Pathways to Profit UOP Dehydrogenation Technology

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1 Pathways to Profit UOP Dehydrogenation Technology Anish Paunwala 16 th INDIAN Petrochem Conference Mumbai, India October 30-31, A Century of Innovation in the Oil and Gas Industry 2014 UOP LLC. All rights reserved. UOP 6570H_R_1

2 Agenda Light Olefin Demand Outlook Light Olefin Supply Routes and Market Shift On-Purpose Propylene Production Technology UOP Oleflex Process Why Customers Choose Oleflex Process? Conclusion Propane Butane UOP Oleflex TM Process Propylene Isobutylene PP Acrylonitrile PO MTBE Cumene Etc.. UOP 6570H_R_2

3 Million MTA Tremendous Opportunities in Petrochemicals Propylene Ethylene Light Olefin Demand World demand for ethylene and propylene growing (about 4%/yr) More than 100 MMTA of additional capacity will be needed by 2025 Consumption being driven by growing middle class in developing regions The world market continues to drive demand for products derived from light olefins Source: IHS Chemical UOP 6570H_R_3

4 Cracker Feed Slate Swings Past Propylene Cracker Feeds Cracker Products Ethane Ethylene E/P Mix LPG Light Naphtha FBR Naphtha Gas Oil Steam Cracker Propylene Butadiene Other C 4 By-products Pygas Shift to lower cost, lighter feeds results in decrease in propylene UOP 6570H_R_4

5 Refinery Shifts Balance Away from Light Olefins Refinery Objective Diesel By Products Ethylene Propylene Refinery economics favor diesel production over gasoline in many regions Less severe catalytic cracking, more mild hydrocracking produce less gasoline and less light byproducts Shift towards heavier diesel reduces byproduct light olefins UOP 6570H_R_5

6 Million MTA Tremendous Opportunities in Light Olefins Light Olefin Supply Propylene - Other Propylene - FCC Propylene - Steam Cracking Ethylene - Steam Cracking Growing share from other sources besides steam cracking and refineries Propylene gap developing Several options for on-purpose propylene production UOP technologies to meet your light olefin market demands Source: IHS Chemical UOP 6570H_R_6

7 Get into the Action with Oleflex Process Feedstocks Products Uses H 2 Fiber Propane Propylene Packaging Propane + Isobutane Propylene + Isobutylene High performance plastic Gasoline Blending Components Isobutane Isobutylene MTBE ETBE UOP Oleflex Process Iso-Octane Synthetic Rubbers & Acrylics Selection of Process Technology Economic Feasibility- Low CoP, Low Investment High IRR or NPV Simple Process and Easy to Operate Proven & Strong Technical Support Safe and Environment Friendly UOP 6570H_R_7

8 $/MT PDH P-P Spread is Main Economic Driver PDH economics primarily driven by the price differentials between propylene and propane PDH Project Economics Example PG Propylene Propane Price Spread, $/MT 1,500 1,300 1, W. Europe SE Asia NE Asia North America Saudi Arabia Capacity 650 KMTA 500 KMTA 350 KMTA Year Data Source: IHS Chemical Profitability is attractive over wide range of price differentials Propylene to Propane differentials support investment in PDH UOP 6570H_R_8

9 C 3 Oleflex Complex Simple Perfection Byproduct H C Deethanizer Oleflex Unit SHP Propylene P-P Splitter C 3 LPG Depropanizer C 4 + Selective Hydrogenation Process converts methyl acetylene & propadiene to valuable propylene Elegant & simple solution! UOP Oleflex Process used in 12 of the 19 operating PDH Units today UOP 6570H_R_9

10 Leverage UOP CCR Experience in PDH/BDH Reactor Section Regeneration Section C 3 Oleflex Unit = 4 Rxs C 4 Oleflex Unit = 3 Rxs Catalyst Flow C C R >250 UOP CCR s in Operation Today Heater Cells Positive Pressure / Pt Catalyst Lowest Energy Usage & Emissions Fewest & Smallest Reactors Catalyst Change-Out without Shutdown Rx Effluent Compressor Fresh & Recycle Feed Dryer H 2 Recycle Cold Box Net Hydrogen To Frac Section Product Recovery Section UOP 6570H_R_10

11 Six Operating C 4 Oleflex Complexes World-Wide ic 4 ic 4= H 2 By-product Oleflex Unit Fresh Methanol Ethermax TM Unit MTBE C 3 - C 4 LPG DIB Column Raffinate Treatment DeC 3 Column C 5 + Butamer TM Unit nc 4 ic 4 Alternate End-Product processing options: ETBE from Ethanol, Tert-Butyl Alcohol from Water Alkylation (Indirect or Direct) High Purity Isobutylene (HPIB) via MTBE Decomposition Others (Methyl MethAcrylate, Isoprene, etc.) UOP 6570H_R_11

12 C 3 /C 4 Oleflex MTBE Complex Net Hydrogen C 2 - Oleflex Unit C 3 /C 4 Separation Section C 3 = DIB Column LPG Butamer Unit Fresh Methanol Ethermax Unit MTBE C 5 + Raffinate Treatment UOP has 20 years of experience for C 3 /C 4 dehydrogenation UOP 6570H_R_12

13 Olefin Capacity, kmta UOP Leads the Way in C 3 and ic 4 Dehydro 12,000 10,000 Award, Design or Construction Commissioned 8,000 6, units UOP has been awarded 28 of the last 33 dehydro projects world-wide since 2011 World s Largest PDH at 1000 kmta and 2 PDH Projects at 750 kmta propylene capacity 4,000 2, units +3 9 units 5 units 5 units 0 C 3 Dehydro ic 4 Dehydro 1 unit C 3 /ic 4 Dehydro Highest ROI and Highly Reliable Technology keeps Oleflex Process as the choice of the industry UOP 6570H_R_13

14 Location of Operating UOP C3 Oleflex Units Russia and China (x2) join the Oleflex Family UOP

15 UOP Proven Track Record of Innovation 30 th licensed Oleflex Unit (>12.0 MMTA) 15th licensed Oleflex Unit (>5.0 MMTA ) 10th licensed Oleflex Unit (>3.0 MMTA) kmta propylene designed kmta propylene designed 2007 DeH-16 Catalyst (6 th Generation) kmta propylene designed kmta propylene designed 2001 DeH-14 Catalyst (5 th Generation) & 350 kmta propylene designed 1996 DeH-12 Catalyst (4 th Generation) kmta propylene designed 2014 DeH-18 (7 th Generation) kmta propylene design 2012 UOP/HPS Training Simulator 2012 UOP/HPS Oleflex Automation Package DeH-8 and DeH-10 Catalysts (2 nd and 3 rd Generations) st Commercial Oleflex Units with DeH-6 Catalyst Continuous Innovation Driven by Customer Needs UOP - CONFIDENTIAL UOP 5809K_RP-15

16 UOP s Modular and Equipment Commitment UOP Enhanced Tubes UOP Column Internals Modular supply by UOP MD / ECMD Trays Smaller tower diameter Close tray spacing Lower column pressure drop High Flux / High Cond Tubes Highest heat transfer performance Closer Approach Fewer / smaller bundles Modular Supply Highest quality Delivered on time & on budget Advance your schedule and improve your bottom line with UOP Equipment & Modular Supply UOP 6005K_RP-16

17 Why Customers Choose UOP Oleflex Lowest Overall Cost of Production: Low feed consumption design available <1.15 Lowest gross / net energy usage Lowest coke Flexible byproduct disposition Smaller Investment Required Fewest reactors on most compact plot space Efficient regeneration requires smaller equipment Constant equipment count Best economy of scale You can choose both! Get lowest CAPEX and OPEX in one design UOP 6570H_R_17

18 Why Customers Choose UOP Oleflex (Cont..) High Reliability / On-Stream Availability Constant process conditions Robust design incorporates largest operating base CCR technology well proven across the industry Smallest Environmental Footprint: Lowest energy leads to lowest CO 2 Low NOx & VOC emissions Non-toxic catalyst system The safest & most environmentally friendly technology also leads in reliability UOP 6570H_R_18

19 In Conclusion UOP s Oleflex Process: Best dehydrogenation technology Lowest CAPEX + lowest CCOP = Best Bottom Line Largest experience base & most reliable technology UOP as Your Technology Provider: The best keeps getting better Continuous innovation for new & existing customers Extensive capabilities with regional support Drive Your Profitability to new heights with UOP as your Technology Provider UOP 6570H_R_19

20 Pathways to Profit - UOP Dehydrogenation Technology Thank You UOP 6570H_R_20

21 UOP 6570H_R_21

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