Electronic Loads. Installation & Operation Manual EL101/300 EL1000

Transcription

1 Electronic Loads Installation & Operation Manual EL101/300 EL /2015

2 Electronic Loads -1- CAUTION Prevent the inputs of the device from electrostatic discharge This may damage the device. Do not connect active objects such as batteries or fuel cells to the power outputs of the device when the device is off This may damage the device.

3 Electronic Loads -2- Unpacking Zahner products are produced carefully, calibrated and tested to achieve a high quality standard. Also the assembling of the accessories and packing is done with great care. Therefore please check the shipment directly after receipt whether the device and all accessories are undamaged. The shipment must contain the following parts: EL1000 EL1000 cable for connection of the EPC40/41/42 (D-Sub9 - Lemosa) cable for connection of a PC USB port (USB-A D-Sub9) with build-in USB-serial converter twisted sense cable (Lemosa plug, blue & green cables) power cord this manual EL300 EL300 with installed control cable for connection of the EPC40/41/42 (Lemosa plug) 2 thick cables (blue and red) with high current banana plugs ( 12mm) twisted sense cable (Lemosa plug, blue & black cables) power cord this manual EL101 EL101 with installed cable for connection of the EPC40/41/42 (Lemosa plug) 2 cables (blue and red) with banana plugs ( 4mm) twisted sense cable (Lemosa plug, blue & black cables) power cord this manual

4 Electronic Loads -3- Basics Today, dynamic measurements on electrochemical objects are of great interest. Modern instruments for impedance measurements, cyclic voltammograms and pulse response experiments provide a broad frequency range from µhz to MHz. At the same time, they provide a huge impedance range from µω to GΩ. Anyway: for most instruments there is one restriction left, they have a limited current range in the magnitude of some Amperes maximum. In the field of electrochemical power generation for example this is only sufficient for 'small' systems. The electrochemical workstations of the IM6 family provide a current range of ±2,5A (Zennium) and ±3A (IM6) and measure impedances down to some µω. Therefore, we provide external potentiostats (EL, PP-Series and XPOT) which can extend the application field of the IM system. The electronic loads EL101/300 and EL1000 are designed as additional potentiostats to allow dynamic investigations on technical systems up to 25 A (EL101), 100 A (EL300) and 200A (EL1000). Their main applications are discharging tests on batteries, accumulators and fuel cells. The electronic loads are easily integrated in the IM6/Zennium system using EPC40/41/42 controller cards. All functions are controlled directly from the Thales software. Up to 16 electronic loads may be controlled by one IM6/Zennium system using up to 4 EPC40/41/42 cards. With the MultiCell functionality of the IM systems the connected electronic loads can be used in parallel. Up to 16 cells may be investigated at the same time. EPC4 / EPC40 / EPC41 / EPC42 The EPC40/41/42 is able to control up to 4 external potentiostats like the EL101/EL300/EL1000, the XPOT and the PP201/211/241. Up to four EPC40/41/42 for a total of 16 external devices can be installed in an IM6 and the Zennium systems. Each port provides analogue and digital interfaces for the communication of the external device with the IM system. The analogue part of the port feeds the device with the DC potential and the AC amplitude at a resolution of 16 bit. Measured current and potential are sent from the external device to the IM to be treated there in the same way as signals from the internal IM cards. The EPC40/41/42 has a bandwidth of 250 khz. A bi-directional serial communication line allows to digitally control the external potentiostat functions and measuring ranges. Besides, the EL1000 electronic load can be controlled by a Windows -PC. In this case they provide the methods Test Sampling as well as U- and I-curves vs. time. They also work as a LabView Virtual Instrument under the LabView software. Furthermore, you can control the EL1000 in a mixed mode with an IM6/Zennium and a PC in parallel. Both devices can be connected and disconnected in operation. Plug or unplug external devices only when both, IM6/Zennium AND the external device, are switched off. Otherwise the devices may be damaged.

5 Electronic Loads -4- Selecting an external device All external IM devices are directly controlled by the Thales software. Each device has a unique device number which is identical with the EPC40/41/42 port number. So, if a device is connected to EPC port 3, you address it with the device number 3. Device number '0' is reserved for the internal potentiostats of the IM system. If an RMUX (relay multiplexer) card is installed, the device numbers of the ELs start with 17, not with 1, because the device numbers 1 to 16 are reserved for the 16 RMUX channels then. To select a device, call the Test Sampling page and click one the # symbol next to the Device Identity box. Device Main # An input box will appear where you can input the device number. Potentiostat Number: 1 Now the selected device type is shown in the Device Identity box, for example: Device EL300#1 # If no device has been connected to the addressed EPC40/41/42 port an error message is displayed and the software automatically selects the internal potentiostat. If the selected device is present but has not been activated yet the software starts to calibrate it automatically. If an external device is changed the new device has to be calibrated before use. The calibration is carried out only for the selected device. All other calibration data keep unchanged. If a device number other than 0 is selected, the parameters of the Test Sampling page now are valid for this device. The following methods are available for external devices: EIS C/E I/E MIE AS impedance measurement parameter impedance measurement current potential curve recording Multiple parallel current potential curve recording series measurements Specific parameters for these methods are to be edited in the pages related to the method. Changing devices When changing the device number, the now inactive device will hold its DC conditions such as DC potential and on/off status as long as it is selected anew or the system is shut off. On the other hand only the selected device is internally connected to the FRA. Therefore only this device is able to output an AC signal superimposed to the DC potential.

6 Electronic Loads -5- EL101 / EL300 The EL101/300 external electronic loads are One-Quadrant-Potentiostats. This means that they are able to sink current but cannot source current. Typical applications are discharging experiments at batteries, accumulators and fuel cells. The EL-series potentiostats can be operated in both potentiostatic and galvanostatic modes, controlled by the Thales software. The output as well as the input are electrically isolated from ground. Whereas the EL101 is air cooled, the EL300 needs water cooling when loaded with more than 25 A. For water cooling you find an inlet and an outlet at the backside of the EL300. The EL300 may get damaged if more than 25 A are applied without water cooling Cell Connections It is important to know that EL potentiostats SINK current from the test object and therefore the cell connections must be as short and as thick as possible. Otherwise the measurements may be faulty and it may even seem that the EL is defective. For this reason, the standard cable set shipped with the ELs should be shortened as far as possible. It is also important to connect the test object with the correct polarity to the EL potentiostat. Whereas typical one-cell-voltages of 0.8V to 1.2V do not damage an EL when being connected with the wrong polarity, cell stacks can do very well. Therefore, we recommend to connect the sense inputs as described in fig. 1 (Full Cell Configuration). Call the Test Sampling page of the Thales software and check for the potential polarity. It must be negative. Now connect the power inputs according to fig.1 with the potentiostat switched off. The displayed potential must not change significantly when connecting the power lines. With the correct polarity the test object may be connected to the EL potentiostat in one of the following ways: 1. Full Cell Configuration (Standard Kelvin Scheme) EL101 This configuration is used with active test objects like batteries, accumulators and fuel cells if a complete cell is to be investigated. sense ZAHNER elektrik power active line The DC potential applied must be negative and greater or equal than the rest potential of the cell. Rest potential set potential 0 V anode pole cathode pole

7 Electronic Loads -6-2.a. Half Cell Configuration Anode EL101 sense This configuration is used with active test objects like batteries, accumulators and fuel cells if only the anodic part of the cell has to be investigated. power active ZAHNER elektrik line The DC potential applied must be greater or equal than the rest potential of the cell. Rest potential set potential anode pole cathode pole Depending on the type of the reference electrode the measured potential may be different from the real potential at the reference electrode site. The real potential can be calculated from the measured potential by subtracting the potential of the reference electrode. 2.b. Half Cell Configuration - Cathode EL101 This configuration is used with active test objects like batteries, accumulators and fuel cells if only the cathodic part of the cell has to be investigated. sense power active ZAHNER elektrik line The DC potential applied must be greater or equal than the rest potential of the cell. Rest potential set potential anode pole cathode pole Depending on the type of the reference electrode the measured potential may be different from the real potential at the reference electrode site. The real potential can be calculated from the measured potential by subtracting the potential of the reference electrode.

8 sense active line Electronic Loads Partial Cell Configuration EL101 This configuration may be used, if a certain part of a battery or fuel cell stack has to be investigated. sense power active ZAHNER elektrik line The DC potential applied must be greater or equal than the rest potential of the cell. Rest potential set potential cathode anode Depending on the type of the reference electrode the measured potential may be different from the real potential at the reference electrode site. The real potential can be calculated from the measured potential by subtracting the potential of the reference electrode. 4. Applications with an additional power supply EL300 power current limit 60 Ampere Volt potential coarse fine 80 This configuration may be used if the potential drop on the power lines is too high to reach the high-current test conditions. In addition it allows experiments on passive objects and batteries under charging conditions and electrolysis cell ZAHNER elektrik output Z The DC potential applied must be higher than the rest potential and must NOT EXCEED U max = +4 V. Rest potential set potential +4 V Built-in buffer amplifier The built-in buffer amplifier may be used to increase the potential range of the EL up to +/-12V. To select the buffer amplifier select any connection scheme 'with buffer' and set the corresponding gain factor. Using the gain factor GAIN=1 the EL will control -4V...+4V. Setting GAIN=0.33 the EL will control a dynamic potential range between -12V and +12V.

9 Electronic Loads -8- EL1000 The EL1000 external electronic load is an One-Quadrant-Potentiostat. This means that it is able to sink current but cannot source current. Typical applications are discharging experiments at batteries, accumulators and fuel cells. The EL-series potentiostats can be operated in both potentiostatic and galvanostatic modes, controlled by the Thales software. The output as well as the input are electrically isolated from ground. The EL1000 is air cooled. Measuring floating objects On the rear of the EL1000 you will find two connectors with a jumper. If the jumper is set, the signal ground is connected to ground via a 100 Ω protective resistor. The EL1000 power stage is NOT connected to signal ground. This is necessary, if the test object is floating (no metallic or electrolytic contact to ground). If any part of the cell is grounded, the jumper must be removed. silver banana jack (protective ground) black banana jack (system ground) When investigating floating objects the jumper must be set. Stand-alone mode Besides the usage of the EL1000 as an external one-quadrant potentiostat for an IM6/Zennium system, it also may be used in a stand-alone mode. The setup is done through an IM system or a PC (Currently not implemented, but will be added with a software update as soon as possible). Normally, the EL1000 should only be connected or disconnected to the IM system if both, the IM6/Zennium and the EL1000 are switched off. If you want to use the EL1000 as a stand-alone device, unselect it in the Test Sampling page of the Thales software (you may e.g. change the device number to the main potentiostat). The inactive device will hold its DC conditions such as DC potential and on/off status as long as it is selected anew or the system is shut off. Now you may unplug the EL1000 at the EPC40/41/42 connector. For regaining access to the EL1000, connect it to the EPC40/41/42 and select it in the Test Sampling page of the Thales software. Cell Connections It is important to know that EL potentiostats SINK current from the test object and therefore the cell connections must be as short and as thick as possible. Otherwise the measurements may be faulty and it may even seem that the EL is defective. It is also important to connect the test object with the correct polarity to the EL potentiostat. When being connected with the wrong polarity, the EL1000 has a protection circuit and will indicate polarity error. Therefore, we recommend to connect the sense inputs as described in fig. 1 (Full Cell Configuration). Call the Test Sampling page of the Thales software and check for the potential polarity. It must be negative. Now connect the power inputs according to fig.1 with the potentiostat switched off. The displayed potential must not change significantly when connecting the power lines. With the correct polarity the test object may be connected to the EL potentiostat in one of the following ways:

10 Electronic Loads Full Cell Configuration (Standard Kelvin Scheme) This configuration is used with active test objects like batteries, accumulators and fuel cells if a complete cell has to be investigated. The DC potential applied must be negative and greater or equal than the rest potential of the cell. Rest potential set potential 0 V 2.a. Half Cell Configuration Anode This configuration is used with active test objects like batteries, accumulators and fuel cells if only the anodic part of the cell has to be investigated. The DC potential applied must be greater or equal than the rest potential of the cell. Rest potential set potential Depending on the type of the reference electrode the measured potential may be different from the real potential at the reference electrode site. The real potential can be calculated from the measured potential by subtracting the potential of the reference electrode. 2.b. Half Cell Configuration - Cathode This configuration is used with active test objects like batteries, accumulators and fuel cells if only the cathodic part of the cell is to be investigated. The DC potential applied must be greater or equal than the rest potential of the cell. Rest potential set potential Depending on the type of the reference electrode the measured potential may be different from the real potential at the reference electrode site. The real potential can be calculated from the measured potential by subtracting the potential of the reference electrode.

11 Electronic Loads Partial Cell Configuration This configuration may be used, if a certain part of a battery or fuel cell stack has to be investigated. The DC potential applied must be greater or equal than the rest potential of the cell. Rest potential set potential Depending on the type of the reference electrode the measured potential may be different from the real potential at the reference electrode site. The real potential can be calculated from the measured potential by subtracting the potential of the reference electrode. 4. Applications with an additional DC sink This configuration may be used to sink more than 200A. The total amount of current from the EL1000 and the additional electronic load must not exceed 680A The DC potential applied must be greater or equal than the rest potential of the cell. Rest potential set potential The measured current must be positive I 0 The total current must NOT EXCEED 680A Example: Ensure to switch on the external load before switching on EL1000 Ensure to switch off EL1000 before switching off external load External DC load with 200A DC EL1000 with 10A DC and 5A amplitude Setup Testsampling EL1000: Galvanostat 210A DC, 5A amplitude

12 Electronic Loads Applications with an additional power supply (serial) This configuration may be used if the potential drop on the power lines is too high to reach the high-current test conditions. In addition it allows experiments on passive objects and batteries under charging conditions and electrolysis cell. The DC potential applied must be higher than the rest potential and must NOT EXCEED U max = +4 V. Rest potential set potential +4 V 5.a. Compensation of voltage drops "Zero Volt Option" 5.b. Electrolysis of fuel cells 5.c. Charging batteries

13 Electronic Loads Applications with an additional power supply (external input) This configuration allows experiments under following conditions: charging, SoC and discharging battieries fuel cell and electrolysis cell operation The 3rd party power supply operates as a galvanostat between positiv input and external input. When the EL1000 is turned off the device shows the external current flowing through the connected object (charging / electrolysis). The EL1000 is now able to sink "negative" currents. In this case only a part from the external current is drawn from the EL1000 and the rest flows through the object (charging / electrolysis). When turn on the EL1000 with zero current the external current from the 3rd party supply is flowing completely through the EL1000 and thus the object has zero current (SoC). Examples: When sinking more current with the EL1000 the additional current portion flows from the object (discharging / fuel cell). The external power supply operates as a galvanostat (setting current limit) and provides a higher potential as the object. EL1000 setting DC current: I < 0 charging battery / electrolysis cell I = 0 battery at state of charge I > 0 discharging battery / fuel cell operation

14 Electronic Loads -13- Built-in buffer amplifier The built-in buffer amplifier may be used to increase the potential range of the EL up to +/-100V. Select the potential range at the cell connection scheme page. The corresponding gain factor will be set automatically. The EL1000 will control -4V...+4V and -100V V. Never plug or unplug a EL1000 at the D-Sub9 connector at the backside of the device with the IM switched on. This may damage the system. It is recommended to fix the D-Sub9 connector with the screws to prevent accidental unplugging. If the EL1000 is unplugged while being selected in the Test Sampling page of the Thales software, it will shut off the current. This is a precaution to prevent undefined situations. The EL1000 need a warm-up time of about 15 minutes after power on. A calibration procedure is initiated automatically with the first access by the IM system. If you access a EL1000 during the warm-up time, please do a forced calibration (EIS menu -> Calibrate) after about 15 minutes. As the EL1000 is optimised for high current (some 100 ma to 200 A) an erroneous current display of some ma is acceptable.

15 Electronic Loads -14- Specifications EL101 EL300 EL1000 Operating modes pot/gal pot/gal pot/gal Potential range ±4V / ±12V ±4V / ±12V ±4V / ±100V Pot. accuracy 0.25% / ±2mV ±0.25% / ±2mV 0.1% / ±5mV Current range 0A 25A 0A 100A 0A 200A Current accuracy 0.25% / ±3mA 0.25% / ±3mA 0.25% / ±10mA Power dissipation T a T a 300W water-cooled T a Frequency range * 10µHz - 10kHz 10µHz - 10µHz - 10µHz - 10µHz - Impedance range 1µΩ - 1kΩ ** 1µΩ - 1kΩ ** 1µΩ - 1kΩ ** Amb. temperature 0 o C 25 o C 0 o C 25 o C 0 o C 25 o C System requirements IM6/Zennium + EPC42 IM6/Zennium + EPC42 IM6/Zennium + EPC42 or PC * Please note that the maximum frequency range only can be achieved with an IM6 or an Zennium equipped with EPC41 or EPC42. With an IM5d the maximum frequency range of external devices is 30kHz. ** Impedances below 1mΩ must be measured galvanostatically.