KORUS-AQ campaign results as a validation. Presenter: Ara Cho (NIER) NIER, NASA, GEMS Algorithm science team, KARI

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KORUS-AQ campaign results as a validation Presenter: Ara Cho (NIER) NIER, NASA, GEMS Algorithm science team, KARI

CONTENTS Introduction Surface Remote Sensing observation Evaluation of GEMS with KORUS-AQ Development of Geo-TASO Algorithm Credit : Geoeye 2

INTRODUCTION 3

Introduction Korea is located in a region of rapid change with strong air quality gradients both in time and space. Started surface observation and forecasting air quality Asian NO 2 emissions from 1980-2003 based on activity data (Ohara et al., 2007)

Introduction There are temporal and spatial limitations of the data to investigate climate change and air pollution (surface monitoring, LEO, ) Geostationary Environmental Monitoring Spectrometer(GEMS) will be launched in 2019. dense in urban area GEMS 5

Goal of KORUS-AQ campaign KORUS-AQ (Korean and U.S.) to implement an integrated observing system for improving understanding of Air Quality Airborne sampling - connecting ground-based and satellite observations - Short term Ground monitoring - The primary method for monitoring exposure. - limited coverage. KORUS-AQ Goals Improve capability for satellite remote sensing of air quality Better understanding of the factors controlling air quality Test and improve model simulation of air quality Satellites - broad coverage, continuity - it needs reliable information on n ear-surface exposure. Modeling - Air quality forecasting and warning service - it needs reliable information such as emission inventory [Courtesy of James Crawford and Joon-young Ahn] 6

Observation platform NASA DC-8 LaRC King Air Hanseo King Air Geostationary Ocean Color Imager (GOCI) GOCI, OMI, MODIS, CALIPSO, IASI, etc Korean and US Air Quality Model Forecasts Surface Remote sensing: (Lidar, Aeronet, Pandora) RV Onnuri RV Kissng 7

Observation platform Surface remote sensing observation AERONET : Aerosol optical properties (AOD, SSA, FMF, AE, refractive index, etc.) Pandora : Total column trace gases (O3 and NO2) 38 AERONET and SONET sites within GOCI domain http://aeronet.gsfc.nasa.gov/new_web/dragon-korus- AQ_2016.html Korea AERONET & Pandora sites [Courtesy, Jhoon Kim] 8

Geostationary satellites aerosol observation MI/COMS (NMSC/KMA, Korea) 15-min interval for East Asia 3-hour interval for Full Disk (day and night) 1 bands in VIS (1 km) 4 bands in IR (4 km) Aerosol products (Yonsei) AOD (4km) Mijin Kim et al. (2014, 2016) GOCI/COMS (KOSC/KIOST, Korea) 1-hour interval for East Asia (total 8 times in daytime) AHI/Himawari-8 (JMA, Japan) 10-min interval for Full Disk (day and night) 8 bands in VIS-NIR (0.5 km) 4 bands in VIS-NIR (0.5/1.0 km) 12 bands in IR (2 km) Aerosol products (Yonsei) AOD, FMF, AE (6 km) Myungje Choi et al. (2016) Aerosol products (Yonsei) AOD, FMF, AE (6 km) Hyunkwang Lim et al. (2016) 9 [Courtesy, Jhoon Kim]

SURFACE REMOTE SENSING IN KORUS-AQ 10

Observation result of Remote sensing Time series of AOD and AE during KORUS-AQ AOD (550 nm) AOD (550 nm) AE (440-870 nm) AERONET AOD at Seoul (megacity region) and Gosan (coastal region) have lower values compare to other recent years (2011 to 2015). AERONET AOD in the latter part of the campaign shows higher values than in the former part and fine particles are usually observed over the Korea peninsula during KORUS-AQ campaign. 11 [Courtesy, Jhoon Kim]

Observation result of Remote sensing Time series of AE and SSA during KORUS-AQ AE (440-870nm) SSA (440nm) 12 [Courtesy, Jhoon Kim]

Observation result of Remote sensing MODIS DT (0.2 ) MODIS DB (0.2 ) VIIRS EDR (0.2 ) MI 4K 0400UTC GOCI 6K 0430UTC AHI 6K 0400UTC MI 4K All meas. GOCI 6K All meas. AHI 6K All meas. High AOD over Western part of Korea MODIS DT (10K) MODIS DB (10K) MI 4K 0400UTC GOCI 6K 0430UTC AHI 6K 0400UTC MI 4K All meas. GOCI 6K All meas. AHI 6K All meas. VIIRS EDR (6K) More frequent GEO measurement 10-30 times higher in No. of collocated data 13 [Courtesy, Jhoon Kim] Similar accuracy with LEO

Observation result of Remote sensing Pandora column amounts (Olympic Park time series) [Courtesy, Jhoon Kim] Pandora Ozone and NO2 measurements have low and high variability, respectively Olympic Park at urban area 14

Observation result of Remote sensing Validation of Pandora O 3, NO 2 using OMI [Courtesy, Jhoon Kim] Seoul R = 0.97 Busan R = 0.98 GIST R = 0.98 Temporal collocation: Averaging Pandora NO2 within ±30 minute from OMI overpass time Spatial collocation: Selecting OMI pixels within 30 km from each Pandora site For O 3, which has smaller spatial and temporal variability than NO 2, it was found that Pandora total VCD has high correlation with OMI (R>0.9). Pandora NO 2 has lower correlation with OMI data than O 3 because OMI has coarse spatial resolution and restricted observation time to measure NO 2 which has large 15 spatial and temporal variability.

Evaluation of GEMS Algorithm with KORUS-AQ 16

To help protect your privacy, PowerPoint has blocked automatic download of this picture. Method Airborne profile data collection and analysis - Airborne and CMAQ profiles during KORUS-AQ Airborne data is more detail! HCHO NO 2 SO 2 - Retrieval Column data using interpolation and integration 17

Evaluation result NO2 Algorithm Evaluation 1. Comparison with OMI satellite OMI Level 2 NO 2 2005. 03 Lat: -5 ~ 45, Lon: 75 ~145 GEMS vs OMI 2. Airborne, 2016.05, 12:00~15:00 LST DC-8 Spiral and track 18

Evaluation result HCHO Algorithm Evaluation 1. Comparison with OMI satellite OMI Level 2 HCHO SCD VCD 2. Airborne, 2016.05(KORUS-AQ), 12:00~15:00 LST SCD 2005, Lat: -5 ~ 45, Lon: 75 ~145 GEMS SCD vs OMI SCD GEMS VCD vs OMI VCD VCD - Slant Column Density(SCD) is similar with OMI, Vertical Column Density(VCD) has lower level of significance than SCD be required retrieve Air Mass Factor precisely 19

DEVELOPMENT OF GEO-TASO ALGORITHM 20

Introduction of Geo-TASO Geo-TASO (Geostationary Trace gas and Aerosol Sensor Optimization) - Payload for aircraft to test algorithms performance of GEMS Retrieval of trace gas from Earth radiation intensity with UV-Vis hyper-spectrometer < Nowlan et al. > System Parameter Dispersion Value UV: 0.14 nm/pix; Vis: 0.28 nm/pix Spectral Passband UV: 280-490 nm; Vis: 560-980 nm Spectral Sampling Spatial images/sampling (at 32 kft AGL) Cross-track swath (at 32 kft AGL) 2-3.5 samples/fwhm 40 by 80m IFOVs; 8 by 50m sampling 8 km < Leitch et al. > 21

Introduction of Geo-TASO To improve GEMS Level2 Algorithms, GeoTASO and Sunphotometer are utilized as a test-bed * GeoTASO : the Airborne payload in KORUS-AQ campaign, * Sunphotometer : an aerosol ground observation Special feature of GeoTASO - Higher spatial resolution - Observations are not guaranteed to see temporal change at specific points. Development of airborne algorithm is needed. 22

Geo-TASO Algorithm Wavelength Cal/Val Algorithm Develop wavelength cal/val algorithm for Geo-TASO with addition of Ozone and ring effect Sensitivity to UV area and cloud is reduced compared with previous algorithm Before After Reference Measurement Reference Measurement Correlaiton: 0.9236 RMSE: 0.6738 Correlation: 0.9978 RMSE: 0.1463 23 [Courtesy, Myoung-hwan Ahn]

Geo-TASO Algorithm Ozone Algorithm GTASO reference (Clear sky) LEAST SQUA RES FITTING DOAS Fitting result (318 331 nm) REFERENCE SPECTRA (SAO) + TEMPERATURE DEPENDENCE + Used Xsec (O 3 243K, O 3 293K ring, SO 2, NO 2 ) Residual is fitted as 1e-03 order 24 24 [Courtesy, Jae-hwan Kim]

Geo-TASO Algorithm NO2 Algorithm NO 2 SCD (May, 17,2016) Spectrum (GEO-TASO) Reference spectrum FWHM: 0.91 nm QDOAS spectral fitting software (developed at the Royal Belgian institute for Space Aeronomy (BIRA-IASB)). Fitting window: 432 ~ 450 nm Cross section: NO 2 _294K (Vandaele et al., 1998), ozone_273k (Bogumil et al., 2000), ring (Chance and Spurr 1997) 25 [Courtesy, Hyunkee Hong]

Geo-TASO Algorithm NO 2 AMF calculation GOCI AOD (May, 17, 2016) The aerosol vertical distribution is based on a Gaussian distribution function (GDF) and Aerosol peak height is assumed as 1 km. [Courtesy, Hyunkee Hong] MODIS SSA (May, 17, 2016) NO 2 AMF (May, 17, 2016) Courtesy of Jhoon Kim and Myeong Jae Choi MODIS surface reflectance (May, 17, 2016) B200 SZA, VZA, RAA, Height 26

Geo-TASO Algorithm Tropospheric NO 2 VCD retrieval NO 2 SCD <May, 17, 2016> Tropospheric NO 2 VCD & in-situ NO 2 VMR at the same time AMF Max: 9.8 10 16 molecules cm -2 Sungnam(14:36) 27 [Courtesy, Hyunkee Hong]

Summary During KORUS-AQ, it is used for observation such as ground-based remote sensing, airborne, satellite, and modeling. The result of surface remote sensing is matched well with last 5 years. In GEMS evaluation, the results of Ozone compared with DC-8 or OMI were significant, but we found that formaldehyde requires AMF improvement. To understand GEO-TASO observation result, we develop GEO-TASO algorithm and it is undergoing improvement. We will evaluate GEMS algorithm more with KORUS-AQ results so that GEMS will offer products with significant quality. 28

THANK YOU FOR YOUR ATTENTION! 29

Retrieval Algorithm Differential Optical Absorption Spectroscopy (DOAS) The beer-lambert law j I( λ) = I ( λ)exp( S ( λ) c o n j= 1 j ) Optical thickness (density) I( λ) τ ln( ) = I ( λ) 0 n j= 1 S j ( λ) c j due to Rayleigh & Mie scattering Calculated from Polynomial models Credit: H. L. Lee Slant columns (SCD) calculated from a fitting method 30 30 / 43

Retrieval Algorithm VCD SCD The AMF is defined as the ratio of the measured slant column to th e vertical column in the atmosph ere: AMF G = 1 cos( θ ) + 1 cos( ϕ) AMF SCD( λ, Θ,...) = VCD From Satellite The AMF i are also often called Scat tering Weights The AMF expresses the sensitivity of the measurement, and depends on a variety of parameters such as: wavelength geometry vertical distribution of the species clouds aerosol loading surface albedo Calculate AMF with RTM Credit: 31 31 / 43