL 20, 836, 2008 Y66W mkeima-red Abso. Emission 436 440 485 620 monomer (MBL) Thin film LED with PC TagCFP 458 480 dimer (Evrogen) AmCyan1 458 489 tetramer, (Clontech) Δλ~12nm mtfp1 462 492 dimer S65A 471 504 without PC Midoriishi Cyan Wild Type GFP 472 396,475 495 508 dimer (MBL) 350 400 450 λ=500nm S65C TurboGFP TagGFP S65L Emerald 479 482 482 484 487 507 502 505 510 509 dimer, (Evrogen) monomer (Evrogen) weak dimer, (Invitrogen) Novel features: Engineering of op. modes Global resonance, not μ-cavity High Intensity Narrow Δλ Next: DBR, tunable

Phosphor Device: Bulk Crystal Growth of Multi-component, Rare Earth Doped Thio-gallate Growth of (Sr 1-x Ca x Ga y In 1-y S:Eu) from high temperature melt: Material selected for comparison with industry results on phosphor LEDs Fabricated preliminary down-conversion structures (excitation @ 451 nm blue LED) (emission area in photos : 3cm 2 ) Emission Wavelength: 560 nm Emission Wavelength: 620 nm (from D. Partha)

We Have On-going and Active Industrial Collaborations With Our Industrial Partners. The biggest problem we face in UV-LED is extraction. We loss 95% of light due to a poor extraction. - Leo Schowalter of Crystal IS P-contact AlN (from Crystal IS) UV-LED Device Grand Challenge : backside emission/ thick epi-layer/ front absorption

On Fabrication Technology - Large scale and Low cost Approaches Feature size Size Scale Pro. speed Comments e-beam write <10nm 300 x 300 μm 2 Slow Expensive Nano-imprint 50-150nm 5 x 5 cm 2 fast Molding material Interferometric lithography*** 50-150nm 5 x 5 cm 2 fast Optics/ 2D pattern (Steve Brueck/ UNM) Holographic lithography (RPI) 50-150nm 5 x 5 cm 2 fast Optics/ 3D pattern 1 3 2 430nm Ar Laser λ=355nm 3D photonic crystal (SY Lin and Prof. M.L. Hsieh, NTNU, Taiwan) Our team has world renowned expertise in nanofabrication. Dr. S. Brueck, pioneers the interferometric lithography method. Dr. S. Y. Lin pioneers the nanofabrication of 2D and 3D photonic crystals.

Thank you!