Supporting information for J. Org. Chem., 1989, 54(19), , DOI: /jo00280a008
|
|
|
- Poppy Harrell
- 5 years ago
- Views:
Transcription
1 Supporting information for J. Org. Chem., 1989, 54(19), , DOI: /jo00280a008 Terms & Conditions Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machinereadable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at Copyright 1989 American Chemical Society
2 10,13Cyclotrichothecene Rearrangement Mechanism of the Trichothecene Bruce B. Jarvis, M. Estela Alvarez, G. Wang, and Herman L. Ammon Supplementary Data 8.15Ether ii; mp C; 1HNMR (CDCl3)???0.87 (s, 3H, H14), 1.73 (dd, J 10.4 and 5.0 Hz, 1H, H7a), 1.78 (d, J 1.4 Hz, 3H, H16), 1.85 (d, J 10.4 Hz, 1H, H7B), 1.97 (ddd, J 3.3, 5.5, and 15.9 Hz, 1H, H3B), 2.68 (dd, J 8.0 and 15.9 Hz, 1H, H3a), 2.72 and 3.01 (AB, J 4.0 Hz, 1H each, H13), 3.25 (dd, J 1.2 and 8.8 Hz, 1H, H15B), 3.82 (d, J 4.0 Hz, 1H, H11), 3.85 (d, J 8.8 Hz, 1H, H15A), 3.89 (d, J 5.5 Hz, 1H, H2), 4.01 (dd, J 3.3 and 8.0 Hz, 1H, H4), 4.16 (dd, J 1.2 and 5.0 Hz, 1H, H8), 5.3 (dq, J 1.4 and 4.0 Hz, 1H, H10); 13CNMR (CDCl3)??? 6.0 (C14), 21.1 (C16), 32.2 (C7), 40.3 (C3), 46.1 (), 47.0 (C13), 51.0 (), 66.6 (), 68.5 (C15), 72.7 (), 75.2 (), 77.4 (C8), 79.5(), (), and (); HRMS (EI, 70 ev), calcd for C15H20O , found Anal, calcd. for C15H20O4: C, 68.16; H, Found: C, 68.29, H, Ether 2: glassy solid; 1HNMR (CDCl3) (s, 3H, H14), 1.55 (m, 3H, H3a and H7), 1.69 (s, 3H, H16), 2.11 (ddd, J 4.8, 7.3, and 10.3 Hz, 1H, H3B), 2.79 and 2.97 (AB, J 4.0 Hz, 1H each, H13), 3.67 (s, 2H, H15), 3.71 (dd, J 1.5 and 4.8 Hz, 1H, H2), 4.16 (d, J 4.3 Hz, 1H, H11), 4.38 (ddd, J 1.5, 3.6, and 7.3 Hz, 1H, H4), and 5.38 (d, J 4.3 Hz, 1H, H10); 13CNMR (CDCl3) (C14), 22.1 (C7), 23.3 (C16), 28.0 (C8), 37.3 (C3), 47.5 (C13), 50.9 (), 52.2 (), 65.6 (), 72.2 (), 78.4 (C15), 79.9 (), 87.9 (), (), and (); HRMS (CI, NH3), calcd for C15H20O3+H , found Anal, calcd. for C15H20O3: C, 72.55; H, Found: C, 72.70; H, 8.15.
3 4Verrucarol Tosylate: mp C; 1HNMR (CDCl3)??? 0.93 (s, 3H, H14), (m, 5H, H3B, H7,H8), 1.68 (s, 3H, H16), 2.23 (dd, J 15.6 and 7.8 Hz, 1H, H3a), 2.42 (s, 3H, ArCH3), 2.77 and 3.07 (AB, J 4 Hz, 2H, C13), (m, 4H, H2, H11,H15), 5.41 (d, J 5.5 Hz, H10), 5.86 (dd, J 3.5 and 8.0 Hz, H4), and 7.5 (AA'BB', 4H, phenyl); 13CNMR (CDCl3), 7.31 (C14), 21.3 (C7), 21.6 (ArCH3), 23.1 (C16), 28.0 (C8), 36.7 (C3), 44.2 (), 48.0 (C13), 49.2 (), 63.7 (), 65.1 (C15), 66.5 (), 78.8 (), 82.9 (), (), 127.8, 129.8, 134.5, (phenyl), and (); MS (C1, CH4), 421 (M++1). Anal. calcd. for 2H28O6S: C, 62.84; H, Found: C, 63.01; H, Cyclotrichothecene 3a: mp C; 1HNMR??? 1.20 (s, 3H, H14), 1.37 (dd, J 4.9 und 13.6 Hz, 1H, H13B), 1.53 (s, 3H, H16), 1.54 (m, 3H, H7 und H13A), 1.80 (dd, J 1.6 und 11.6 Hz, 1 H, H3a), (m, 2H, H10 and H3B), 3.65 (d, J 3.6 Hz, 1H, H11), 3.73 and 4.03 (AB, J 9.3 Hz, 1H each, H15), 3.87 (dd, J 1.6 and 4.5 Hz, 1 H, H2), 4.40 (d, J 8.0 Hz, 1H, H4); 13CNMR (CDCl3) (C14), 20.9 (C16), 26.3 (C7), 28.3 (C3), 29.6 (C8), 38.9 (C13), 42.8 (), 48.5 (), 49.9 (), 70.9 (), 77.6 (), 78.5 (C15), 78.9 (), 79.3 (), 81.7 (); HRMS (EI, 70 ev) calcd for C15H22O , found Anal, calcd. for C15H12O4: C, 67.65; H, Found: C, 67.80; H, Xray data for 3a: Crystals from dichloromethane; EnrafNonius CAD4 diffractometer, MoKa radiation (graphite monochromator,??? A, orthorhombic, P212121,Z 4; a (7), b (2), c (1), 1436 data measured to??? 25, 1373 unique data, 950I > 3???(I); calculations with TEXSAN system (TEXRAY Structure Analysis, version 2.0, Molecular Structure Corp., 3200 A Research Forest Drive, The Woodlands, TX 77381); structure solved with direct methods link MITHRIL; fullmatrix
4 leastsquares refinement, anisotropic temperature factors for C and O, isotropic terms for H; final R, wtd R 0.032, See attached Tables. Cyclotrichothecene 3b: Glassy solid; 1HNMR (CDCl3)??? 1.07 (s, 3H, H14), 1.20 (s, 3H, H16), (m, 4H, H13 and H7), 1.78 (dd, J 1.6 and 11.6 Hz, 1H, H3a), 2.24 (ddd, J 4.5, 8.0, and 11.6 Hz, 1H, H3B), 2.40 (m, 1H, H10), 3.12 (s, 3H, OCH3), 3.53 (d, J 3.6 Hz, 1H, H11), 3.68 and 3.98 (AB, J 8.9 Hz, 1H each, H15), 3.88 (dd, J 1.6 and 4.5 Hz, 1H, H2), 4.38 (d, J 8.0 Hz 1H, H4); HRMS (FAB, 1:1 glycerol: DMSO) calcd for C16H24O4+H C16H24O4: C, 68.54; H, Found C, 68.72; H, , found Anal, calcd. for Ether i: Glassy solid; 1HNMR (CDCl3)??? 1.16 (s, 3H, H14), 1.23 (m, 2H, H7), 1.55 (s, 3H, H16), 1.87 (ddd, J 8.4,11.0 and 13.8 Hz, 1H, H3B), 2.21 (ddd, J 1.8, 5.5, and 13.8 Hz, 1H, H3a), 3.32 (s, 3H, OCH3), 3.34 and 3.84 (AB, J 8.9 Hz, 1H each, H15), 3.65 and 3.73 (AB after D2O exchange, J 7.0 Hz, 1H each, H13), 3.96 (dd, J 5.5 and 11.0 Hz, H2), (m, 2H, H4 and H11), 5.27 (d, J 5.0 Hz, 1H, H10); HRMS (FAB, 1:1 glycerol: DMSO) calcd for C16H24O4+H , found Anal, calcd. for C16H24O4: C, 68.54; H Found C, 68.66; H, 8.73.
5 Xray data for 3a: Crystals from dichloromethane; EnrafNonius CAD4 diffractometer, MoKa radiation, graphite monochromator,??? 0,71069 A; orthorhombic, P212121; C19H30O3, MW 306.4, Z 4, PXray (7), g cm3; a b (2), c (1) A; 1436 data measured to???max of 25, 1373 unique data, 950 I??? 3???(I); crystallographic calculations with TEXSAN system (TEXRAY Structure Analysis, version 2.0, Molecular Structure Corp., 3200 Research Forest Drive, The Woodlnads, TX 77381); structure solved with MITHRIL (G. J. Gilmore, MITHRIL, A Computer Program for the Automatic Solution of Crystal Structures from Xray Data, Univ. of Glasgow, Scotland, 1983) direct methods link; fullmatrix leastsquares refinement with anisotropic temperature factors for C and O, isotropic terms for H; final R, wtd R 0.032, 0.033; final difference map peaks from e A3. See attached tables. Intramolecular Distances (A) for 3a atom atom distance atom atom distance O2 O2 O4 O7 O8 O8 C3 C15 C3 C (4) 1.452(4) 1.441(4) 1.420(4) 1.418(5) 1.438(5) 1.511(6) 1.533(5) 1.517(6) 1.541(5) 1.530(5) 1.533(5) C7 C8 C15 C7 C8 C16 C13 C (4) 1.532(5) 1.537(5) 1.539(5) 1.513(6) 1.518(5) 1.523(6) 1.530(5) 1.521(5) 1.537(5) 1.517(5)
6 Intramolecular Bond Angles (A) for 3a atom atom atom angle atom atom atom angle Cll ,8(3) C7 C (3 C (3) 04 C (3 02 C (3) 04 C ( (3) 04 CIO 104.3(3 C (3) C8 C (3 C (3) C8 CIO 109.7(3 08 C (4) C16 CIO 112.1( (3) Cll CIO 110.7(3 C (3) Cll C (3 C (3) CIO C (3 C (3) 02 Cll CIO 109.4(3 C (3) 02 Cll 111.8( (3) Cll 110.6( (3) 07 C ( (3) (3 Cll C (3) (3 Cll C (3) C (3 Cll 107.3(3) C (3 C15 C (3) 100.3(3 C (3) C13 CIO 110.3(3 C (3) 08 C (3 C8 C (3)
7 Table 1. Atom O2 O4 O7 O8 C3 C7 C8 C13 C14 C15 C16 H04 H07 H2A H3A H3B H4B H7A H7B H8A H8B H10 H11 H13A H13B H14A H14B H14C H15A H15B H16A H16B H16C Fractional coordinates and estimated standard deviations (in parentheses) for 3a X Y Z (4) (2) ( (4) (2) ( (4) (2) ( (4) (2) ( (6) (3) ( (8) (4) ( (7) (4) ( (5) (3) ( (5) (3) ( (6) (4) ( (6) (4) ( (5) (3) (? (6) (3) ( (5) (3) ( (5) (3) ( (6) (3) ( (6) (3) ( (7) (4) ( (8) (4) ( (5) (3) (2) (6) (4) (3) (5) (3) (2) (5) (3) (2) (6) (3) (2) (5) (3) (2) (5) (3) (2) (5) (3) (2) (5) (3) (2) (5) (3) (2) (5) (3) (2) (4) (3) (2) (5) (2) (2) (6) (3) (2) (5) (3) (2) (6) (3) (2) (5) (3) (2) (5) (3) (2) (6) (3) (3) (7) (4) (3) (6) (3) (3) (6) (3) (3)
8 Table 2. U values (Ang**2) and estimated standard deviations (in parentheses) for 3a ATOM U or U11 U22 U33 U12 U13 U23 O2 O4 O7 O8 C3 C7 C8 C13 C14 C15 C16 H04 H07 H2A H3A H3B H4B H7A H7B H8A H8B H10 H11 H13A H13B H14A H14B H14C H15A H15B 0.055(2) 0.063(2) 0.052(2) 0.070(2) 0.045(2) 0.077(4) 0.054(3) 0.034(2) 0.030(2) 0.031(2) 0.048(3) 0.043(2) 0.025(2) 0.035(2) 0.033(2) 0.026(2) 0.036(2) 0.049(3) 0.069(4) 0.06(2) 0.02(1) 0.020(8) 0.05(1) 0.05(1) 0.06(1) (1) 0.028( (1) (1) ( (1) 0.022( (1) (1) ( (2) 0.041( (2) (2) ( (2) 0.036( (2) (2) ( (2) 0.029( (2) (2) ( (3) 0.025( (3) (2) ( (2) 0.028( (2) (2) ( (2) 0.025( (2) (2) ( (2) ( (2) (2) ( (3) 0.036( (2) (2) ( (2) ( (2) (2) ( (2) 0.026( (2) (2) ( (2) 0.032( (2) (2) ( (2) 0.023( (2) (2) ( (2) 0.026( (2) (2) ( (2) 0.036( (2) (2) ( (2) 0.046( (2) (2) ( (3) 0.040( (2) (2) ( (3) 0.037( (3) (2) (2 H16A H16B H16C 0.07(2) 0.05(1) 0.05(1)
J. Am. Chem. Soc., 1996, 118(13), , DOI: /ja
J. Am. Chem. Soc., 996, 8(3), 3225-3232, DOI:0.02/ja9539756 Terms & Conditions Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society
Allylic and benzylic sp 3 C-H oxidation in water
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information Allylic and benzylic sp 3 C-H oxidation in water
Supplementary Figures
Supplementary Information Bottom-up synthesis of finite models of helical (n,m)-single-wall carbon nanotubes Shunpei Hitosugi, Waka Nakanishi, Takashi Yamasaki and Hiroyuki Isobe* Department of Chemistry,
Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Information Iron(II) Bromide-Catalyzed Oxidative Coupling of Benzylamines with ortho-substituted
Structure-Reactivity Relationships of Zwitterionic 1,3-Diaza-Claisen Rearrangements. Supporting Information
Structure-Reactivity Relationships of Zwitterionic 1,3-Diaza-Claisen Rearrangements Rachel A. Potter, Amy Bowser, Yanbo Yang and José S. Madalengoitia, * Joseph W. Ziller * Department of Chemistry, University
Electronic Supplementary Information
Electronic Supplementary Information Si-H activation of Hydrosilanes leading to Hydrido Silyl and Bis(silyl) Nickel Complexes Thomas Zell, a Thomas Schaub, a Krzysztof Radacki, a Udo Radius* a a Institut
Supplementary Figure S1. 19 F NMR spectra of the reaction of 5e with XeF 2 in toluene-d 8.
Supplementary Figure S1. 19 F NMR spectra of the reaction of 5e with XeF 2 in toluene-d 8. Supplementary Figure S2. 31 P NMR spectra of 5e and the reaction of 5e with XeF 2 in toluene-d 8. Supplementary
Novel Enzymatic Synthesis of 4-O-Cinnamoyl Quinic and Shikimic Acid Derivatives
Revised: May 003 Novel Enzymatic Synthesis of --Cinnamoyl Quinic and Shikimic Acid Derivatives Nuria Armesto, Miguel Ferrero, Susana Fernández, and Vicente Gotor* Departamento de Química rgánica e Inorgánica,
metal-organic papers Caesium sodium bis(formate) m388 Alcock et al. CsNa(CHO 2 ) 2 doi: /s Acta Cryst. (2006).
metal-organic papers Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Caesium sodium bis(formate) Nathaniel W. Alcock, Michael P. Wilson and P. Mark Rodger* Department of Chemistry,
Synthesis and their spectroscopic distinction of. benzonaphthonaphthyridines and its isomer
Synthesis and their spectroscopic distinction of benzonaphthonaphthyridines and its isomer Kolandaivel Prabha and Karnam Jayaramapillai Rajendra Prasad* Department of Chemistry, Bharathiar University Coimbatore,
Regioselective Heck Arylation of Unsaturated Alcohols by
Supporting Information for: Regioselective Heck Arylation of Unsaturated Alcohols by Palladium Catalysis in Ionic Liquid Jun Mo, Lijin Xu, Jiwu Ruan, Shifang Liu and Jianliang Xiao* Liverpool Centre for
The Title Goes Here with Each Initial Letter Capitalized
The Title Goes Here with Each Initial Letter Capitalized Author s Name 1,a),b) and Author s Name 2,3,c) 1 Replace this text with an author s affiliation (use complete addresses). Note the use of superscript
Supporting Information
Acid-Catalyzed Reactions of 3-Hydroxy-2-oxindoles with Electron-rich Substrates: Synthesis of 2-Oxindoles with All-Carbon Quaternary Center Lakshmana K. Kinthada, Santanu Ghosh, Subhadip De, Subhajit Bhunia,
Electronic Supplementary Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2016 Solid-state Inclusion of C 60 and C 70 in a Co-polymer Induced by Metal-Ligand Coordination
Total Synthesis of the Neoclerodane Diterpene Salvinorin A via an Intramolecular Diels Alder Strategy
Total Synthesis of the Neoclerodane Diterpene Salvinorin A via an Intramolecular Diels Alder Strategy Yuzhou Wang and Peter Metz* Fakultät Chemie und Lebensmittelchemie, Organische Chemie I, Technische
Table S1 Comparison of CypA observed Bragg data vs. calculated from Normal Modes.
Table S1 Comparison of CypA observed Bragg data vs. calculated from Normal Modes. Resolution (Å) R-factor CC 44.560-11.070 0.5713 0.4144 11.070-8.698 0.3325 0.6957 8.697-6.834 0.2987 0.7324 6.831-5.369
Supplementary Material (ESI) for Chemical Communications This journal is The Royal Society of Chemistry Electronic Supplementary Information
Electronic Supplementary Information Synthesis of the bis potassium salts of 5-hydroxy-3-oxo-pent-4-enoic acids and their use for the efficient preparation of 4-hydroxy-2H-pyran-2-ones and other heterocycles
Halogen-free water-stable aluminates as replacement for persistent fluorinated weakly-coordinating anions
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2014 Halogen-free water-stable aluminates as replacement for persistent fluorinated weakly-coordinating
EARTH MATERIALS OPTICS AND MINERALS
EARTH MATERIALS OPTICS AND MINERALS Wave Terms FREQUENCY (f) number of cycles per unit time [units = Hertz (Hz)] 1 Hz = 1 cycle/s T = 1/f; f = 1/T; T f = 1 Waves can coexist in the same space with other
SUPPORTING INFORMATION
Dual-Cavity Baskets Promote Encapsulation in Water in an Allosteric Fashion Shigui Chen, Makoto Yamasaki, Shane Polen, Judith Gallucci, Christopher M. Hadad and Jovica D. Badjić* Department of Chemistry
Supporting Information. for
Supporting Information for Copper Complexes for Fluorescence-Based NO Detection in Aqueous Solution Mi Hee Lim and Stephen J. Lippard Department of Chemistry, Massachusetts Institute of Technology, Cambridge,
$%&#!#$!!!#'((#!)*+"!!,!#*+- ) %() (. %( ) //. 0 1 ) (2.
!!"##! $%&#!#$!!!#'((#!)*+"!!,!#*+- ) %() (. %( ) //. 0 1 ) (2. / 3 /!. 4 5 5.. 0 )67 )" ) +-889:+ 5 7777777777 77777777 * )67* )" ).0; ((, ((
Rietveld refinements collection strategies!
Rietveld refinements collection strategies! Luca Lutterotti! Department of Materials Engineering and Industrial Technologies! University of Trento - Italy! Quality of the experiment! A good refinement,
Supplementary material
Supplementary material Supramolecular self assembled chlorophyll derivative fullerene donor - acceptor system for photoinduced charge separation; Zn pyro-pheophorbide a fulleronicotine dyad Jari Kavakka,
Rapid consecutive three-component coupling-fiesselmann synthesis of luminescent 2,4-disubstituted thiophenes and oligothiophenes
Rapid consecutive three-component coupling-fiesselmann synthesis of luminescent 2,4-disubstituted thiophenes and oligothiophenes Marco Teiber, and Thomas J. J. Müller* Institut für Organische Chemie und
Supporting information for the manuscript
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2019 Supporting information for the manuscript Facile N-functionalization and strong magnetic
Supporting Information. for. TEMPO-derived spin labels linked to the nucleobases. adenine and cytosine for probing local structural
Supporting Information for TEMPO-derived spin labels linked to the nucleobases adenine and cytosine for probing local structural perturbations in DNA by EPR spectroscopy Dnyaneshwar B. Gophane and Snorri
SUPPORTING INFORMATION
S1 SUPPORTING INFORMATION Cyclization of 1,6-enynes catalyzed by gold nanoparticles supported on TiO 2 : Significant changes in selectivity and mechanism, as compared to homogeneous Au-catalysis Charis
Properties of Light I
Properties of Light I Light definition Light Spectrum Wavelength in nm (1nm = 10-7 cm) Visible/White Light Cosmic Gamma X-Rays Ultra Violet Infra Red Micro Waves Radio Waves 1 Theory of Light Two complimentary
research communications Pd 20 Sn 13 revisited: crystal structure of Pd 6.69 Sn Chemical context 2. Structural commentary
research communications Pd 20 Sn 13 revisited: crystal structure of Pd 6.69 Sn 4.31 ISSN 2056-9890 Wilhelm Klein, Hanpeng Jin, Viktor Hlukhyy and Thomas F. Fässler* Technische Universität München, Department
X-ray Powder Diffraction
X-ray Powder Diffraction Chemistry 754 Solid State Chemistry Lecture #8 April 15, 2004 Single Crystal Diffraction Diffracted Beam Incident Beam Powder Diffraction Diffracted Beam Incident Beam In powder
Novel bi- and tridentate phosphane and thioether ligands derived from chiral α-hydroxy acids
Pergamon Tetrahedron: Asymmetry 10 (1999) 1207 1215 TETRAHEDRON: ASYMMETRY Novel bi- and tridentate phosphane and thioether ligands derived from chiral α-hydroxy acids Jens Christoffers and Ulrich Rößler
Three-component synthesis of polysubstituted pyrrole core containing heterocyclic scaffolds over magnetically separable nanocrystalline copper ferrite
Three-component synthesis of polysubstituted pyrrole core containing heterocyclic scaffolds over magnetically separable nanocrystalline copper ferrite Sanjay Paul, Gargi Pal, Asish R. Das* Department of
Finding Information. Summer Use the New Features. Markush Search
Use the New Features Summer 2010 This release of SciFinder provides a pathway to finding additional patent information via Markush searching. Other search and usability enhancements include automatic removal
Modular Synthesis of Naphtho-Thiophenes by Pd- Catalyzed Tandem Direct-Arylation/Suzuki- Coupling
Modular Synthesis of Naphtho-Thiophenes by Pd- Catalyzed Tandem Direct-Arylation/Suzuki- Coupling Norman Nicolaus, Patrick T. Franke and Mark Lautens* [*]Davenport Chemical Laboratories Department of Chemistry,
Supporting Information. One-pot four-component synthesis of pyrimidyl and. pyrazolyl substituted azulenes by glyoxylation
Supporting Information for One-pot four-component synthesis of pyrimidyl and pyrazolyl substituted azulenes by glyoxylation decarbonylative alkynylation cyclocondensation sequences Charlotte F. Gers, Julia
Supporting Information. Rapid access to unsymmetrical tolanes and alkynones by sequentially palladium catalyzed one pot processes
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2016 Supporting Information Rapid access to unsymmetrical tolanes and alkynones
Supplementary Information
Supplementary Information Supplementary Figure S1 The scheme of MtbHadAB/MtbHadBC dehydration reaction. The reaction is reversible. However, in the context of FAS-II elongation cycle, this reaction tends
FRET in Orthogonally Arranged Chromophores. Supporting Information
FRET in rthogonally Arranged Chromophores Heinz Langhals* a, Andreas Walter and Andreas J. Esterbauer a Eberhard Riedle* b and Igor Pugliesi b a Department of Chemistry, LMU University of Munich, Butenandtstraße
Electronic Supplementary Material for PCCP This journal is The Owner Societies 2005 EXPERIMENTAL SECTION
This journal is The wner Societies 00 EXPERIMETAL SECTI General Techniques: All reactions were carried out with dry, freshly distilled solvents under anhydrous conditions, unless otherwise stated. Tetrahydrofuran
16. CIF, CIFTAB and Electronic Publication
16. CIF, CIFTAB and Electronic Publication 16.1 CIF archive format The CIF format represents a major step forward in the archiving, publication and communication of crystallographic data. At last it is
Integrating Data with Publications: Greater Interactivity and Challenges for Long-Term Preservation of the Scientific Record
Integrating Data with Publications: Greater Interactivity and Challenges for Long-Term Preservation of the Scientific Record Brian McMahon International Union of Crystallography 5 Abbey Square Chester
Supporting Information for. Selective Double-Carbomagnesiation of Internal Alkynes Catalyzed by Iron-N-Heterocyclic Carbene
Supporting Information for Selective Double-Carbomagnesiation of Internal Alkynes Catalyzed by Iron-N-Heterocyclic Carbene Complexes: A Convenient Method to Highly Substituted 1,3-Dienyl Magnesium Reagents
MS-FINDER tutorial. Last edited in Aug 10, 2018
MS-FINDER tutorial Last edited in Aug 10, 2018 Abstract The purpose of metabolomics is to perform the comprehensive analysis for small biomolecules of living organisms. Gas chromatography coupled with
Stress and Texture by XRD Bob He, Bruker AXS
Stress and Texture by XRD Bob He, Bruker AXS Intensity Conventional X-ray Diffractometer Divergence slit Antiscatter slit Monochromator Bragg-Brentano Geometry. Scanning over range to collect XRD pattern.
Supporting Information for: 1: Kansas State University, Department of Chemistry, 213 CB Building, 1212 Mid-Campus
Supporting Information for: Insights from Theory and Experiment on the Photochromic spiro- Dihydropyrrolo-Pyridazine/Betaine System Amendra Fernando, Tej B. Shrestha,,2 Yao Liu, 3 Aruni P. Malalasekera,
Refinement. DLS-CCP4 Data Collection and Structure Solution Workshop December Diamond Light Source, Oxfordshire, UK
Refinement DLS-CCP4 Data Collection and Structure Solution Workshop December 13-20 2016 Diamond Light Source, Oxfordshire, UK Oleg Kovalevskiy Rob Nicholls okovalev@mrc-lmb.cam.ac.uk nicholls@mrc-lmb.cam.ac.uk
Supporting Information Treatment of Vinca minor Leaves with Methyl Jasmonate Extensively Alters the Pattern and Composition of Indole Alkaloids
Supporting Information Treatment of Vinca minor Leaves with Methyl Jasmonate Extensively Alters the Pattern and Composition of Indole Alkaloids Sara Abouzeid, Ulrike Beutling, Frank Surup, Fatma M. Abdel
Supporting Information for Efficient Two-Step Synthesis of Biodiesel from Greases
Supporting Information for Efficient Two-Step Synthesis of Biodiesel from Greases Helen L. Ngo,a,*, Nicholas A. Zafiropoulos,a, Thomas A. Foglia,*, Edward T. Samulski, and Wenbin Lin * U.S. Department
Table of Contents Overview...2 Selecting Post-Processing: ColorMap...3 Overview of Options Copyright, license, warranty/disclaimer...
1 P a g e ColorMap Post-Processing Plugin for OpenPolScope software ColorMap processing with Pol-Acquisition and Pol-Analyzer plugin v. 2.0, Last Modified: April 16, 2013; Revision 1.00 Copyright, license,
CLEAN ROOM PANEL - CRP5
RELIABLE MEASUREMENTS IN CLEAN ROOMS Measures differential pressure, humidity and temperature Designed specifically for clean rooms Removable humidity and temperature probes for simpler adjustment and
2-D D Symmetry. Symmetry (Part II) Point Group m 3 4. The set of symmetry operations that leave the appearance of the crystal structure
Symmetry (Part II) Lecture 6 Point Group The set of symmetry operations that leave the appearance of the crystal structure unchanged. There are 32 possible point groups (i.e., unique combinations of symmetry
C E R T I F I C A T E O F C O M P L I A N C E
C E R T I F I C A T E O F C O M P L I A N C E Certificate Number 20160301-E135493 Report Reference Issue Date E135493-A32-UL 2016-MARCH-01 Issued to: VICOR CORP 25 FRONTAGE RD ANDOVER MA 01810 This is
Brief Instructions. The MATLAB working directory should be populated with the following files:
MOF-FIT A Matlab routine for determining breathing angles and other crystal structure deformations of MOFs using a visual fit and a graphical user interface Brief Instructions The MATLAB working directory
Supporting Information. for. Naphthablins B and C, Meroterpenoids Identified from the Marine Sediment-Derived
Supporting Information for Naphthablins B and C, Meroterpenoids Identified from the Marine Sediment-Derived Streptomyces sp. CP26-58 Using HeLa Cell-Based Cytological Profiling Hana Martucci, Scott E.
cif_pd.dic 1 PD_BLOCK
cif_pd.dic 1 PD_BLOCK Dictionary name: cif_pd.dic Dictionary version: 1.0 Dictionary last updated: 1997-10-29 _pd_block_[pd] _pd_block_id is used to assign a unique id code to a data block. This code is
Quick Instruction. For EXAFS Data Analysis
Quick Instruction For EXAFS Data Analysis Using WinXAS, FEFF 7 and ATOMS Programs Farideh Jalilehvand Department of Chemistry University of Calgary e-mail: faridehj@ucalgary.ca Last updated: December 2002
Fundamentals of Rietveld Refinement II. Refinement of a Single Phase
Fundamentals of Rietveld Refinement II. Refinement of a Single Phase An Introduction to Rietveld Refinement using PANalytical X Pert HighScore Plus v3.0e Scott A Speakman, Ph.D. MIT Center for Materials
Crystal Quality Analysis Group
Crystal Quality Analysis Group Contents Contents 1. Overview...1 2. Measurement principles...3 2.1 Considerations related to orientation and diffraction conditions... 3 2.2 Rocking curve measurement...
ILI2511. ILI2511 Single Chip Capacitive Touch Sensor Controller. Specification ILI TECHNOLOGY CORP. Version: V1.4. Date: 2018/7/5
Single Chip Capacitive Touch Sensor Controller Specification Version: V1.4 Date: 2018/7/5 ILI TECHNOLOGY CORP. 8F., No.1, Taiyuan 2 nd St., Zhubei City, Hsinchu County 302, Taiwan (R.O.C.) Tel.886-3-5600099;
nacthe Gaerttner LINAC Center
Thermal Neutron Scattering Measurements and Analysis Y. Danon, E. Liu, C. Wendorff, K. Ramic Rensselaer Polytechnic Institute, Troy, NY, 12180 Kick-off Meeting: WPEC SG42, Thermal Scattering Kernel S(a,b):
SUPPORTING INFORMATION. Maltose Binding Protein Effectively Stabilizes the Partially. Closed Conformation of the ATP-binding Cassette Transporter
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2017 SUPPORTING INFORMATION Maltose Binding Protein Effectively Stabilizes the Partially
Supplementary Information
Supplementary Information Interferometric scattering microscopy with polarization-selective dual detection scheme: Capturing the orientational information of anisotropic nanometric objects Il-Buem Lee
Collect and Reduce Intensity Data -- APEX
Collect and Reduce Intensity Data -- APEX General Steps in Collecting Intensity Data Note that the steps outlined below are generally followed when using all modern automated diffractometers, regardless
BIOCLASS AND ICLASS SE BIOMETRIC READER COMPATIBILITY APPLICATION NOTE
BIOCLASS AND ICLASS SE BIOMETRIC READER COMPATIBILITY APPLICATION NOTE June 2017 hidglobal.com Copyright 2017 HID Global Corporation/ASSA ABLOY AB. All rights reserved. This document may not be reproduced,
1
In the following tutorial we will determine by fitting the standard instrumental broadening supposing that the LaB 6 NIST powder sample broadening is negligible. This can be achieved in the MAUD program
A range of CCT options available in 70CRI (4000K 5700K) 150mm length x 45mm width footprint designed for use with standard third party optics
ILLUMINATION LUXEON XR-TX High performance LED modules with extreme efficacy for robust lighting designs LUXEON XR-TX products are LED modules optimized for lighting applications requiring high efficacy
One-pot selective synthesis of a fullerene bisadduct for
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Electronic Supporting Information: One-pot selective synthesis of a fullerene bisadduct
CH-1107EX HDMI/CAT6 to Single CAT6 Extender
CH-1107EX /CAT6 to Single CAT6 Extender Operation Manual DISCLAIMERS The information in this manual has been carefully checked and is believed to be accurate. Cypress Technology assumes no responsibility
Ch8: Straight Line Graph. x f(x) p 0.5 q 2 4 R 16. (a) Find the values of p, q and r. [3]
![Ch8: Straight Line Graph. x f(x) p 0.5 q 2 4 R 16. (a) Find the values of p, q and r. [3]](/thumbs/78/77995389.jpg "Ch8: Straight Line Graph. x f(x) p 0.5 q 2 4 R 16. (a) Find the values of p, q and r. [3]")
Ch8: Straight Line Graph. Answer the whole of this question on a sheet of graph paper. The table gives values of f() =, for 4. 0 3 4 f() p 0.5 q 4 R 6 (a) Find the values of p, q and r. [3] Using a scale
3D Printing: Chemistry and Crystal Structures
3D Printing: Chemistry and Crystal Structures Ian Bruno - Director, Strategic Partnerships The Cambridge Crystallographic Data Centre @ijbruno @ccdc_cambridge Science of 3D Printing SLA 2015 Annual Conference,
NVR-CV. Network Video Recorder Hot-Swappable Tray for 3.5 HDD x 4 or 2.5 HDD x 4 Gigabit Ethernet x 2 COM x 2, USB2.0 x 6. VGA x 1, DVI-D x 1
Netw ork Video Recorder N V R - CV Network Video Recorder Hot-Swappable Tray for 3.5 HDD x 4 or 2.5 HDD x 4 Gigabit Ethernet x 2 COM x 2, USB2.0 x 6 VGA x 1, DVI-D x 1 Manual 1st Ed. Oct. 2013 Copyright
Supporting Information
Electronic upplementary Material (EI) for RC dvances. This journal is The Royal ociety of Chemistry 204 upporting Information for ynthesis of thiazolidines via regioselective addition of unsymmetric thioureas
Application of CAD/CAE/CAM Technology in Plastics Injection Mould Design and Manufacture. Ming He Dai,Zhi Dong Yun
Advanced Materials Research Vols. 399-401 (2012) pp 2271-2275 Online available since 2011/Nov/22 at www.scientific.net (2012) Trans Tech Publications, Switzerland doi:10.4028/www.scientific.net/amr.399-401.2271
Opto Proximity Switches
SIMATIC PXO0 K form Accessories Operating mode Diffuse Retroreflective Thru-beam Sensor for plastic optical fibers Sensing range cm 10 via potentiometer) 0 via potentiometer) 100 via potentiometer) Depends
Structure Solution and Refinement with OLEX2
Structure Solution and Refinement with OLEX2 By Carla Slebodnick Department of Chemistry, Virginia Tech This version: 29 July 2014 (software version Olex2-1.2.5, Compilation Info: 2014.07.22 svn.r2960
Cambridge International Examinations Cambridge International General Certificate of Secondary Education
Cambridge International Examinations Cambridge International General Certificate of Secondary Education * 6 2 1 2 8 9 0 3 0 2 * MATHEMATICS 0580/22 Paper 2 (Extended) May/June 2016 1 hour 30 minutes Candidates
Structural Refinement based on the Rietveld Method. An introduction to the basics by Cora Lind
Structural Refinement based on the Rietveld Method An introduction to the basics by Cora Lind Outline What, when and why? - Possibilities and limitations Examples Data collection Parameters and what to
Structural Refinement based on the Rietveld Method
Structural Refinement based on the Rietveld Method An introduction to the basics by Cora Lind Outline What, when and why? - Possibilities and limitations Examples Data collection Parameters and what to
BABA B F C FINE CHEMICALS. Product List. Baba Fine Chemicals
BABA B F C FINE CHEMICALS Product List Baba Fine Chemicals (IS 9001 : 2008 Certified) D-119, EXPRT PRMTIN INDUSTRIAL PARK (EPIP), SITE-5, INDUSTRIAL AREA, KASNA, GREATER NIDA, GAUTAM BUDH NAGAR-201306
Rietveld-Method part I
Rietveld-Method part I Dr. Peter G. Weidler Institute of Functional Interfaces IFG 1 KIT 10/31/17 The Research University in the Helmholtz Association Name of Institute, Faculty, Department www.kit.edu
Rhodium- and Non-Metal-Catalyzed Approaches for the Conversion of Isoxazol-5-ones to 2,3-Dihydro-6H-1,3- Oxazin-6-ones
Supporting Information Rhodium- and Non-Metal-Catalyzed Approaches for the Conversion of Isoxazol-5-ones to 2,3-Dihydro-6H-1,3- Oxazin-6-ones Igor D. Jurberg a,b,* and Huw M. L. Davies a,* a Department
C E R T I F I C A T E O F C O M P L I A N C E
C E R T I F I C A T E O F C O M P L I A N C E Certificate Number 20171128-E135493 Report Reference Issue Date E135493-A36-UL 2017-NOVEMBER-28 Issued to: VICOR CORP 25 FRONTAGE RD ANDOVER, MA 01810-5424
Installation of the ACD/Labs Online Add-in to ChemDraw and ISIS/Draw
Installation of the ACD/Labs Online Add-in to ChemDraw and ISIS/Draw Version 8.0 Robin Martin and David Fung Advanced Chemistry Development, Inc. Toronto, ON, Canada www.acdlabs.com Introduction ACD/Labs
Fast, Intuitive Structure Determination V: Structure Refinement and Report Generation. January 28, 2014
Fast, Intuitive Structure Determination V: Structure Refinement and Report Generation January 28, 2014 Welcome Dr. Michael Ruf Product Manager Crystallography Bruker AXS Inc. Madison, WI, USA Bruce C.
Thursday 19 June 2014 Morning
F Thursday 19 June 2014 Morning GCSE METHODS IN MATHEMATICS B392/01 Methods in Mathematics 2 (Foundation Tier) *3053239230* Candidates answer on the Question Paper. OCR supplied materials: None Other materials
Tuesday 22 January 2013 Afternoon
F Tuesday 22 January 2013 Afternoon GCSE METHODS IN MATHEMATICS B392/01 Methods in Mathematics 2 (Foundation Tier) * B 3 1 6 9 5 0 1 1 3 * Candidates answer on the Question Paper. OCR supplied materials:
File E Project 93ME39941, Issued: November 29, 1993 New: April 26, 2006 REPORT COMPONENT - POWER SUPPLIES. For Use In
File E156996 Project 93ME39941, Issued: November 29, 1993 New: April 26, 2006 REPORT On COMPONENT - POWER SUPPLIES For Use In INFORMATION TECHNOLOGY EQUIPMENT Vicor Corp. Andover, MA Copyright 1993, Underwriters
ACS EXAM STUDY GUIDE PDF
ACS EXAM STUDY GUIDE PDF - Are you looking for acs exam study guide Books? Now, you will be happy that at this time acs exam study guide PDF is available at our online library. With our complete resources,
Introduction to Mercury
Introduction to Mercury The Cambridge Crystallographic Data Centre (CCDC) distributes Mercury, which is a program that can be used to view and analyze crystal structure data. We will be using it over the
NMR INSTRUMENT INSTRUCTIONS: Safety and Sample Preparation
NMR INSTRUMENT INSTRUCTIONS: Safety and Sample Preparation The GVSU chemistry department owns 2 NMR spectrometers. A JEOL Eclipse 300 MHz and a Varian Inova 400 MHz. Due to their strong, constant magnetic
research papers CRYSTMET: a database of the structures and powder patterns of metals and intermetallics 1. Introduction
Acta Crystallographica Section B Structural Science ISSN 0108-7681 CRYSTMET: a database of the structures and powder patterns of metals and intermetallics Peter S. White, a * John R. Rodgers b and Yvon
MILLER INDICES AND SYMMETRY CONTENT: A DEMONSTRATION USING SHAPE, A COMPUTER PROGRAM FOR DRAWING CRYSTALS
MILLER INDICES AND SYMMETRY CONTENT: A DEMONSTRATION USING SHAPE, A COMPUTER PROGRAM FOR DRAWING CRYSTALS Michael A. Velbel Department of Geological Sciences 206 Natural Science Building Michigan State
Fast, Intuitive Structure Determination II: Crystal Indexing and Data Collection Strategy. April 2,
Fast, Intuitive Structure Determination II: Crystal Indexing and Data Collection Strategy April 2, 2013 1 Welcome I I Dr. Michael Ruf Product Manager Crystallography Bruker AXS Inc. Madison, WI, USA Bruce
Complete the following to the best of your ability. DO NOT use a calculator. Show all work.
Name: Summer Work Algebra 1 2016 Complete the following to the best of your ability. DO NOT use a calculator. Show all work. 1. You have a 35 degree angle. Determine the complementary angle AND the supplementary
How to Create a Reaction Answer Set
How to Create a Reaction Answer Set Find all relevant reactions based on criteria you specify Search the world s largest, publicly available source of reactions and quickly find highly relevant results,
NHD WG-BxTGH-VZ#-3VR
NHD-320240WG-BxTGH-VZ#-3VR Graphic Liquid Crystal Display Module NHD- Newhaven Display 320240-320 x 240 Pixels WG- Display Type: Graphic Bx- Model T- White LED Backlight G- STN - Gray H- Transflective,
Formula for the asymmetric diffraction peak profiles based on double Soller slit geometry
REVIEW OF SCIENTIFIC INSTRUMENTS VOLUME 69, NUMBER 6 JUNE 1998 Formula for the asymmetric diffraction peak profiles based on double Soller slit geometry Takashi Ida Department of Material Science, Faculty
Supplementary Table 1. Data collection and refinement statistics
Supplementary Table 1. Data collection and refinement statistics APY-EphA4 APY-βAla8.am-EphA4 Crystal Space group P2 1 P2 1 Cell dimensions a, b, c (Å) 36.27, 127.7, 84.57 37.22, 127.2, 84.6 α, β, γ (
Symmetry. Motif: the fundamental part of a symmetric design that, when repeated, creates the whole pattern
Symmetry Motif: the fundamental part of a symmetric design that, when repeated, creates the whole pattern Operation: some act that reproduces the motif to create the pattern Element: an operation located