ANNUAL GROUNDWATER MONITORING REPORT FOR YEAR 2013 LAS CRUCES FOOTHILLS LANDFILL LAS CRUCES, NEW MEXICO
|
|
- Tabitha Howard
- 5 years ago
- Views:
Transcription
1 ANNUAL GROUWATER MONITORING REPORT FOR YEAR 2013 LAS CRUCES FOOTHILLS LAFILL LAS CRUCES, NEW MEXICO prepared by Annie M. McCoy, CPG Roger Peery, CPG JOHN SHOMAKER & ASSOCIATES, INC. Water Resource and Environmental Consultants 2611 Broadbent Parkway NE Albuquerque, New Mexico prepared for City of Las Cruces Utilities Division New Mexico April 2014
2 SECO SEMI-ANNUAL GROUWATER MONITORING REPORT FOR YEAR 2013 LAS CRUCES FOOTHILLS LAFILL LAS CRUCES, NEW MEXICO prepared by Annie M. McCoy, CPG Roger Peery, CPG JOHN SHOMAKER & ASSOCIATES, INC. Water-Resource and Environmental Consultants 2611 Broadbent Parkway NE Albuquerque, New Mexico prepared for Las Cruces Utilities, New Mexico April 3, 2014
3 JSAI ii SECO SEMI-ANNUAL GROUWATER MONITORING REPORT FOR YEAR 2013, LAS CRUCES FOOTHILLS LAFILL, LAS CRUCES, NEW MEXICO EXECUTIVE SUMMARY At Las Cruces Foothills Landfill, monitor wells MW-1 through MW-4 have been sampled at least 25 times since 1999, MW-5 through MW-7 have been sampled at least 17 times since 2003, and MW-8 and MW-9 have been sampled 7 times since 2010, establishing baseline conditions and defining the extent of groundwater contamination at the site based on Assessment Monitoring Levels (AMLs) of constituents of concern. The primary constituents of concern are PCE, TCE, methylene chloride, and trichlorofluoromethane. The occurrences of PCE, TCE, methylene chloride, and trichlorofluoromethane in monitor wells are likely related to leachate derived from Las Cruces Foothills Landfill. Contaminant transport mechanisms appear to be active in the vadose zone, and controlled by a clay-rich horizon that lies beneath Las Cruces Foothills Landfill. The driving force for contaminant transport in groundwater is the hydraulic gradient. Downgradient contaminant migration in the groundwater is limited by a relatively flat hydraulic gradient west of the Jornada Horst, and historical PCE and TCE concentration trends in downgradient monitor wells MW-5 and MW-6 do not indicate that the plume is moving. In 2013, monitor wells MW-1 through MW-9 were sampled in June 2013, and MW-1, MW-2, MW-3, MW-4, and MW-7 were sampled in December For monitor wells that were sampled in both June and December, parameter concentrations varied little between the two sampling events and in some cases, concentrations were slightly lower in December. Distribution of PCE and TCE concentrations detected in the groundwater monitoring network are illustrated on Figures 4 and 7. The nature and extent of groundwater contamination have been determined by the monitoring network. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
4 JSAI iii CONTENTS page EXECUTIVE SUMMARY... ii 1.0 INTRODUCTION Background Information Previous Site Reports Prepared by JSAI MONITOR WELLS PURGING A WATER-LEVEL MEASUREMENTS GROUWATER SAMPLING Well Purging Sampling Monitor Wells MW-1 through MW RESULTS Direction of Groundwater Flow and Hydraulic Gradient Background and Baseline Concentrations Summary of Parameters Exceeding the Assessment Monitoring Level (AML) Historical PCE Concentrations PCE Concentrations Historical and 2013 TCE Concentrations Historical and 2013 Methylene Chloride Concentrations Historical and 2013 Trichlorofluoromethane Concentrations Historical and 2013 Total Phenolics Concentrations Historical and 2013 Total Iron Concentrations Additional Parameters Detected in Monitor Well MW NATURE A EXTENT OF GROUWATER CONTAMINANTS Sources of PCE, TCE, and Methylene Chloride Sources of Contaminants Detected at Assessment Monitor Wells MW-8 and MW PCE TDS and chloride CONTAMINANT TRANSPORT MECHANISMS CONCLUSIONS A RECOMMEATIONS REFERENCES...21 JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
5 JSAI iv TABLES page Table 1. Average depth to water and water column, screen interval, pump setting, and pump type installed in monitor wells MW-1 through MW-7, Las Cruces Foothills Landfill, Las Cruces, New Mexico... 5 Table 2. Average depth to water and water column, screen interval, pump setting, and pump type installed in assessment monitor wells MW-8 and MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico... 6 Table 3. Pre-sampling event purging schedule for 2013 sampling events at monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico... 7 Table 4. Water-level measurements for 2013 sampling events at monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico... 8 Table 5. Summary of parameters that were detected above the AML in monitor wells at Las Cruces Foothills Landfill, 2013, Las Cruces, New Mexico JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
6 JSAI v ILLUSTRATIONS (follow text) Figure 1. Aerial photograph showing locations of Las Cruces Foothills Landfill, monitor wells, groundwater elevation contours, and direction of groundwater flow in June Figure 2. Aerial photograph showing locations of Las Cruces Foothills Landfill, monitor wells, groundwater elevation contours, and direction of groundwater flow in December Figure 3. Graphs showing water-level elevations versus time for monitor wells MW-1, MW-2, MW-3, MW-4, MW-5, MW-6, MW-7, MW-8, and MW-9, Las Cruces Foothills Landfill, New Mexico. Figure 4. Graph showing PCE concentrations versus time for monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, New Mexico. Figure 5. Site map showing concentration contours of PCE in groundwater, June 25 and 26, 2013, Las Cruces Foothills Landfill, New Mexico. Figure 6. Site map showing concentration contours of PCE in groundwater, December 19, 2013, Las Cruces Foothills Landfill, New Mexico. Figure 7. Graph showing TCE concentrations versus time for monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, New Mexico. Figure 8. Site map showing concentration contours of TCE in groundwater, June 25 and 26, 2013, Las Cruces Foothills Landfill, New Mexico. Figure 9. Site map showing concentration contours of TCE in groundwater, December 19, 2013, Las Cruces Foothills Landfill, New Mexico. Figure 10. Graph showing methylene chloride concentrations versus time for monitor wells MW-2, MW-4, and MW-7, Las Cruces Foothills Landfill, New Mexico. Figure 11. Graph showing trichlorofluoromethane concentrations versus time for monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, New Mexico. Figure 12. Graph showing total iron concentrations versus time for monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, New Mexico. Figure 13. Piper diagram showing hydrogeochemical classification of groundwater sampled between December 2005 and 2013 at Las Cruces Foothills Landfill monitor wells, and geothermal groundwater in the area, Las Cruces, New Mexico. Figure 14. Aerial photograph showing Las Cruces Foothills Landfill monitor wells and groundwater elevation contours in December Figure 15. Aerial photograph showing locations of existing monitor wells, faults in the subsurface, line of schematic geologic cross-section A-A, and bedrock high, Las Cruces Foothills Landfill, New Mexico. Figure 16. West to east hydrogeologic cross-section, Las Cruces Foothills Landfill, New Mexico. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
7 JSAI vi APPEICES (follow illustrations) Appendix A. Summary of water-level measurements from monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico Appendix B. Baseline and background monitoring data for monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico Appendix C. Copies of laboratory reports for the June 25 and 26, 2013 and December 19, 2013 sampling events. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
8 JSAI vii ABBREVIATIONS AML BLM CAL DBCP EDB EPA F Fig(s). ft ft amsl ft bgl ft bmp ft/ft gpm gw GWPS GWQB JSAI mg/l MW NMED NMSU PCB PCE PQL PSTB PVC SWB TCE USGS VOCs assessment monitoring level Bureau of Land Management corrective action level 1,2-dibromo-3-chloropropane ethylene dibromide Environmental Protection Agency degrees Fahrenheit Figure(s) feet/foot feet above mean sea level feet below ground level feet below measuring point feet per foot gallons per minute groundwater groundwater protection standard Ground Water Quality Bureau John Shomaker & Associates, Inc. milligrams per liter monitor well New Mexico Environment Department New Mexico State University polychlorinated biphenyl tetrachloroethene practical quantitation limit petroleum storage tank bureau polyvinyl chloride Solid Waste Bureau trichloroethene U.S. Geological Survey volatile organic compounds JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
9 JSAI SECO SEMI-ANNUAL GROUWATER MONITORING REPORT FOR YEAR 2013, LAS CRUCES FOOTHILLS LAFILL, LAS CRUCES, NEW MEXICO 1.0 INTRODUCTION Las Cruces Foothills Landfill, owned and operated by the City of Las Cruces, has been undergoing site closure. The City of Las Cruces Utilities Department contracted with John Shomaker & Associates, Inc. (JSAI) to oversee groundwater monitoring activities to fulfill the requirements of the New Mexico Environment Department Solid Waste Bureau (NMED/SWB) regulations (NMAC ). Presented in this report are the following: Results of the year 2013 sampling events (monitor wells MW-1 through MW-9 on June 25 and 26, 2013; MW-1 through MW-4, and MW-7, on December 19, 2013), and summary of past sampling. Background values for each constituent from upgradient monitor well MW-3 calculated using analytical results from all five 1999 sampling events, and the May 2000 sampling event. Baseline values for each constituent from monitor wells MW-1, MW-2, MW-3, and MW-4, calculated using analytical results from all 1999 sampling events, and the May 2000 sampling event. Baseline values for each constituent from monitor wells MW-5, MW-6, and MW-7, calculated using analytical results from all 2003 sampling events, and the December 2004 sampling event. Baseline values for each constituent from monitor wells MW-8 and MW-9, calculated using analytical results from the December 2010 sampling event, and all 2011 sampling events. Demonstration of source for constituents detected above the groundwater protection standard (GWPS) or assessment monitoring level (AML). Recommended strategy for continued monitoring requirements. Las Cruces Foothills Landfill is located east of Las Cruces city limits in Section 11 of Township 23 South, Range 2 East, at the east end of East Lohman Avenue (Fig. 1).
10 JSAI Background Information Las Cruces Foothills Landfill was in operation for approximately 15 years, from 1980 to There are no precise records of volume and types of waste deposited at the landfill, although, the fill material is approximately 40 ft below current surface grade and consists of household and construction waste. There are no records of hazardous waste delivered to this landfill. The landfill has been capped with a low hydraulic conductivity protective cover and recontoured. Currently, the landfill has a groundwater monitoring system consisting of nine monitor wells (MW-1 through MW-9). The first groundwater monitor well, MW-1, was installed in Monitor wells MW-2, MW-3, and MW-4 were installed during January 1999, and MW-5, MW-6, and MW-7 were installed during March and April 2003, to fulfill the requirements of 20 NMAC 9.1 Part 1 Subpart VIII, Section 802. Monitor wells MW-8 and MW-9 were installed in September Monitor well locations are shown on Figure 1. The City equipped MW-1, MW-2, MW-3, and MW-4 with dedicated pumps prior to the June 2001 sampling event in order to reduce the opportunity for contamination to be introduced into the wells during the purging and sampling process. Monitor wells MW-5, MW-6, and MW-7 were equipped with dedicated pumps prior to their first sampling event in July 2003, and MW-8 and MW-9 were equipped with dedicated pumps prior to their first sampling event in December The depth to groundwater beneath the landfill is approximately 400 ft, and the climate is considered semi-arid to arid with approximately 9.27 inches of precipitation per year (New Mexico State University (NMSU) weather station, period of record 1959 to 2012). The evaporation rate is almost 10 times the precipitation rate. The type of material beneath the landfill consists of semi-consolidated to very well-consolidated sand, silt, and clay. Observations during monitor-well drilling and analysis of geophysical logs from MW-2, located at the west end (downgradient) of the landfill, indicated a strange odor in the drilling fluid when drilling at a depth of 455 feet below ground level (ft bgl). JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
11 JSAI Previous Site Reports Prepared by JSAI JSAI prepared the report Results from installation of ground-water monitoring system, and proposed ground-water monitoring plan, Las Cruces Landfill, Las Cruces, New Mexico (Finch, 1999) for the City of Las Cruces in support of landfill closure documentation required by the NMED/SWB. The Finch (JSAI, 1999) report describes details about the installation of the groundwater monitoring system, the hydrogeologic setting, and the groundwater monitoring plan (to fulfill requirements of 20 NMAC 9.1 Part 1 Subpart VIII, Section 803.A through E). The NMED/SWB approved the proposed groundwater monitoring plan on May 10, The detection-monitoring program was completed, and baseline and background concentrations were established for monitor wells MW-1 through MW-4. The NMED/SWB provided written approval of a semi-annual sampling schedule and alternate parameter list for monitor wells MW-1 through MW-4 in July The NMED/SWB provided written approval of an annual sampling schedule for MW-1 through MW-7 and alternate parameter list in February In December 2008, MW-1 through MW-7 were sampled for all parameters in the Groundwater Monitoring Parameter List Subsections A through C (NMAC ). The NMED/SWB provided written approval of an alternate parameter list for MW-1 through MW-7 in October In April 2012, the NMED/SWB provided written approval of the City s request to not sample MW-1 and MW-2 in 2012, as they are directly upgradient of MW-5 and MW-6 and may be redundant for monitoring purposes. The groundwater monitoring plan was amended in March 2009 based on the installation of three additional monitor wells in 2003, sampling methods developed with dedicated submersible pumps in each monitor well, previously-approved alternate sampling schedules and parameter lists, and the NMED/SWB request to collect a vadose-zone gas sample from MW-7. JSAI prepared the following groundwater monitoring reports for the City of Las Cruces, which were submitted to the NMED/SWB: Annual ground-water monitoring report for year 2000, Las Cruces Landfill, Las Cruces, New Mexico (Peery and Armour, 2001) Annual ground-water monitoring report for year 2001, Las Cruces Landfill, Las Cruces, New Mexico (Peery and McCoy, 2002) Annual ground-water monitoring report for year 2002, Las Cruces Landfill, Las Cruces, New Mexico (Peery and McCoy, 2003) Annual ground-water monitoring report for year 2003, Las Cruces Landfill, Las Cruces, New Mexico (Peery and McCoy, 2004) JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
12 JSAI 4 Annual ground-water monitoring report for year 2004, Las Cruces Landfill, Las Cruces, New Mexico (Peery and McCoy, 2005) Annual ground-water monitoring report for year 2005, Las Cruces Landfill, Las Cruces, New Mexico (McCoy and Peery, 2006) Annual ground-water monitoring report for year 2006, Las Cruces Landfill, Las Cruces, New Mexico (McCoy and Peery, 2007; an amendment letter for monitor well MW-4, which was sampled late due to a pump problem, was submitted to NMED/SWB on August 6, 2007) Annual ground-water monitoring report for year 2007, Las Cruces Landfill, Las Cruces, New Mexico (McCoy and Peery, 2008) Annual groundwater monitoring report for year 2008, and proposed reduced parameter list, Las Cruces Foothills Landfill, Las Cruces, New Mexico (McCoy and Peery, 2009) Annual groundwater monitoring report for year 2009, Las Cruces Foothills Landfill, Las Cruces, New Mexico (McCoy and Peery, 2010) Annual groundwater monitoring report for year 2010, Las Cruces Foothills Landfill, Las Cruces, New Mexico (McCoy and Peery, 2011) Annual groundwater monitoring report for year 2011, Las Cruces Foothills Landfill, Las Cruces, New Mexico (McCoy and Peery, 2012) Annual groundwater monitoring report for year 2012, Las Cruces Foothills Landfill, Las Cruces, New Mexico (McCoy and Peery, 2012) First semi-annual groundwater monitoring event of the 2013 monitoring period for Las Cruces Foothills Landfill (letter report from A. McCoy to J. Dyer, NMED/SWB, Permitting Section, September 17, 2013) 2.0 MONITOR WELLS Monitor wells MW-1 through MW-7 were completed to depths ranging from 340 to 464 ft bgl along the western, eastern, and southern perimeters of Las Cruces Foothills Landfill, and within 1,000 ft of the western and southern perimeters (Fig. 1). The monitor wells have 20- to 60-ft screen intervals that either span the water table or are below the water table (Table 1). Dedicated submersible pumps manufactured by Grundfos were installed in MW-1, MW-2, MW-3, and MW-4 in June 2001, and in MW-5, MW-6, and MW-7 in June Drop-pipes for MW-1, MW-2, MW-5, MW-6, and MW-7 consist of 3/4-inch diameter, schedule 40 stainless steel. Stainless steel drop-pipe was used for these wells because of the high temperature of the groundwater. Drop-pipes for MW-3 and MW-4 consist of 1-inch diameter, schedule 80 PVC. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
13 JSAI 5 Table 1. Average depth to water and water column, screen interval, pump setting, and pump type installed in monitor wells MW-1 through MW-7, Las Cruces Foothills Landfill, Las Cruces, New Mexico monitor well average depth to water, ft bmp well depth, ft bgl average water column, ft screen interval, ft bgl schd. 40 PVC casing diameter (OD), in. pump setting, ft bgl Grundfos pump MW (20) SQE10C-340NE MW (40) SQE10C-340NE MW (40) SQE05B-290NE MW (40) SQE10C-340NE MW (60) Redi-Flo3-380 MW (60) Redi-Flo3-380 MW (60) Redi-Flo3-380 ft bmp - feet below measuring point ft bgl - feet below ground level OD - outside diameter Assessment monitor wells MW-8 and MW-9 were completed to depths of 430 ft bgl and 415 ft bgl, respectively, in September 2010 to verify the limits of Las Cruces Foothills Landfill contaminant plume to the south and west of the landfill. Assessment monitor well MW-8 was completed about 1,600 ft southeast of MW-7, and MW-9 was completed about 1,700 ft west of MW-6 (Fig. 1). The monitor wells have 60-ft screen intervals that either span the water table or are below the water table (Table 2). Dedicated submersible pumps manufactured by Grundfos were installed in MW-8 and MW-9 in December Drop-pipes for MW-8 and MW-9 consist of 3/4-inch diameter, schedule 40 stainless steel. Stainless steel drop-pipe was used for these wells because of the high temperature of the groundwater. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
14 JSAI 6 Table 2. Average depth to water and water column, screen interval, pump setting, and pump type installed in assessment monitor wells MW-8 and MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico monitor well average depth to water, ft bmp well depth, ft bgl average water column, ft screen interval, ft bgl schd. 80 PVC casing diameter (OD), in. pump setting, ft bgl Grundfos pump MW (60) SQE-410 MW (60) SQE-410 ft bmp - feet below measuring point ft bgl - feet below ground level OD - outside diameter 3.0 PURGING A WATER-LEVEL MEASUREMENTS Due to low yield and slow rate of recovery, monitor wells MW-1 through MW-7 were purged about 1 week prior to sampling (Table 3). Additional purging of these wells was performed on the day of sampling to the extent possible based on drawdown. Due to the effects of the extremely high-temperature groundwater on the operation of the pump, it takes several hours to purge MW-8 while allowing the pump to cool for 20-minute intervals. For this reason, MW-8 was also purged about 1 week prior to sampling. Monitor well MW-9 produces sufficient water to be purged immediately prior to sampling. Water-level measurements were made prior to purging the wells in June and December Measurements were made to the nearest 0.01 ft with a wire-line sounder. Water-level measurements were referenced from the top of casing at a labeled measuring point. Waterlevel measurements for the year 2013 are summarized in Table 4, and past water-level measurements are presented in Appendix A. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
15 JSAI 7 Table 3. Pre-sampling event purging schedule for 2013 sampling events at monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico monitor well date purged pumping rate during purging, gpm duration of purging, min MW-1 MW-2 MW-3 MW-4 6/18/ a 12/12/ a 6/19/ /12/ /18/ a 12/12/ a 6/19/ /12/ MW-5 6/19/ MW-6 6/18/ MW-7 6/19/ /12/ a MW-8 6/18/ MW-9 6/26/ pumped dry gpm - gallons per minute min - minutes JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
16 JSAI 8 Table 4. Water-level measurements for 2013 sampling events at monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico monitor well date top of casing elevation, ft amsl depth to water, ft bmp water-level elevation, ft amsl MW-1 MW-2 MW-3 MW-4 6/18/13 4, , /12/13 4, , /19/13 4, , /12/13 4, , /18/13 4, , /12/13 4, , /19/13 4, , /12/13 4, , MW-5 6/19/13 4, , MW-6 6/18/13 4, , MW-7 6/19/13 4, , /12/13 4, , MW-8 6/18/13 4, , MW-9 6/26/13 4, , elevation is top of sounding tube (sounding tube is 0.42 ft below surveyed top of MW-5 well vault elevation) 2 elevation is top of sounding tube (sounding tube is 0.35 ft below surveyed top of MW-6 well vault elevation) 3 elevation is top of sounding tube (sounding tube is 0.35 ft below surveyed top of MW-7 well vault elevation) 4 surveyed top of sounding tube ft bmp - feet below measuring point ft amsl - feet above mean sea level JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
17 JSAI GROUWATER SAMPLING On June 25 and 26, 2013, Las Cruces Foothills Landfill monitor wells MW-1 through MW-9 were sampled by Las Cruces Water Quality Laboratory staff. On December 19, 2013, MW-1 through MW-4 and MW-7 were sampled by City of Las Cruces Water Quality Laboratory staff. During the 2013 semi-annual sampling events, groundwater samples were collected in bottles with appropriate preservatives provided by Hall Environmental Analysis Laboratories, Inc. (Hall) of Albuquerque, New Mexico. Samples were placed on ice, and chain-of-custody protocol was followed. 4.1 Well Purging Dedicated submersible pumps were used to produce water from each well. Due to low yield and slow rate of recovery, monitoring wells MW-1 through MW-8 were purged about 1 week prior to sampling. Additional purging of these wells was performed on the day of sampling to the extent possible based on drawdown. MW-9 was only purged on the day of sampling. For details on well purging, see Section 3.0 and Table Sampling Monitor Wells MW-1 through MW-9 On June 25 and 26, 2013, samples from monitor wells MW-1 through MW-9 were submitted to Hall for analysis according to the reduced parameter list submitted by JSAI to NMED/SWB on October 12, 2009, and approved by NMED/SWB on October 13, 2009, including major-ion chemistry, nitrates, metals and other inorganics, total phenolics, total organic carbon, and volatile organic compounds (VOCs). On December 19, 2013, samples from monitor wells MW-1 through MW-4 and MW-7 were submitted to Hall for analysis according to the reduced parameter list approved by NMED/SWB on October 13, Copies of laboratory reports for 2013 sampling events are provided in Appendix C. Note that MW-1 and MW-2 are directly upgradient of MW-5 and MW-6 and these two pairs of monitor wells may be redundant for monitoring purposes; thus, MW-1 and MW-2 were substituted for MW-5 and MW-6 in the December 2013 sampling event. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
18 JSAI RESULTS The City of Las Cruces has performed at least 25 sampling events at monitor wells MW-1 through MW-4 since January 1999, when the groundwater monitoring system was installed (MW-1 was also sampled five times between 1990 and 1996). These sampling events included analysis of parameters required for monitoring at municipal landfills (NMED/SWB regulations Section 1100, tables I and II; NMAC Subsections A, B, and C). The City has performed at least 17 sampling events at monitor wells MW-5 through MW-7 since July 2003, including analysis according to NMED/SWB regulations Section 1100, tables I and II; and NMAC Subsections A, B, and C. The City has performed 7 sampling events at monitor wells MW-8 and MW-9 since December 2010, including analysis according to NMAC Subsections A, B, and C. Review of the 2013 laboratory results for monitor wells MW-1 through MW-9 did not reveal any anomalies in the dataset. 5.1 Direction of Groundwater Flow and Hydraulic Gradient Based on the depth-to-water measurements collected in December 2013, the direction of groundwater flow beneath the landfill remains west-southwest. This is similar to the direction of groundwater flow reported by JSAI during previous sampling events. Groundwater elevation contours and direction of groundwater flow in June 2013 are presented in Figure 1, and groundwater elevation contours and direction of groundwater flow in December 2013 are presented in Figure 2. The hydraulic gradient beneath the landfill was about ft/ft in June 2013 and ft/ft in December 2013, compared to ft/ft in December 2012, and ft/ft in December Graphs showing the time-series trend in water levels for the monitor wells are presented in Figure 3. The average linear groundwater flow velocity calculated using a version of Darcy s Law (method defined in June 21, 2008, letter from James Dyer of NMED/SWB), assuming a hydraulic conductivity value of 0.2 ft/day for the alluvium over the Jornada Horst, and an effective porosity of 0.2, is ft/day. It is interesting to note that the groundwater elevation at MW-9 is generally higher than the groundwater elevation at MW-6 (Figs. 2 and 3). This information, as well as water-quality results discussed below, suggests upwelling of geothermal groundwater near MW-9. It has also been observed that air discharges from the top of casing at MW-9. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
19 JSAI 11 The water levels in monitor wells MW-1, MW-2, MW-4, and MW-7 declined by 4.92 to 5.66 ft between December 2012 and December 2013 (Fig. 3). The water level in upgradient monitor well MW-3 rose by 1.75 ft between December 2012 and December Water levels in monitor wells MW-5 and MW-6 declined by 2.32 ft and 6.85 ft, respectively, between June 2012 and June Water-level declines since December 2011 in MW-1, MW-2, MW-5, and MW-6 represent a reversal of a general increasing trend in these wells since Groundwater elevation contours define a groundwater mound between MW-1 and MW-5 (Fig. 1). Based on a comparison of water levels in MW-1 and MW-5, and in MW-5 and MW-6, this mound formed between December 2012 and June Background and Baseline Concentrations According to NMAC, background concentrations shall be determined from a well that has not been affected by a release from the landfill. The average concentration for each parameter sampled from hydraulically upgradient monitor well MW-3 was used to establish background values. As specified in E(3) NMAC, if the background concentration is below the practical quantitation limit (PQL), the PQL may be used to establish background. The established background concentrations for each parameter sampled, and corresponding standard deviations, are provided in Appendix B on the spreadsheet for MW-3 (last two columns in spreadsheet). Baseline concentrations were determined for MW-1, MW-2, and MW-4 through MW-9 in the same manner that background concentrations were determined for upgradient monitor well MW-3. According to E(1) NMAC, background and baseline concentrations for each parameter sampled from each well must be established from the dataset listed in Appendix B using at least four sampling events during the first semi-annual event, and at least one additional sampling during the subsequent semi-annual event. For MW-1 through MW-4, JSAI determined background and baseline concentrations by using the data from the five detection sampling events in 1999 (four events for MW-1), and the May 2000 detection sampling event. For MW-5, MW-6, and MW-7, baseline concentrations were established using the six sampling events in 2003 and the sampling event in For MW-8 and MW-9, baseline concentrations were established using the December 2010 sampling event, and the four sampling events in The background and baseline concentrations for each monitor well, and corresponding standard deviations, are presented in Appendix B (last two columns in spreadsheets). JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
20 JSAI Summary of Parameters Exceeding the Assessment Monitoring Level (AML) In June and December 2013, several inorganic and organic parameters exceeded the AML, as defined using the flowchart prepared by NMED/SWB (last revision 12/30/10), and direction by NMED/SWB Project Manager James Dyer, who stated in a June 21, 2008 letter that only Subsection A parameters need to have AMLs or CALs established. A list of these parameters for each monitor well, and corresponding AMLs, is shown in Table Historical PCE Concentrations PCE concentrations from each sampling event are presented in Figure 4. PCE concentrations have been at or above the AML of mg/l in MW-1 and MW-2 in each sampling event, except in MW-2 in September 1999 and December 2004 (Fig. 4). Historically, PCE concentrations have ranged from to mg/l in MW-1, and from to mg/l in MW-2. The PCE concentration in upgradient monitor well MW-3 was above the AML in the first sampling event in January 1999, but has been below laboratory detection limits in each subsequent sampling event (indicating possible laboratory error in the January 1999 analysis). PCE concentrations have been above the AML in MW-4, MW-5, MW-6, and MW-7 in each sampling event, except MW-4 and MW-5 in December 2004 (indicating possible laboratory error in the December 2004 analysis). Historically, PCE concentrations have ranged from < to mg/l in MW-4, <0.005 to mg/l in MW-5, to mg/l in MW-6, and to mg/l in MW-7. PCE has been detected at concentrations below the AML in MW-1 in each sampling event, except the first sampling event at the well, when PCE was below the laboratory detection limit. PCE concentrations have been below laboratory detection limits in MW-9 in each sampling event. In summary, PCE concentrations in MW-1 through MW-6 have exceeded AML by less than mg/l, and PCE concentrations in MW-7 have exceeded AML by less than mg/l PCE Concentrations PCE concentrations ranged from < to mg/l in MW-3 through MW-9 in PCE concentrations were above the GWPS of mg/l in MW-1, MW-4, MW-6, and MW-7 in June and December 2013 (Figs. 4 through 6; Table 5). PCE concentrations were above the AML of mg/l in MW-1, and MW-4 through MW-7, and at the AML in MW-2 in PCE concentrations were below the laboratory detection limit of mg/l in MW-3 and MW-9 in Concentration contours for PCE in groundwater at the site in June 2013 are presented in Figure 5, and PCE contours in December 2013 are presented in Figure 6. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
21 JSAI 13 Table 5. Summary of parameters that were detected above the AML in monitor wells at Las Cruces Foothills Landfill, 2013, Las Cruces, New Mexico monitor well sampling event parameter units GWPS CAL AML result MW-1 MW-2 6/25/13 tetrachloroethene (PCE) 1 mg/l /19/13 tetrachloroethene (PCE) 1 mg/l /25/13 tetrachloroethene (PCE) 1 mg/l /19/13 tetrachloroethene (PCE) 1 mg/l /25/13 tetrachloroethene (PCE) 1 mg/l /25/13 trichloroethene (TCE) 1 mg/l /25/13 methylene chloride 1 mg/l MW-4 6/25/13 trichlorofluoromethane 1 mg/l na na b /19/13 tetrachloroethene (PCE) 1 mg/l /19/13 trichloroethene (TCE) 1 mg/l /19/13 methylene chloride 1 mg/l MW-5 6/26/13 tetrachloroethene (PCE) 1 mg/l MW-6 6/26/13 tetrachloroethene (PCE) 1 mg/l /26/13 tetrachloroethene (PCE) 1 mg/l /26/13 trichloroethene (TCE) 1 mg/l MW-7 6/26/13 trichlorofluoromethane 1 mg/l na na b /19/13 tetrachloroethene (PCE) 1 mg/l MW-9 12/19/13 trichloroethene (TCE) 1 mg/l /19/13 trichlorofluoromethane 1 mg/l na na b /26/13 total dissolved solids mg/l 1,000 1, ,600 6/26/13 chloride mg/l hazardous b 95 percent increase over PQL bold text indicates concentrations that exceed the AML AML - assessment monitoring level GWPS - groundwater protection standard CAL - corrective action level, equal to GWPS ( B NMAC) mg/l - milligrams per liter na - no GWPS for this parameter PQL - practical quantitation limit JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
22 JSAI 14 In summary, PCE concentrations in MW-1, and MW-4 through MW-7 exceeded the AML by less than mg/l in Notable trends in PCE concentrations include general decreasing trends in MW-2 and MW-6 since December 2009 (Fig. 4) Historical and 2013 TCE Concentrations Trichloroethene (TCE) concentrations from each sampling event are presented in Figure 7. TCE concentrations have been below the AML of mg/l in MW-1, MW-2, upgradient monitor well MW-3, MW-5, MW-6, MW-8, and MW-9 in each sampling event. TCE concentrations have been below laboratory detection limits in upgradient monitor well MW-3 in each sampling event. TCE concentrations have ranged from to mg/l in MW-4 between December 2005 and 2013, exceeding the AML in each sampling event, except December TCE has been on a general increasing trend in MW-4 since January 1999, but concentrations have been relatively stable since December TCE concentrations have ranged from to mg/l in MW-7 between August 2003 and 2013, exceeding the AML in each sampling event except July 2003 and December TCE concentrations have exceeded the AML by less than mg/l in MW-4 and MW-7, and concentrations have remained relatively stable since December Concentration contours for TCE in groundwater at the site in June 2013 are presented in Figure 8, and TCE contours in December 2013 are presented in Figure Historical and 2013 Methylene Chloride Concentrations Methylene chloride concentrations have been below the AML of mg/l in MW-1, MW-2, upgradient monitor well MW-3, and MW-5 through MW-9 in each sampling event. Methylene chloride concentrations have been below laboratory detection limits in upgradient monitor well MW-3 and MW-5 through MW-9 in each sampling event. Methylene chloride concentrations have ranged from to mg/l in MW-4 between December 2005 and 2013, exceeding the GWPS of mg/l. Methylene chloride concentrations in MW-4 have exceeded the AML by less than mg/l, but are on a general increasing trend (Fig. 10). JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
23 JSAI Historical and 2013 Trichlorofluoromethane Concentrations Trichlorofluoromethane concentrations for monitor wells in which trichlorofluoromethane has been detected above the PQL of mg/l (MW-2, MW-4, and MW-7) are presented in Figure 11. Historically, trichlorofluoromethane concentrations have been below laboratory detection limits in MW-1, upgradient monitor well MW-3, MW-5, MW-6, MW-8, and MW-9. Trichlorofluoromethane concentrations have been above the AML of mg/l (because there is no GWPS for trichlorofluoromethane, the AML is equal to PQL + (0.95 * PQL)) in MW-4 between September 1999 and July 2003, and again in December 2008 and 2010, and June Trichlorofluoromethane concentrations have been above the AML of mg/l in MW-7 in July 2003, and between December 2008 and In summary, trichlorofluoromethane concentrations in MW-4 and MW-7 have exceeded the AML by less than mg/l, and concentrations have remained relatively stable since December Historical and 2013 Total Phenolics Concentrations Total phenolics concentrations were intermittently detected above the GWPS of mg/l in monitor wells MW-1, MW-2, upgradient monitor well MW-3, and MW-4 between January 1999 and September The highest concentration was mg/l, detected in MW-2 in January Total phenolics concentrations have been below laboratory detection limits in MW-1, MW-2, MW-3, and MW-4 in each sampling event since December Total phenolics concentrations have been below laboratory detection limits in MW-5 through MW-9 in each sampling event, except MW-6 in July 2003 (indicating possible laboratory error). Total phenolics were below the laboratory detection limit of mg/l in all monitor wells in Historical and 2013 Total Iron Concentrations Total iron concentrations in each sampling event are presented in Figure 12. Total iron concentrations were detected above the GWPS of 1.0 mg/l in MW-1, MW-2, and upgradient monitor well MW-3 in 1999; in MW-1 in November 2000 and June 2001; and in MW-7 in July Elevated iron concentrations were likely due to slightly turbid water samples, and turbidity has been minimized by the installation of dedicated sampling pumps at MW-1, MW-2, MW-3, and MW-4 in June 2001, and at MW-5, MW-6, and MW-7 in June Total iron concentrations were below the AML in all monitor wells in JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
24 JSAI Additional Parameters Detected in Monitor Well MW-9 Total dissolved solids (TDS) and chloride concentrations exceeded AMLs of 750 mg/l and mg/l, respectively, in June 2013 (Table 5). 6.0 NATURE A EXTENT OF GROUWATER CONTAMINANTS 6.1 Sources of PCE, TCE, and Methylene Chloride PCE has been detected in MW-1, MW-2, and MW-4 through MW-7 at concentrations that exceed the AML of mg/l in each sampling event between January 1999 and 2013 (except for MW-2 in September 1999, and MW-2, MW-4, and MW-5 in December 2004). TCE has been detected at concentrations that exceed the AML of mg/l in MW-4 in each sampling event between December 2005 and 2013 (except December 2012), and in MW-7 in each sampling event between August 2003 and 2013 (except for December 2010). Concentration contour maps for PCE and TCE presented in Figures 5, 6, 8, and 9 define the extent of groundwater contamination at the site in In upgradient monitor well MW-3, PCE and TCE have been below laboratory detection limits of mg/l in each sampling event (except PCE in January 1999, which may be due to laboratory error). The absence of these VOCs in upgradient well MW-3 in 26 consecutive sampling events suggests that these contaminants are associated with the landfill materials. Groundwater monitoring results provide evidence that PCE and TCE are present as dissolved phases in groundwater and no phase-separated sources have been observed. PCE and TCE are associated with solvents commonly used for dry cleaning, paint removal, and degreasing processes. Under anaerobic conditions, the chemical and biological transformation pathway indicates that hexachloroethane breaks down to PCE, which breaks down to TCE, which breaks down to trans-1,2-dichloroethylene, cis-1,2-dichloroethylene, 1,1-dichloroethylene, and vinyl chloride (Barbee, 1994). Over time, PCE typically is biologically transformed to TCE in soils and groundwater under a range of anaerobic and aerobic conditions. The higher temperatures in MW-1, MW-5, and MW-6 may be slowing the biological transformation of PCE to TCE relative to MW-4. Monitor well MW-4 represents an end-member among the landfill monitor wells in terms of JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
25 JSAI 17 temperature (only MW-3 has a cooler temperature than MW-4) and major ion geochemistry (see Fig. 13). Monitor wells MW-4 and MW-7 have the highest TCE concentrations at the landfill, and appear to share the same structural setting, located in a graben east of the Jornada Horst (Figs. 15 and 16). Methylene chloride has been detected in MW-4 above the GWPS of mg/l since Methylene chloride is commonly used as a solvent in paint strippers and removers, and as a metal cleaning and finishing solvent. It is also used as a propellant in aerosols for paints, automotive products, and insect sprays. Trichlorofluoromethane has been detected in MW-7 above the AML of mg/l since December Trichlorofluoromethane was used as a refrigerant and a cleaning/rinsing agent, but U.S. production ended in 1996 due to ozone depletion potential. The occurrences of PCE, TCE, methylene chloride and trichlorofluoromethane in Las Cruces Foothills Landfill monitor wells are probably not due to other contamination plumes in the area (Peery and McCoy, 2003; Peery and McCoy, 2005). In order to identify potential alternative contamination sources, JSAI contacted state and federal agencies including the EPA, U.S. Geological Survey (USGS), NMED/SWB, NMED Groundwater Quality Bureau (GWQB), and NMED Petroleum Storage Tank Bureau (PSTB). According to the NMED/SWB, there are two closed landfill sites located approximately 1 mile from Las Cruces Foothills Landfill. The exact locations of the closed landfills are not known, but they are located to the southwest and downgradient of the existing landfill. Neither of these sites has monitor wells, and both are reported to be owned by the City of Las Cruces (Dan Fuqua, NMED/SWB, oral communication, February 26, 2004). The NMED/GWQB did not have any information on contamination, spills, or monitored discharges near Las Cruces Foothills Landfill (Bart Faris, oral communication, February 26, 2004). According to the NMED/PSTB, there are 39 active leaky underground storage tank sites and 85 sites requiring no further action in the City of Las Cruces, as of February 15, 2011 ( These sites are located over 1 mile downgradient of Las Cruces Foothills Landfill. The contaminated sites identified by EPA and NMED, including the Griggs and Walnut PCE plume, are located at least 1 mile downgradient of Las Cruces Foothills Landfill, and there is no evidence to indicate that the contamination at the landfill is associated with any of these sites (JSAI, 2006). JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
26 JSAI Sources of Contaminants Detected at Assessment Monitor Wells MW-8 and MW PCE PCE has been detected in MW-8 at concentrations below the AML, with a concentration of mg/l in June PCE detections at MW-8 are likely associated with contaminants from Las Cruces Foothills Landfill. PCE and TCE detections at MW-4 and MW-7 provide evidence for contaminant migration southeastward. It is possible that the direction of lateral and vertical leachate migration in the vadose zone is controlling the observed groundwater plume. The observed hydraulic gradient is east to west TDS and chloride TDS and chloride concentrations exceeded AMLs in MW-9 in June 2013 (Table 5). The major ion geochemistry of groundwater sampled at MW-9 is similar to that of geothermal wells at New Mexico State University (Fig. 13). The relatively high groundwater elevation at MW-9, combined with the major ion geochemistry, indicate geothermal upwelling. Thus, elevated TDS and chloride concentrations are naturally-occurring and characteristic of geothermal groundwater in the area. The major ion geochemistry at many of the landfill monitor wells appears to represent mixing between the cool calcium-bicarbonate type groundwater sampled at MW-4 (groundwater in the Santa Fe Group aquifer of the Jornada Basin), and the hot sodium-sulfate type groundwater sampled at MW-9 (geothermal upwelling; Fig. 13). Elevated fluoride and manganese concentrations, and radium-226 and -228 activity in MW-9 in 2011 were also attributed to naturally-occurring variability in groundwater quality, and characteristic of geothermal groundwater in the area (McCoy and Peery, 2012). 7.0 CONTAMINANT TRANSPORT MECHANISMS The driving force for contaminant transport in groundwater is the hydraulic gradient. Figure 14 presents groundwater elevation contours in the area, and shows that the hydraulic gradient west of Las Cruces Foothills Landfill is relatively flat ( ft/ft, compared to ft/ft at the landfill), limiting downgradient contaminant migration. Historical PCE and TCE concentration trends in downgradient monitor wells MW-5 and MW-6 do not indicate that the plume is moving (Figs. 4 and 7). JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
27 JSAI 19 Between 2005 and 2010, rising water-level trends at monitor wells MW-1, MW-2, MW-5, and MW-6 indicated flattening of the hydraulic gradient across the Jornada Horst. The flattening of the hydraulic gradient was likely due to the development of a groundwater mound resulting from a recharge event occurring at the water table directly west of the landfill. Water-level data for 2011 through 2013 show that the increasing trend has reversed. Waterlevel declines at landfill monitor wells may also be influenced by regional pumping in response to persistent drought conditions. Nonetheless, downgradient contaminant migration to the west of the monitoring well network is limited by a relatively flat hydraulic gradient between the Jornada Horst and Interstate 25 (Fig. 14). Groundwater-elevation contours define a groundwater mound between MW-1 and MW-5 (Fig. 1). Based on a comparison of water levels in MW-1 and MW-5, and in MW-5 and MW-6, this mound formed between December 2012 and June Additional water level data are needed to determine whether this mound represents a discrete pulse of recharge, or a continuous source. Analysis of the geology and structures beneath Las Cruces Foothills Landfill shows that contaminant transport mechanisms active in the vadose zone may be responsible for the variation in contaminant concentrations in different landfill monitor wells. For example, PCE concentrations have been elevated in MW-6 in each sampling event. The clay-rich horizon A appears to pinch out just upgradient of MW-6 and may drop contamination at this point. PCE and TCE detections at MW-4 and MW-7 provide evidence for contaminant migration southeastward in the vadose zone. The geology and structure beneath Las Cruces Foothills Landfill are presented in Figures 15 and 16. Concentration contour maps for PCE and TCE presented in Figures 5, 6, 8, and 9 define the extent of groundwater contamination at the site. PCE and TCE were below laboratory detection limits in MW-9 between December 2010 and 2013, helping constrain the extent of contamination at Las Cruces Foothills Landfill to the west of MW-6. PCE was detected at MW-8 in 2013, providing evidence for contaminant migration southeastward, across the groundwater gradient, parallel to the graben containing MW-4, MW-7, and MW-8 (Figs. 5 and 15). JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
28 JSAI CONCLUSIONS A RECOMMEATIONS At Las Cruces Foothills Landfill, monitor wells MW-1 through MW-4 have been sampled at least 25 times since 1999, MW-5 through MW-7 have been sampled at least 17 times since 2003, and MW-8 and MW-9 have been sample 7 times since 2010, establishing baseline conditions and defining the extent of groundwater contamination at the site based on AMLs of constituents of concern. The primary constituents of concern are PCE, TCE, methylene chloride, and trichlorofluoromethane. The occurrences of PCE, TCE, methylene chloride, and trichlorofluoromethane in monitor wells are related to leachate derived from Las Cruces Foothills Landfill. Contaminant transport mechanisms appear to be active in the vadose zone, and controlled by a clay-rich horizon that lies beneath Las Cruces Foothills Landfill. The driving force for contaminant transport in groundwater is the hydraulic gradient. Downgradient contaminant migration in the groundwater is limited by a relatively flat hydraulic gradient west of the Jornada Horst, and historical PCE and TCE concentration trends in downgradient monitor wells MW-5 and MW-6 do not indicate that the plume is moving. Groundwater elevation contours define a groundwater mound between MW-1 and MW-5, which appears to have formed between December 2012 and June Additional data are needed to determine whether this mound represents a discrete pulse of recharge, or a continuous source; therefore, JSAI recommends that water-level measurements be collected at all monitor wells on a semi-annual basis. It is recommended that groundwater monitoring be continued at Las Cruces Foothills Landfill to track the extent and nature of the contaminant plume. Monitor wells MW-3 through MW-7 will be sampled in the first semi-annual event in 2014, which will allow for the comparison of summer and winter sampling results, and monitor wells MW-1 through MW-9 will be sampled in the second semi-annual event in During the first semi-annual event in 2014, monitor wells will be sampled according to the reduced parameter list approved for MW-1 through MW-7 by NMED/SWB on October 13, 2009, which includes major-ion chemistry, nitrates, metals and other inorganics, total phenolics, total organic carbon, and VOCs. During the second semi-annual event in 2014, monitor wells will be sampled according to NMAC Subsections A and C, as it will be 5 years since the approval of the reduced parameter list. The second semi-annual report for 2014 will include a proposed reduced parameter list for continued groundwater monitoring. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
29 JSAI REFERENCES Barbee, G.C., 1994, Fate of chlorinated aliphatic hydrocarbons in the vadose zone and groundwater: Groundwater Monitoring and Remediation, 1994, vol. 9, No. 1, pp [JSAI] John Shomaker & Associates, Inc., 1999, Results from installation of groundwater monitoring system, and proposed groundwater monitoring plan, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by Finch, S. T., Jr., of John Shomaker & Associates, Inc. for the City of Las Cruces, 25 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2000, Annual groundwater monitoring report, determination of background values, and alternate parameter list request, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by Finch, S.T., Jr., of John Shomaker & Associates, Inc. for City of Las Cruces, 13 p. plus figs and appendices. [JSAI] John Shomaker & Associates, Inc., 2001, Annual groundwater monitoring report for year 2000, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by Peery, R. L., and Armour, J., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 13 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2002, Annual groundwater monitoring report for year 2001, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by Peery, R. L., and McCoy, A. M., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 18 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2003, Annual groundwater monitoring report for year 2002, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by Peery, R. L., and McCoy, A. M., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 24 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2004, Annual groundwater monitoring report for year 2003, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by Peery, R. L., and McCoy, A. M., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 31 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2005, Annual groundwater monitoring report for year 2004, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by McCoy, A. M., and Peery, R., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 21 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2006, Annual groundwater monitoring report for year 2005, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by McCoy, A. M., and Peery, R., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 23 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2006a, Groundwater-flow and solute-transport model for the Griggs and Walnut Superfund site, Las Cruces, New Mexico: consultant s report prepared by Laura H. Petronis, Steven T. Finch, Jr., and John W. Shomaker of John Shomaker & Associates, Inc., in association with Daniel B. Stephens & Associates, Inc., for the Griggs and Walnut Joint Superfund Project, City of Las Cruces, and Doña Ana County, New Mexico, 53 p. plus figures and appendices. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
30 JSAI 22 [JSAI] John Shomaker & Associates, Inc., 2007, Annual groundwater monitoring report for year 2006, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by McCoy, A. M., and Peery, R., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 22 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2008, Annual groundwater monitoring report for year 2007, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by McCoy, A. M., and Peery, R., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 21 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2009, Annual groundwater monitoring report for year 2008, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by McCoy, A. M., and Peery, R., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 30 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2010, Annual groundwater monitoring report for year 2009, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by McCoy, A. M., and Peery, R., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 22 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2011, Annual groundwater monitoring report for year 2010, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by McCoy, A. M., Miller, S.A. and Peery, R., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 26 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2012, Annual groundwater monitoring report for year 2011, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by McCoy, A. M., and Peery, R., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 23 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2013, Annual groundwater monitoring report for year 2012, Las Cruces Landfill, Las Cruces, New Mexico: consultant s report prepared by McCoy, A. M., and Peery, R., of John Shomaker & Associates, Inc. for the City of Las Cruces, New Mexico, 22 p. plus figures and appendices. [JSAI] John Shomaker & Associates, Inc., 2013a, First semi-annual groundwater monitoring event of the 2013 monitoring period for Las Cruces Foothills Landfill: consultant s letter report prepared by McCoy, A.M., of John Shomaker & Associates, Inc. to James Dyer, NMED/SWB, Permitting Section, on behalf of the City of Las Cruces, 3 p. plus figures and appendices. Woodward, D.G., and Myers, R.G., 1997, Seismic investigation of the buried horst between the Jornada del Muerto and Mesilla ground-water basins near Las Cruces, Dona Ana County, New Mexico: U.S. Geological Survey Water-Resources Investigations Report , 49 p. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
31 JSAI ILLUSTRATIONS JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
32 !! East Lohman Ave !!!!!!!!!!!!!!!!!!! MW MW-6 MW ! MW-1 MW ! 3880!!!! 3900 MW LAFILL < !!!! 3940! MW-4!! 3960!!!!! 3980! !!!!! !!!!!! 4040!!!!!!! MW-3 ³ T23S MW landfill well Explanation ,000 2,000 Feet < flow direction water-level elevation contour, ft amsl city limits top of bedrock contour, ft amsl (USGS WRIR ) area where top of bedrock high is above the water table Aerial Photography date: May 2011 Figure 1. Aerial photograph showing locations of Las Cruces Foothills Landfill monitor wells, groundwater elevation contours, and direction of groundwater flow in June JOHN SHOMAKER & ASSOCIATES, INC.
33 3800!! 4000 R02E ³ !! * MW-9 East Lohman Ave. * MW-5 * MW-6!!!!!!!!!!!!!!!!!!! ! MW-1 MW ! 3880!!!! 3900 MW-7 LAFILL <!!!! ! MW-4!! 3960!!!! !!!!! !!!!!! 4040!!!!!!! MW T23S 3920 * MW Explanation ,000 2,000 Feet < landfill well flow direction water-level elevation contour, ft amsl 3800 city limits * not measured top of bedrock contour, ft amsl (USGS WRIR ) area where top of bedrock high is above the water table Aerial Photography date: May 2011 Figure 2. Aerial photograph showing locations of Las Cruces Foothills Landfill monitor wells, groundwater elevation contours, and direction of groundwater flow in December JOHN SHOMAKER & ASSOCIATES, INC.
34 water-level elevation, ft amsl 3,884 3,882 3,880 3,878 3,876 3,874 3,872 3,870 3,868 Las Cruces Foothills Landfill Monitor Well MW-1 temperature temperature, degrees F water-level elevation, ft amsl 3,870 3,868 3,866 3,864 3,862 3,860 3,858 3,856 3,854 Las Cruces Foothills Landfill Monitor Well MW-2 temperature temperature, degrees F 3, , , , water-level elevation, ft amsl 3,850 Las Cruces Foothills Landfill Monitor Well MW ,850 Las Cruces Foothills Landfill Monitor Well MW water-level elevation, ft amsl 3,848 3,846 3,844 3,842 3,840 3,838 3,836 3,834 temperature temperature, degrees F 3,848 3,846 3,844 3,842 3,840 3,838 3,836 3, , , , , Dec-02 Dec-03 Dec-04 Dec-05 Dec-06 Dec-07 Dec-08 Dec-09 Dec-10 Dec-11 Dec-12 Dec-13 Dec-02 Dec-03 Dec-04 Dec-05 Dec-06 Dec-07 Dec-08 Dec-09 Dec-10 Dec-11 Dec-12 Dec-13 Dec-98 Dec-99 Dec-00 Dec-01 Dec-02 Dec-03 Dec-04 Dec-05 Dec-06 Dec-07 Dec-08 Dec-09 Dec-10 Dec-11 Dec-12 Dec-13 Dec-98 Dec-99 Dec-00 Dec-01 Dec-02 Dec-03 Dec-04 Dec-05 Dec-06 Dec-07 Dec-08 Dec-09 Dec-10 Dec-11 Dec-12 Dec-13 4,060 4,058 4,056 4,054 4,052 4,050 4,048 4,046 4,044 Las Cruces Foothills Landfill Monitor Well MW-3 temperature temperature, degrees F water-level elevation, ft amsl 3,951 3,949 3,947 3,945 3,943 3,941 3,939 3,937 3,935 Las Cruces Foothills Landfill Monitor Well MW-4 temperature temperature, degrees F 4, , , , water-level elevation, ft amsl Dec-98 Dec-99 Dec-00 Dec-01 Dec-02 Dec-03 Dec-04 Dec-05 Dec-06 Dec-07 Dec-08 Dec-09 Dec-10 Dec-11 Dec-12 Dec-13 Dec-98 Dec-99 Dec-00 Dec-01 Dec-02 Dec-03 Dec-04 Dec-05 Dec-06 Dec-07 Dec-08 Dec-09 Dec-10 Dec-11 Dec-12 Dec-13 temperature temperature, degrees F 3,926 Las Cruces Foothills Landfill Monitor Well MW ,934 Las Cruces Foothills Landfill Monitor Well MW water-level elevation, ft amsl 3,924 3,922 3,920 3,918 3,916 3,914 3,912 3,910 temperature temperature, degrees F water-level elevation, ft amsl 3,932 3,930 3,928 3,926 3,924 3,922 3,920 3,918 temperature temperature, degrees F 3, , ,906 Dec-02 Dec-03 Dec-04 Dec-05 Dec-06 3, ,854 Las Cruces Foothills Landfill Monitor Well MW ,852 3,850 3,848 3,846 3,844 3,842 3,840 3, Figure 3. Graphs showing water-level elevations versus time for monitor wells MW-1, MW-2, MW-3, MW-4, MW-5, MW-6, MW-7, MW-8, and MW-9, Las Cruces Foothills Landfill, New Mexico. 3, , Dec-09 Mar-10 Jun-10 Sep-10 Dec-10 Mar-11 Jun-11 Sep-11 Dec-11 Mar-12 Jun-12 Sep-12 Dec-12 Mar-13 Jun-13 Sep-13 Dec-13 Dec-07 Dec-08 Dec-09 Dec-10 Dec-11 Dec-12 Dec Dec-09 Mar-10 Jun-10 Sep-10 Dec-10 Mar-11 Jun-11 Sep-11 Dec-11 Mar-12 Jun-12 Sep-12 Dec-12 Mar-13 Jun-13 Sep-13 Dec-13 water-level elevation, ft amsl temperature temperature, degrees F JOHN SHOMAKER & ASSOCIATES, INC.
35 MW-1 MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9 GWPS AML Graph values of mg/l represent sample results below the lab detection limits. GWPS is mg/l. AML is 50 percent of GWPS Dec-98 Dec-99 Dec-00 Dec-01 Dec-02 Dec-03 Dec-04 Dec-05 Dec-06 Dec-07 Dec-08 Dec-09 Dec-10 Dec-11 Dec-12 Dec-13 PCE concentration, mg/l Figure 4. Graph showing PCE concentrations versus time for monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, New Mexico. JOHN SHOMAKER & ASSOCIATES, INC.
36 3800!! 4000 R02E ³ !! < T23S East Lohman Ave MW MW-6 MW !!!!!!!!!!!!!!!!!!! ! MW-1 MW-2! 0.01!!!! LAFILL MW !!!! 0.011! MW !!!!!!!!!!! <0.0005!!!!!!!!!!!!! MW-3 MW Explanation ,000 2,000 Feet landfill well PCE concentration contour, mg/l = AML = GWPS 3800 city limits top of bedrock contour, ft amsl (USGS WRIR ) area where top of bedrock high is above the water table Aerial Photography date: May 2011 Figure 5. Site map showing concentration contours of PCE in groundwater, June 25 and 26, 2013 Las Cruces Foothills Landfill, New Mexico. JOHN SHOMAKER & ASSOCIATES, INC.
37 3800!! 4000 R02E ³ !! < MW-9 East Lohman Ave. MW MW !!!!!!!!!!!!!!!!!!! ! MW-1 MW-2! 0.01!!!! LAFILL MW-7!!!! 0.011! MW !!!!!!!!!!! <0.0005!!!!!!!!!!!!! MW T23S MW Explanation ,000 2,000 Feet landfill well PCE concentration contour, mg/l = AML = GWPS 3800 city limits top of bedrock contour, ft amsl (USGS WRIR ) area where top of bedrock high is above the water table Aerial Photography date: May 2011 Figure 6. Site map showing concentration contours of PCE in groundwater, December 19, 2013, Las Cruces Foothills Landfill, New Mexico. JOHN SHOMAKER & ASSOCIATES, INC.
38 MW-1 Graph values of mg/l represent sample results below the lab detection limits MW-2 GWPS is mg/l. AML is 50 percent of GWPS MW Dec-98 Dec-99 Dec-00 Dec-01 Dec-02 Dec-03 Dec-04 Dec-05 Dec-06 Dec-07 Dec-08 Dec-09 Dec-10 Dec-11 Dec-12 Dec-13 TCE concentration, mg/l MW-4 MW-5 MW-6 MW-7 MW-8 MW-9 AML GWPS Figure 7. Graph showing TCE concentrations versus time for monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, New Mexico. JOHN SHOMAKER & ASSOCIATES, INC.
39 3800!! 4000 R02E ³ !! MW-9 <0.001 East Lohman Ave. MW-5 <0.001 MW-6 <0.001!!!!!!!!!!!!!!!!!!!! MW MW ! !!!! MW-7 LAFILL 0.001!!!!! MW !!!!!!!!!!!!!!!!!!!!!!!! MW-3 < T23S MW-8 < Explanation ,000 2,000 Feet landfill well TCE concentration contours, mg/l = AML 3800 city limits top of bedrock contour, ft amsl (USGS WRIR ) area where top of bedrock high is above the water table Aerial Photography date: May 2011 Figure 8. Site map showing concentration contours of TCE in groundwater, June 25 and 26, 2013, Las Cruces Foothills Landfill, New Mexico. JOHN SHOMAKER & ASSOCIATES, INC.
40 3800!! 4000 R02E ³ !! MW-9 * East Lohman Ave. MW-5 * MW-6 *!!!!!!!!!!!!!!!!!!!! MW MW ! !!!! MW-7 LAFILL 0.001!!!!! MW !!!!!!!!!!!!!!!!!!!!!!!! MW-3 < T23S MW-8 * 3900 Explanation ,000 2,000 Feet landfill well TCE concentration contours, mg/l = AML 3800 city limits * not measured top of bedrock contour, ft amsl (USGS WRIR ) area where top of bedrock high is above the water table Aerial Photography date: May 2011 Figure 9. Site map showing concentration contours of TCE in groundwater, December 19, 2013, Las Cruces Foothills Landfill, New Mexico. JOHN SHOMAKER & ASSOCIATES, INC.
41 MW-1 MW-2 MW-3 MW-4 MW-5 Graph values of mg/l represent sample results below the lab detection limits. GWPS is mg/l. AML is 50 percent of GWPS Dec-98 Dec-99 Dec-00 Dec-01 Dec-02 Dec-03 Dec-04 Dec-05 Dec-06 Dec-07 Dec-08 Dec-09 Dec-10 Dec-11 Dec-12 Dec-13 methylene chloride concentration, mg/l MW-6 MW-7 MW-8 MW-9 AML GWPS Figure 10. Graph showing methylene chloride concentrations versus time for monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, New Mexico. JOHN SHOMAKER & ASSOCIATES, INC.
42 MW-2 MW-4 Graph values of mg/l represent sample results below the lab detection limits. AML is (PQL + (0.95*PQL)) = mg/l. trichlorofluoromethane concentration, mg/l MW Dec-98 Dec-99 Dec-00 Dec-01 Dec-02 Dec-03 Dec-04 Dec-05 Dec-06 Dec-07 Dec-08 Dec-09 Dec-10 Dec-11 Dec-12 Dec-13 AML Figure 11. Graph showing trichlorofluoromethane concentrations versus time for monitor wells MW-2, MW-4 and MW-7, Las Cruces Foothills Landfill, New Mexico. JOHN SHOMAKER & ASSOCIATES, INC.
43 total iron concentration, mg/l (log scale). 1, Graph values of 0.01 mg/l represent sample results below the lab detection limits Dec-98 Dec-99 Dec-00 Dec-01 Dec-02 Dec-03 Dec-04 Dec-05 Dec-06 Dec-07 Dec-08 Dec-09 Dec-10 Dec-11 Dec-12 Dec-13 GWPS is 1.0 mg/l. AML is 75 percent of GWPS. MW-1 MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9 GWPS AML Figure 12. Graph showing total iron concentrations versus time for monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico. JOHN SHOMAKER & ASSOCIATES, INC.
44 EXPLANATION median gw temp MW F MW F MW F MW F MW F MW F MW F 60 Ca-Mg-SO4-Cl 60 MW F MW F Ca-Mg- HCO3-CO3 40 Na-K- SO4-Cl 20 NMSU geothermal wells Mg SO Na-K-HCO3-CO Ca Na+K HCO3 Cl Figure 13. Piper diagram showing hydrogeochemical classification of groundwater sampled between December 2005 and 2013 at Las Cruces Foothills Landfill monitor wells, and geothermal groundwater in the area, Las Cruces, New Mexico. JOHN SHOMAKER & ASSOCIATES, INC.
45 ! 4000 R02E ³ 3900 ") ") MW-9 * MW-5 * !!!! 3860!!!!!!!! MW-6 * 3880!! 3920 LAFILL!!!!! MW MW !! 4020!!! 4040!!!! MW T23S MW-8 ") 27 ") ") * 3800 ") 26 ") ") ") (17) 0 1,000 2,000 4,000 Feet 3840 ") 3800 Explanation ") municipal well landfill well monitoring well WLE_ water-level elevation contour, ft amsl city limits top of bedrock contour, ft amsl area where top of bedrock high is above the water table * not measured Aerial Photography date: May 2011 Figure 14. Aerial photograph showing Las Cruces Foothills Landfill monitor wells and groundwater elevation contours in December JOHN SHOMAKER & ASSOCIATES, INC.
46 !! 4000 R02E ³ D U ³ A MW-9 T23S 3900 D U MW-5 MW !!!!!!!!!!!!!!!!!!!! MW-1 MW-2!!!!! 3800 LAFILL MW-7!!!!! MW-4!!!!!!! D U! MW-3!!!!!!!!!!! A'!!!!!!! ³ MW U D Explanation 0 1,150 2,300 Feet ³ ³ landfill monitoring well line of section fault in subsurface (referenced from Woodward and Myers (1997)) city limits top of bedrock contour, ft amsl area where top of bedrock high is above the water table Aerial Photography date: May 2011 Figure15.Aerialphotographshowinglocationsofexistingmonitorwels,faultsinthesubsurface,lineofschematic geologiccros-sectiona-a,andbedrock high,lascrucesfoothilslandfil,newmexico. JOHNSHOMAKER& ASSOCIATES,INC.
47 A A West East 4400 MW-3 MW MW-5 MW-2 EXPLANATION MW-9 landfill elevation, feet above mean sea level Hydrogeologic Unit sand and gravel poorly consolidated clay and silt medium-grained moderately consolidated fine-grained consolidated volcaniclastics basalt water-level elevation, June 2013 well with screen section feet 500 horizontal scale 3700 Figure 16. West to east hydrogeologic cross-section, Las Cruces Foothills Landfill, New Mexico. JOHN SHOMAKER & ASSOCIATES, INC.
48 JSAI APPEICES JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
49 JSAI Appendix A. Summary of water-level measurements from monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
50 JSAI Summary of water-level measurements from monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico well date top of casing elevation (ft amsl) depth to water (ft bmp) water-level elevation (ft amsl) MW-1 01/11/99 4, , MW-1 04/01/99 4, , MW-1 05/06/99 4, , MW-1 07/07/99 4, , MW-1 09/15/99 4, , MW-1 11/03/99 4, , MW-1 05/18/00 4, , MW-1 06/13/01 4, , MW-1 10/29/01 4, , MW-1 11/06/01 4, , MW-1 03/25/02 4, , MW-1 04/03/02 4, , MW-1 07/12/02 4, , MW-1 09/25/02 4, , MW-1 12/18/02 4, , MW-1 07/15/03 4, , MW-1 12/29/03 4, , MW-1 12/2/04 4, , MW-1 12/14/05 4, , MW-1 12/12/06 4, , MW-1 01/11/08 4, , MW-1 12/23/08 4, , MW-1 12/29/09 4, , MW-1 12/29/10 4, , MW-1 12/27/11 4, , MW-1 12/12/12 4, , MW-1 6/18/13 4, , MW-1 12/12/13 4, , MW-2 01/11/99 4, , MW-2 04/01/99 4, , MW-2 05/06/99 4, , MW-2 07/07/99 4, , MW-2 09/15/99 4, , MW-2 11/03/99 4, , MW-2 05/18/00 4, , MW-2 11/09/00 4, , MW-2 06/13/01 4, , measurement made from ground level ft bmp - feet below measuring point ft amsl - feet above mean sea level JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
51 JSAI Summary of water-level measurements from monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico (continued) well date top of casing elevation (ft amsl) depth to water (ft bmp) water-level elevation (ft amsl) MW-2 10/29/01 4, , MW-2 11/02/01 4, , MW-2 11/06/01 4, , MW-2 03/25/02 4, , MW-2 04/03/02 4, , MW-2 07/12/02 4, , MW-2 09/25/02 4, , MW-2 12/18/02 4, , MW-2 07/15/03 4, , MW-2 12/29/03 4, , MW-2 12/2/04 4, , MW-2 12/14/05 4, , MW-2 12/12/06 4, , MW-2 01/11/08 4, , MW-2 12/23/08 4, , MW-2 12/29/09 4, , MW-2 12/29/10 4, , MW-2 12/27/11 4, , MW-2 12/12/12 4, , MW-2 6/19/13 4, , MW-2 12/12/13 4, , MW-3 01/11/99 4, , MW-3 04/01/99 4, , MW-3 05/06/99 4, , MW-3 07/07/99 4, , MW-3 09/15/99 4, , MW-3 11/03/99 4, , MW-3 05/18/00 4, , MW-3 11/09/00 4, , MW-3 06/13/01 4, , MW-3 10/29/01 4, , MW-3 11/02/01 4, , MW-3 11/06/01 4, , MW-3 03/25/02 4, , MW-3 04/03/02 4, , MW-3 07/12/02 4, , MW-3 09/25/02 4, , ft bmp - feet below measuring point ft amsl - feet above mean sea level JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
52 JSAI Summary of water-level measurements from monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico (continued) well date top of casing elevation (ft amsl) depth to water (ft bmp) water-level elevation (ft amsl) MW-3 12/18/02 4, , MW-3 07/15/03 4, , MW-3 12/29/03 4, , MW-3 12/2/04 4, , MW-3 12/14/05 4, , MW-3 12/12/06 4, , MW-3 01/11/08 4, , MW-3 12/23/08 4, , MW-3 12/29/09 4, , MW-3 12/29/10 4, , MW-3 05/12/11 4, , MW-3 12/20/11 4, , MW-3 6/12/12 4, , MW-3 12/12/12 4, , MW-3 6/18/13 4, , MW-3 12/12/13 4, , MW-4 01/11/99 4, , MW-4 04/01/99 4, , MW-4 05/06/99 4, , MW-4 07/07/99 4, , MW-4 09/15/99 4, , MW-4 11/03/99 4, , MW-4 05/18/00 4, , MW-4 11/09/00 4, , MW-4 06/13/01 4, , MW-4 10/29/01 4, , MW-4 11/06/01 4, , MW-4 03/25/02 4, , MW-4 04/03/02 4, , MW-4 07/12/02 4, , MW-4 09/25/02 4, , MW-4 12/18/02 4, , MW-4 07/15/03 4, , MW-4 12/29/03 4, , MW-4 12/2/04 4, , MW-4 12/14/05 4, , MW-4 12/12/06 4, , MW-4 01/11/08 4, , ft bmp - feet below measuring point ft amsl - feet above mean sea level JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
53 JSAI Summary of water-level measurements from monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico (continued) well date top of casing elevation (ft amsl) depth to water (ft bmp) water-level elevation (ft amsl) MW-4 12/23/08 4, , MW-4 12/29/09 4, , MW-4 12/29/10 4, , MW-4 12/27/11 4, , MW-4 6/12/12 4, , MW-4 12/12/12 4, , MW-4 6/19/13 4, , MW-4 12/12/13 4, , MW-5 07/15/03 4, , MW-5 08/27/03 4, , MW-5 09/29/03 4, , MW-5 10/27/03 4, , MW-5 11/25/03 4, , MW-5 12/29/03 4, , MW-5 12/2/04 4, , MW-5 12/14/05 4, , MW-5 12/12/06 4, , MW-5 01/11/08 4, ,835.0 MW-5 12/23/08 4, , MW-5 12/29/09 4, , MW-5 12/29/10 4, , MW-5 12/28/11 4, , MW-5 6/12/12 4, , MW-5 12/13/12 4, , MW-5 6/19/13 4, , MW-6 07/15/03 4, , MW-6 08/27/03 4, , MW-6 09/29/03 4, , MW-6 10/27/03 4, , MW-6 11/25/03 4, , MW-6 12/29/03 4, , MW-6 12/2/04 4, , MW-6 12/14/05 4, , MW-6 12/12/06 4, , MW-6 01/11/08 4, , MW-6 12/23/08 4, , MW-6 12/29/09 4, , ft bmp - feet below measuring point ft amsl - feet above mean sea level JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
54 JSAI Summary of water-level measurements from monitor wells MW-1 through MW-9, Las Cruces Foothills Landfill, Las Cruces, New Mexico (concluded) well date top of casing elevation (ft amsl) depth to water (ft bmp) water-level elevation (ft amsl) MW-6 12/29/10 4, , MW-6 12/28/11 4, , MW-6 6/12/12 4, , MW-6 12/13/12 4, , MW-6 6/18/13 4, , MW-7 7/15/03 4, , MW-7 8/27/03 4, , MW-7 9/29/03 4, , MW-7 10/27/03 4, , MW-7 11/25/03 4, , MW-7 12/29/03 4, , MW-7 12/2/04 4, , MW-7 12/14/05 4, , MW-7 12/12/06 4, , MW-7 1/11/08 4, ,910.7 MW-7 12/23/08 4, , MW-7 12/29/09 4, , MW-7 12/29/10 4, , MW-7 12/28/11 4, , MW-7 6/12/12 4, , MW-7 12/13/12 4, , MW-7 6/19/13 4, , MW-7 12/12/13 4, , MW-8 12/29/10 4, , MW-8 05/18/11 4, , MW-8 08/23/11 4, , MW-8 11/28/11 4, , MW-8 12/29/11 4, , MW-8 12/13/12 4, , MW-8 6/18/13 4, , MW-9 12/29/10 4, , MW-9 05/18/11 4, , MW-9 08/23/11 4, , MW-9 11/28/11 4, , MW-9 12/29/11 4, , MW-9 12/20/12 4, , MW-9 6/26/13 4, , ft bmp - feet below measuring point ft amsl - feet above mean sea level JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
55 JSAI Appendix B. Baseline and background monitoring data for monitor wells MW-1 through MW-9 Las Cruces Foothills Landfill, Las Cruces, New Mexico JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
56 JSAI MW-1 JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
57 APPEIX B Las Cruces Foothills Landfill MW-1 Page 1 of 4 Las Cruces Foothills Landfill monitoring well MW-1 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-1 average deviation date 3/1/90 5/19/92 7/20/92 12/7/93 6/7/96 5/11/99 7/7/99 9/15/99 11/3/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 12/19/12 6/25/13 12/19/13 5/11/99 to 5/11/99 to 5/18/00 5/18/00 Field Parameters water level elevation - ft amsl - x x x x x x , , , , , , , , , , , , , conductivity - µs/cm x 300 x ph - ph units x temperature - deg F Major Ions calcium mg/l x 24.7 x x chloride mg/l x 16.1 x x fluoride mg/l x 0.62 x x x x x x 0.54 x 0.52 x x x x magnesium mg/l x 5.7 x x potassium mg/l x 1.6 x x sodium mg/l x 31.9 x x sulfate mg/l x 34.6 x x alkalinity - mg/l x 96.5 x x bicarbonate alkalinity mg/l x x x carbonate alkalinity mg/l - <1.0 <1.0 x <1.0 x <1.0 <1.0 <1.0 <1.0 < x <1.0 <2.0 <2.0 <2.0 <2.0 <4.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <1.0 x total dissolved solids - mg/l 1, x 213 x x Nitrogen Species ammonia as N mg/l - x 1.08 x 0.27 x <0.01 <0.01 x x < < <0.50 <1.0 < <1.0 < Kjeldahl nitrogen mg/l - x 1.1 x 0.8 x x <1.0 x x 1.1 x <1.0 x x x x x x nitrate as N mg/l 10 x 1.21 x 3.22 x <0.05 x < <1.0 < <0.1 < < nitrite mg/l - < x 3.22 x <0.05 < <0.05 <0.05 <0.05 x < <0.10 <0.1 <1.0 x x x x x x x x x x x total nitrogen - mg/l - x x x x x x x x x x x x x x x x x x x x x x x <1.0 x x x x x x x x Metals aluminum mg/l 5.0 x 0.28 x x <0.05 <0.05 < < x <0.10 <0.03 <0.03 <0.03 <3.0 <3.0 x x x <0.02 x <0.02 x x x x antimony mg/l x x x x x < < < < < < < <0.05 < (") <0.004 < <0.003 x x x x <0.001 <0.001 <0.001 < <0.001 <0.001 < x arsenic mg/l x x <0.005 < < < <0.01 x x x x <0.006 <0.002 <0.001 < < < barium mg/l x 0.09 x x x x x beryllium mg/l x x x x x < < < < < < < < <0.003 < <0.001 <0.001 < <0.002 x x x x <0.003 x < <0.002 <0.002 <0.002 < x boron mg/l 0.75 x 0.1 x 0.05 x < <0.01 x < <0.1 <0.5 x x x x <0.04 x <0.04 x x x x cadmium mg/l <0.005 <0.005 x <0.005 x < < < < <0.005 < <0.001 <0.001 < <0.002 x x x x <0.002 <0.002 <0.002 < <0.002 <0.002 < chromium mg/l x x < < < <0.005 < <0.002 < <0.01 x x x x <0.006 <0.006 < <0.006 <0.006 < cobalt mg/l 0.05 x <0.01 x <0.01 x < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.010 <0.001 < <0.03 x x x x <0.006 <0.006 < <0.006 <0.006 < x copper mg/l 1.0 x 0.03 x x <0.01 < <0.01 < < <0.06 x x x x <0.006 <0.006 < <0.006 <0.006 < iron mg/l x 4.86 x < x lead mg/l x x < <0.005 < <0.002 < <0.01 x x x x <0.005 <0.005 < <0.001 < manganese mg/l x 0.05 x <0.005 <0.005 x <0.03 <0.03 <0.03 <0.03 < mercury mg/l < < x < x < < < < < < < <0.07 <0.20 < <0.001 x x x x < x < x x x x molybdenum mg/l 1.0 x <0.05 x <0.05 x <0.05 <0.05 <0.05 < x < <0.010 <0.75 x x x x <0.008 x x x x x x 0.00 x nickel mg/l 0.2 x <0.05 x <0.05 x <0.005 < < <0.05 x x x x <0.01 <0.01 < <0.01 <0.01 < selenium mg/l 0.05 < x x < < <0.01 < < <0.005 x x x x <0.001 <0.001 < < silver mg/l 0.05 <0.02 <0.02 x <0.02 x <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.005 < <0.002 <0.002 <0.010 <0.01 x x x x <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.02 x thallium mg/l x x x x x < < < < <0.01 <0.010 <0.003 < <0.001 x x x x <0.001 <0.001 <0.001 < <0.001 <0.001 < tin mg/l - x x x x x x x x x x x x x <0.01 x x x x x x x x x <0.1 x x x x x x x x uranium mg/l 0.03 x x x x < x < <0.002 <2.5 x x x x <0.001 x x x x x x vanadium mg/l - x x x x x < <0.05 <0.05 x <0.05 <0.05 <0.05 <0.01 < <0.050 <0.08 x x x x <0.05 <0.05 < <0.05 <0.05 < x zinc mg/l 10.0 x 0.86 x 0.14 x x 0.21 < <0.02 <0.020 <0.008 <0.008 <0.020 <0.05 x x x x <0.02 <0.02 < <0.01 <0.01 < total organic carbon - mg/l - x x x 0.5 x x <1.0 <1.0 < < phosphate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.50 x <0.5 x x x x x x sulfide mg/l - x x x x x x x x x x x x x <1.0 x x x x x x x x x <1 x x x x x x x x cyanide mg/l 0.2 x x <0.02 <0.02 x <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 < < < <0.005 <0.01 <0.1 x x x x <0.005 x x x x x x x x perchlorate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x total phenolics 1 - mg/l x x 0.03 x x 0.02 <0.02 <0.003 <0.003 <0.003 < (^) < <0.005 <0.003 <0.003 <0.003 <0.003 < < < < < < < x Polychlorinated Biphenyls (PCBs) mg/l x x < < x < < < < < < < < (^^) (^^) (^^) (^^) (^^) (^^) x x x x (^^) x x x x x x < x Volatile Organic Compounds 1,1,1,2-Tetrachloroethane mg/l 0.02 x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x 1,1,1-Trichloroethane mg/l 0.06 x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x 1,1,2,2-Tetrachloroethane mg/l 0.01 x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x 1,1,2-Trichloroethane mg/l x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x 1,1-Dichloroethane mg/l x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x 1,1-Dichloroethylene (1,1-Dichloroethene; 1,1-DCE) mg/l x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x 1,1-Dichloropropene mg/l - x x x x x x x x x x x x x <0.001 <0.001 <0.001 x < x x x x x <0.005 x x x x x x x x 1,2 Dibromo-3-chloropropane (DBCP) mg/l x x x x x < < < < < < < < < <0.001 < < < < < < < < < < < < < < < < x 1,2,3-Trichlorobenzene mg/l - x x <0.001 x x <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x < x 1,2,3-Trichloropropane mg/l 0.01 x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x 1,2,4-Trichlorobenzene mg/l - x x <0.001 x x <0.001 < < < < < < < <0.02 <0.001 x <0.001 < x x x x x <0.001 x x x x x x < x 1,2-Dichlorobenzene (o-dichlorobenzene) mg/l 0.6 x x x x x x x x x x x x x <0.001 <0.001 <0.001 <0.001 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x x 1,2-Dichloroethane (EDC) mg/l x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x 1,2-Dichloropropane mg/l x x <0.001 x x <0.001 < < < < < < < < <0.001 < <0.001 < < < < < < < < < < < < < < x 1,3-Dichlorobenzene (m-dichlorobenzene) mg/l - x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < x x x x x <0.01 <0.001 x x x x x < x 1,3-Dichloropropane mg/l - x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < x x x x x <0.01 x x x x x x < x 1,4-Dichlorobenzene (p-dichlorobenzene) mg/l x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 < <0.001 <0.001 <0.001 < x 2,2-Dichloropropane mg/l - x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < x x x x x <0.015 x x x x x x < x 2-Butanone (Methyl Ethyl Ketone) (MEK) mg/l - x x <0.005 x x <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 <0.01 <0.01 <0.01 <0.025 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
58 APPEIX B Las Cruces Foothills Landfill MW-1 Page 2 of 4 Las Cruces Foothills Landfill monitoring well MW-1 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-1 average deviation date 3/1/90 5/19/92 7/20/92 12/7/93 6/7/96 5/11/99 7/7/99 9/15/99 11/3/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 12/19/12 6/25/13 12/19/13 5/11/99 to 5/11/99 to 5/18/00 5/18/00 2-Chlorotoluene mg/l - x x <0.001 x x <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x < x 2-Hexanone (Butyl Ketone) mg/l 0.02 x x <0.002 x x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 <0.01 <0.01 <0.001 <0.025 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x 4-Chlorotoluene mg/l - x x <0.001 x x <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x < x 4-Methyl-2-pentanone mg/l - x x x x x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 <0.01 <0.01 <0.001 <0.025 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 x x x x x x <0.002 x Acetone mg/l - x x <0.005 x x x <0.01 <0.01 <0.01 <0.01 <0.01 < <0.01 <0.01 <0.01 <0.01 <0.025 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Acrolein mg/l - x x x x x x x x x x x x x <0.005 <0.005 <0.005 x <0.025 x x x x x <0.1 x x x x x x x x Acrylonitrile mg/l - x x x x x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.005 <0.005 <0.005 <0.005 <0.025 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Benzene mg/l x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x Bis(chloromethyl) ether mg/l - x x x x x x x x x x x x x x x x x x x x x x x (#) x x x x x x x x Bromochloromethane mg/l - x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 < x Bromomethane (methyl bromide) mg/l - <0.001 <0.001 < < < < < < < <0.002 < < <0.002 <0.002 <0.001 < <0.001 <0.001 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x Carbon Disulfide mg/l - x x x x x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.005 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Carbon Tetrachloride mg/l x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x Chlorobenzene mg/l 0.1 x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x Chloroethane mg/l - x x <0.001 x x <0.001 < < < < < < < <0.002 <0.001 < <0.001 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 < x Chloromethane (methyl chloride) mg/l 0.02 x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 < <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x Chloroprene (2-Chloro-1,3-butadiene) mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x cis-1,2-dichloroethylene (cis-1,2-dichloroethene) mg/l 0.07 x x x x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 < < x cis-1,3-dichloropropene mg/l - x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x Dibromomethane (methylene bromide) mg/l - x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x Dichlorodifluoromethane mg/l - x x <0.001 x x < x x x x < x Ethyl methacrylate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.01 x x x x x x x x Ethylbenzene mg/l 0.75 x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < <0.001 <0.001 <0.001 < x Ethylene Dibromide (1,2-Dibromoethane) (EDB) mg/l 5E-05 x x x < x < < < < < < < < < <0.01 < < < < < < < < < < < < < < < < x Hexachlorobutadiene mg/l - x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < x x x x x <0.001 x x x x x x < x Isobutyl alcohol mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.05 x x x x x x x x Isopropylbenzene mg/l - x x <0.001 x x <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x < x Methacrylonitrile mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.005 x x x x x x x x Methyl Iodide (Iodomethane) mg/l - x x x x x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.005 <0.005 <0.005 <0.005 <0.005 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Methyl methacrylate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.03 x x x x x x x x Methylene Chloride mg/l x x <0.005 x x <0.002 < < < < < < <0.001 <0.001 < <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 < x n-butylbenzene mg/l - x x <0.001 x x <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x < x Propionitrile mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.06 x x x x x x x x Propylbenzene mg/l - x x <0.001 x x <0.001 < < < < < < < x <0.001 x <0.001 x x x x x x x x x x x x x < x sec-butylbenzene mg/l - x x <0.001 x x <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x < x Styrene mg/l 0.1 x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x tert-butyl methyl ether (MTBE) (a) mg/l 0.1 x x <0.005 x x <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x <0.001 x <0.001 <0.005 x x x x x <0.001 x x x x x x <0.002 x tert-butylbenzene mg/l - x x <0.001 x x <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x < x Tetrachloroethene (PCE) mg/l x x x x Tetrahydrofuran (THF) mg/l - x x <0.005 x x <0.001 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.010 x x x x x x x x x x x x <0.002 x Toluene mg/l 0.75 x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < <0.001 <0.001 <0.001 < x Total Xylenes (m&p and o) 1 - mg/l 0.62 x x <0.001 x x < < < < < < < <0.001 <0.001 <0.002 <0.002 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.002 < <0.002 <0.002 <0.002 < x trans-1,2-dichloroethene mg/l 0.1 x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 < <0.001 <0.001 <0.001 < x trans-1,3-dichloropropene mg/l - x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x trans-1,4-dichloro-2-butene mg/l - x x <0.002 x x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.010 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Trichloroethene (TCE) mg/l x x <0.001 x x <0.001 < < < < < < <0.001 <0.001 <0.001 < <0.001 <0.001 < <0.001 <0.001 < < x Trichlorofluoromethane mg/l - x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 < <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 < <0.001 <0.001 <0.001 x Vinyl acetate mg/l - x x <0.001 x x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.025 <0.05 <0.05 <0.05 <0.05 <0.05 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Vinyl Chloride mg/l x x x x x <0.001 < < < < < < < < <0.001 < <0.001 < < < < < < < < < < < < < < x Trihalomethanes (THM) Bromodichloromethane mg/l - x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x Bromoform mg/l 0.1 x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.001 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x Chloroform mg/l 0.1 x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x Dibromochloromethane mg/l - x x <0.001 x x <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x Semi Volatile Organic Compounds 1,2,4,5-Tetrachlorobenzene mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 1,2-Diphenylhydrazine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 1,4-Naphthoquinone mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 1-Chloronaphthalene - mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x 1-Methylnaphthalene mg/l - x x x x x x x x x x x x x x x < < <0.005 <0.01 x x x x <0.001 x x x x x x x x 1-Naphthylamine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 2,4,6-Trinitrotoluene (TNT) mg/l - x x x x x x x x x x x x x x x x x x x x x x x < x x x x x x x x 2,4-Dinitrotoluene (2,4-DNT) mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 2,6-Dinitrotoluene 1 (2,6-DNT) mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 2-Chloronaphthalene mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 2-Methylnaphthalene mg/l - x x x x x x x x x x x x x x x < < <0.010 <0.01 x x x x <0.001 x x x x x x x x 2-Naphthylamine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 2-Nitroaniline (o-nitroaniline) mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 2-Picoline mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 3,3'-Dichlorobenzidine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 3,3'-Dimethylbenzidine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 3-Methylcholanthrene mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 3-Nitroaniline (m-nitroaniline) mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 4-Aminobiphenyl mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
59 APPEIX B Las Cruces Foothills Landfill MW-1 Page 3 of 4 Las Cruces Foothills Landfill monitoring well MW-1 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-1 average deviation date 3/1/90 5/19/92 7/20/92 12/7/93 6/7/96 5/11/99 7/7/99 9/15/99 11/3/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 12/19/12 6/25/13 12/19/13 5/11/99 to 5/11/99 to 5/18/00 5/18/00 4-Bromophenylphenyl ether mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 4-Chloroaniline (p-chloroanaline) mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 4-Chlorophenylphenyl ether mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 4-Nitroaniline (p-nitroaniline) mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 7,12-Dimethylbenz (a) anthracene mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Acenaphthene mg/l - x x x x x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x Acenaphthylene mg/l - x x x x x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x Acetophenone mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x alpha,alpha-dimethylphenethylamine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Aniline mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Anthracene mg/l - x x x x x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x Benzidine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Benzo (a) anthracene mg/l - x x x x x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x Benzo (b) fluoranthene mg/l - x x x x x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x Benzo (g,h,i) perylene mg/l - x x x x x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x Benzo (k) fluoranthene mg/l - x x x x x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x Benzo[a]pyrene mg/l x x x <0.001 x <0.001 < < < < < < < x < < < <0.005 < x x x x < x x x x x x < x Benzoic acid mg/l x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x Benzyl alcohol mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x bis (2-Chloroethoxy) methane mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x bis (2-Chloroethyl) ether mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x bis (2-Chloroisopropyl) ether (bis (2-chloro-1-methylethyl) ether) mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x bis (2-Ethylhexyl) phthalate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Butylbenzylphthalate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Carbazole mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Chlorobenzilate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Chrysene mg/l - x x x x x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x Diallate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Dibenz (a,j) acridine mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x Dibenzo (a,h) anthracene mg/l - x x x x x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x Dibenzofuran mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Diethylene Glycol Monobutyl Ether mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x Diethylphthalate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Dimethylphthalate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Di-n-butylphthalate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Di-n-octylphthalate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Diphenylamine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Ethyl methanesulfonate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Fluoranthene mg/l - x x x x x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x Fluorene mg/l - x x x x x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x Hexachlorobenzene mg/l - x x x x x x x x x x x x x x x x x x x x x x x < x x x x x x x x Hexachlorocyclopentadiene mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Hexachloroethane mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Hexachloropropene mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x HMX mg/l - x x x x x x x x x x x x x x x x x x x x x x x < x x x x x x x x Indeno (1,2,3-cd) pyrene mg/l - x x x x x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x Isophorone mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Isosafrole mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x m-dinitrobenzene (1,3-DNB) mg/l - x x x x x x x x x x x x x x x x x x x x x x x < x x x x x x x x Methapyrilene mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Methyl methanesulfonate mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Naphthalene mg/l 0.03 x x <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 < < < <0.02 < < < < <0.01 x x x x <0.001 x x x x x x < x Nitrobenzene mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosodiethylamine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosodimethylamine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosodi-n-butylamine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosodinpropylamine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosodiphenylamine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosomethylethylamine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosopiperidine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosopyrrolidine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x o-toluidine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x p-(dimethylamino) azobenzene mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Pentachlorobenzene mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Pentachloronitrobenzene mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Phenacetin mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Phenanthrene mg/l - x x <0.01 <0.01 x <0.001 < < < < < < < <0.02 < < < <0.005 x x x x x <0.001 x x x x x x < x p-phenylenediamine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Pronamide mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Pyrene mg/l - x x <0.01 <0.01 x < < < < < < < < <0.02 < < < <0.005 x x x x x <0.001 x x x x x x < x Pyridine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x RDX mg/l - x x x x x x x x x x x x x x x x x x x x x x x < x x x x x x x x Safrole mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
60 APPEIX B Las Cruces Foothills Landfill MW-1 Page 4 of 4 Las Cruces Foothills Landfill monitoring well MW-1 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-1 average deviation date 3/1/90 5/19/92 7/20/92 12/7/93 6/7/96 5/11/99 7/7/99 9/15/99 11/3/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 12/19/12 6/25/13 12/19/13 5/11/99 to 5/11/99 to 5/18/00 5/18/00 sym-trinitrobenzene 1 (1,3,5-trinitrobenzene, 1,3,5-TN mg/l - x x x x x x x x x x x x x x x x x x x x x x x < x x x x x x x x Semi Volatile Organic Compounds - Phenolics x 2,3,4,6-Tetrachlorophenol mg/l - x x x x x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x 2,4,5-Trichlorophenol mg/l - x x x x x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x 2,4,6-Trichlorophenol mg/l - x x x x x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x 2,4-Dichlorophenol mg/l - x x x x x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x 2,4-Dimethylphenol mg/l - x x x x x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x 2,4-Dinitrophenol mg/l - x x x x x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x 2,6-Dichlorophenol mg/l - x x x x x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x 2-Chlorophenol mg/l - x x x x x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x 2-Methylphenol (o-cresol) mg/l - x x x x x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x 2-Nitrophenol (o-nitrophenol) mg/l - x x x x x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x 3-Methylphenol/4-Methylphenol (m&p-cresol) / mg/l - x x x x x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x 4,6-Dinitro-2-methylphenol (4,6-Dinitro-o-cresol) mg/l - x x x x x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x p-chloro-m-cresol (4-Chloro-3-methylphenol) mg/l - x x x x x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x 4-Nitrophenol (p-nitrophenol) mg/l - x x x x x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x 5-Nitro-o-toluidine mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Pentachlorophenol mg/l - x x x x x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x Phenol 1 (a) mg/l x x x x x x x x x x x x x < x x x x x x x x x <0.001 x x x x x x x x Radium 226 and pci/l 5 x x x < Ra-226, total pci/l - x x x <2.5 x x x x x x x x x x Ra-228 1, total pci/l - x x x <2.5 x x x x -0.4 x x x x x x Chlorinated Pesticides 4,4'-DDD (p,p'-ddd) mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x 4,4'-DDE (p,p'-dde) mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x 4,4'DDT (p,p'-ddt) mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x aldrin mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x alpha-bhc mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x alpha-chlordane mg/l - x x x x x x x x x x x x x < < x x x x x x x x x x x x x x x x x beta-bhc mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x Chlordane mg/l x x x x x x x x x x x x x x x x x x x x x x x < x x x x x x x x delta-bhc mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x Dieldrin mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x Endosulfan I (alpha-endosulfan) mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x Endosulfan II (beta-endosulfan) mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x Endosulfan sulfate mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x Endrin aldehyde mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x Endrin ketone mg/l - x x x x x x x x x x x x x < < x x x x x x x x x x x x x x x x x Endrin mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x gamma-bhc mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x gamma-chlordane mg/l - x x x x x x x x x x x x x < < x x x x x x x x x x x x x x x x x Heptachlor epoxide mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x Heptachlor mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x Isodrin mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Kepone mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Methoxychlor mg/l - x x x x x x x x x x x x x < < x x x x x x x x < x x x x x x x x Toxaphene mg/l - x x x x x x x x x x x x x <0.003 < x x x x x x x x <0.001 x x x x x x x x Polychlorinated Biphenyls (PCBs) 1 mg/l Arochlor mg/l - x x x x x x x x x x x x x < < < < < < x x x x < x x x x x x x x Arochlor mg/l - x x x x x x x x x x x x x < < < < < < x x x x < x x x x x x x x Arochlor mg/l - x x x x x x x x x x x x x < < < < < < x x x x < x x x x x x x x Arochlor mg/l - x x x x x x x x x x x x x < < < < < < x x x x < x x x x x x x x Arochlor mg/l - x x x x x x x x x x x x x < < < < < < x x x x < x x x x x x x x Arochlor mg/l - x x x x x x x x x x x x x < < < < < < x x x x < x x x x x x x x Arochlor mg/l - x x x x x x x x x x x x x < < < < < < x x x x < x x x x x x x x Other Pesticides and Herbicides 1 2,3,7,8-TCDD ng/l 0.03 x x x x x x x x x x x x x x x x x x x x x x x < x x x x x x x x 2,4,5-T mg/l - x x x x x x x x x x x x x <0.002 x x x x x x x x x < x x x x x x x x 2,4-Dichlorophenoxyacetic acid (2,4-D) mg/l - x x x x x x x x x x x x x <0.002 x x x x x x x x x < x x x x x x x x Dimethoate mg/l - x x x x x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x Dinoseb mg/l - x x x x x x x x x x x x x <0.002 x x x x x x x x x < x x x x x x x x Disulfoton mg/l - x x x x x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x Famphur mg/l - x x x x x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x Methyl parathion mg/l - x x x x x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x o,o,o-triethyl phosphorothioate mg/l - x x x x x x x x x x x x x <0.003 x x x x x x x x x <0.001 x x x x x x x x Parathion (Ethyl) mg/l - x x x x x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x Phorate mg/l - x x x x x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x Silvex mg/l - x x x x x x x x x x x x x <0.002 x x x x x x x x x < x x x x x x x x o,o-diethyl o-2pyrazinyl phosphorothioate (Thionazin) mg/l - x x x x x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 1 hazardous x parameter not analyzed (^) See section entitled 'Semi volatile organic compounds - phenolics' for break-out of phenolics concentrations. (^^) See section entitled 'Polychlorinated Biphenyls (PCBs)' for break-out of PCB concentrations. (") This concentration attributed to laboratory contamination of method blank and not the presence of antimony in the ground water sampled. (#) Scanned for and not detected, breaks down almost immediately in water. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
61 JSAI MW-2 JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
62 APPEIX B Las Cruces Foothills Landfill MW-2 Page 1 of 5 Las Cruces Foothills Landfill monitoring well MW-2 *no sampling of MW-2 on 7/15/03 because pump was not working baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-2 average deviation date 1/12/99 5/11/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 Field Parameters water level elevation NA ft amsl , conductivity NA µs/cm ph NA ph units temperature NA deg F Major Ions calcium mg/l x chloride mg/l x fluoride mg/l x x x x x 0.57 x 0.57 x x x x magnesium mg/l x potassium mg/l x sodium mg/l x sulfate mg/l x alkalinity NA mg/l x bicarbonate alkalinity mg/l x carbonate alkalinity mg/l - <1.0 <1.0 <1.0 <1.0 <1.0 x x x x x <1.0 <2.0 <2.0 <2.0 <4.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <1.0 x total dissolved solids NA mg/l 1, x Nitrogen Species ammonia as N mg/l <0.01 < <0.01 < <0.01 x x <0.05 <0.05 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1.0 <1.0 < <1.0 < Kjeldahl nitrogen mg/l < <0.01 x 0.89 < <1.0 x x x x <1.0 x x x x x x nitrate as N mg/l x < < nitrite mg/l <0.05 <0.05 <0.05 <0.05 < <0.05 x <0.10 <0.1 <0.10 <1.0 x x x x x x x x x x x total nitrogen - mg/l - x x x x x x x x x x x x x x x x x x 1.7 x x x x x x x x Metals aluminum mg/l <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 x <0.10 < <3.0 <3.0 x x x <0.02 x <0.02 x x x x antimony mg/l < < < < < < < < <0.05 < (") <0.004 <0.003 x x x x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x arsenic mg/l <0.005 < <0.004 <0.004 <0.01 x x x x barium mg/l x x x x beryllium mg/l < < < < < < < < <0.003 < <0.001 <0.001 <0.002 x x x x <0.003 x < <0.002 <0.002 < x boron mg/l 0.75 < <0.01 x < <0.5 x x x x <0.04 x <0.04 x x x x cadmium mg/l < < < < < < < <0.005 < <0.001 <0.001 <0.002 x x x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 < chromium mg/l 0.05 < < < <0.005 < < <0.01 x x x x <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 < cobalt mg/l 0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.010 <0.001 <0.001 <0.03 x x x x <0.006 <0.006 < <0.006 <0.006 <0.006 <0.01 x copper mg/l < <0.01 <0.010 < <0.06 x x x x <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 < iron mg/l < < <0.01 x < <0.10 <0.05 <0.05 <0.05 <0.02 < < lead mg/l < <0.005 < < <0.01 x x x x <0.005 <0.005 <0.005 < <0.001 < manganese mg/l < < <0.005 <0.005 x <0.010 < <0.03 <0.03 <0.03 <0.03 <0.03 <0.002 <0.002 < <0.002 <0.002 < mercury mg/l < < < < < < < < <0.07 <0.20 <0.001 x x x x < x < x x x x molybdenum mg/l 1.0 <0.05 <0.05 <0.05 <0.05 < x < <0.75 x x x x <0.008 x <0.008 x x x x <0.05 x nickel mg/l <0.005 < < <0.05 x x x x <0.01 <0.01 < <0.01 < selenium mg/l <0.01 < <0.003 <0.005 x x x x <0.001 <0.001 <0.001 < < silver mg/l 0.05 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 < <0.02 <0.005 < <0.002 <0.002 <0.01 x x x x <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.02 x thallium mg/l < < < < <0.01 <0.010 <0.003 <0.003 <0.001 x x x x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < tin mg/l - x x x x x x x x x <0.01 x x x x x x x x <0.1 x x x x x x x x uranium mg/l x < <2.5 x x x x x x x x x x vanadium mg/l - <0.05 < <0.05 < <0.05 <0.05 <0.05 <0.01 < <0.08 x x x x <0.05 <0.05 < <0.05 < x zinc mg/l < <0.01 < <0.020 < <0.05 x x x x <0.02 <0.02 < <0.01 < total organic carbon - mg/l <0.5 <0.5 < x < < <1.0 <1.0 < <1.0 < phosphate mg/l - x x x x x x x x x x x x x x x x x x <0.50 x <0.50 x x x x x x sulfide mg/l - x x x x x x x x x <1.0 x x x x x x x x 3 x x x x x x x x cyanide mg/l 0.2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.005 < <0.005 <0.005 <0.1 x x x x <0.005 x x x x x x <0.02 x perchlorate mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x total phenolics 1 - mg/l <0.005 < < < (^) < <0.003 <0.003 <0.003 <0.003 <0.003 < < < < < < < < Polychlorinated Biphenyls (PCBs) mg/l < < < < < < < < (^^) (^^) (^^) (^^) (^^) x x x x (^^) x x x x x x < x Volatile Organic Compounds 1,1,1,2-Tetrachloroethane mg/l 0.02 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,1-Trichloroethane mg/l 0.06 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,2,2-Tetrachloroethane mg/l 0.01 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,2-Trichloroethane mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloroethane mg/l <0.001 <0.001 < < < < <0.001 <0.001 <0.001 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < <0.001 <0.001 <0.001 x 1,1-Dichloroethylene (1,1-Dichloroethene; 1,1-DCE) mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloropropene mg/l - x x x x x x x x x <0.001 <0.001 <0.001 x x x x x x <0.005 x x x x x x x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
63 APPEIX B Las Cruces Foothills Landfill MW-2 Page 2 of 5 Las Cruces Foothills Landfill monitoring well MW-2 *no sampling of MW-2 on 7/15/03 because pump was not working baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-2 average deviation date 1/12/99 5/11/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 1,2 Dibromo-3-chloropropane (DBCP) mg/l <0.01 <0.01 < < < < < < < < <0.001 x < < < < < < < < < < < < < <0.01 x 1,2,3-Trichlorobenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 x x x x x x x x x x x x <0.001 x 1,2,3-Trichloropropane mg/l 0.01 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2,4-Trichlorobenzene mg/l - <0.001 <0.001 < < < < < < < <0.02 <0.001 x <0.001 x x x x x <0.001 x x x x x x <0.001 x 1,2-Dichlorobenzene (o-dichlorobenzene) mg/l 0.6 x x x x x x x x x <0.001 <0.001 <0.001 x <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x x 1,2-Dichloroethane (EDC) mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2-Dichloropropane mg/l <0.001 <0.001 < < < < < < < < <0.001 < < < < < < < < < < < < < < <0.001 x 1,3-Dichlorobenzene (m-dichlorobenzene) mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 x x x x x <0.01 <0.001 x x x x x <0.001 x 1,3-Dichloropropane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 x x x x x <0.01 x x x x x x <0.001 x 1,4-Dichlorobenzene (p-dichlorobenzene) mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 2,2-Dichloropropane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 x x x x x <0.015 x x x x x x <0.001 x 2-Butanone (Methyl Ethyl Ketone) (MEK) mg/l - <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x 2-Chlorotoluene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 x x x x x x x x x x x x <0.001 x 2-Hexanone (Butyl Ketone) mg/l 0.02 x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 <0.01 <0.01 <0.01 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x 4-Chlorotoluene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 x x x x x x x x x x x x <0.001 x 4-Methyl-2-pentanone mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 <0.01 <0.01 <0.01 <0.04 <0.015 <0.015 <0.015 <0.015 <0.04 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x Acetone mg/l - x x <0.01 <0.01 <0.01 <0.01 <0.01 < <0.01 <0.01 <0.01 <0.01 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Acrolein mg/l - x x x x x x x x x <0.005 <0.05 <0.005 x x x x x x <0.1 x x x x x x x x Acrylonitrile mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.005 <0.05 <0.005 <0.005 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Benzene mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Bis(chloromethyl) ether mg/l - x x x x x x x x x x x x x x x x x x (#) x x x x x x x x Bromochloromethane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 x Bromomethane (methyl bromide) mg/l - <0.001 <0.001 < < < < < < < <0.002 <0.001 <0.001 <0.001 <0.002 <0.02 <0.02 <0.02 <0.02 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 x Carbon Disulfide mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x Carbon Tetrachloride mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chlorobenzene mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroethane mg/l - <0.001 <0.001 < < < < < < < <0.002 <0.001 <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 x Chloromethane (methyl chloride) mg/l 0.02 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroprene (2-Chloro-1,3-butadiene) mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x cis-1,2-dichloroethylene (cis-1,2-dichloroethene) mg/l 0.07 <0.001 <0.001 < < < < <0.001 <0.001 <0.001 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < <0.001 <0.001 <0.001 <0.001 x cis-1,3-dichloropropene mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dibromomethane (methylene bromide) mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dichlorodifluoromethane mg/l x x x x < < < x Ethyl methacrylate mg/l - x x x x x x x x x x x x x x x x x x <0.01 x x x x x x x x Ethylbenzene mg/l 0.75 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Ethylene Dibromide (1,2-Dibromoethane) (EDB) mg/l <0.001 <0.001 < < < < < < < < <0.001 x < < < < < < < < < < < < < <0.001 x Hexachlorobutadiene mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 x x x x x <0.001 x x x x x x <0.001 x Isobutyl alcohol mg/l - x x x x x x x x x x x x x x x x x x <0.05 x x x x x x x x Isopropylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 x x x x x x x x x x x x <0.001 x Methacrylonitrile mg/l - x x x x x x x x x x x x x x x x x x <0.005 x x x x x x x x Methyl Iodide (Iodomethane) mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.005 <0.001 <0.005 <0.005 <0.001 <0.04 <0.04 <0.04 <0.04 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x Methyl methacrylate mg/l - x x x x x x x x x x x x x x x x x x <0.03 x x x x x x x x Methylene Chloride mg/l <0.002 <0.002 < < < <0.001 <0.001 < <0.001 <0.015 <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 x n-butylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 x x x x x x x x x x x x <0.001 x Propionitrile mg/l - x x x x x x x x x x x x x x x x x x <0.06 x x x x x x x x Propylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 x x x x x x x x x x x x <0.001 x sec-butylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 x x x x x x x x x x x x <0.001 x Styrene mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x tert-butyl methyl ether (MTBE) (a) mg/l 0.1 <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 < x <0.001 x <0.001 x x x x x <0.001 x x x x x x <0.01 x tert-butylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 x x x x x x x x x x x x <0.001 x Tetrachloroethene (PCE) mg/l < Tetrahydrofuran (THF) mg/l - <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x x x x x x x x x x x x x <0.01 x Toluene mg/l 0.75 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < <0.001 <0.001 <0.001 <0.001 x Total Xylenes (m&p and o) 1 NA mg/l 0.62 <0.001 < < < < < < < <0.002 <0.001 <0.002 <0.002 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.002 < <0.002 <0.002 <0.002 <0.001 x trans-1,2-dichloroethene mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.005 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x trans-1,3-dichloropropene mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x trans-1,4-dichloro-2-butene mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x Trichloroethene (TCE) mg/l < < < < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < < Trichlorofluoromethane mg/l - <0.001 <0.001 < < < <0.001 <0.001 <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 < <0.001 <0.001 <0.001 <0.001 x Vinyl acetate mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x Vinyl Chloride mg/l <0.001 <0.001 < < < < < < < < <0.001 < < < < < < < < < < < < < < <0.001 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
64 APPEIX B Las Cruces Foothills Landfill MW-2 Page 3 of 5 Las Cruces Foothills Landfill monitoring well MW-2 *no sampling of MW-2 on 7/15/03 because pump was not working baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-2 average deviation date 1/12/99 5/11/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 Trihalomethanes (THM) Bromodichloromethane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Bromoform mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroform mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dibromochloromethane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Semi Volatile Organic Compounds 1,2,4,5-Tetrachlorobenzene mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 1,2-Diphenylhydrazine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 1,4-Naphthoquinone mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 1-Chloronaphthalene NA mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x 1-Methylnaphthalene mg/l - x x x x x x x x x x x < < <0.01 x x x x <0.001 x x x x x x x x 1-Naphthylamine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 2,4,6-Trinitrotoluene (TNT) mg/l - x x x x x x x x x x x x x x x x x x < x x x x x x x x 2,4-Dinitrotoluene (2,4-DNT) mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 2,6-Dinitrotoluene 1 (2,6-DNT) mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 2-Chloronaphthalene mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 2-Methylnaphthalene mg/l - x x x x x x x x x x x < < <0.01 x x x x <0.001 x x x x x x x x 2-Naphthylamine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 2-Nitroaniline (o-nitroaniline) mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 2-Picoline mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 3,3'-Dichlorobenzidine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 3,3'-Dimethylbenzidine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 3-Methylcholanthrene mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 3-Nitroaniline (m-nitroaniline) mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 4-Aminobiphenyl mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 4-Bromophenylphenyl ether mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 4-Chloroaniline (p-chloroanaline) mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 4-Chlorophenylphenyl ether mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 4-Nitroaniline (p-nitroaniline) mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 7,12-Dimethylbenz (a) anthracene mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Acenaphthene mg/l - x x x x x x x x x <0.02 < < < < x x x x < x x x x x x x x Acenaphthylene mg/l - x x x x x x x x x <0.02 < < < x x x x x <0.001 x x x x x x x x Acetophenone mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x alpha,alpha-dimethylphenethylamine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Aniline mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Anthracene mg/l - x x x x x x x x x <0.02 < < < x x x x x <0.001 x x x x x x x x Benzidine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Benzo (a) anthracene mg/l - x x x x x x x x x <0.02 < < < x x x x x <0.001 x x x x x x x x Benzo (b) fluoranthene mg/l <0.1 <0.001 < < < < < < < <0.02 < < < x x x x x <0.001 x x x x x x <0.1 x Benzo (g,h,i) perylene mg/l - x x x x x x x x x <0.02 < < < x x x x x < x x x x x x x x Benzo (k) fluoranthene mg/l - x x x x x x x x x <0.02 < < < x x x x x < x x x x x x x x Benzo[a]pyrene mg/l - x x x x x x x x x <0.02 < < < x x x x x < x x x x x x x x Benzoic acid mg/l x x x x x <0.1 x x x x x x x x x x x x x x x Benzyl alcohol mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x bis (2-Chloroethoxy) methane mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x bis (2-Chloroethyl) ether mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x bis (2-Chloroisopropyl) ether (bis (2-chloro-1-methylethyl) ether) mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x bis (2-Ethylhexyl) phthalate mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Butylbenzylphthalate mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Carbazole mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Chlorobenzilate mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Chrysene mg/l - x x x x x x x x x <0.02 < < < x x x x x < x x x x x x x x Diallate mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Dibenz(a,j)acridine mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x Dibenzo (a,h) anthracene mg/l - x x x x x x x x x <0.02 < < < x x x x x < x x x x x x x x Dibenzofuran mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Diethylene Glycol Monobutyl Ether mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x Diethylphthalate mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Dimethylphthalate mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Di-n-butylphthalate mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Di-n-octylphthalate mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
65 APPEIX B Las Cruces Foothills Landfill MW-2 Page 4 of 5 Las Cruces Foothills Landfill monitoring well MW-2 *no sampling of MW-2 on 7/15/03 because pump was not working baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-2 average deviation date 1/12/99 5/11/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 Diphenylamine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Ethyl methanesulfonate mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Fluoranthene mg/l - x x x x x x x x x <0.02 < < < x x x x x <0.001 x x x x x x x x Fluorene mg/l - x x x x x x x x x <0.02 < < < x x x x x <0.001 x x x x x x x x Hexachlorobenzene mg/l - x x x x x x x x x x x x x x x x x x < x x x x x x x x Hexachlorocyclopentadiene mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Hexachloroethane mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Hexachloropropene mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x HMX mg/l - x x x x x x x x x x x x x x x x x x < x x x x x x x x Indeno (1,2,3-cd) pyrene mg/l - x x x x x x x x x <0.02 < < < x x x x x < x x x x x x x x Isophorone mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Isosafrole mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x m-dinitrobenzene (1,3-DNB) mg/l - x x x x x x x x x x x x x x x x x x < x x x x x x x x Methapyrilene mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Methyl methanesulfonate mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Naphthalene mg/l 0.03 <1.0 <0.001 <0.001 <0.001 <0.001 < < < < <0.02 < < < <0.01 x x x x <0.001 x x x x x x <1.0 x Nitrobenzene mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosodiethylamine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosodimethylamine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosodi-n-butylamine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosodinpropylamine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosodiphenylamine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosomethylethylamine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosopiperidine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x n-nitrosopyrrolidine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x o-toluidine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x p-(dimethylamino) azobenzene mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Pentachlorobenzene mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Pentachloronitrobenzene mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Phenacetin mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Phenanthrene mg/l - <0.1 <0.001 < < < < < < < <0.02 < < < x x x x x <0.001 x x x x x x <0.1 x p-phenylenediamine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Pronamide mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Pyrene mg/l - <0.25 <0.001 < < < < < < < <0.02 < < < x x x x x <0.001 x x x x x x <0.25 x Pyridine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x RDX mg/l - x x x x x x x x x x x x x x x x x x < x x x x x x x x Safrole mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x sym-trinitrobenzene 1 (1,3,5-trinitrobenzene, 1,3,5-TNB) mg/l - x x x x x x x x x x x x x x x x x x < x x x x x x x x Semi Volatile Organic Compounds - Phenolics x 2,3,4,6-Tetrachlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x <0.001 x x x x x x x x 2,4,5-Trichlorophenol mg/l - x x x x x x x x x <0.1 x x x x x x x x <0.001 x x x x x x x x 2,4,6-Trichlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x <0.001 x x x x x x x x 2,4-Dichlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x <0.001 x x x x x x x x 2,4-Dimethylphenol mg/l - x x x x x x x x x <0.02 x x x x x x x x <0.001 x x x x x x x x 2,4-Dinitrophenol mg/l - x x x x x x x x x <0.1 x x x x x x x x <0.001 x x x x x x x x 2,6-Dichlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x <0.001 x x x x x x x x 2-Chlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x <0.001 x x x x x x x x 2-Methylphenol (o-cresol) mg/l - x x x x x x x x x <0.02 x x x x x x x x <0.001 x x x x x x x x 2-Nitrophenol (o-nitrophenol) mg/l - x x x x x x x x x <0.02 x x x x x x x x <0.001 x x x x x x x x 3-Methylphenol/4-Methylphenol (m&p-cresol) / mg/l - x x x x x x x x x <0.02 x x x x x x x x <0.001 x x x x x x x x 4,6-Dinitro-2-methylphenol (4,6-Dinitro-o-cresol) mg/l - x x x x x x x x x <0.1 x x x x x x x x <0.001 x x x x x x x x p-chloro-m-cresol (4-Chloro-3-methylphenol) mg/l - x x x x x x x x x <0.02 x x x x x x x x <0.001 x x x x x x x x 4-Nitrophenol (p-nitrophenol) mg/l - x x x x x x x x x <0.1 x x x x x x x x <0.001 x x x x x x x x 5-Nitro-o-toluidine mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Pentachlorophenol mg/l - x x x x x x x x x <0.1 x x x x x x x x <0.001 x x x x x x x x Phenol 1 (a) mg/l x x x x x x x x x < x x x x x x x x <0.001 x x x x x x x x Radium 226 and 228 NA pci/l x <2.5 x x x x Ra-226, total NA pci/l x <2.5 x x x x 0.2 x x x x x x Ra-228 1, total NA pci/l x <2.5 x x x x 0.04 x x x x x x Chlorinated Pesticides 4,4'-DDD (p,p'-ddd) mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x 4,4'-DDE (p,p'-dde) mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
66 APPEIX B Las Cruces Foothills Landfill MW-2 Page 5 of 5 Las Cruces Foothills Landfill monitoring well MW-2 *no sampling of MW-2 on 7/15/03 because pump was not working baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-2 average deviation date 1/12/99 5/11/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 4,4'DDT (p,p'-ddt) mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x aldrin mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x alpha-bhc mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x alpha-chlordane mg/l - x x x x x x x x x < < x x x x x x x x x x x x x x x x beta-bhc mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x Chlordane mg/l x x x x x x x x x x x x x x x x x x < x x x x x x x x delta-bhc mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x Dieldrin mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x Endosulfan I (alpha-endosulfan) mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x Endosulfan II (beta-endosulfan) mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x Endosulfan sulfate mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x Endrin aldehyde mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x Endrin ketone mg/l - x x x x x x x x x < < x x x x x x x x x x x x x x x x Endrin mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x gamma-bhc mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x gamma-chlordane mg/l - x x x x x x x x x < < x x x x x x x x x x x x x x x x Heptachlor epoxide mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x Heptachlor mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x Isodrin mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Kepone mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x Methoxychlor mg/l - x x x x x x x x x < < x x x x x x x < x x x x x x x x Toxaphene mg/l - x x x x x x x x x <0.003 < x x x x x x x <0.001 x x x x x x x x Polychlorinated Biphenyls (PCBs) 1 mg/l Arochlor mg/l - x x x x x x x x x < < < < < x x x x < x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < x x x x < x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < x x x x < x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < x x x x < x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < x x x x < x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < x x x x < x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < x x x x < x x x x x x x x Other Pesticides and Herbicides 1 2,3,7,8-TCDD ng/l 0.03 x x x x x x x x x x x x x x x x x x < x x x x x x x x 2,4,5-T mg/l - x x x x x x x x x <0.002 x x x x x x x x < x x x x x x x x 2,4-Dichlorophenoxyacetic acid (2,4-D) mg/l - x x x x x x x x x <0.002 x x x x x x x x < x x x x x x x x Dimethoate mg/l - x x x x x x x x x <0.002 x x x x x x x x <0.001 x x x x x x x x Dinoseb mg/l - x x x x x x x x x <0.002 x x x x x x x x < x x x x x x x x Disulfoton mg/l - x x x x x x x x x <0.002 x x x x x x x x <0.001 x x x x x x x x Famphur mg/l - x x x x x x x x x <0.002 x x x x x x x x <0.001 x x x x x x x x Methyl parathion mg/l - x x x x x x x x x <0.002 x x x x x x x x <0.001 x x x x x x x x o,o,o-triethyl phosphorothioate mg/l - x x x x x x x x x <0.003 x x x x x x x x <0.001 x x x x x x x x Parathion (Ethyl) mg/l - x x x x x x x x x <0.002 x x x x x x x x <0.001 x x x x x x x x Phorate mg/l - x x x x x x x x x <0.002 x x x x x x x x <0.001 x x x x x x x x Silvex mg/l - x x x x x x x x x <0.002 x x x x x x x x < x x x x x x x x o,o-diethyl o-2pyrazinyl phosphorothioate (Thionazin) mg/l - x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x 1 hazardous x parameter not analyzed (^) See section entitled 'Semi volatile organic compounds - phenolics' for break-out of phenolics concentrations. (^^) See section entitled 'Polychlorinated Biphenyls (PCBs)' for break-out of PCB concentrations. (") This concentration attributed to laboratory contamination of method blank and not the presence of antimony in the ground water sampled. (#) Scanned for and not detected, breaks down almost immediately in water. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
67 JSAI MW-3 JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
68 APPEIX B Las Cruces Foothills Landfill MW-3 Page 1 of 5 Las Cruces Foothills Landfill monitoring well MW-3 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-3 average deviation date 1/12/99 5/15/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 5/18/11 12/27/11 6/19/12 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 Field Parameters water level elevation ft amsl conductivity µs/cm ph ph units temperature deg F pumped dry Major Ions calcium mg/l x x chloride mg/l x x fluoride mg/l x x x x x 0.76 x 0.71 x x x x x x magnesium mg/l x x potassium mg/l x x sodium mg/l x x sulfate mg/l x x alkalinity NA mg/l x x bicarbonate alkalinity mg/l x x carbonate alkalinity mg/l - <1.0 <1.0 <1.0 < x 1 x x <20 <2.0 <4.0 < <2.0 <2.0 x <2.0 <2.0 < < x total dissolved solids NA mg/l 1, x x Nitrogen Species ammonia as N mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x <0.05 <0.05 <0.1 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 <1.0 <1.0 x <1.0 <1.0 <1.0 <1.0 < Kjeldahl nitrogen mg/l < <0.1 < x <0.050 <0.5 <0.5 <1 <1.0 x x x x <1.0 x x x x x x x x nitrate as N mg/l x <1.0 < x < nitrite mg/l - x 0.33 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 x <0.10 <0.1 <0.1 < x x x x x x x x x x x x x 0.33 x total nitrogen - mg/l - x x x x x x x x x x x x x x x x x x x <1.0 x x x x x x x x x x Metals aluminum mg/l < < < x <3.0 <3.0 x x x 0.04 x x x x x x x antimony mg/l < < < < < <0.05 < (") <0.004 < <0.003 x x x x <0.001 <0.001 <0.001 x < <0.001 <0.001 <0.001 < arsenic mg/l <0.005 < <0.004 < <0.01 x x x x x barium mg/l <0.02 x x x x x beryllium mg/l < < < < < < < < <0.003 < <0.001 <0.001 < <0.002 x x x x <0.003 x <0.001 x <0.002 <0.002 <0.002 < x boron mg/l < <0.01 x < <0.1 <0.5 x x x x <0.04 x x x x x x x x cadmium mg/l < < < < < <0.005 < <0.001 < <0.002 x x x x <0.002 <0.002 <0.002 x <0.002 <0.002 <0.002 <0.002 < chromium mg/l <0.01 x x x x x < <0.006 < cobalt mg/l 0.05 <0.01 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.010 <0.001 < <0.03 x x x x <0.006 <0.006 <0.006 x <0.006 <0.006 <0.006 < x copper mg/l < <0.06 x x x x x iron mg/l < < x <0.10 < < x <0.02 <0.02 < < lead mg/l < < < <0.01 x x x x <0.005 <0.005 <0.005 x < manganese mg/l < < <0.005 <0.005 x < <0.010 <0.03 <0.03 <0.03 <0.03 < x < <0.002 < mercury mg/l < < < < < < < <0.07 <0.2 < <0.001 x x x x < x < x x x x x x molybdenum mg/l 1.0 <0.05 <0.05 <0.05 <0.05 < x < <0.010 <0.75 x x x x <0.008 x <0.008 x x x x x x <0.05 x nickel mg/l <0.05 x x x x x < <0.01 < selenium mg/l <0.01 <0.01 <0.003 < <0.005 x x x x <0.001 <0.001 <0.001 x < <0.001 < < silver mg/l 0.05 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 < <0.02 <0.005 < <0.002 <0.002 <0.010 <0.01 x x x x <0.005 < <0.005 x <0.005 <0.005 <0.005 <0.005 <0.005 <0.02 x thallium mg/l < < < < < <0.01 <0.010 <0.003 < <0.001 x x x x <0.001 <0.001 <0.001 x < <0.001 <0.001 <0.001 < tin mg/l - x x x x x x x x x <0.01 x x x x x x x x x <0.1 x x x x x x x x x x uranium mg/l x < <2.5 x x x x x x x x x x x x vanadium mg/l - <0.05 < <0.05 < <0.05 <0.05 <0.05 <0.01 < <0.050 <0.08 x x x x <0.05 <0.050 <0.05 x < <0.05 < x zinc mg/l < x x x x x total organic carbon - mg/l x <1.0 1 <0.5 <0.5 <0.5 <0.5 <1.0 <1.0 <1.0 <1.0 x 0.26 < <1.0 < phosphate mg/l - x x x x x x x x x x x x x x x x x x x <0.50 x <0.50 x x x x x x x x sulfide mg/l - x x x x x x x x x <1.0 x x x x x x x x x 3 x x x x x x x x x x cyanide mg/l 0.2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.005 < <0.005 <0.005 <0.01 <0.1 x x x x <0.005 x x x x x x x x <0.02 x perchlorate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x total phenolics 1 - mg/l <0.005 <0.02 <0.003 <0.003 < (^) <0.003 <0.005 <0.003 <0.003 <0.003 <0.003 < < < < x < < < < < x Polychlorinated Biphenyls (PCBs) mg/l < < < < < < < < < (^^) (^^) x (^^) (^^) (^^) x x x x (^^) x x x x x x x x < x Volatile Organic Compounds 1,1,1,2-Tetrachloroethane mg/l - x x <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.005 <0.01 <0.01 <0.01 <0.01 <0.025 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x 1,1,1-Trichloroethane mg/l 0.02 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,2,2-Tetrachloroethane mg/l 0.06 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,2-Trichloroethane mg/l 0.01 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloroethane mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloroethylene (1,1-Dichloroethene; 1,1-DCE) mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloropropene mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.001 x x x x <0.005 x x x x x x x x <0.001 x 1,2 Dibromo-3-chloropropane (DBCP) mg/l - x x x x x x x x x <0.001 <0.001 <0.001 x < < < < < < < < < x < < < < < x x 1,2,3-Trichlorobenzene mg/l <0.01 <0.01 < < < < < < < < <0.001 < < <0.010 x x x x x x x x x x x x x x <0.01 x 1,2,3-Trichloropropane mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2,4-Trichlorobenzene mg/l 0.01 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < x x x x x <0.001 x x x x x x x x <0.001 x 1,2-Dichlorobenzene (o-dichlorobenzene) mg/l - <0.001 <0.001 < < < < < < < <0.02 <0.001 x <0.001 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2-Dichloroethane (EDC) mg/l 0.6 x x x x x x x x x <0.001 <0.001 <0.001 x < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
69 APPEIX B Las Cruces Foothills Landfill MW-3 Page 2 of 5 Las Cruces Foothills Landfill monitoring well MW-3 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-3 average deviation date 1/12/99 5/15/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 5/18/11 12/27/11 6/19/12 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 1,2-Dichloropropane mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < < < < < < < < < x < < < < < <0.001 x 1,3-Dichlorobenzene (m-dichlorobenzene) mg/l <0.001 <0.001 < < < < < < < < <0.001 < < < x x x x x <0.01 <0.001 x x x x x x x <0.001 x 1,3-Dichloropropane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < x x x x x <0.01 x x x x x x x x <0.001 x 1,4-Dichlorobenzene (p-dichlorobenzene) mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 2,2-Dichloropropane mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < x x x x x <0.015 x x x x x x x x <0.001 x 2-Butanone (Methyl Ethyl Ketone) (MEK) mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 x <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 x 2-Chlorotoluene mg/l - <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 <0.01 <0.01 <0.01 <0.025 x x x x x x x x x x x x x x <0.01 x 2-Hexanone (Butyl Ketone) mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 x <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 x 4-Chlorotoluene mg/l 0.02 x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 <0.01 <0.01 <0.01 <0.025 x x x x x x x x x x x x x x <0.002 x 4-Methyl-2-pentanone mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < <0.04 <0.15 <0.15 <0.15 <0.15 <0.04 <0.01 <0.01 x <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 x Acetone mg/l - x x <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.005 <0.01 <0.01 <0.01 <0.01 <0.025 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 x <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Acrolein mg/l - x x x x x x x x x <0.005 <0.005 <0.005 x <0.025 x x x x x <0.1 x x x x x x x x x x Acrylonitrile mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.005 <0.005 <0.005 <0.005 <0.025 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.01 <0.01 x <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Benzene mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Bis(chloromethyl) ether mg/l - x x x x x x x x x x x x x x x x x x x (#) x x x x x x x x x x Bromochloromethane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.002 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.002 <0.002 x <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 x Bromomethane (methyl bromide) mg/l - <0.001 <0.001 < < < < < < < <0.002 <0.001 <0.001 <0.001 <0.001 <0.002 <0.02 <0.02 <0.02 <0.02 <0.002 <0.002 <0.002 x <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 x Carbon Disulfide mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.005 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 x <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Carbon Tetrachloride mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 x Chlorobenzene mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroethane mg/l - <0.001 <0.001 < < < < < < < <0.002 <0.001 <0.001 <0.001 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 <0.002 x <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 x Chloromethane (methyl chloride) mg/l 0.02 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroprene (2-Chloro-1,3-butadiene) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x cis-1,2-dichloroethylene (cis-1,2-dichloroethene) mg/l 0.07 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x cis-1,3-dichloropropene mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dibromomethane (methylene bromide) mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dichlorodifluoromethane mg/l <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 x <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 < x Ethyl methacrylate mg/l - x x x x x x x x x x x x x x x x x x x <0.01 x x x x x x x x x x Ethylbenzene mg/l 0.75 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Ethylene Dibromide (1,2-Dibromoethane) (EDB) mg/l <0.001 <0.001 < < < < < < < < <0.001 < < < < < < < < < < < x < < < < < <0.001 x Hexachlorobutadiene mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < x x x x x <0.001 x x x x x x x x <0.001 x Isobutyl alcohol mg/l - x x x x x x x x x x x x x x x x x x x <0.05 x x x x x x x x x x Isopropylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x x <0.001 x Methacrylonitrile mg/l - x x x x x x x x x x x x x x x x x x x <0.005 x x x x x x x x x x Methyl Iodide (Iodomethane) mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.04 <0.04 <0.04 <0.04 <0.001 <0.01 <0.01 x <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Methyl methacrylate mg/l - x x x x x x x x x x x x x x x x x x x <0.03 x x x x x x x x x x Methylene Chloride mg/l <0.002 <0.002 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.015 <0.001 <0.001 <0.001 <0.001 <0.015 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 x n-butylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x x <0.001 x Propionitrile mg/l - x x x x x x x x x x x x x x x x x x x <0.06 x x x x x x x x x x Propylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x x <0.001 x sec-butylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x x <0.001 x Styrene mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x tert-butyl methyl ether (MTBE) (a) mg/l 0.1 <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x <0.001 x <0.001 <0.005 x x x x x <0.001 x x x x x x x x <0.01 x tert-butylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x x <0.001 x Tetrachloroethene (PCE) mg/l <0.001 < < < < < < < < <0.001 < < < < < < < < < < < x < < < < < x Tetrahydrofuran (THF) mg/l - <0.001 <0.001 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.010 x x x x x x x x x x x x x x <0.001 x Toluene mg/l 0.75 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Total Xylenes (m&p and o) 1 NA mg/l 0.62 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.002 <0.002 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.002 <0.002 x <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 x trans-1,2-dichloroethene mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.002 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x trans-1,3-dichloropropene mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x trans-1,4-dichloro-2-butene mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.010 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 x Trichloroethene (TCE) mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Trichlorofluoromethane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Vinyl acetate mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.025 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 x <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Vinyl Chloride mg/l <0.001 <0.001 < < < < < < < < <0.001 < < < < < < < < < < < x < < < < < <0.001 x Trihalomethanes (THM) Bromodichloromethane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Bromoform mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.001 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroform mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dibromochloromethane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Semi Volatile Organic Compounds 1,2,4,5-Tetrachlorobenzene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 1,2-Diphenylhydrazine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 1,4-Naphthoquinone mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 1-Chloronaphthalene NA mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x 1-Methylnaphthalene mg/l - x x x x x x x x x x x < < <0.005 <0.01 x x x x <0.001 x x x x x x x x x x 1-Naphthylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 2,4,6-Trinitrotoluene (TNT) mg/l - x x x x x x x x x x x x x x x x x x x < x x < x x x x x x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
70 APPEIX B Las Cruces Foothills Landfill MW-3 Page 3 of 5 Las Cruces Foothills Landfill monitoring well MW-3 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-3 average deviation date 1/12/99 5/15/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 5/18/11 12/27/11 6/19/12 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 2,4-Dinitrotoluene (2,4-DNT) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x < x x x x x x x 2,6-Dinitrotoluene 1 (2,6-DNT) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x < x x x x x x x 2-Chloronaphthalene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 2-Methylnaphthalene mg/l - x x x x x x x x x x x < < <0.010 <0.01 x x x x <0.001 x x x x x x x x x x 2-Naphthylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 2-Nitroaniline (o-nitroaniline) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 2-Picoline mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 3,3'-Dichlorobenzidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 3,3'-Dimethylbenzidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 3-Methylcholanthrene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 3-Nitroaniline (m-nitroaniline) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 4-Aminobiphenyl mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 4-Bromophenylphenyl ether mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 4-Chloroaniline (p-chloroanaline) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 4-Chlorophenylphenyl ether mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 4-Nitroaniline (p-nitroaniline) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 7,12-Dimethylbenz (a) anthracene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Acenaphthene mg/l - x x x x x x x x x <0.02 < < < <0.005 < x x x x < x x x x x x x x x x Acenaphthylene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x x Acetophenone mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x alpha,alpha-dimethylphenethylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Aniline mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Anthracene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x x Benzidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Benzo (a) anthracene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x x Benzo (b) fluoranthene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x x x Benzo (g,h,i) perylene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x x x Benzo (k) fluoranthene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x x x Benzo[a]pyrene mg/l <0.001 < < < < < < < <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x Benzoic acid mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x Benzyl alcohol mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x bis (2-Chloroethoxy) methane mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x bis (2-Chloroethyl) ether mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x bis (2-Chloroisopropyl) ether (bis (2-chloro-1-methylethyl) ether) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x bis (2-Ethylhexyl) phthalate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Butylbenzylphthalate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Carbazole mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Chlorobenzilate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Chrysene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x x x Diallate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Dibenz(a,j)acridine mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x Dibenzo (a,h) anthracene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x x x Dibenzofuran mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Diethylene Glycol Monobutyl Ether mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x Diethylphthalate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Dimethylphthalate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Di-n-butylphthalate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Di-n-octylphthalate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Diphenylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Ethyl methanesulfonate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Fluoranthene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x x Fluorene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x x Hexachlorobenzene mg/l - x x x x x x x x x x x x x x x x x x x < x x x x x x x x x x Hexachlorocyclopentadiene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Hexachloroethane mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Hexachloropropene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x HMX mg/l - x x x x x x x x x x x x x x x x x x x < x x < x x x x x x x Indeno (1,2,3-cd) pyrene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x x x Isophorone mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Isosafrole mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x m-dinitrobenzene (1,3-DNB) mg/l - x x x x x x x x x x x x x x x x x x x < x x < x x x x x x x Methapyrilene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Methyl methanesulfonate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Naphthalene mg/l <0.001 <0.001 <0.001 <0.001 < < < < <0.02 < < < < <0.01 x x x x <0.001 x x x x x x x x x Nitrobenzene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x < x x x x x x x n-nitrosodiethylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x n-nitrosodimethylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
71 APPEIX B Las Cruces Foothills Landfill MW-3 Page 4 of 5 Las Cruces Foothills Landfill monitoring well MW-3 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-3 average deviation date 1/12/99 5/15/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 5/18/11 12/27/11 6/19/12 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 n-nitrosodi-n-butylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x n-nitrosodinpropylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x n-nitrosodiphenylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x n-nitrosomethylethylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x n-nitrosopiperidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x n-nitrosopyrrolidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x o-toluidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x p-(dimethylamino) azobenzene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Pentachlorobenzene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Pentachloronitrobenzene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Phenacetin mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Phenanthrene mg/l <0.001 < < < < < < < <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x p-phenylenediamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Pronamide mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Pyrene mg/l <0.001 < < < < < < < <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x Pyridine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x RDX mg/l - x x x x x x x x x x x x x x x x x x x < x x < x x x x x x x Safrole mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x sym-trinitrobenzene 1 (1,3,5-trinitrobenzene, 1,3,5-TN mg/l - x x x x x x x x x x x x x x x x x x x < x x < x x x x x x x Semi Volatile Organic Compounds - Phenolics x 2,3,4,6-Tetrachlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x x 2,4,5-Trichlorophenol mg/l - x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x x x 2,4,6-Trichlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x x 2,4-Dichlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x x 2,4-Dimethylphenol mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x x 2,4-Dinitrophenol mg/l - x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x x x 2,6-Dichlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x x 2-Chlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x x 2-Methylphenol (o-cresol) mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x x 2-Nitrophenol (o-nitrophenol) mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x x 3-Methylphenol/4-Methylphenol (m&p-cresol) / mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x x 4,6-Dinitro-2-methylphenol (4,6-Dinitro-o-cresol) mg/l - x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x x x p-chloro-m-cresol (4-Chloro-3-methylphenol) mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x x 4-Nitrophenol (p-nitrophenol) mg/l - x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x x x 5-Nitro-o-toluidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Pentachlorophenol mg/l - x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x x x Phenol 1 (a) mg/l x x x x x x x x x < x x x x x x x x x <0.001 x x x x x x x x x x Radium 226 and 228 NA pci/l x <2.5 x x x x Ra-226, total NA pci/l x <2.5 x x x x 0.03 x x x x x x x x Ra-228 1, total NA pci/l x <2.5 x x x x 0.32 x x x x x x x x Chlorinated Pesticides 4,4'-DDD (p,p'-ddd) mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x 4,4'-DDE (p,p'-dde) mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x 4,4'DDT (p,p'-ddt) mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x aldrin mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x alpha-bhc mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x alpha-chlordane mg/l - x x x x x x x x x < < x x x x x x x x x x x x x x x x x x x beta-bhc mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x Chlordane mg/l x x x x x x x x x x x x x x x x x x x < x x x x x x x x x x delta-bhc mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x Dieldrin mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x Endosulfan I (alpha-endosulfan) mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x Endosulfan II (beta-endosulfan) mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x Endosulfan sulfate mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x Endrin aldehyde mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x Endrin ketone mg/l - x x x x x x x x x < < x x x x x x x x x x x x x x x x x x x Endrin mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x gamma-bhc mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x gamma-chlordane mg/l - x x x x x x x x x < < x x x x x x x x x x x x x x x x x x x Heptachlor epoxide mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x Heptachlor mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x Isodrin mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Kepone mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x Methoxychlor mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x x Toxaphene mg/l - x x x x x x x x x <0.003 < x x x x x x x x <0.001 x x x x x x x x x x Polychlorinated Biphenyls (PCBs) 1 mg/l Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
72 APPEIX B Las Cruces Foothills Landfill MW-3 Page 5 of 5 Las Cruces Foothills Landfill monitoring well MW-3 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-3 average deviation date 1/12/99 5/15/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 5/18/11 12/27/11 6/19/12 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x x Other Pesticides and Herbicides 1 x x x x x x x 2,3,7,8-TCDD ng/l 0.03 x x x x x x x x x x x x x x x x x x x < x x x x x x x x x x 2,4,5-T mg/l - x x x x x x x x x <0.002 x x x x x x x x x < x x x x x x x x x x 2,4-Dichlorophenoxyacetic acid (2,4-D) mg/l - x x x x x x x x x <0.002 x x x x x x x x x < x x x x x x x x x x Dimethoate mg/l - x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x x x Dinoseb mg/l - x x x x x x x x x <0.002 x x x x x x x x x < x x x x x x x x x x Disulfoton mg/l - x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x x x Famphur mg/l - x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x x x Methyl parathion mg/l - x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x x x o,o,o-triethyl phosphorothioate mg/l - x x x x x x x x x <0.003 x x x x x x x x x <0.001 x x x x x x x x x x Parathion (Ethyl) mg/l - x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x x x Phorate mg/l - x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x x x Silvex mg/l - x x x x x x x x x <0.002 x x x x x x x x x < x x x x x x x x x x o,o-diethyl o-2pyrazinyl phosphorothioate (Thionazin mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x x 1 hazardous x parameter not analyzed (^) See section entitled 'Semi volatile organic compounds - phenolics' for break-out of phenolics concentrations. (^^) See section entitled 'Polychlorinated Biphenyls (PCBs)' for break-out of PCB concentrations. (") This concentration attributed to laboratory contamination of method blank and not the presence of antimony in the ground water sampled. (#) Scanned for and not detected, breaks down almost immediately in water. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
73 JSAI MW-4 JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
74 Page 1 of 5 APPEIX B Las Cruces Foothills Landfill MW-4 Las Cruces Foothills Landfill monitoring well MW-4 *no sampling of MW-4 on 12/12/06 because pump was not working baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-4 average deviation date 1/12/99 5/11/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 6/21/07 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 6/19/12 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 Field Parameters water level elevation ft amsl conductivity µs/cm ph ph units temperature deg F Major Ions calcium mg/l x chloride mg/l x fluoride mg/l x <0.4 x x x x 0.31 x 0.29 x x x x x magnesium mg/l x potassium mg/l x sodium mg/l x sulfate mg/l x alkalinity NA mg/l x bicarbonate alkalinity mg/l x carbonate alkalinity mg/l - <1.0 <1.0 <1.0 <1.0 < x 1 x <20 <2.0 <4.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <1.0 x total dissolved solids NA mg/l 1, x Nitrogen Species ammonia as N mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x <0.05 <0.05 <0.1 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.01 x Kjeldahl nitrogen mg/l - <0.1 <0.1 <0.1 <0.1 < <0.1 <0.1 <0.1 x <0.050 < <1 <1.0 x x x x <1.0 x x x x x x x <0.1 x nitrate as N mg/l x <1.0 1 < < nitrite mg/l <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 x <0.10 <0.1 <0.1 <0.1 <1.0 x x x x x x x x x x x x total nitrogen - mg/l - x x x x x x x x x x x x x x x x x x x <1.0 x x x x x x x x x Metals aluminum mg/l 5.0 <0.05 <0.05 <0.05 < <0.05 <0.05 <0.05 <0.05 x <0.10 <0.03 <0.03 <0.03 <3.0 <3.0 x x x <0.02 x <0.02 x x x x x <0.05 x antimony mg/l < < < < < < < < < <0.05 < (") <0.004 < <0.003 x x x x <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 < x arsenic mg/l <0.005 < <0.004 < <0.01 x x x x <0.001 < <0.001 <0.001 <0.001 < barium mg/l x x x x beryllium mg/l < < < < < < < < < <0.003 < <0.001 <0.001 < <0.002 x x x x <0.003 x < <0.002 <0.002 <0.002 <0.002 < x boron mg/l 0.75 < < <0.01 x < <0.1 <0.5 x x x x 0.05 x x x x x x cadmium mg/l < < < < < < < < < <0.005 < <0.001 <0.001 < <0.002 x x x x <0.002 < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 < x chromium mg/l 0.05 < < < <0.005 < <0.002 < <0.01 x x x x <0.006 < < <0.006 <0.006 <0.006 < cobalt mg/l 0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.010 <0.001 < <0.03 x x x x <0.006 < < <0.006 <0.006 <0.006 <0.006 <0.01 x copper mg/l < < < < < <0.01 < <0.06 x x x x <0.006 < < < iron mg/l 1.0 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 x <0.10 <0.007 <0.007 <0.10 <0.1 <0.1 <0.1 <0.1 <0.1 <0.05 <0.050 < <0.02 <0.02 <0.02 <0.02 <0.05 x lead mg/l < < < < < <0.005 < <0.002 < <0.01 x x x x <0.005 < < x manganese mg/l 0.2 < <0.02 < < <0.005 <0.005 x < <0.010 <0.03 <0.030 <0.03 <0.03 < < x mercury mg/l < < < < < < < < < <0.07 <0.2 < <0.001 x x x x < x < x x x x x x molybdenum mg/l 1.0 <0.05 <0.05 <0.05 <0.05 < x <0.010 <0.002 <0.002 <0.010 <0.75 x x x x <0.008 x <0.008 x x x x x <0.05 x nickel mg/l <0.005 < <0.002 < <0.05 x x x x <0.01 <0.010 <0.01 < < <0.01 < selenium mg/l < <0.001 <0.01 <0.010 <0.003 < <0.005 x x x x <0.001 <0.001 < <0.001 < < silver mg/l 0.05 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 < <0.02 <0.005 < <0.002 <0.002 <0.010 <0.01 x x x x <0.005 < <0.005 <0.005 <0.005 < <0.005 <0.02 x thallium mg/l < < < < < < < < <0.01 <0.02 <0.003 < <0.001 x x x x <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 < x tin mg/l - x x x x x x x x x <0.01 x x x x x x x x x <0.1 x x x x x x x x x uranium mg/l x < <2.5 x x x x x x x x x x x vanadium mg/l - <0.05 < <0.05 < <0.05 <0.05 <0.05 <0.01 < <0.050 <0.08 x x x x <0.05 <0.050 < <0.05 <0.05 <0.05 < x zinc mg/l 10.0 <0.01 <0.01 <0.01 <0.01 < <0.01 <0.01 <0.01 <0.02 < <0.008 <0.020 <0.05 x x x x <0.02 <0.020 < <0.01 x total organic carbon - mg/l - < < < x <1.0 < <0.5 <1.0 < < < <1.0 < phosphate mg/l - x x x x x x x x x x x x x x x x x x x <0.50 x <0.50 x x x x x x x sulfide mg/l - x x x x x x x x x <1.0 x x x x x x x x x 3 x x x x x x x x x cyanide mg/l 0.2 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.005 < <0.005 <0.005 <0.01 <0.1 x x x x <0.005 x x x x x x x <0.02 x perchlorate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x total phenolics 1 - mg/l <0.005 <0.02 <0.003 < < (^) <0.003 <0.003 <0.005 <0.003 <0.003 <0.003 <0.003 < < < < < < < < < x Polychlorinated Biphenyls (PCBs) mg/l < < < < < < < < (^^) (^^) (^^) (^^) (^^) (^^) x x x x (^^) x x x x x x x < x Volatile Organic Compounds 1,1,1,2-Tetrachloroethane mg/l 0.02 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,1-Trichloroethane mg/l 0.06 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,2,2-Tetrachloroethane mg/l 0.01 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,2-Trichloroethane mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloroethane mg/l <0.005 <0.005 <0.005 <0.005 < ,1-Dichloroethylene (1,1-Dichloroethene; 1,1-DCE) mg/l < < < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 < x 1,1-Dichloropropene mg/l - x x x x x x x x x <0.001 <0.001 <0.001 x < x x x x x <0.005 x x x x x x x x x 1,2 Dibromo-3-chloropropane (DBCP) mg/l <0.01 <0.01 < < < < < < < x <0.001 < < < < < < < < < < < < < < < < <0.01 x 1,2,3-Trichlorobenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x <0.001 x 1,2,3-Trichloropropane mg/l 0.01 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2,4-Trichlorobenzene mg/l - <0.001 <0.001 < < < < < < < <0.02 <0.001 x <0.001 < x x x x x <0.001 x x x x x x x <0.001 x 1,2-Dichlorobenzene (o-dichlorobenzene) mg/l 0.6 x x x x x x x x x <0.001 <0.001 <0.001 x < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x x 1,2-Dichloroethane (EDC) mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
75 Page 2 of 5 APPEIX B Las Cruces Foothills Landfill MW-4 Las Cruces Foothills Landfill monitoring well MW-4 *no sampling of MW-4 on 12/12/06 because pump was not working baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-4 average deviation date 1/12/99 5/11/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 6/21/07 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 6/19/12 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 1,2-Dichloropropane mg/l <0.001 <0.001 < < < < < < < < <0.001 < < < < < < < < < < < < < < < < <0.001 x 1,3-Dichlorobenzene (m-dichlorobenzene) mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < x x x x x <0.01 <0.001 x x x x x x <0.001 x 1,3-Dichloropropane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < x x x x x <0.01 x x x x x x x <0.001 x 1,4-Dichlorobenzene (p-dichlorobenzene) mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 x 2,2-Dichloropropane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < x x x x x <0.015 x x x x x x x <0.001 x 2-Butanone (Methyl Ethyl Ketone) (MEK) mg/l - <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 <0.01 <0.01 <0.01 <0.025 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x 2-Chlorotoluene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x <0.001 x 2-Hexanone (Butyl Ketone) mg/l 0.02 x x x x x x x x x x x <0.01 <0.01 <0.025 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x 4-Chlorotoluene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x <0.001 x 4-Methyl-2-pentanone mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 <0.01 <0.001 <0.01 <0.025 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 x x x x x x x <0.002 x Acetone mg/l - x x <0.01 <0.01 <0.01 <0.01 <0.01 < <0.01 <0.01 <0.01 <0.01 <0.025 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Acrolein mg/l - x x x x x x x x x <0.005 <0.005 <0.005 x <0.025 x x x x x <0.1 x x x x x x x x x Acrylonitrile mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.005 <0.005 <0.005 <0.005 <0.025 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Benzene mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.001 < <0.001 <0.001 <0.001 <0.001 < < <0.001 <0.001 <0.001 x Bis(chloromethyl) ether mg/l - x x x x x x x x x x x x x x x x x x x (# ) x x x x x x x x x Bromochloromethane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.002 <0.02 <0.002 <0.002 <0.002 <0.002 <0.02 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 x Bromomethane (methyl bromide) mg/l - <0.001 <0.001 < < < < < < < <0.002 <0.001 <0.001 <0.001 <0.001 <0.002 <0.02 <0.02 <0.02 <0.02 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 x Carbon Disulfide mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.005 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Carbon Tetrachloride mg/l <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chlorobenzene mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroethane mg/l - <0.001 <0.001 < < < < < < < <0.002 <0.001 <0.001 <0.001 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 x Chloromethane (methyl chloride) mg/l 0.02 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroprene (2-Chloro-1,3-butadiene) mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x x x cis-1,2-dichloroethylene (cis-1,2-dichloroethene) mg/l 0.07 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 < <0.001 x cis-1,3-dichloropropene mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dibromomethane (methylene bromide) mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dichlorodifluoromethane mg/l < x x Ethyl methacrylate mg/l - x x x x x x x x x x x x x x x x x x x <0.01 x x x x x x x x x Ethylbenzene mg/l 0.75 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Ethylene Dibromide (1,2-Dibromoethane) (EDB) mg/l 5E-05 <0.001 <0.001 < < < < < < < x <0.001 < < < < < < < < < < < < < < < < <0.001 x Hexachlorobutadiene mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < x x x x x <0.001 x x x x x x x <0.001 x Isobutyl alcohol mg/l - x x x x x x x x x x x x x x x x x x x <0.05 x x x x x x x x x Isopropylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x <0.001 x Methacrylonitrile mg/l - x x x x x x x x x x x x x x x x x x x <0.005 x x x x x x x x x Methyl Iodide (Iodomethane) mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.005 <0.005 <0.005 <0.005 <0.005 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Methyl methacrylate mg/l - x x x x x x x x x x x x x x x x x x x <0.03 x x x x x x x x x Methylene Chloride mg/l <0.002 <0.002 < < < < < <0.002 x n-butylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x <0.001 x Propionitrile mg/l - x x x x x x x x x x x x x x x x x x x <0.06 <0.01 x x x x x x x x Propylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x <0.001 x sec-butylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x <0.001 x Styrene mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x tert-butyl methyl ether (MTBE) (a) mg/l 0.1 <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x <0.001 x <0.001 <0.005 x x x x x <0.001 x x x x x x x <0.01 x tert-butylbenzene mg/l - <0.001 <0.001 < < < < < < < x <0.001 x <0.001 < x x x x x x x x x x x x x <0.001 x Tetrachloroethene (PCE) mg/l < Tetrahydrofuran (THF) mg/l - <0.001 <0.001 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.010 x x x x x x x x x x x x x <0.001 x Toluene mg/l 0.75 <0.001 <0.001 < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 x Total Xylenes (m&p and o) 1 NA mg/l 0.62 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.002 <0.002 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.002 < <0.002 <0.002 <0.002 <0.002 <0.001 x trans-1,2-dichloroethene mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 x trans-1,3-dichloropropene mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x trans-1,4-dichloro-2-butene mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.010 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Trichloroethene (TCE) mg/l < Trichlorofluoromethane mg/l < <0.01 <0.01 <0.01 <0.01 < < Vinyl acetate mg/l - x x <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.025 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 x Vinyl Chloride mg/l <0.001 <0.001 < < < < < < < < <0.001 < < < < < < < < < < < < < <0.001 x Trihalomethanes (THM) Bromodichloromethane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Bromoform mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 <0.001 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroform mg/l 0.1 <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dibromochloromethane mg/l - <0.001 <0.001 < < < < < < < <0.001 <0.001 <0.001 <0.001 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Semi Volatile Organic Compounds 1,2,4,5-Tetrachlorobenzene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 1,2-Diphenylhydrazine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 1,4-Naphthoquinone mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 1-Chloronaphthalene NA mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x x x 1-Methylnaphthalene mg/l - x x x x x x x x x x x < < <0.005 <0.01 x x x x <0.001 x x x x x x x x x 1-Naphthylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 2,4,6-Trinitrotoluene (TNT) mg/l - x x x x x x x x x x x x x x x x x x x < x x x x x x x x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
76 Page 3 of 5 APPEIX B Las Cruces Foothills Landfill MW-4 Las Cruces Foothills Landfill monitoring well MW-4 *no sampling of MW-4 on 12/12/06 because pump was not working baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-4 average deviation date 1/12/99 5/11/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 6/21/07 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 6/19/12 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 2,4-Dinitrotoluene (2,4-DNT) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 2,6-Dinitrotoluene 1 (2,6-DNT) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 2-Chloronaphthalene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 2-Methylnaphthalene mg/l - x x x x x x x x x x x < < <0.010 <0.01 x x x x <0.001 x x x x x x x x x 2-Naphthylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 2-Nitroaniline (o-nitroaniline) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 2-Picoline mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 3,3'-Dichlorobenzidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 3,3'-Dimethylbenzidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 3-Methylcholanthrene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 3-Nitroaniline (m-nitroaniline) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 4-Aminobiphenyl mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 4-Bromophenylphenyl ether mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 4-Chloroaniline (p-chloroanaline) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 4-Chlorophenylphenyl ether mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 4-Nitroaniline (p-nitroaniline) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x 7,12-Dimethylbenz (a) anthracene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Acenaphthene mg/l - x x x x x x x x x <0.02 < < < <0.005 < x x x x < x x x x x x x x x Acenaphthylene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x Acetophenone mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x alpha,alpha-dimethylphenethylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Aniline mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Anthracene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x Benzidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Benzo (a) anthracene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x Benzo (b) fluoranthene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x x Benzo (g,h,i) perylene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x x Benzo (k) fluoranthene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x x Benzo[a]pyrene mg/l <0.1 <0.001 < < < < < < < <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x <0.1 x Benzoic acid mg/l x x x x x x x x x x x x x x x x x x x x x x x Benzyl alcohol mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x bis (2-Chloroethoxy) methane mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x bis (2-Chloroethyl) ether mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x bis (2-Chloroisopropyl) ether (bis (2-chloro-1-methylethyl) ether) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x bis (2-Ethylhexyl) phthalate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Butylbenzylphthalate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Carbazole mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Chlorobenzilate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Chrysene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x x Diallate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Dibenz(a,j)acridine mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x x x Dibenzo (a,h) anthracene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x x Dibenzofuran mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Diethylene Glycol Monobutyl Ether mg/l - x x x x x x x x x x x x x x x x x x x x x x x x x x x x x Diethylphthalate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Dimethylphthalate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Di-n-butylphthalate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Di-n-octylphthalate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Diphenylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Ethyl methanesulfonate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Fluoranthene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x Fluorene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x x x Hexachlorobenzene mg/l - x x x x x x x x x x x x x x x x x x x < x x x x x x x x x Hexachlorocyclopentadiene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Hexachloroethane mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Hexachloropropene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x HMX mg/l - x x x x x x x x x x x x x x x x x x x < x x x x x x x x x Indeno (1,2,3-cd) pyrene mg/l - x x x x x x x x x <0.02 < < < <0.005 x x x x x < x x x x x x x x x Isophorone mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Isosafrole mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x m-dinitrobenzene (1,3-DNB) mg/l - x x x x x x x x x x x x x x x x x x x < x x x x x x x x x Methapyrilene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Methyl methanesulfonate mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Naphthalene mg/l 0.03 <1.0 <0.001 <0.001 <0.001 <0.001 < < <0.02 < < < <0.005 <0.01 x x x x <0.001 x x x x x x x <1.0 x Nitrobenzene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x n-nitrosodiethylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x n-nitrosodimethylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
77 Page 4 of 5 APPEIX B Las Cruces Foothills Landfill MW-4 Las Cruces Foothills Landfill monitoring well MW-4 *no sampling of MW-4 on 12/12/06 because pump was not working baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-4 average deviation date 1/12/99 5/11/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 6/21/07 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 6/19/12 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 n-nitrosodi-n-butylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x n-nitrosodinpropylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x n-nitrosodiphenylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x n-nitrosomethylethylamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x n-nitrosopiperidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x n-nitrosopyrrolidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x o-toluidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x p-(dimethylamino) azobenzene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Pentachlorobenzene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Pentachloronitrobenzene mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Phenacetin mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Phenanthrene mg/l - <0.1 <0.001 < < < < < < < <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x <0.1 x p-phenylenediamine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Pronamide mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Pyrene mg/l - <0.25 <0.001 < < < < < < < <0.02 < < < <0.005 x x x x x <0.001 x x x x x x x <0.25 x Pyridine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x RDX mg/l - x x x x x x x x x x x x x x x x x x x < x x x x x x x x x Safrole mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x sym-trinitrobenzene 1 (1,3,5-trinitrobenzene, 1,3,5-TNB) mg/l - x x x x x x x x x x x x x x x x x x x < x x x x x x x x x Semi Volatile Organic Compounds - Phenolics x 2,3,4,6-Tetrachlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x 2,4,5-Trichlorophenol mg/l - x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x x 2,4,6-Trichlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x 2,4-Dichlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x 2,4-Dimethylphenol mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x 2,4-Dinitrophenol mg/l - x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x x 2,6-Dichlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x 2-Chlorophenol mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x 2-Methylphenol (o-cresol) mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x 2-Nitrophenol (o-nitrophenol) mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x 3-Methylphenol/4-Methylphenol (m&p-cresol) / mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x 4,6-Dinitro-2-methylphenol (4,6-Dinitro-o-cresol) mg/l - x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x x 4-Chloro-3-methylphenol (p-chloro-m-cresol) mg/l - x x x x x x x x x <0.02 x x x x x x x x x <0.001 x x x x x x x x x 4-Nitrophenol (p-nitrophenol) mg/l - x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x x 5-Nitro-o-toluidine mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Pentachlorophenol mg/l - x x x x x x x x x <0.1 x x x x x x x x x <0.001 x x x x x x x x x Phenol 1 (a) mg/l x x x x x x x x x < x x x x x x x x x <0.001 x x x x x x x x x Radium 226 and 228 NA pci/l x <2.5 x x x x Ra-226, total NA pci/l x <2.5 x x x x 0.13 x x x x x x x Ra-228 1, total NA pci/l x <2.5 x x x x 1.4 x x x x x x x Chlorinated Pesticides 4,4'-DDD (p,p'-ddd) mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x 4,4'-DDE (p,p'-dde) mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x 4,4'DDT (p,p'-ddt) mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x aldrin mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x alpha-bhc mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x alpha-chlordane mg/l - x x x x x x x x x < < x x x x x x x x x x x x x x x x x x beta-bhc mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x Chlordane mg/l x x x x x x x x x x x x x x x x x x x < x x x x x x x x x delta-bhc mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x Dieldrin mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x Endosulfan I (alpha-endosulfan) mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x Endosulfan II (beta-endosulfan) mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x Endosulfan sulfate mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x Endrin aldehyde mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x Endrin ketone mg/l - x x x x x x x x x < < x x x x x x x x x x x x x x x x x x Endrin mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x gamma-bhc mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x gamma-chlordane mg/l - x x x x x x x x x < < x x x x x x x x x x x x x x x x x x Heptachlor epoxide mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x Heptachlor mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x Isodrin mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Kepone mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x Methoxychlor mg/l - x x x x x x x x x < < x x x x x x x x < x x x x x x x x x Toxaphene mg/l - x x x x x x x x x <0.003 < x x x x x x x x <0.001 x x x x x x x x x Polychlorinated Biphenyls (PCBs) 1 mg/l Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
78 Page 5 of 5 APPEIX B Las Cruces Foothills Landfill MW-4 Las Cruces Foothills Landfill monitoring well MW-4 *no sampling of MW-4 on 12/12/06 because pump was not working baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-4 average deviation date 1/12/99 5/11/99 7/7/99 9/1/99 11/1/99 5/18/00 11/9/00 6/13/01 11/6/01 4/3/02 7/12/02 9/25/02 12/18/02 7/15/03 12/29/03 12/2/04 12/14/05 6/21/07 1/18/08 12/23/08 12/29/09 12/29/10 12/27/11 6/19/12 12/19/12 6/25/13 12/19/13 1/12/99 to 1/12/99 to 5/18/00 5/18/00 Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x Arochlor mg/l - x x x x x x x x x < < < < < < x x x x < x x x x x x x x x Other Pesticides and Herbicides 1 2,3,7,8-TCDD ng/l 0.03 x x x x x x x x x x x x x x x x x x x < x x x x x x x x x 2,4,5-T mg/l - x x x x x x x x x <0.002 x x x x x x x x x < x x x x x x x x x 2,4-Dichlorophenoxyacetic acid (2,4-D) mg/l - x x x x x x x x x <0.002 x x x x x x x x x < x x x x x x x x x Dimethoate mg/l - x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x x Dinoseb mg/l - x x x x x x x x x <0.002 x x x x x x x x x < x x x x x x x x x Disulfoton mg/l - x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x x Famphur mg/l - x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x x Methyl parathion mg/l - x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x x o,o,o-triethyl phosphorothioate mg/l - x x x x x x x x x <0.003 x x x x x x x x x <0.001 x x x x x x x x x Parathion (Ethyl) mg/l - x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x x Phorate mg/l - x x x x x x x x x <0.002 x x x x x x x x x <0.001 x x x x x x x x x Silvex mg/l - x x x x x x x x x <0.002 x x x x x x x x x < x x x x x x x x x o,o-diethyl o-2pyrazinyl phosphorothioate (Thionazin) mg/l - x x x x x x x x x x x x x x x x x x x <0.001 x x x x x x x x x * baseline averages and standard deviations are based on 1999 and 2000 data only as per requirements in Environmental Protection, subpart 803. Ground Water Sampling and Analysis, hazardous x parameter not analyzed (^) See section entitled 'Semi volatile organic compounds - phenolics' for break-out of phenolics concentrations. (^^) See section entitled 'Polychlorinated Biphenyls (PCBs)' for break-out of PCB concentrations. (") This concentration attributed to laboratory contamination of method blank and not the presence of antimony in the ground water sampled. (#) Scanned for and not detected, breaks down almost immediately in water. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
79 JSAI MW-5 JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
80 APPEIX B Las Cruces Foothills Landfill MW-5 Page 1 of 6 Las Cruces Foothills Landfill monitoring well MW-5 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-5 average deviation date 7/15/03 8/27/03 9/29/03 10/29/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/20/12 6/26/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 Field Parameters water level elevation ft amsl , conductivity µs/cm ph ph units (a) temperature deg F Major Ions calcium mg/l chloride mg/l fluoride mg/l x x x x 0.59 x 0.58 x x x x magnesium mg/l potassium mg/l sodium mg/l sulfate mg/l alkalinity NA mg/l bicarbonate alkalinity mg/l carbonate alkalinity mg/l - <20 <2 <2.0 <2.0 <2.0 <2.0 <4.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 x total dissolved solids NA mg/l 1, Nitrogen Species ammonia as N mg/l - <0.1 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.5 x Kjeldahl nitrogen mg/l - <1 <1.0 <1.0 <1.0 <1.0 <1.0 x x x x <1.0 x x x x x x <1.0 x nitrate as N mg/l nitrite mg/l - < x x x x x x x x x x x total nitrogen - mg/l - x x x x x x x x x x 2.7 x x x x x x x x Metals aluminum mg/l <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 x x x <0.02 x 0.02 x x x x <3.0 x antimony mg/l < <0.003 <0.003 <0.003 <0.003 <0.003 x x x x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.003 x arsenic mg/l <0.01 <0.01 <0.01 <0.01 <0.01 x x x x x barium mg/l x x x x beryllium mg/l < <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.003 x < <0.002 <0.002 <0.002 <0.002 x boron mg/l 0.75 <0.1 <0.5 <0.5 <0.5 <0.5 <0.5 x x x x x x x x x <0.5 x cadmium mg/l < <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.002 < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x chromium mg/l <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < < <0.006 <0.006 < x cobalt mg/l <0.03 <0.03 <0.03 <0.03 <0.03 x x x x <0.006 < < <0.006 <0.006 < x copper mg/l <0.06 <0.06 <0.06 <0.06 <0.06 x x x x <0.006 < <0.006 <0.006 <0.006 <0.006 < x iron mg/l <0.1 <0.1 <0.1 <0.1 <0.1 x <0.1 <0.1 <0.1 < <0.05 < <0.02 < x lead mg/l <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.005 < <0.005 <0.005 <0.005 <0.005 < x manganese mg/l 0.2 <0.010 <0.03 <0.03 <0.03 <0.03 <0.03 x <0.03 <0.03 <0.03 < < <0.002 <0.002 <0.002 <0.03 x mercury mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x < x x x x <0.001 x molybdenum mg/l 1.0 <0.010 <0.75 <0.75 <0.75 <0.75 <0.75 x x x x <0.008 x <0.008 x x x x <0.75 x nickel mg/l <0.05 <0.05 <0.05 <0.05 <0.05 x x x x < <0.01 <0.01 <0.01 <0.01 < x selenium mg/l <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 < < x silver mg/l 0.05 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.005 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.01 x thallium mg/l <0.001 <0.001 <0.001 <0.001 <0.001 x x x x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < x tin mg/l - <0.10 x x x x <0.4 x x x x <0.1 x x x x x x <0.4 x uranium mg/l 0.03 <0.002 <2.5 <2.5 <2.5 <2.5 <2.5 x x x x x x x x x x <2.5 x vanadium mg/l - <0.050 <0.08 <0.08 <0.08 <0.08 <0.08 x x x x <0.05 <0.050 < <0.05 <0.05 <0.05 <0.08 x zinc mg/l <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.02 <0.020 < <0.01 <0.01 < x total organic carbon - mg/l - 1 <1.0 <1.0 <1.0 < <0.5 <0.5 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 < phosphate mg/l - x x x x x x x x x x <0.50 x <0.50 x x x x x x sulfide mg/l - <0.1 x x x x <4.0 x x x x 2 x x x x x x <4.0 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
81 APPEIX B Las Cruces Foothills Landfill MW-5 Page 2 of 6 Las Cruces Foothills Landfill monitoring well MW-5 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-5 average deviation date 7/15/03 8/27/03 9/29/03 10/29/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/20/12 6/26/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 cyanide mg/l 0.2 <0.01 <0.1 <0.1 <0.1 <0.1 <0.1 x x x x <0.005 x x x x x x <0.1 x perchlorate mg/l - x x x x x x x x x x <0.001 x x x x x x x x total phenolics 1 - mg/l <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 < < < < < < < < <0.003 x Polychlorinated Biphenyls (PCBs) mg/l (^^) (^^) (^^) (^^) (^^) (^^) x x x x (^^) x x x x x x (^^) (^^) Volatile Organic Compounds 1,1,1,2-Tetrachloroethane mg/l 0.02 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x 1,1,1-Trichloroethane mg/l 0.06 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x 1,1,2,2-Tetrachloroethane mg/l 0.01 < <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x 1,1,2-Trichloroethane mg/l < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 x 1,1-Dichloroethane mg/l < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x 1,1-Dichloroethylene (1,1-Dichloroethene; 1,1-DCE) mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloropropene mg/l - < <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.005 x x x x x x <0.005 x 1,2 Dibromo-3-chloropropane (DBCP) mg/l <0.01 < < < < < < < < < < < < < < < < < x 1,2,3-Trichlorobenzene mg/l - < x x x x x x x x x x x x x x x x < x 1,2,3-Trichloropropane mg/l 0.01 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x 1,2,4-Trichlorobenzene mg/l - < x x x x x x x x x <0.001 x x x x x x < x 1,2-Dichlorobenzene (o-dichlorobenzene) mg/l 0.6 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x 1,2-Dichloroethane (EDC) mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2-Dichloropropane mg/l < < < < < < < < < < < < < < < < < < x 1,3-Dichlorobenzene (m-dichlorobenzene) mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 <0.001 x x x x x <0.01 x 1,3-Dichloropropane mg/l - < <0.005 <0.01 <0.01 <0.01 <0.01 x x x x <0.01 x x x x x x <0.01 x 1,4-Dichlorobenzene (p-dichlorobenzene) mg/l < <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.015 x 2,2-Dichloropropane mg/l - < < <0.015 <0.015 <0.015 <0.015 x x x x <0.015 x x x x x x <0.015 x 2-Butanone (Methyl Ethyl Ketone) (MEK) mg/l - <0.025 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x 2-Chlorotoluene mg/l - < x x x x x x x x x x x x x x x x < x 2-Hexanone (Butyl Ketone) mg/l 0.02 <0.025 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.05 x 4-Chlorotoluene mg/l - < x x x x x x x x x x x x x x x x < x 4-Methyl-2-pentanone mg/l - <0.025 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.015 x Acetone mg/l - <0.025 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 < <0.01 <0.01 <0.01 <0.1 x Acetonitrile mg/l - <0.100 <0.100 <0.1 <0.1 <0.1 <0.1 x x x x <0.1 x x x x x x <0.1 x Acrolein mg/l - <0.025 <0.1 <0.1 <0.1 <0.1 <0.1 x x x x <0.1 x x x x x x <0.1 x Acrylonitrile mg/l - <0.025 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.2 x Allyl chloride mg/l - x <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.01 x x x x x x <0.01 x Benzene mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Bis(chloromethyl) ether mg/l - x x x x x x x x x x (#) x x x x x x x x Bromochloromethane mg/l - <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x Bromomethane (methyl bromide) mg/l - <0.001 <0.01 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.02 x Carbon Disulfide mg/l - <0.005 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.1 x Carbon Tetrachloride mg/l < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 x Chlorobenzene mg/l 0.1 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x Chloroethane mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 x Chloromethane (methyl chloride) mg/l 0.02 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroprene (2-Chloro-1,3-butadiene) mg/l - <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 x x x x x x x x x x x <0.05 x cis-1,2-dichloroethylene (cis-1,2-dichloroethene) mg/l 0.07 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < <0.001 <0.001 <0.001 <0.005 x cis-1,3-dichloropropene mg/l - < <0.001 <0.02 <0.02 <0.02 <0.02 x x x x <0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.02 x Dibromomethane (methylene bromide) mg/l - < <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.02 x Dichlorodifluoromethane mg/l <0.005 <0.005 <0.005 <0.005 <0.005 x x x < < <0.005 x Ethyl methacrylate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.01 x x x x x x <0.01 x Ethylbenzene mg/l 0.75 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x Ethylene Dibromide (1,2-Dibromoethane) (EDB) mg/l < < < < < < < < < < < < < < < < < x Hexachlorobutadiene mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
82 APPEIX B Las Cruces Foothills Landfill MW-5 Page 3 of 6 Las Cruces Foothills Landfill monitoring well MW-5 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-5 average deviation date 7/15/03 8/27/03 9/29/03 10/29/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/20/12 6/26/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 Isobutyl alcohol mg/l - <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.05 x x x x x x <0.05 x Isopropylbenzene mg/l - < x x x x x x x x x x x x x x x x < x Methacrylonitrile mg/l - <0.025 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.005 x x x x x x <0.005 x Methyl Iodide (Iodomethane) mg/l - <0.005 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.04 x Methyl methacrylate mg/l - <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 x x x x <0.03 x x x x x x <0.03 x Methylene Chloride mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x n-butylbenzene mg/l - < x x x x x x x x x x x x x x x x < x Propionitrile mg/l - <0.01 <0.06 <0.06 <0.06 <0.06 <0.06 x x x x <0.06 x x x x x x <0.06 x Propylbenzene mg/l - < x x x x x x x x x x x x x x x x < x sec-butylbenzene mg/l - < x x x x x x x x x x x x x x x x < x Styrene mg/l 0.1 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x tert-butyl methyl ether (MTBE) (a) mg/l 0.1 <0.005 x x x x x x x x x <0.001 x x x x x x <0.005 x tert-butylbenzene mg/l - < x x x x x x x x x x x x x x x x < x Tetrachloroethene (PCE) mg/l < Tetrahydrofuran (THF) mg/l - <0.01 x x x x x x x x x x x x x x x x <0.01 x Toluene mg/l <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 < x Total Xylenes (m&p and o) 1 NA mg/l 0.62 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.005 x trans-1,2-dichloroethene mg/l 0.1 < <0.005 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 x trans-1,3-dichloropropene mg/l - <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x trans-1,4-dichloro-2-butene mg/l - <0.010 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.1 x Trichloroethene (TCE) mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 x Trichlorofluoromethane mg/l - <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 < <0.001 <0.001 <0.001 <0.01 x Vinyl acetate mg/l - <0.025 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.05 x Vinyl chloride mg/l < < < < < < < < < < < < < < < < < < x Trihalomethanes (THM) Bromodichloromethane mg/l - < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x Bromoform mg/l 0.1 <0.001 <0.001 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.015 x Chloroform mg/l 0.1 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x Dibromochloromethane mg/l - < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x Semi Volatile Organic Compounds 1,2,4,5-Tetrachlorobenzene mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 1,2-Diphenylhydrazine mg/l - <0.005 x x x x x x x x x <0.001 x x x x x x <0.005 x 1,4-Naphthoquinone mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 1-Chloronaphthalene NA mg/l - <0.005 x x x x x x x x x x x x x x x x <0.005 x 1-Methylnaphthalene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 1-Naphthylamine mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 2,4,6-Trinitrotoluene (TNT) mg/l - x x x x x x x x x x < x x x x x x x x 2,4-Dinitrotoluene (2,4-DNT) mg/l - <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 x x x x x x <0.005 x 2,6-Dinitrotoluene 1 (2,6-DNT) mg/l - <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 x x x x x x <0.005 x 2-Acetylaminofluorene mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x 2-Chloronaphthalene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 2-Methylnaphthalene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 2-Naphthylamine mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 2-Nitroaniline (o-nitroaniline) mg/l - <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 2-Picoline mg/l - <0.01 x x x x x x x x x <0.001 x x x x x x <0.01 x 3,3'-Dichlorobenzidine mg/l - <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 3,3'-Dimethylbenzidine mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 3-Methylcholanthrene mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 3-Nitroaniline (m-nitroaniline) mg/l - <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.001 x x x x x x <0.05 x 4-Aminobiphenyl mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x 4-Bromophenylphenyl ether mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
83 APPEIX B Las Cruces Foothills Landfill MW-5 Page 4 of 6 Las Cruces Foothills Landfill monitoring well MW-5 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-5 average deviation date 7/15/03 8/27/03 9/29/03 10/29/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/20/12 6/26/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 4-Chloroaniline (p-chloroanaline) mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x 4-Chlorophenylphenyl ether mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 4-Nitroaniline (p-nitroaniline) mg/l - <0.05 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x 5-Nitro-o-toluidine mg/l - x x x x x x x x x x <0.001 x x x x x x x x 7,12-Dimethylbenz (a) anthracene mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Acenaphthene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Acenaphthylene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Acetophenone mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x alpha,alpha-dimethylphenethylamine mg/l - <0.01 x x x x x x x x x <0.001 x x x x x x <0.01 x Aniline mg/l - <0.01 x x x x x x x x x <0.001 x x x x x x <0.01 x Anthracene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Benzidine mg/l - <0.05 x x x x x x x x x <0.001 x x x x x x <0.05 x Benzo (a) anthracene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x Benzo (a) pyrene mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x < x x x x x x <0.02 x Benzo (b) fluoranthene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Benzo (g,h,i) perylene mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x < x x x x x x <0.02 x Benzo (k) fluoranthene mg/l <0.005 < < < < < x x x x < x x x x x x < x Benzoic acid mg/l <0.05 x x x x x x x x x x x x x x x x <0.05 x Benzyl alcohol mg/l - <0.02 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x bis (2-Chloroethoxy) methane mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x bis (2-Chloroethyl) ether mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x bis (2-Chloroisopropyl) ether (bis (2-chloro-1-methylethyl) ether) mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x bis (2-Ethylhexyl) phthalate mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Butylbenzylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Carbazole mg/l - <0.005 x x x x x x x x x <0.001 x x x x x x <0.005 x Chlorobenzilate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Chrysene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x Diallate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Dibenz (a,j) acridine mg/l - <0.01 x x x x x x x x x x x x x x x x <0.01 x Dibenzo (a,h) anthracene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x Dibenzofuran mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Diethylene Glycol Monobutyl Ether mg/l - x x x x x x x x x x x x x x x x x x x Diethylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Dimethylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Di-n-butylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Di-n-octylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Diphenylamine mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Ethyl methanesulfonate mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Fluoranthene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Fluorene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Hexachlorobenzene mg/l - <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Hexachlorocyclopentadiene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Hexachloroethane mg/l - <0.005 <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.001 x x x x x x <0.05 x Hexachloropropene mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x HMX mg/l - x x x x x x x x x x < x x x x x x x x Indeno (1,2,3-cd) pyrene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x Isophorone mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Isosafrole mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x m-dinitrobenzene (1,3-DNB) mg/l - x <0.02 <0.02 <0.02 <0.02 <0.02 x x x x < x x x x x x <0.02 x Methapyrilene mg/l - <0.1 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
84 APPEIX B Las Cruces Foothills Landfill MW-5 Page 5 of 6 Las Cruces Foothills Landfill monitoring well MW-5 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-5 average deviation date 7/15/03 8/27/03 9/29/03 10/29/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/20/12 6/26/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 Methyl methanesulfonate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Naphthalene mg/l 0.03 <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Nitrobenzene mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x n-nitrosodiethylamine mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x n-nitrosodimethylamine mg/l - <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.001 x x x x x x <0.002 x n-nitrosodi-n-butylamine mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x n-nitrosodinpropylamine mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x n-nitrosodiphenylamine mg/l - <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 x x x x x x <0.005 x n-nitrosomethylethylamine mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x n-nitrosopiperidine mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x n-nitrosopyrrolidine mg/l - <0.02 <0.04 <0.04 <0.04 <0.04 <0.04 x x x x <0.001 x x x x x x <0.04 x o-toluidine mg/l - <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.001 x x x x x x <0.002 x p-(dimethylamino) azobenzene mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Pentachlorobenzene mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Pentachloronitrobenzene mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Phenacetin mg/l - <0.02 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Phenanthrene mg/l - <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 x x x x <0.001 x x x x x x <0.001 x p-phenylenediamine mg/l - <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Pronamide mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Pyrene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Pyridine mg/l - <0.01 x x x x x x x x x <0.001 x x x x x x <0.01 x RDX mg/l - x x x x x x x x x x < x x x x x x x x Safrole mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x sym-trinitrobenzene 1 (1,3,5-TNB) mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x x x x x x x x <0.01 x Semi Volatile Organic Compounds - Phenolics 2,3,4,6-Tetrachlorophenol mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2,4,5-Trichlorophenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2,4,6-Trichlorophenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2,4-Dichlorophenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2,4-Dimethylphenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2,4-Dinitrophenol mg/l - <0.05 <0.05 <0.05 <0.05 <0.05 x x x x x <0.001 x x x x x x <0.05 x 2,6-Dichlorophenol mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2-Chlorophenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2-Methylphenol (o-cresol) mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2-Nitrophenol (o-nitrophenol) mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 3-Methylphenol/4-Methylphenol (m&p-cresol) / mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 x x x x x <0.001 x x x x x x <0.02 x 4,6-Dinitro-2-methylphenol (4,6-Dinitro-o-cresol) mg/l - <0.05 <0.05 <0.05 <0.05 <0.05 x x x x x <0.001 x x x x x x <0.05 x p-chloro-m-cresol (4-Chloro-3-methylphenol) mg/l - <0.02 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 x x x x x x <0.005 x 4-Nitrophenol (p-nitrophenol) mg/l - <0.05 <0.05 <0.05 <0.05 <0.05 x x x x x <0.001 x x x x x x <0.05 x Pentachlorophenol mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 x x x x x <0.001 x x x x x x <0.02 x Phenol 1 (a) mg/l <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x Radium 226 and 228 NA pci/l Ra-226, total NA pci/l <2.5 <2.5 <2.5 <2.5 <2.5 x x x x 0.14 x x x x x x <2.5 x Ra-228 1, total NA pci/l <2.5 <2.5 <2.5 <2.5 <2.5 x x x x 0.16 x x x x x x <2.5 x Chlorinated Pesticides 4,4'-DDD (p,p'-ddd) mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x 4,4'-DDE (p,p'-dde) mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x 4,4'-DDT (p,p'-ddt) mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x aldrin mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x alpha-bhc mg/l - < < < < < < x x x x < x x x x x x < x alpha-chlordane mg/l - < alpha + alpha + alpha + alpha + alpha + x x x x x x x x x x x alpha + x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
85 APPEIX B Las Cruces Foothills Landfill MW-5 Page 6 of 6 Las Cruces Foothills Landfill monitoring well MW-5 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-5 average deviation date 7/15/03 8/27/03 9/29/03 10/29/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/20/12 6/26/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 beta-bhc mg/l - < < < < < < x x x x < x x x x x x < x Chlordane mg/l x x x x x x x x x x < x x x x x x x x delta-bhc mg/l - < < < < < < x x x x < x x x x x x < x Dieldrin mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Endosulfan I (alpha-endosulfan) mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Endosulfan II (beta-endosulfan) mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Endosulfan sulfate mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Endrin aldehyde mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Endrin ketone mg/l - < x x x x x x x x x x x x x x x x < x Endrin mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x gamma-bhc mg/l - < < < < < < x x x x < x x x x x x < x gamma-chlordane mg/l - < see above see above see above see above see above x x x x x x x x x x x see above x Heptachlor epoxide mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Heptachlor mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Isodrin mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Kepone mg/l - <0.025 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Methoxychlor mg/l - <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x Toxaphene mg/l - <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 x x x x <0.001 x x x x x x <0.001 x Polychlorinated Biphenyls (PCBs) Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Other Pesticides and Herbicides 1 2,3,7,8-TCDD ng/l 0.03 x x x x x x x x x x < x x x x x x x x 2,4,5-T mg/l - <0.001 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x < x x x x x x <0.002 x 2,4-Dichlorophenoxyacetic acid (2,4-D) mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x Dimethoate mg/l - < <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Dinoseb mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x < x x x x x x <0.02 x Disulfoton mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Famphur mg/l - < <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Methyl parathion mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x o,o,o-triethyl phosphorothioate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Parathion (Ethyl) mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Phorate mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Silvex 1 (2,4,5-TP) mg/l - <0.001 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x < x x x x x x <0.002 x o,o-diethyl o-2pyrazinyl phosphorothioate (Thionazin) mg/l - x <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x * baseline averages and standard deviations are based on 1999 and 2000 data only as per requirements in Environmental Protection, subpart 803. Ground Water Sampling and Analysis, hazardous x parameter not analyzed (^^) See section entitled 'Polychlorinated Biphenyls (PCBs)' for break-out of PCB concentrations. (#) Scanned for and not detected, breaks down almost immediately in water. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
86 JSAI MW-6 JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
87 APPEIX B Page 1 of 6 Las Cruces Foothills Landfill MW-6 Las Cruces Foothills Landfill monitoring well MW-6 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-6 average deviation date 7/15/03 8/27/03 9/29/03 10/27/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/20/12 6/26/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 Field Parameters water level elevation ft amsl , conductivity µs/cm - pumped dry ph ph units temperature deg F - pumped dry Major Ions calcium mg/l chloride mg/l fluoride mg/l x x x x 0.56 x 0.55 x x x x magnesium mg/l potassium mg/l sodium mg/l sulfate mg/l alkalinity NA mg/l bicarbonate alkalinity mg/l carbonate alkalinity mg/l - <20 <2.0 <2.0 <2.0 <2.0 <2.0 <4.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 x total dissolved solids NA mg/l 1, Nitrogen Species ammonia as N mg/l - <0.1 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.5 x Kjeldahl nitrogen mg/l - 2 <1.0 <1.0 <1.0 <1.0 <1.0 x x x x <1.0 x x x x x x 2.00 x nitrate as N mg/l nitrite mg/l - < x x x x x x x x x x x total nitrogen - mg/l - x x x x x x x x x x 2.5 x x x x x x x x Metals aluminum mg/l <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 x x x <0.02 x <0.020 x x x x 0.09 x antimony mg/l < <0.003 <0.003 <0.003 <0.003 <0.003 x x x x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.003 x arsenic mg/l <0.01 <0.01 <0.01 <0.01 <0.01 x x x x x barium mg/l x x x x beryllium mg/l < <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.003 x < <0.002 <0.002 <0.002 <0.002 x boron mg/l 0.75 <0.1 <0.5 <0.5 <0.5 <0.5 <0.5 x x x x <0.04 x <0.04 x x x x <0.5 x cadmium mg/l < <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.002 < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x chromium mg/l <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.006 < <0.006 <0.006 <0.006 <0.006 < x cobalt mg/l <0.03 <0.03 <0.03 <0.03 <0.03 x x x x <0.006 < < <0.006 <0.006 < x copper mg/l <0.06 <0.06 <0.06 <0.06 <0.06 x x x x < <0.006 <0.006 <0.006 <0.006 < x iron mg/l <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.05 <0.05 < <0.02 <0.02 < x lead mg/l 0.05 < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.01 x manganese mg/l <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 < x mercury mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x < x x x x <0.001 x molybdenum mg/l 1.0 <0.010 <0.75 <0.75 <0.75 <0.75 <0.75 x x x x <0.008 x <0.008 x x x x <0.75 x nickel mg/l <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 < x selenium mg/l <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 < < x silver mg/l 0.05 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.01 x thallium mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x tin mg/l - <0.10 x x x x <0.4 x x x x <0.1 x x x x x x <0.4 x uranium mg/l 0.03 <0.002 <2.5 <2.5 <2.5 <2.5 <2.5 x x x x x x x x x x <2.5 x vanadium mg/l - <0.050 <0.08 <0.08 <0.08 <0.08 <0.08 x x x x <0.05 <0.05 < <0.05 <0.05 <0.05 <0.08 x zinc mg/l <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.02 <0.02 < <0.01 <0.01 < x total organic carbon - mg/l - <0.5 <1.0 <1.0 <1.0 <0.5 <0.5 <0.5 < < <1.0 < <0.5 x phosphate mg/l - x x x x x x x x x x <0.50 x <0.50 x x x x x x sulfide mg/l - <0.1 x x x x <4.0 x x x x 3 x x x x x x <4.0 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
88 APPEIX B Page 2 of 6 Las Cruces Foothills Landfill MW-6 Las Cruces Foothills Landfill monitoring well MW-6 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-6 average deviation date 7/15/03 8/27/03 9/29/03 10/27/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/20/12 6/26/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 cyanide mg/l 0.2 <0.01 <0.1 <0.1 <0.1 <0.1 <0.1 x x x x <0.005 x x x x x x <0.1 x perchlorate mg/l - x x x x x x x x x x <0.001 x x x x x x x x total phenolics 1 - mg/l <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 < < < < < < < < x Polychlorinated Biphenyls (PCBs) mg/l (^^) (^^) (^^) (^^) (^^) (^^) x x x x (^^) x x x x x x (^^) x Volatile Organic Compounds 1,1,1,2-Tetrachloroethane mg/l 0.02 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x 1,1,1-Trichloroethane mg/l 0.06 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x 1,1,2,2-Tetrachloroethane mg/l 0.01 < <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x 1,1,2-Trichloroethane mg/l < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 x 1,1-Dichloroethane mg/l < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x 1,1-Dichloroethylene (1,1-Dichloroethene; 1,1-DCE) mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloropropene mg/l - < <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.005 x x x x x x <0.005 x 1,2 Dibromo-3-chloropropane (DBCP) mg/l <0.010 < < < < < < < < < < < < < < < < < x 1,2,3-Trichlorobenzene mg/l - < x x x x x x x x x x x x x x x x < x 1,2,3-Trichloropropane mg/l 0.01 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x 1,2,4-Trichlorobenzene mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 1,2-Dichlorobenzene (o-dichlorobenzene) mg/l 0.6 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x 1,2-Dichloroethane (EDC) mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2-Dichloropropane mg/l < < < < < < < < < < < < < < < < < < x 1,3-Dichlorobenzene (m-dichlorobenzene) mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 <0.001 x x x x x <0.01 x 1,3-Dichloropropane mg/l - < <0.005 <0.01 <0.01 <0.01 <0.01 x x x x <0.01 x x x x x x <0.01 x 1,4-Dichlorobenzene (p-dichlorobenzene) mg/l < <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.015 x 2,2-Dichloropropane mg/l - < < <0.015 <0.015 <0.015 <0.015 x x x x <0.015 x x x x x x <0.015 x 2-Butanone (Methyl Ethyl Ketone) (MEK) mg/l - <0.025 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x 2-Chlorotoluene mg/l - < x x x x x x x x x x x x x x x x < x 2-Hexanone (Butyl Ketone) mg/l 0.02 <0.025 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.05 x 4-Chlorotoluene mg/l - < x x x x x x x x x x x x x x x x < x 4-Methyl-2-pentanone mg/l - <0.025 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.015 x Acetone mg/l - <0.025 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.1 x Acetonitrile mg/l - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 x x x x <0.1 x x x x x x <0.1 x Acrolein mg/l - <0.025 <0.1 <0.1 <0.1 <0.1 <0.1 x x x x <0.1 x x x x x x <0.1 x Acrylonitrile mg/l - <0.025 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.2 x Allyl chloride mg/l - x <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.01 x x x x x x <0.01 x Benzene mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Bis(chloromethyl) ether mg/l - x x x x x x x x x x (#) x x x x x x x x Bromochloromethane mg/l - <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 < <0.002 <0.002 <0.002 <0.002 x Bromomethane (methyl bromide) mg/l - <0.001 <0.01 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.02 x Carbon Disulfide mg/l - <0.005 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.1 x Carbon Tetrachloride mg/l < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 x Chlorobenzene mg/l 0.1 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x Chloroethane mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 x Chloromethane (methyl chloride) mg/l 0.02 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroprene (2-Chloro-1,3-butadiene) mg/l - <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 x x x x x x x x x x x <0.05 x cis-1,2-dichloroethylene (cis-1,2-dichloroethene) mg/l <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < <0.001 <0.001 <0.001 <0.005 x cis-1,3-dichloropropene mg/l - < <0.001 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.02 x Dibromomethane (methylene bromide) mg/l - < <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.02 x Dichlorodifluoromethane mg/l < x <0.005 < Ethyl methacrylate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.01 x x x x x x <0.01 x Ethylbenzene mg/l 0.75 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x Ethylene Dibromide (1,2-Dibromoethane) (EDB) mg/l < < < < < < < < < < < < < < < < < < x Hexachlorobutadiene mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
89 APPEIX B Page 3 of 6 Las Cruces Foothills Landfill MW-6 Las Cruces Foothills Landfill monitoring well MW-6 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-6 average deviation date 7/15/03 8/27/03 9/29/03 10/27/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/20/12 6/26/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 Isobutyl alcohol mg/l - <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.05 x x x x x x <0.05 x Isopropylbenzene mg/l - < x x x x x x x x x x x x x x x x < x Methacrylonitrile mg/l - <0.025 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.005 x x x x x x <0.005 x Methyl Iodide (Iodomethane) mg/l - <0.005 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.04 x Methyl methacrylate mg/l - <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 x x x x <0.03 x x x x x x <0.03 x Methylene Chloride mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x n-butylbenzene mg/l - < x x x x x x x x x x x x x x x x < x Propionitrile mg/l - <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 x x x x <0.06 x x x x x x <0.06 x Propylbenzene mg/l - < x x x x x x x x x x x x x x x x < x sec-butylbenzene mg/l - < x x x x x x x x x x x x x x x x < x Styrene mg/l 0.1 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x tert-butyl methyl ether (MTBE) (a) mg/l 0.1 <0.005 x x x x x x x x x <0.001 x x x x x x <0.005 x tert-butylbenzene mg/l - < x x x x x x x x x x x x x x x x < x Tetrachloroethene (PCE) mg/l Tetrahydrofuran (THF) mg/l - <0.010 x x x x x x x x x x x x x x x x <0.010 x Toluene mg/l <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < <0.001 <0.001 <0.001 <0.005 x Total Xylenes (m&p and o) 1 NA mg/l 0.62 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.002 < <0.002 <0.002 <0.002 <0.005 x trans-1,2-dichloroethene mg/l 0.1 < <0.005 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 x trans-1,3-dichloropropene mg/l - <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x trans-1,4-dichloro-2-butene mg/l - <0.010 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.1 x Trichloroethene (TCE) mg/l <0.001 <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 x Trichlorofluoromethane mg/l - <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 < <0.001 <0.001 <0.001 <0.01 x Vinyl acetate mg/l - <0.025 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.05 x Vinyl chloride mg/l < < < < < < < < < < < < < < < < < < x Trihalomethanes (THM) Bromodichloromethane mg/l - < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x Bromoform mg/l 0.1 <0.001 <0.001 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.015 x Chloroform mg/l 0.1 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x Dibromochloromethane mg/l - < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x Semi Volatile Organic Compounds 1,2,4,5-Tetrachlorobenzene mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 1,2-Diphenylhydrazine mg/l - <0.005 x x x x x x x x x <0.001 x x x x x x <0.005 x 1,4-Naphthoquinone mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 1-Chloronaphthalene NA mg/l - <0.005 x x x x x x x x x x x x x x x x <0.005 x 1-Methylnaphthalene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 1-Naphthylamine mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 2,4,6-Trinitrotoluene (TNT) mg/l - x x x x x x x x x x < x x x x x x x x 2,4-Dinitrotoluene (2,4-DNT) mg/l - <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 x x x x x x <0.005 x 2,6-Dinitrotoluene 1 (2,6-DNT) mg/l - <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 x x x x x x <0.005 x 2-Acetylaminofluorene mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x 2-Chloronaphthalene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 2-Methylnaphthalene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 2-Naphthylamine mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 2-Nitroaniline (o-nitroaniline) mg/l - <0.050 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 2-Picoline mg/l - <0.010 x x x x x x x x x <0.001 x x x x x x <0.01 x 3,3'-Dichlorobenzidine mg/l - <0.050 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 3,3'-Dimethylbenzidine mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 3-Methylcholanthrene mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 3-Nitroaniline (m-nitroaniline) mg/l - <0.050 <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.001 x x x x x x <0.05 x 4-Aminobiphenyl mg/l - <0.020 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x 4-Bromophenylphenyl ether mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
90 APPEIX B Page 4 of 6 Las Cruces Foothills Landfill MW-6 Las Cruces Foothills Landfill monitoring well MW-6 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-6 average deviation date 7/15/03 8/27/03 9/29/03 10/27/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/20/12 6/26/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 4-Chloroaniline (p-chloroanaline) mg/l - <0.020 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x 4-Chlorophenylphenyl ether mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x 4-Nitroaniline (p-nitroaniline) mg/l - <0.050 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x 5-Nitro-o-toluidine mg/l - x x x x x x x x x x <0.001 x x x x x x x x 7,12-Dimethylbenz (a) anthracene mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Acenaphthene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Acenaphthylene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Acetophenone mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x alpha,alpha-dimethylphenethylamine mg/l - <0.010 x x x x x x x x x <0.001 x x x x x x <0.01 x Aniline mg/l - <0.010 x x x x x x x x x <0.001 x x x x x x <0.01 x Anthracene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Benzidine mg/l - <0.050 x x x x x x x x x <0.001 x x x x x x <0.05 x Benzo (a) anthracene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x Benzo (a) pyrene mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x < x x x x x x <0.02 x Benzo (b) fluoranthene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Benzo (g,h,i) perylene mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x < x x x x x x <0.02 x Benzo (k) fluoranthene mg/l <0.005 < < < < < x x x x < x x x x x x < x Benzoic acid mg/l <0.050 x x x x x x x x x x x x x x x x <0.05 x Benzyl alcohol mg/l - <0.020 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x bis (2-Chloroethoxy) methane mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x bis (2-Chloroethyl) ether mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x bis (2-Chloroisopropyl) ether (bis (2-chloro-1-methylethyl) ether) mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x bis (2-Ethylhexyl) phthalate mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Butylbenzylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Carbazole mg/l - <0.005 x x x x x x x x x <0.001 x x x x x x <0.005 x Chlorobenzilate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Chrysene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x Diallate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Dibenz (a,j) acridine mg/l - <0.010 x x x x x x x x x x x x x x x x <0.01 x Dibenzo (a,h) anthracene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x Dibenzofuran mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Diethylene Glycol Monobutyl Ether mg/l - x x x x x x x x x x x x x x x x x x x Diethylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Dimethylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Di-n-butylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Di-n-octylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Diphenylamine mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Ethyl methanesulfonate mg/l - <0.020 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Fluoranthene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Fluorene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Hexachlorobenzene mg/l - <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Hexachlorocyclopentadiene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Hexachloroethane mg/l - <0.005 <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.001 x x x x x x <0.05 x Hexachloropropene mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x HMX mg/l - x x x x x x x x x x < x x x x x x x x Indeno (1,2,3-cd) pyrene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x Isophorone mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Isosafrole mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x m-dinitrobenzene (1,3-DNB) mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x x x x x x x x <0.02 x Methapyrilene mg/l - <0.1 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Methyl methanesulfonate mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
91 APPEIX B Page 5 of 6 Las Cruces Foothills Landfill MW-6 Las Cruces Foothills Landfill monitoring well MW-6 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-6 average deviation date 7/15/03 8/27/03 9/29/03 10/27/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/20/12 6/26/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 Naphthalene mg/l 0.03 <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Nitrobenzene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x n-nitrosodiethylamine mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x n-nitrosodimethylamine mg/l - <0.010 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.001 x x x x x x <0.002 x n-nitrosodi-n-butylamine mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x n-nitrosodinpropylamine mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x n-nitrosodiphenylamine mg/l - <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 x x x x x x <0.005 x n-nitrosomethylethylamine mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x n-nitrosopiperidine mg/l - <0.020 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x n-nitrosopyrrolidine mg/l - <0.02 <0.04 <0.04 <0.04 <0.04 <0.04 x x x x <0.001 x x x x x x <0.04 x o-toluidine mg/l - <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.001 x x x x x x <0.002 x p-(dimethylamino) azobenzene mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Pentachlorobenzene mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Pentachloronitrobenzene mg/l - <0.020 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Phenacetin mg/l - <0.020 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Phenanthrene mg/l - <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 x x x x <0.001 x x x x x x <0.001 x p-phenylenediamine mg/l - <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Pronamide mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Pyrene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Pyridine mg/l - <0.010 x x x x x x x x x <0.001 x x x x x x <0.01 x RDX mg/l - x x x x x x x x x x < x x x x x x x x Safrole mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x sym-trinitrobenzene 1 (1,3,5-TNB) mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x x x x x x x x <0.01 x Semi Volatile Organic Compounds - Phenolics 2,3,4,6-Tetrachlorophenol mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2,4,5-Trichlorophenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2,4,6-Trichlorophenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2,4-Dichlorophenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2,4-Dimethylphenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2,4-Dinitrophenol mg/l - <0.05 <0.05 <0.05 <0.05 <0.05 x x x x x <0.001 x x x x x x <0.05 x 2,6-Dichlorophenol mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2-Chlorophenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2-Methylphenol (o-cresol) mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 2-Nitrophenol (o-nitrophenol) mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x 3-Methylphenol/4-Methylphenol (m&p-cresol) / mg/l - x <0.02 <0.02 <0.02 <0.02 x x x x x <0.001 x x x x x x <0.02 x 4,6-Dinitro-2-methylphenol (4,6-Dinitro-o-cresol) mg/l - <0.05 <0.05 <0.05 <0.05 <0.05 x x x x x <0.001 x x x x x x <0.05 x p-chloro-m-cresol (4-Chloro-3-methylphenol) mg/l - <0.020 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 x x x x x x <0.005 x 4-Nitrophenol (p-nitrophenol) mg/l - <0.05 <0.05 <0.05 <0.05 <0.05 x x x x x <0.001 x x x x x x <0.05 x Pentachlorophenol mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 x x x x x <0.001 x x x x x x <0.02 x Phenol 1 (a) mg/l <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x <0.01 x Radium 226 and 228 NA pci/l Ra-226, total NA pci/l <2.5 <2.5 <2.5 <2.5 <2.5 x x x x 0.2 x x x x x x <2.5 x Ra-228 1, total NA pci/l - <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 x x x x 0.25 x x x x x x <2.5 x Chlorinated Pesticides 4,4'-DDD (p,p'-ddd) mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x 4,4'-DDE (p,p'-dde) mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x 4,4'-DDT (p,p'-ddt) mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x aldrin mg/l - < <0.01 <0.0.1 <0.0.1 <0.0.1 <0.0.1 x x x x < x x x x x x <0.0.1 x alpha-bhc mg/l - < < < < < < x x x x < x x x x x x < x alpha-chlordane mg/l - < alpha + alpha + alpha + alpha + alpha + x x x x x x x x x x x alpha + x beta-bhc mg/l - < < < < < < x x x x < x x x x x x < x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
92 APPEIX B Page 6 of 6 Las Cruces Foothills Landfill MW-6 Las Cruces Foothills Landfill monitoring well MW-6 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-6 average deviation date 7/15/03 8/27/03 9/29/03 10/27/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/20/12 6/26/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 Chlordane mg/l x x x x x x x x x x < x x x x x x x x delta-bhc mg/l - < < < < < < x x x x < x x x x x x < x Dieldrin mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Endosulfan I (alpha-endosulfan) mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Endosulfan II (beta-endosulfan) mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Endosulfan sulfate mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Endrin aldehyde mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Endrin ketone mg/l - < x x x x x x x x x x x x x x x x < x Endrin mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x gamma-bhc mg/l - < < < < < < x x x x < x x x x x x < x gamma-chlordane mg/l - < see above see above see above see above see above x x x x x x x x x x x see above x Heptachlor epoxide mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Heptachlor mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x <0.001 x Isodrin mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Kepone mg/l - <0.025 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Methoxychlor mg/l - <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x Toxaphene mg/l - <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 x x x x <0.001 x x x x x x <0.001 x Polychlorinated Biphenyls (PCBs) Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x < x Other Pesticides and Herbicides 1 2,3,7,8-TCDD ng/l 0.03 x x x x x x <1.30 x x x < x x x x x x x x 2,4,5-T mg/l - <0.001 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x < x x x x x x <0.002 x 2,4-Dichlorophenoxyacetic acid (2,4-D) mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x <0.01 x Dimethoate mg/l - < <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Dinoseb mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x < x x x x x x <0.02 x Disulfoton mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Famphur mg/l - < <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x Methyl parathion mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x o,o,o-triethyl phosphorothioate mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Parathion (Ethyl) mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Phorate mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x <0.01 x Silvex 1 (2,4,5-TP) mg/l - <0.001 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x < x x x x x x <0.002 x o,o-diethyl o-2pyrazinyl phosphorothioate (Thionazin) mg/l - x <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x <0.02 x * baseline averages and standard deviations are based on 1999 and 2000 data only as per requirements in Environmental Protection, subpart 803. Ground Water Sampling and Analysis, hazardous x parameter not analyzed (^^) See section entitled 'Polychlorinated Biphenyls (PCBs)' for break-out of PCB concentrations. (#) Scanned for and not detected, breaks down almost immediately in water. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
93 JSAI MW-7 JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
94 APPEIX B Page 1 of 6 Las Cruces Foothills Landfill MW-7 Las Cruces Foothills Landfill monitoring well MW-7 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-7 average deviation date 7/15/03 8/27/03 9/29/03 10/27/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/19/12 6/26/13 12/19/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 Field Parameters water level elevation ft amsl , conductivity µs/cm ph ph units temperature deg F Major Ions calcium mg/l chloride mg/l fluoride mg/l x x x x 0.69 x 0.65 x x x x x 0.76 <0.001 magnesium mg/l potassium mg/l sodium mg/l sulfate mg/l alkalinity NA mg/l bicarbonate alkalinity mg/l carbonate alkalinity mg/l - <20 <2.0 <2.0 <2.0 <2.0 <2.0 <4.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 x total dissolved solids NA mg/l 1, Nitrogen Species ammonia as N mg/l - <0.1 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.5 x Kjeldahl nitrogen mg/l - <1 <1.0 <1.0 <1.0 <1.0 <1.0 x x x x <1.0 x x x x x x x <1.0 x nitrate as N mg/l <1.0 <1.0 <1.0 <1.0 < < <1.0 <1.0 x nitrite mg/l - <0.1 <1.0 <1.0 <1.0 <1.0 <1.0 x x x x x x x x x x x x <1.0 x total nitrogen - mg/l - x x x x x x x x x x 1.1 x x x x x x x x x Metals aluminum mg/l <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 x x x <0.02 x 0.04 x x x x x <3.0 x antimony mg/l < <0.003 <0.003 <0.003 <0.003 <0.003 x x x x <0.001 <0.001 < < < <0.001 <0.001 <0.003 x arsenic mg/l <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.002 < < < <0.001 <0.01 x barium mg/l < x x x x beryllium mg/l <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.003 x < <0.002 <0.002 <0.002 <0.002 <0.002 x boron mg/l 0.75 <0.1 <0.5 <0.5 <0.5 <0.5 <0.5 x x x x <0.04 x <0.04 x x x x x <0.5 x cadmium mg/l < <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.002 < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x chromium mg/l <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.006 < < <0.006 <0.006 <0.006 <0.006 <0.01 x cobalt mg/l <0.03 <0.03 <0.03 <0.03 <0.03 x x x x <0.006 < < <0.006 <0.006 <0.006 <0.006 <0.03 x copper mg/l <0.06 <0.06 <0.06 <0.06 <0.06 x x x x <0.006 <0.006 <0.006 <0.006 <0.006 <0.06 x iron mg/l <0.1 <0.1 <0.1 < <0.1 <0.1 <0.1 < <0.02 < lead mg/l 0.05 < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.005 < <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.01 x manganese mg/l <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 < <0.03 x mercury mg/l <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x < x x x x x <0.001 x molybdenum mg/l 1.0 <0.010 <0.75 <0.75 <0.75 <0.75 <0.75 x x x x <0.008 x <0.008 x x x x x <0.75 x nickel mg/l <0.05 <0.05 <0.05 <0.05 <0.05 x x x x < < <0.01 <0.01 <0.01 <0.01 <0.05 x selenium mg/l <0.005 <0.005 <0.005 <0.005 <0.005 x x x x < < < <0.005 x silver mg/l 0.05 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.005 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.01 x thallium mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x <0.001 <0.001 <0.001 <0.001 < < <0.001 <0.001 <0.001 x tin mg/l - <0.10 x x x x <0.4 x x x x <0.1 x x x x x x x <0.4 x uranium mg/l <2.5 <2.5 <2.5 <2.5 <2.5 x x x x x x x x x x x <2.5 x vanadium mg/l - <0.050 <0.08 <0.08 <0.08 <0.08 <0.08 x x x x <0.05 <0.050 < <0.05 <0.05 <0.05 <0.05 <0.08 x zinc mg/l <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.02 <0.020 < <0.01 <0.01 <0.01 <0.01 <0.05 x total organic carbon - mg/l <1.0 <1.0 < < <0.5 <0.5 <1.0 <1.0 <1.0 < <1.0 <1.0 <1.0 < phosphate mg/l - x x x x x x x x x x <0.50 x <0.50 x x x x x x x sulfide mg/l - <0.1 x x x x <4.0 x x x x 2 x x x x x x x <4.0 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
95 APPEIX B Page 2 of 6 Las Cruces Foothills Landfill MW-7 Las Cruces Foothills Landfill monitoring well MW-7 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-7 average deviation date 7/15/03 8/27/03 9/29/03 10/27/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/19/12 6/26/13 12/19/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 cyanide mg/l 0.2 <0.01 <0.1 <0.1 <0.1 <0.1 <0.1 x x x x <0.005 x x x x x x x <0.1 x perchlorate mg/l - x x x x x x x x x x <0.001 x x x x x x x x x total phenolics 1 - mg/l <0.005 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 < < < < < < < < < <0.003 x Polychlorinated Biphenyls (PCBs) mg/l (^^) (^^) (^^) (^^) (^^) (^^) x x x x (^^) x x x x x x x (^^) x Volatile Organic Compounds 1,1,1,2-Tetrachloroethane mg/l 0.02 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x 1,1,1-Trichloroethane mg/l 0.06 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x 1,1,2,2-Tetrachloroethane mg/l 0.01 < <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x 1,1,2-Trichloroethane mg/l < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 x 1,1-Dichloroethane mg/l < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.005 x 1,1-Dichloroethylene (1,1-Dichloroethene; 1,1-DCE) mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloropropene mg/l - < <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.005 x x x x x x x <0.005 x 1,2 Dibromo-3-chloropropane (DBCP) mg/l <0.010 < < < < < x x x x < < < < < < < < < x 1,2,3-Trichlorobenzene mg/l - < x x x x x x x x x x x x x x x x x < x 1,2,3-Trichloropropane mg/l 0.01 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x 1,2,4-Trichlorobenzene mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 1,2-Dichlorobenzene (o-dichlorobenzene) mg/l 0.6 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x 1,2-Dichloroethane (EDC) mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2-Dichloropropane mg/l < < < < < < < < < < < < < < < < < < < x 1,3-Dichlorobenzene (m-dichlorobenzene) mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 <0.001 x x x x x x <0.01 x 1,3-Dichloropropane mg/l - < <0.005 <0.01 <0.01 <0.01 <0.01 x x x x <0.01 x x x x x x x <0.01 x 1,4-Dichlorobenzene (p-dichlorobenzene) mg/l < <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.015 x 2,2-Dichloropropane mg/l - < < <0.015 <0.015 <0.015 <0.015 x x x x <0.015 x x x x x x x <0.015 x 2-Butanone (Methyl Ethyl Ketone) (MEK) mg/l - <0.025 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x 2-Chlorotoluene mg/l - < x x x x x x x x x x x x x x x x x < x 2-Hexanone (Butyl Ketone) mg/l 0.02 <0.025 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.05 x 4-Chlorotoluene mg/l - < x x x x x x x x x x x x x x x x x < x 4-Methyl-2-pentanone mg/l - <0.025 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.015 x Acetone mg/l - <0.025 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.1 x Acetonitrile mg/l - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.2 <0.2 <0.2 <0.1 x x x x x x x <0.1 x Acrolein mg/l - <0.025 <0.1 <0.1 <0.1 <0.1 <0.1 x x x x <0.1 x x x x x x x <0.1 x Acrylonitrile mg/l - <0.025 <0.2 <0.2 <0.2 <0.2 <0.2 x x x x <0.2 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.2 x Allyl chloride mg/l - x <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.01 x x x x x x x <0.01 x Benzene mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 x Bis(chloromethyl) ether mg/l - x x x x x x x x x x (#) x x x x x x x x x Bromochloromethane mg/l - <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x Bromomethane (methyl bromide) mg/l - <0.001 <0.01 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.02 x Carbon Disulfide mg/l - <0.005 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.1 x Carbon Tetrachloride mg/l < <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 x Chlorobenzene mg/l 0.1 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x Chloroethane mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.01 x Chloromethane (methyl chloride) mg/l 0.02 < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroprene (2-Chloro-1,3-butadiene) mg/l - <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 x x x x x x x x x x x x <0.05 x cis-1,2-dichloroethylene (cis-1,2-dichloroethene) mg/l <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 < < <0.005 x cis-1,3-dichloropropene mg/l - < <0.001 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.02 x Dibromomethane (methylene bromide) mg/l - < <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.02 x Dichlorodifluoromethane mg/l x < Ethyl methacrylate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.01 x x x x x x x <0.01 x Ethylbenzene mg/l 0.75 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.005 x Ethylene Dibromide (1,2-Dibromoethane) (EDB) mg/l < < < < < < x x x x < < < E-06 < < < < < x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
96 APPEIX B Page 3 of 6 Las Cruces Foothills Landfill MW-7 Las Cruces Foothills Landfill monitoring well MW-7 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-7 average deviation date 7/15/03 8/27/03 9/29/03 10/27/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/19/12 6/26/13 12/19/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 Hexachlorobutadiene mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Isobutyl alcohol mg/l - <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.05 x x x x x x x <0.05 x Isopropylbenzene mg/l - < x x x x x x x x x x x x x x x x x < x Methacrylonitrile mg/l - <0.025 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.005 x x x x x x x <0.005 x Methyl Iodide (Iodomethane) mg/l - <0.005 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.04 x Methyl methacrylate mg/l - <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 x x x x <0.03 x x x x x x x <0.03 x Methylene Chloride mg/l < <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.001 x n-butylbenzene mg/l - < x x x x x x x x x x x x x x x x x < x Propionitrile mg/l - <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 x x x x <0.06 x x x x x x x <0.06 x Propylbenzene mg/l - < x x x x x x x x x x x x x x x x x < x sec-butylbenzene mg/l - < x x x x x x x x x x x x x x x x x < x Styrene mg/l 0.1 < <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x tert-butyl methyl ether (MTBE) (a) mg/l 0.1 <0.005 x x x x x x x x x <0.001 x x x x x x x <0.005 x tert-butylbenzene mg/l - < x x x x x x x x x x x x x x x x x < x Tetrachloroethene (PCE) mg/l Tetrahydrofuran (THF) mg/l - <0.01 x x x x x x x x x x x x x x x x x <0.01 x Toluene mg/l <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 < Total Xylenes (m&p and o) 1 NA mg/l 0.62 <0.001 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.002 < <0.002 <0.002 <0.002 <0.002 <0.005 x trans-1,2-dichloroethene mg/l 0.1 < <0.005 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.001 < <0.001 <0.001 <0.001 <0.001 <0.002 x trans-1,3-dichloropropene mg/l - <0.001 <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.01 x trans-1,4-dichloro-2-butene mg/l - <0.01 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.1 x Trichloroethene (TCE) mg/l Trichlorofluoromethane mg/l <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 < x Vinyl acetate mg/l - <0.025 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.05 x Vinyl chloride mg/l < < < < < < < < < < < < < < < < < x Trihalomethanes (THM) Bromodichloromethane mg/l - < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < < < < < < <0.005 x Bromoform mg/l 0.1 <0.001 <0.001 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.001 < < < < < < <0.015 x Chloroform mg/l 0.1 < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < < < < < < <0.005 x Dibromochloromethane mg/l - < <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 < < < < < < <0.005 x Semi Volatile Organic Compounds 1,2,4,5-Tetrachlorobenzene mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 1,2-Diphenylhydrazine mg/l - <0.005 x x x x x x x x x <0.001 x x x x x x x <0.005 x 1,4-Naphthoquinone mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 1-Chloronaphthalene NA mg/l - <0.005 x x x x x x x x x x x x x x x x x <0.005 x 1-Methylnaphthalene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 1-Naphthylamine mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 2,4,6-Trinitrotoluene (TNT) mg/l - x x x x x x x x x x < x x x x x x x x x 2,4-Dinitrotoluene (2,4-DNT) mg/l - <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 x x x x x x x <0.005 x 2,6-Dinitrotoluene 1 (2,6-DNT) mg/l - <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 x x x x x x x <0.005 x 2-Acetylaminofluorene mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x 2-Chloronaphthalene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 2-Methylnaphthalene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 2-Naphthylamine mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 2-Nitroaniline (o-nitroaniline) mg/l - <0.050 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 2-Picoline mg/l - <0.010 x x x x x x x x x <0.001 x x x x x x x <0.01 x 3,3'-Dichlorobenzidine mg/l - <0.050 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 3,3'-Dimethylbenzidine mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 3-Methylcholanthrene mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 3-Nitroaniline (m-nitroaniline) mg/l - <0.050 <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.001 x x x x x x x <0.05 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
97 APPEIX B Page 4 of 6 Las Cruces Foothills Landfill MW-7 Las Cruces Foothills Landfill monitoring well MW-7 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-7 average deviation date 7/15/03 8/27/03 9/29/03 10/27/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/19/12 6/26/13 12/19/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 4-Aminobiphenyl mg/l - <0.020 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x 4-Bromophenylphenyl ether mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 4-Chloroaniline (p-chloroanaline) mg/l - <0.020 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x 4-Chlorophenylphenyl ether mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 4-Nitroaniline (p-nitroaniline) mg/l - <0.050 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x 5-Nitro-o-toluidine mg/l - <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x 7,12-Dimethylbenz (a) anthracene mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Acenaphthene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Acenaphthylene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Acetophenone mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x alpha,alpha-dimethylphenethylamine mg/l - <0.010 x x x x x x x x x <0.001 x x x x x x x <0.01 x Aniline mg/l - <0.010 x x x x x x x x x <0.001 x x x x x x x <0.01 x Anthracene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Benzidine mg/l - <0.050 x x x x x x x x x <0.001 x x x x x x x <0.05 x Benzo (a) anthracene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x x <0.01 x Benzo (a) pyrene mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x < x x x x x x x <0.02 x Benzo (b) fluoranthene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Benzo (g,h,i) perylene mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x < x x x x x x x <0.02 x Benzo (k) fluoranthene mg/l <0.005 < < < < < x x x x < x x x x x x x < x Benzoic acid mg/l <0.050 x x x x x x x x x x x x x x x x x <0.05 x Benzyl alcohol mg/l - <0.020 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x bis (2-Chloroethoxy) methane mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x bis (2-Chloroethyl) ether mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x bis (2-Chloroisopropyl) ether (bis (2-chloro-1-methylethyl) ethe mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x bis (2-Ethylhexyl) phthalate mg/l <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x Butylbenzylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Carbazole mg/l - <0.005 x x x x x x x x x <0.001 x x x x x x x <0.005 x Chlorobenzilate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Chrysene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x x <0.01 x Diallate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Dibenz (a,j) acridine mg/l - <0.010 x x x x x x x x x x x x x x x x x <0.01 x Dibenzo (a,h) anthracene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x x <0.01 x Dibenzofuran mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Diethylene Glycol Monobutyl Ether mg/l - x x x x x x x x x x x x x x x x x x x x Diethylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Dimethylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Di-n-butylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Di-n-octylphthalate mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Diphenylamine mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Ethyl methanesulfonate mg/l - <0.020 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x Fluoranthene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Fluorene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Hexachlorobenzene mg/l - <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x x <0.001 x Hexachlorocyclopentadiene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Hexachloroethane mg/l - <0.005 <0.05 <0.05 <0.05 <0.05 <0.05 x x x x <0.001 x x x x x x x <0.05 x Hexachloropropene mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x HMX mg/l - x x x x x x x x x x < x x x x x x x x x Indeno (1,2,3-cd) pyrene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x x <0.01 x Isophorone mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Isosafrole mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
98 APPEIX B Page 5 of 6 Las Cruces Foothills Landfill MW-7 Las Cruces Foothills Landfill monitoring well MW-7 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-7 average deviation date 7/15/03 8/27/03 9/29/03 10/27/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/19/12 6/26/13 12/19/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 m-dinitrobenzene (1,3-DNB) mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x x x x x x x x x <0.02 x Methapyrilene mg/l - <0.1 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x Methyl methanesulfonate mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Naphthalene mg/l 0.03 <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Nitrobenzene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x n-nitrosodiethylamine mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x n-nitrosodimethylamine mg/l - <0.010 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.001 x x x x x x x <0.002 x n-nitrosodi-n-butylamine mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x n-nitrosodinpropylamine mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x n-nitrosodiphenylamine mg/l - <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 x x x x x x x <0.005 x n-nitrosomethylethylamine mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x n-nitrosopiperidine mg/l - <0.020 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x n-nitrosopyrrolidine mg/l - <0.02 <0.04 <0.04 <0.04 <0.04 <0.04 x x x x <0.001 x x x x x x x <0.04 x o-toluidine mg/l - <0.01 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x <0.001 x x x x x x x <0.002 x p-(dimethylamino) azobenzene mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Pentachlorobenzene mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Pentachloronitrobenzene mg/l - <0.020 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x Phenacetin mg/l - <0.020 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Phenanthrene mg/l - <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 x x x x <0.001 x x x x x x x <0.001 x p-phenylenediamine mg/l - <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Pronamide mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Pyrene mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Pyridine mg/l - <0.010 x x x x x x x x x <0.001 x x x x x x x <0.01 x RDX mg/l - x x x x x x x x x x < x x x x x x x x x Safrole mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x sym-trinitrobenzene 1 (1,3,5-TNB) mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x x x x x x x x x <0.01 x Semi Volatile Organic Compounds - Phenolics 2,3,4,6-Tetrachlorophenol mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x x <0.01 x 2,4,5-Trichlorophenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x x <0.01 x 2,4,6-Trichlorophenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x x <0.01 x 2,4-Dichlorophenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x x <0.01 x 2,4-Dimethylphenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x x <0.01 x 2,4-Dinitrophenol mg/l - <0.050 <0.05 <0.05 <0.05 <0.05 x x x x x <0.001 x x x x x x x <0.05 x 2,6-Dichlorophenol mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x x <0.01 x 2-Chlorophenol mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x x <0.01 x 2-Methylphenol (o-cresol) mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x x <0.01 x 2-Nitrophenol (o-nitrophenol) mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x x <0.01 x 3-Methylphenol/4-Methylphenol (m&p-cresol) / mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 x x x x x <0.001 x x x x x x x <0.02 x 4,6-Dinitro-2-methylphenol (4,6-Dinitro-o-cresol) mg/l - <0.050 <0.05 <0.05 <0.05 <0.05 x x x x x <0.001 x x x x x x x <0.05 x p-chloro-m-cresol (4-Chloro-3-methylphenol) mg/l - <0.020 <0.005 <0.005 <0.005 <0.005 <0.005 x x x x <0.001 x x x x x x x <0.005 x 4-Nitrophenol (p-nitrophenol) mg/l - <0.050 <0.05 <0.05 <0.05 <0.05 x x x x x <0.001 x x x x x x x <0.05 x Pentachlorophenol mg/l - <0.020 <0.02 <0.02 <0.02 <0.02 x x x x x <0.001 x x x x x x x <0.02 x Phenol 1 (a) mg/l <0.005 <0.01 <0.01 <0.01 <0.01 x x x x x <0.001 x x x x x x x <0.01 x Radium 226 and 228 NA pci/l Ra-226, total NA pci/l <2.5 <2.5 <2.5 <2.5 <2.5 x x x x 0.12 x x x x x x x <2.5 x Ra-228 1, total NA pci/l <2.5 <2.5 <2.5 <2.5 <2.5 x x x x 1.9 x x x x x x x <2.5 x Chlorinated Pesticides 4,4'-DDD (p,p'-ddd) mg/l - < <0.01 <0.0.1 <0.0.1 <0.0.1 <0.0.1 x x x x < x x x x x x x <0.0.1 x 4,4'-DDE (p,p'-dde) mg/l - < < < < < < x x x x < x x x x x x x < x 4,4'-DDT (p,p'-ddt) mg/l - < < < < < < x x x x < x x x x x x x < x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
99 APPEIX B Page 6 of 6 Las Cruces Foothills Landfill MW-7 Las Cruces Foothills Landfill monitoring well MW-7 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-7 average deviation date 7/15/03 8/27/03 9/29/03 10/27/03 11/25/03 12/29/03 12/2/04 12/14/05 12/12/06 1/18/08 12/23/08 12/29/09 12/29/10 12/28/11 6/19/12 12/19/12 6/26/13 12/19/13 7/15/03 to 7/15/03 to 12/2/04 12/2/04 aldrin mg/l - < < < < < < x x x x < x x x x x x x < x alpha-bhc mg/l - < < < < < < x x x x < x x x x x x x < x alpha-chlordane mg/l - < alpha + alpha + alpha + alpha + alpha + x x x x x x x x x x x x alpha + x beta-bhc mg/l - < see above see above see above see above see above x x x x x x x x x x x x see above x Chlordane mg/l x x x x x x x x x x x x x x x x x x x x delta-bhc mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x x <0.001 x Dieldrin mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x x <0.001 x Endosulfan I (alpha-endosulfan) mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x x <0.001 x Endosulfan II (beta-endosulfan) mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x x <0.001 x Endosulfan sulfate mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x x <0.001 x Endrin aldehyde mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x x <0.001 x Endrin ketone mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x x <0.001 x Endrin mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x x <0.001 x gamma-bhc mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x x <0.001 x gamma-chlordane mg/l - < x x x x x x x x x x x x x x x x x < x Heptachlor epoxide mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x x <0.001 x Heptachlor mg/l - < <0.001 <0.001 <0.001 <0.001 <0.001 x x x x < x x x x x x x <0.001 x Isodrin mg/l - <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x Kepone mg/l - <0.025 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x Methoxychlor mg/l - <0.001 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x x <0.01 x Toxaphene mg/l - <0.005 <0.001 <0.001 <0.001 <0.001 <0.001 x x x x <0.001 x x x x x x x <0.001 x Polychlorinated Biphenyls (PCBs) Arochlor mg/l - < < < < < < x x x x < x x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x x < x Arochlor mg/l - < < < < < < x x x x < x x x x x x x < x Other Pesticides and Herbicides 1 2,3,7,8-TCDD ng/l 0.03 x x x x x x x x x x < x x x x x x x x x 2,4,5-T mg/l - <0.001 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x < x x x x x x x <0.002 x 2,4-Dichlorophenoxyacetic acid (2,4-D) mg/l - <0.005 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x < x x x x x x x <0.01 x Dimethoate mg/l - < <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x Dinoseb mg/l - <0.005 <0.02 <0.02 <0.02 <0.02 <0.02 x x x x < x x x x x x x <0.02 x Disulfoton mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Famphur mg/l - < <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x Methyl parathion mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x o,o,o-triethyl phosphorothioate mg/l - <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Parathion (Ethyl) mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Phorate mg/l - < <0.01 <0.01 <0.01 <0.01 <0.01 x x x x <0.001 x x x x x x x <0.01 x Silvex 1 (2,4,5-TP) mg/l - <0.001 <0.002 <0.002 <0.002 <0.002 <0.002 x x x x < x x x x x x x <0.002 x o,o-diethyl o-2pyrazinyl phosphorothioate (Thionazin) mg/l - x <0.02 <0.02 <0.02 <0.02 <0.02 x x x x <0.001 x x x x x x x <0.02 x * baseline averages and standard deviations are based on 1999 and 2000 data only as per requirements in Environmental Protection, subpart 803. Ground Water Sampling and Analysis, hazardous x parameter not analyzed (^^) See section entitled 'Polychlorinated Biphenyls (PCBs)' for break-out of PCB concentrations. (#) Scanned for and not detected, breaks down almost immediately in water. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
100 JSAI MW-8 JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
101 APPEIX B Las Cruces Foothills Landfill MW-8 Page 1 of 4 Las Cruces Foothills Landfill monitoring well MW-8 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-8 average deviation date 12/29/10 5/18/11 8/23/11 11/28/11 12/29/11 12/20/12 6/26/13 12/29/10 to 12/29/10 to 12/29/11 12/29/11 Field Parameters water level elevation ft amsl , conductivity µs/cm ph ph units temperature deg F Major Ions calcium mg/l chloride mg/l fluoride mg/l x x magnesium mg/l potassium mg/l sodium mg/l sulfate mg/l alkalinity NA mg/l bicarbonate alkalinity mg/l carbonate alkalinity mg/l - <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 x total dissolved solids NA mg/l 1, Nitrogen Species ammonia as N mg/l - <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 x Kjeldahl nitrogen mg/l - <1.0 <1.0 <1.0 <1.0 <1.0 x x <1.0 x nitrate as N mg/l x x x x x x nitrite mg/l - x x x x x x x x x total nitrogen - mg/l - <1.0 <1.0 <1.0 <1.0 <1.0 x x <1.0 x Metals aluminum mg/l x x antimony mg/l <0.001 <0.001 <0.001 <0.001 <0.001 < x arsenic mg/l 0.01 < barium mg/l beryllium mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 <0.002 <0.001 x boron mg/l 0.75 <0.04 <0.04 <0.04 <0.04 <0.04 x x <0.04 x cadmium mg/l <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x chromium mg/l 0.05 < <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 x cobalt mg/l 0.05 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 x copper mg/l 1.0 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 x iron mg/l 1.0 < <0.05 <0.05 <0.05 < x lead mg/l 0.05 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.005 x manganese mg/l < < mercury mg/l < < < < < x x < x molybdenum mg/l <0.008 <0.008 <0.008 x x nickel mg/l 0.2 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x selenium mg/l 0.05 <0.001 <0.001 < <0.001 <0.001 < x silver mg/l 0.05 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 x thallium mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x tin mg/l - <0.01 x x x x x x <0.01 x uranium mg/l 0.03 <0.001 <0.001 <0.001 <0.001 <0.001 x x <0.001 x vanadium mg/l - <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 x zinc mg/l 10.0 <0.02 <0.02 <0.02 <0.02 <0.02 <0.01 <0.01 <0.02 x total organic carbon - mg/l phosphate mg/l - <0.5 <0.5 <0.5 <0.5 <0.5 x x <0.5 x sulfide mg/l - <0.1 x x x x x x <0.1 x cyanide mg/l 0.2 <0.01 <0.01 <0.01 <0.02 <0.01 x x <0.02 x perchlorate mg/l x x x x x x total phenolics 1 - mg/l < < < < < < < < x Polychlorinated Biphenyls (PCBs) mg/l < < < < < x x < x Volatile Organic Compounds 1,1,1,2-Tetrachloroethane mg/l 0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,1-Trichloroethane mg/l 0.06 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,2,2-Tetrachloroethane mg/l 0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,2-Trichloroethane mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloroethane mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloroethylene (1,1-Dichloroethene; 1,1-DCE) mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloropropene mg/l - <0.001 x x x x x x <0.001 x 1,2 Dibromo-3-chloropropane (DBCP) mg/l < < < < < < < < x 1,2,3-Trichlorobenzene mg/l - x x x x x x x x x 1,2,3-Trichloropropane mg/l 0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2,4-Trichlorobenzene mg/l - <0.01 x x x x x x <0.01 x 1,2-Dichlorobenzene (o-dichlorobenzene) mg/l 0.6 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2-Dichloroethane (EDC) mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2-Dichloropropane mg/l < < < < < < < < x 1,3-Dichlorobenzene (m-dichlorobenzene) mg/l - <0.001 x x x x x x <0.001 x 1,3-Dichloropropane mg/l - <0.001 x x x x x x <0.001 x 1,4-Dichlorobenzene (p-dichlorobenzene) mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 2,2-Dichloropropane mg/l - <0.001 x x x x x x <0.001 x 2-Butanone (Methyl Ethyl Ketone) (MEK) mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x 2-Chlorotoluene mg/l - x x x x x x x x x 2-Hexanone (Butyl Ketone) mg/l 0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
102 APPEIX B Las Cruces Foothills Landfill MW-8 Page 2 of 4 Las Cruces Foothills Landfill monitoring well MW-8 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-8 average deviation date 12/29/10 5/18/11 8/23/11 11/28/11 12/29/11 12/20/12 6/26/13 12/29/10 to 12/29/10 to 12/29/11 12/29/11 4-Chlorotoluene mg/l - x x x x x x x x x 4-Methyl-2-pentanone mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Acetone mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Acetonitrile mg/l - <0.1 x x x x x x <0.1 x Acrolein mg/l - <0.1 x x x x x x <0.1 x Acrylonitrile mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Allyl chloride mg/l - <0.01 x x x x x x <0.01 x Benzene mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Bis(chloromethyl) ether mg/l - (#) x x x x x x (#) x Bromochloromethane mg/l - <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x Bromomethane (methyl bromide) mg/l - <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x Carbon Disulfide mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Carbon Tetrachloride mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chlorobenzene mg/l 0.1 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroethane mg/l - <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x Chloromethane (methyl chloride) mg/l 0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroprene (2-Chloro-1,3-butadiene) mg/l - <0.05 x x x x x x <0.05 x cis-1,2-dichloroethylene (cis-1,2-dichloroethene) mg/l 0.07 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x cis-1,3-dichloropropene mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dibromomethane (methylene bromide) mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dichlorodifluoromethane mg/l - <0.001 <0.001 <0.001 <0.001 < <0.001 x Ethyl methacrylate mg/l - <0.01 x x x x x x <0.01 x Ethylbenzene mg/l 0.75 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Ethylene Dibromide (1,2-Dibromoethane) (EDB) mg/l < < < < < < < < x Hexachlorobutadiene mg/l - <0.01 x x x x x x <0.01 x Isobutyl alcohol mg/l - <0.05 x x x x x x <0.05 x Isopropylbenzene mg/l - x x x x x x x x x Methacrylonitrile mg/l - <0.005 x x x x x x <0.005 x Methyl Iodide (Iodomethane) mg/l - <0.01 x x x x x x <0.01 x Methyl methacrylate mg/l - <0.03 x x x x x x <0.03 x Methylene Chloride mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x n-butylbenzene mg/l - x x x x x x x x x Propionitrile mg/l - <0.06 x x x x x x <0.06 x Propylbenzene mg/l - x x x x x x x x x sec-butylbenzene mg/l - x x x x x x x x x Styrene mg/l 0.1 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x tert-butyl methyl ether (MTBE) (a) mg/l 0.1 <0.001 x x x x x x <0.001 x tert-butylbenzene mg/l - x x x x x x x x x Tetrachloroethene (PCE) mg/l < Tetrahydrofuran (THF) mg/l - x x x x x x x x x Toluene mg/l 0.75 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Total Xylenes (m&p and o) 1 NA mg/l 0.62 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x trans-1,2-dichloroethene mg/l 0.1 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x trans-1,3-dichloropropene mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x trans-1,4-dichloro-2-butene mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Trichloroethene (TCE) mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Trichlorofluoromethane mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Vinyl acetate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Vinyl chloride mg/l < < < < < < < < x Trihalomethanes (THM) Bromodichloromethane mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Bromoform mg/l 0.1 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroform mg/l 0.1 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dibromochloromethane mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Semi Volatile Organic Compounds 1,2,4,5-Tetrachlorobenzene mg/l - <0.01 x x x x x x <0.01 x 1,2-Diphenylhydrazine mg/l - <0.01 x x x x x x <0.01 x 1,4-Naphthoquinone mg/l - <0.01 x x x x x x <0.01 x 1-Chloronaphthalene NA mg/l - x x x x x x x x x 1-Methylnaphthalene mg/l - <0.01 <0.002 <0.002 <0.002 <0.002 x x <0.01 x 1-Naphthylamine mg/l - <0.01 x x x x x x <0.01 x 2,4,6-Trinitrotoluene (TNT) mg/l - < < < x x x x < x 2,4-Dinitrotoluene (2,4-DNT) mg/l - < < < x x x x < x 2,6-Dinitrotoluene 1 (2,6-DNT) mg/l - < < < x x x x < x 2-Acetylaminofluorene mg/l - <0.01 x x x x x x <0.01 x 2-Chloronaphthalene mg/l - <0.01 x x x x x x <0.01 x 2-Methylnaphthalene mg/l - <0.01 <0.002 <0.002 <0.002 <0.002 x x <0.01 x 2-Naphthylamine mg/l - <0.01 x x x x x x <0.01 x 2-Nitroaniline (o-nitroaniline) mg/l - <0.01 x x x x x x <0.01 x 2-Picoline mg/l - <0.01 x x x x x x <0.01 x 3,3'-Dichlorobenzidine mg/l - <0.01 x x x x x x <0.01 x 3,3'-Dimethylbenzidine mg/l - <0.01 x x x x x x <0.01 x 3-Methylcholanthrene mg/l - <0.01 x x x x x x <0.01 x 3-Nitroaniline (m-nitroaniline) mg/l - <0.01 x x x x x x <0.01 x 4-Aminobiphenyl mg/l - <0.01 x x x x x x <0.01 x 4-Bromophenylphenyl ether mg/l - <0.01 x x x x x x <0.01 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
103 APPEIX B Las Cruces Foothills Landfill MW-8 Page 3 of 4 Las Cruces Foothills Landfill monitoring well MW-8 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-8 average deviation date 12/29/10 5/18/11 8/23/11 11/28/11 12/29/11 12/20/12 6/26/13 12/29/10 to 12/29/10 to 12/29/11 12/29/11 4-Chloroaniline (p-chloroanaline) mg/l - <0.01 x x x x x x <0.01 x 4-Chlorophenylphenyl ether mg/l - <0.01 x x x x x x <0.01 x 4-Nitroaniline (p-nitroaniline) mg/l - <0.01 x x x x x x <0.01 x 5-Nitro-o-toluidine mg/l - <0.01 x x x x x x <0.01 x 7,12-Dimethylbenz (a) anthracene mg/l - <0.01 x x x x x x <0.01 x Acenaphthene mg/l - <0.01 x x x x x x <0.01 x Acenaphthylene mg/l - <0.01 x x x x x x <0.01 x Acetophenone mg/l x x x x x x x alpha,alpha-dimethylphenethylamine mg/l - <0.01 x x x x x x <0.01 x Aniline mg/l - <0.01 x x x x x x <0.01 x Anthracene mg/l - <0.01 x x x x x x <0.01 x Benzidine mg/l - <0.01 x x x x x x <0.01 x Benzo (a) anthracene mg/l - < x x x x x x < x Benzo (a) pyrene mg/l < < < < < x x < x Benzo (b) fluoranthene mg/l - < x x x x x x < x Benzo (g,h,i) perylene mg/l - <0.01 x x x x x x <0.01 x Benzo (k) fluoranthene mg/l - < x x x x x x < x Benzoic acid mg/l - x x x x x x x x x Benzyl alcohol mg/l - <0.01 x x x x x x <0.01 x bis (2-Chloroethoxy) methane mg/l - <0.01 x x x x x x <0.01 x bis (2-Chloroethyl) ether mg/l - <0.01 x x x x x x <0.01 x bis (2-Chloroisopropyl) ether (bis (2-chloro-1-methylethyl) ether) mg/l - <0.01 x x x x x x <0.01 x bis (2-Ethylhexyl) phthalate mg/l - <0.005 x x x x x x <0.005 x Butylbenzylphthalate mg/l - <0.01 x x x x x x <0.01 x Carbazole mg/l - <0.01 x x x x x x <0.01 x Chlorobenzilate mg/l - <0.01 x x x x x x <0.01 x Chrysene mg/l - < x x x x x x < x Diallate mg/l - <0.01 x x x x x x <0.01 x Dibenz (a,j) acridine mg/l - x x x x x x x x x Dibenzo (a,h) anthracene mg/l - < x x x x x x < x Dibenzofuran mg/l - <0.01 x x x x x x <0.01 x Diethylene Glycol Monobutyl Ether mg/l - x x x x x x x x x Diethylphthalate mg/l - <0.01 x x x x x x <0.01 x Dimethylphthalate mg/l - <0.01 x x x x x x <0.01 x Di-n-butylphthalate mg/l - <0.01 x x x x x x <0.01 x Di-n-octylphthalate mg/l - <0.01 x x x x x x <0.01 x Diphenylamine mg/l - <0.01 x x x x x x <0.01 x Ethyl methanesulfonate mg/l - <0.01 x x x x x x <0.01 x Fluoranthene mg/l - <0.01 x x x x x x <0.01 x Fluorene mg/l - <0.01 x x x x x x <0.01 x Hexachlorobenzene mg/l - <0.001 x x x x x x <0.001 x Hexachlorocyclopentadiene mg/l - <0.01 x x x x x x <0.01 x Hexachloroethane mg/l - <0.01 x x x x x x <0.01 x Hexachloropropene mg/l - <0.01 x x x x x x <0.01 x HMX mg/l < < x x x x < x Indeno (1,2,3-cd) pyrene mg/l - < x x x x x x < x Isophorone mg/l - <0.01 x x x x x x <0.01 x Isosafrole mg/l - <0.01 x x x x x x <0.01 x m-dinitrobenzene (1,3-DNB) mg/l - < < < x x x x < x Methapyrilene mg/l - <0.01 x x x x x x <0.01 x Methyl methanesulfonate mg/l - <0.01 x x x x x x <0.01 x Naphthalene mg/l 0.03 <0.01 <0.002 <0.002 <0.002 <0.002 x x <0.01 x Nitrobenzene mg/l - <0.01 < < x x x x <0.01 x n-nitrosodiethylamine mg/l - <0.01 x x x x x x <0.01 x n-nitrosodimethylamine mg/l - <0.01 x x x x x x <0.01 x n-nitrosodi-n-butylamine mg/l - <0.01 x x x x x x <0.01 x n-nitrosodinpropylamine mg/l - <0.01 x x x x x x <0.01 x n-nitrosodiphenylamine mg/l - <0.002 x x x x x x <0.002 x n-nitrosomethylethylamine mg/l - <0.002 x x x x x x <0.002 x n-nitrosopiperidine mg/l - <0.01 x x x x x x <0.01 x n-nitrosopyrrolidine mg/l - <0.01 x x x x x x <0.01 x o-toluidine mg/l - <0.002 x x x x x x <0.002 x p-(dimethylamino) azobenzene mg/l - <0.01 x x x x x x <0.01 x Pentachlorobenzene mg/l - <0.01 x x x x x x <0.01 x Pentachloronitrobenzene mg/l - <0.01 x x x x x x <0.01 x Phenacetin mg/l - <0.01 x x x x x x <0.01 x Phenanthrene mg/l - <0.01 x x x x x x <0.01 x p-phenylenediamine mg/l - <0.01 x x x x x x <0.01 x Pronamide mg/l - <0.01 x x x x x x <0.01 x Pyrene mg/l - <0.01 x x x x x x <0.01 x Pyridine mg/l - <0.01 x x x x x x <0.01 x RDX mg/l < < x x x x < x Safrole mg/l - <0.01 x x x x x x <0.01 x sym-trinitrobenzene 1 (1,3,5-TNB) mg/l - < < < x x x x < x Semi Volatile Organic Compounds - Phenolics 2,3,4,6-Tetrachlorophenol mg/l - <0.01 x x x x x x <0.01 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
104 APPEIX B Las Cruces Foothills Landfill MW-8 Page 4 of 4 Las Cruces Foothills Landfill monitoring well MW-8 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-8 average deviation date 12/29/10 5/18/11 8/23/11 11/28/11 12/29/11 12/20/12 6/26/13 12/29/10 to 12/29/10 to 12/29/11 12/29/11 2,4,5-Trichlorophenol mg/l - <0.01 x x x x x x <0.01 x 2,4,6-Trichlorophenol mg/l - <0.01 x x x x x x <0.01 x 2,4-Dichlorophenol mg/l - <0.01 x x x x x x <0.01 x 2,4-Dimethylphenol mg/l - <0.01 x x x x x x <0.01 x 2,4-Dinitrophenol mg/l - <0.01 x x x x x x <0.01 x 2,6-Dichlorophenol mg/l - <0.01 x x x x x x <0.01 x 2-Chlorophenol mg/l - <0.01 x x x x x x <0.01 x 2-Methylphenol (o-cresol) mg/l - <0.01 x x x x x x <0.01 x 2-Nitrophenol (o-nitrophenol) mg/l - <0.01 x x x x x x <0.01 x 3-Methylphenol/4-Methylphenol (m&p-cresol) / mg/l - <0.01 x x x x x x <0.01 x 4,6-Dinitro-2-methylphenol (4,6-Dinitro-o-cresol) mg/l - <0.01 x x x x x x <0.01 x p-chloro-m-cresol (4-Chloro-3-methylphenol) mg/l - <0.005 x x x x x x <0.005 x 4-Nitrophenol (p-nitrophenol) mg/l - <0.01 x x x x x x <0.01 x Pentachlorophenol mg/l - <0.01 x x x x x x <0.01 x Phenol 1 (a) mg/l <0.01 x x x x x x <0.01 x Radium 226 and 228 NA pci/l x x Ra-226, total NA pci/l x x Ra-228 1, total NA pci/l x x Chlorinated Pesticides 4,4'-DDD (p,p'-ddd) mg/l - <0.01 x x x x x x <0.01 x 4,4'-DDE (p,p'-dde) mg/l - < x x x x x x < x 4,4'-DDT (p,p'-ddt) mg/l - < x x x x x x < x aldrin mg/l - < x x x x x x < x alpha-bhc mg/l - < x x x x x x < x alpha-chlordane mg/l - x x x x x x x x x beta-bhc mg/l - < x x x x x x < x Chlordane mg/l <0.005 x x x x x x <0.005 x delta-bhc mg/l - < x x x x x x < x Dieldrin mg/l - <0.001 x x x x x x <0.001 x Endosulfan I (alpha-endosulfan) mg/l - <0.001 x x x x x x <0.001 x Endosulfan II (beta-endosulfan) mg/l - <0.001 x x x x x x <0.001 x Endosulfan sulfate mg/l - <0.001 x x x x x x <0.001 x Endrin aldehyde mg/l - <0.001 x x x x x x <0.001 x Endrin ketone mg/l - x x x x x x x x x Endrin mg/l - <0.001 x x x x x x <0.001 x gamma-bhc mg/l - < x x x x x x < x gamma-chlordane mg/l - x x x x x x x x x Heptachlor epoxide mg/l - <0.001 x x x x x x <0.001 x Heptachlor mg/l - <0.001 x x x x x x <0.001 x Isodrin mg/l - <0.01 x x x x x x <0.01 x Kepone mg/l - <0.01 x x x x x x <0.01 x Methoxychlor mg/l - <0.01 x x x x x x <0.01 x Toxaphene mg/l - <0.001 x x x x x x <0.001 x Polychlorinated Biphenyls (PCBs) 1 Arochlor mg/l - < < < < < x x < x Arochlor mg/l - < < < < < x x < x Arochlor mg/l - < < < < < x x < x Arochlor mg/l - < < < < < x x < x Arochlor mg/l - < < < < < x x < x Arochlor mg/l - < < < < < x x < x Arochlor mg/l - < < < < < x x < x Other Pesticides and Herbicides 1 2,3,7,8-TCDD ng/l 0.03 < x x x x x x < x 2,4,5-T mg/l - < x x x x x x < x 2,4-Dichlorophenoxyacetic acid (2,4-D) mg/l - < x x x x x x < x Dimethoate mg/l - <0.01 x x x x x x <0.01 x Dinoseb mg/l - < x x x x x x < x Disulfoton mg/l - <0.01 x x x x x x <0.01 x Famphur mg/l - <0.005 x x x x x x <0.005 x Methyl parathion mg/l - <0.01 x x x x x x <0.01 x o,o,o-triethyl phosphorothioate mg/l - <0.01 x x x x x x <0.01 x Parathion (Ethyl) mg/l - <0.01 x x x x x x <0.01 x Phorate mg/l - <0.01 x x x x x x <0.01 x Silvex 1 (2,4,5-TP) mg/l - < x x x x x x < x o,o-diethyl o-2pyrazinyl phosphorothioate (Thionazin) mg/l - <0.01 x x x x x x <0.01 x * baseline averages and standard deviations are based on 1999 and 2000 data only as per requirements in EPA, Subpart 803., Ground Water Sampling and Analysis, hazardous x parameter not analyzed (#) Scanned for and not detected, breaks down almost immediately in water. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
105 JSAI MW-9 JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
106 APPEIX B Las Cruces Foothills Landfill MW-9 Page 1 of 4 Las Cruces Foothills Landfill monitoring well MW-9 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-9 average deviation date 12/29/10 5/18/11 8/23/11 11/28/11 12/29/11 12/20/12 6/26/13 12/29/10 to 12/29/10 to 12/29/11 12/29/11 Field Parameters water level elevation ft amsl , conductivity µs/cm , ph ph units temperature deg F Major Ions calcium mg/l chloride mg/l fluoride mg/l x x magnesium mg/l potassium mg/l sodium mg/l sulfate mg/l alkalinity NA mg/l bicarbonate alkalinity mg/l carbonate alkalinity mg/l - <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 x total dissolved solids NA mg/l 1, , Nitrogen Species ammonia as N mg/l - <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 x Kjeldahl nitrogen mg/l - <1.0 <1.0 <1.0 <1.0 <1.0 x x <1.0 x nitrate as N mg/l x x x x <0.1 <0.1 x x nitrite mg/l - x x x x x x x x x total nitrogen - mg/l - <1.0 <1.0 <1.0 <1.0 <1.0 x x <1.0 x Metals aluminum mg/l 5.0 <0.02 <0.02 < <0.02 x x x antimony mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x arsenic mg/l 0.01 <0.001 <0.001 <0.001 <0.001 <0.001 < <0.001 x barium mg/l beryllium mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.002 <0.002 <0.001 x boron mg/l x x cadmium mg/l <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x chromium mg/l 0.05 <0.006 <0.006 < <0.006 <0.006 <0.006 <0.006 x cobalt mg/l 0.05 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 x copper mg/l 1.0 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 x iron mg/l lead mg/l 0.05 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.001 <0.005 x manganese mg/l mercury mg/l < < < < < x x < x molybdenum mg/l <0.008 <0.008 x x nickel mg/l selenium mg/l 0.05 <0.001 <0.001 < <0.001 < x silver mg/l 0.05 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.025 <0.005 x thallium mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x tin mg/l - <0.01 x x x x x x <0.01 x uranium mg/l x x vanadium mg/l - <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 x zinc mg/l 10.0 <0.02 <0.02 < total organic carbon - mg/l < <1.0 <1.0 <1.0 < phosphate mg/l - <0.5 <0.5 <0.5 <0.5 <0.5 x x <0.5 x sulfide mg/l - <0.1 x x x x x x <0.1 x cyanide mg/l 0.2 <0.01 <0.01 <0.01 <0.02 <0.01 x x <0.02 x perchlorate mg/l - < < x x x x x < x total phenolics 1 - mg/l < < < < < < < < x Polychlorinated Biphenyls (PCBs) mg/l < < < < < x x < x Volatile Organic Compounds 1,1,1,2-Tetrachloroethane mg/l 0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,1-Trichloroethane mg/l 0.06 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,2,2-Tetrachloroethane mg/l 0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1,2-Trichloroethane mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloroethane mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloroethylene (1,1-Dichloroethene; 1,1-DCE) mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,1-Dichloropropene mg/l - <0.001 x x x x x x <0.001 x 1,2 Dibromo-3-chloropropane (DBCP) mg/l < < < < < < < < x 1,2,3-Trichlorobenzene mg/l - x x x x x x x x x 1,2,3-Trichloropropane mg/l 0.01 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2,4-Trichlorobenzene mg/l - <0.01 x x x x x x <0.01 x 1,2-Dichlorobenzene (o-dichlorobenzene) mg/l 0.6 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2-Dichloroethane (EDC) mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 1,2-Dichloropropane mg/l < < < < < < < < x 1,3-Dichlorobenzene (m-dichlorobenzene) mg/l - <0.001 x x x x x x <0.001 x 1,3-Dichloropropane mg/l - <0.001 x x x x x x <0.001 x 1,4-Dichlorobenzene (p-dichlorobenzene) mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x 2,2-Dichloropropane mg/l - <0.001 x x x x x x <0.001 x 2-Butanone (Methyl Ethyl Ketone) (MEK) mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x 2-Chlorotoluene mg/l - x x x x x x x x x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
107 APPEIX B Las Cruces Foothills Landfill MW-9 Page 2 of 4 Las Cruces Foothills Landfill monitoring well MW-9 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-9 average deviation date 12/29/10 5/18/11 8/23/11 11/28/11 12/29/11 12/20/12 6/26/13 12/29/10 to 12/29/10 to 12/29/11 12/29/11 2-Hexanone (Butyl Ketone) mg/l 0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x 4-Chlorotoluene mg/l - x x x x x x x x x 4-Methyl-2-pentanone mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Acetone mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Acetonitrile mg/l - <0.1 x x x x x x <0.1 x Acrolein mg/l - <0.1 x x x x x x <0.1 x Acrylonitrile mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Allyl chloride mg/l - <0.01 x x x x x x <0.01 x Benzene mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Bis(chloromethyl) ether mg/l - (#) x x x x x x (#) x Bromochloromethane mg/l - <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x Bromomethane (methyl bromide) mg/l - <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x Carbon Disulfide mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Carbon Tetrachloride mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chlorobenzene mg/l 0.1 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroethane mg/l - <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x Chloromethane (methyl chloride) mg/l 0.02 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroprene (2-Chloro-1,3-butadiene) mg/l - <0.05 x x x x x x <0.05 x cis-1,2-dichloroethylene (cis-1,2-dichloroethene) mg/l 0.07 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x cis-1,3-dichloropropene mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dibromomethane (methylene bromide) mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dichlorodifluoromethane mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Ethyl methacrylate mg/l - <0.01 x x x x x x <0.01 x Ethylbenzene mg/l 0.75 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Ethylene Dibromide (1,2-Dibromoethane) (EDB) mg/l < < < < < < < < x Hexachlorobutadiene mg/l - <0.01 x x x x x x <0.01 x Isobutyl alcohol mg/l - <0.05 x x x x x x <0.05 x Isopropylbenzene mg/l - x x x x x x x x x Methacrylonitrile mg/l - <0.005 x x x x x x <0.005 x Methyl Iodide (Iodomethane) mg/l - <0.01 x x x x x x <0.01 x Methyl methacrylate mg/l - <0.03 x x x x x x <0.03 x Methylene Chloride mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x n-butylbenzene mg/l - x x x x x x x x x Propionitrile mg/l - <0.06 x x x x x x <0.06 x Propylbenzene mg/l - x x x x x x x x x sec-butylbenzene mg/l - x x x x x x x x x Styrene mg/l 0.1 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x tert-butyl methyl ether (MTBE) (a) mg/l 0.1 <0.001 x x x x x x <0.001 x tert-butylbenzene mg/l - x x x x x x x x x Tetrachloroethene (PCE) mg/l < < < < < < < < x Tetrahydrofuran (THF) mg/l - x x x x x x x x x Toluene mg/l 0.75 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Total Xylenes (m&p and o) 1 NA mg/l 0.62 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 x trans-1,2-dichloroethene mg/l 0.1 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x trans-1,3-dichloropropene mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x trans-1,4-dichloro-2-butene mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Trichloroethene (TCE) mg/l <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Trichlorofluoromethane mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Vinyl acetate mg/l - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 x Vinyl chloride mg/l < < < < < < < < x Trihalomethanes (THM) Bromodichloromethane mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Bromoform mg/l 0.1 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Chloroform mg/l 0.1 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Dibromochloromethane mg/l - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 x Semi Volatile Organic Compounds 1,2,4,5-Tetrachlorobenzene mg/l - <0.01 x x x x x x <0.01 x 1,2-Diphenylhydrazine mg/l - <0.01 x x x x x x <0.01 x 1,4-Naphthoquinone mg/l - <0.01 x x x x x x <0.01 x 1-Chloronaphthalene NA mg/l - x x x x x x x x x 1-Methylnaphthalene mg/l - <0.01 <0.002 <0.002 <0.002 <0.002 x x <0.01 x 1-Naphthylamine mg/l - <0.01 x x x x x x <0.01 x 2,4,6-Trinitrotoluene (TNT) mg/l - < < < x x x x < x 2,4-Dinitrotoluene (2,4-DNT) mg/l - < < < x x x x < x 2,6-Dinitrotoluene 1 (2,6-DNT) mg/l - < < < x x x x < x 2-Acetylaminofluorene mg/l - <0.01 x x x x x x <0.01 x 2-Chloronaphthalene mg/l - <0.01 x x x x x x <0.01 x 2-Methylnaphthalene mg/l - <0.01 <0.002 <0.002 <0.002 <0.002 x x <0.01 x 2-Naphthylamine mg/l - <0.01 x x x x x x <0.01 x 2-Nitroaniline (o-nitroaniline) mg/l - <0.01 x x x x x x <0.01 x 2-Picoline mg/l - <0.01 x x x x x x <0.01 x 3,3'-Dichlorobenzidine mg/l - <0.01 x x x x x x <0.01 x 3,3'-Dimethylbenzidine mg/l - <0.01 x x x x x x <0.01 x 3-Methylcholanthrene mg/l - <0.01 x x x x x x <0.01 x 3-Nitroaniline (m-nitroaniline) mg/l - <0.01 x x x x x x <0.01 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
108 APPEIX B Las Cruces Foothills Landfill MW-9 Page 3 of 4 Las Cruces Foothills Landfill monitoring well MW-9 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-9 average deviation date 12/29/10 5/18/11 8/23/11 11/28/11 12/29/11 12/20/12 6/26/13 12/29/10 to 12/29/10 to 12/29/11 12/29/11 4-Aminobiphenyl mg/l - <0.01 x x x x x x <0.01 x 4-Bromophenylphenyl ether mg/l - <0.01 x x x x x x <0.01 x 4-Chloroaniline (p-chloroanaline) mg/l - <0.01 x x x x x x <0.01 x 4-Chlorophenylphenyl ether mg/l - <0.01 x x x x x x <0.01 x 4-Nitroaniline (p-nitroaniline) mg/l - <0.01 x x x x x x <0.01 x 5-Nitro-o-toluidine mg/l - <0.01 x x x x x x <0.01 x 7,12-Dimethylbenz (a) anthracene mg/l - <0.01 x x x x x x <0.01 x Acenaphthene mg/l - <0.01 x x x x x x <0.01 x Acenaphthylene mg/l - <0.01 x x x x x x <0.01 x Acetophenone mg/l - <0.01 x x x x x x <0.01 x alpha,alpha-dimethylphenethylamine mg/l - <0.01 x x x x x x <0.01 x Aniline mg/l - <0.01 x x x x x x <0.01 x Anthracene mg/l - <0.01 x x x x x x <0.01 x Benzidine mg/l - <0.01 x x x x x x <0.01 x Benzo (a) anthracene mg/l - < x x x x x x < x Benzo (a) pyrene mg/l < < < < < x x < x Benzo (b) fluoranthene mg/l - < x x x x x x < x Benzo (g,h,i) perylene mg/l - <0.01 x x x x x x <0.01 x Benzo (k) fluoranthene mg/l - < x x x x x x < x Benzoic acid mg/l - x x x x x x x x x Benzyl alcohol mg/l - <0.01 x x x x x x <0.01 x bis (2-Chloroethoxy) methane mg/l - <0.01 x x x x x x <0.01 x bis (2-Chloroethyl) ether mg/l - <0.01 x x x x x x <0.01 x bis (2-Chloroisopropyl) ether (bis (2-chloro-1-methylethyl) ether) mg/l - <0.01 x x x x x x <0.01 x bis (2-Ethylhexyl) phthalate mg/l - <0.005 x x x x x x <0.005 x Butylbenzylphthalate mg/l - <0.01 x x x x x x <0.01 x Carbazole mg/l - <0.01 x x x x x x <0.01 x Chlorobenzilate mg/l - <0.01 x x x x x x <0.01 x Chrysene mg/l - < x x x x x x < x Diallate mg/l - <0.01 x x x x x x <0.01 x Dibenz (a,j) acridine mg/l - x x x x x x x x x Dibenzo (a,h) anthracene mg/l - < x x x x x x < x Dibenzofuran mg/l - <0.01 x x x x x x <0.01 x Diethylene Glycol Monobutyl Ether mg/l - x x x x x x x x x Diethylphthalate mg/l - <0.01 x x x x x x <0.01 x Dimethylphthalate mg/l - <0.01 x x x x x x <0.01 x Di-n-butylphthalate mg/l - <0.01 x x x x x x <0.01 x Di-n-octylphthalate mg/l - <0.01 x x x x x x <0.01 x Diphenylamine mg/l - <0.01 x x x x x x <0.01 x Ethyl methanesulfonate mg/l - <0.01 x x x x x x <0.01 x Fluoranthene mg/l - <0.01 x x x x x x <0.01 x Fluorene mg/l - <0.01 x x x x x x <0.01 x Hexachlorobenzene mg/l - <0.001 x x x x x x <0.001 x Hexachlorocyclopentadiene mg/l - <0.01 x x x x x x <0.01 x Hexachloroethane mg/l - <0.01 x x x x x x <0.01 x Hexachloropropene mg/l - <0.01 x x x x x x <0.01 x HMX mg/l < < x x x x < x Indeno (1,2,3-cd) pyrene mg/l - < x x x x x x < x Isophorone mg/l - <0.01 x x x x x x <0.01 x Isosafrole mg/l - <0.01 x x x x x x <0.01 x m-dinitrobenzene (1,3-DNB) mg/l - < < < x x x x < x Methapyrilene mg/l - <0.01 x x x x x x <0.01 x Methyl methanesulfonate mg/l - <0.01 x x x x x x <0.01 x Naphthalene mg/l 0.03 <0.01 <0.002 <0.002 <0.002 <0.002 x x <0.01 x Nitrobenzene mg/l - <0.01 < < x x x x <0.01 x n-nitrosodiethylamine mg/l - <0.01 x x x x x x <0.01 x n-nitrosodimethylamine mg/l - <0.01 x x x x x x <0.01 x n-nitrosodi-n-butylamine mg/l - <0.01 x x x x x x <0.01 x n-nitrosodinpropylamine mg/l - <0.010 x x x x x x <0.01 x n-nitrosodiphenylamine mg/l - <0.002 x x x x x x <0.002 x n-nitrosomethylethylamine mg/l - <0.002 x x x x x x <0.002 x n-nitrosopiperidine mg/l - <0.01 x x x x x x <0.01 x n-nitrosopyrrolidine mg/l - <0.01 x x x x x x <0.01 x o-toluidine mg/l - <0.002 x x x x x x <0.002 x p-(dimethylamino) azobenzene mg/l - <0.01 x x x x x x <0.01 x Pentachlorobenzene mg/l - <0.01 x x x x x x <0.01 x Pentachloronitrobenzene mg/l - <0.01 x x x x x x <0.01 x Phenacetin mg/l - <0.01 x x x x x x <0.01 x Phenanthrene mg/l - <0.01 x x x x x x <0.01 x p-phenylenediamine mg/l - <0.01 x x x x x x <0.01 x Pronamide mg/l - <0.01 x x x x x x <0.01 x Pyrene mg/l - <0.01 x x x x x x <0.01 x Pyridine mg/l - <0.01 x x x x x x <0.01 x RDX mg/l < < x x x x < x Safrole mg/l - <0.01 x x x x x x <0.01 x JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
109 APPEIX B Las Cruces Foothills Landfill MW-9 Page 4 of 4 Las Cruces Foothills Landfill monitoring well MW-9 baseline standard constituent CAS Number unit GWPS RESULTS FOR MW-9 average deviation date 12/29/10 5/18/11 8/23/11 11/28/11 12/29/11 12/20/12 6/26/13 12/29/10 to 12/29/10 to 12/29/11 12/29/11 sym-trinitrobenzene 1 (1,3,5-TNB) mg/l - < < < x x x x < x Semi Volatile Organic Compounds - Phenolics 2,3,4,6-Tetrachlorophenol mg/l - <0.01 x x x x x x <0.01 x 2,4,5-Trichlorophenol mg/l - <0.01 x x x x x x <0.01 x 2,4,6-Trichlorophenol mg/l - <0.01 x x x x x x <0.01 x 2,4-Dichlorophenol mg/l - <0.01 x x x x x x <0.01 x 2,4-Dimethylphenol mg/l - <0.01 x x x x x x <0.01 x 2,4-Dinitrophenol mg/l - <0.01 x x x x x x <0.01 x 2,6-Dichlorophenol mg/l - <0.01 x x x x x x <0.01 x 2-Chlorophenol mg/l - <0.01 x x x x x x <0.01 x 2-Methylphenol (o-cresol) mg/l - <0.01 x x x x x x <0.01 x 2-Nitrophenol (o-nitrophenol) mg/l - <0.01 x x x x x x <0.01 x 3-Methylphenol/4-Methylphenol (m&p-cresol) / mg/l - <0.01 x x x x x x <0.01 x 4,6-Dinitro-2-methylphenol (4,6-Dinitro-o-cresol) mg/l - <0.01 x x x x x x <0.01 x p-chloro-m-cresol (4-Chloro-3-methylphenol) mg/l - <0.005 x x x x x x <0.005 x 4-Nitrophenol (p-nitrophenol) mg/l - <0.01 x x x x x x <0.01 x Pentachlorophenol mg/l - <0.01 x x x x x x <0.01 x Phenol 1 (a) mg/l <0.01 x x x x x x <0.01 x Radium 226 and 228 NA pci/l x x Ra-226, total NA pci/l x x Ra-228 1, total NA pci/l x x Chlorinated Pesticides 4,4'-DDD (p,p'-ddd) mg/l - <0.001 x x x x x x <0.01 x 4,4'-DDE (p,p'-dde) mg/l - <0.001 x x x x x x < x 4,4'-DDT (p,p'-ddt) mg/l - <0.001 x x x x x x < x aldrin mg/l - <0.01 x x x x x x < x alpha-bhc mg/l - < x x x x x x < x alpha-chlordane mg/l - x x x x x x x x x beta-bhc mg/l - < x x x x x x < x Chlordane mg/l <0.005 x x x x x x <0.005 x delta-bhc mg/l - < x x x x x x < x Dieldrin mg/l - <0.001 x x x x x x <0.001 x Endosulfan I (alpha-endosulfan) mg/l - <0.001 x x x x x x <0.001 x Endosulfan II (beta-endosulfan) mg/l - <0.001 x x x x x x <0.001 x Endosulfan sulfate mg/l - <0.001 x x x x x x <0.001 x Endrin aldehyde mg/l - <0.001 x x x x x x <0.001 x Endrin ketone mg/l - x x x x x x x x x Endrin mg/l - <0.001 x x x x x x <0.001 x gamma-bhc mg/l - < x x x x x x < x gamma-chlordane mg/l - x x x x x x x x x Heptachlor epoxide mg/l - <0.001 x x x x x x <0.001 x Heptachlor mg/l - <0.001 x x x x x x <0.001 x Isodrin mg/l - <0.01 x x x x x x <0.01 x Kepone mg/l - <0.01 x x x x x x <0.01 x Methoxychlor mg/l - <0.01 x x x x x x <0.01 x Toxaphene mg/l - <0.001 x x x x x x <0.001 x Polychlorinated Biphenyls (PCBs) 1 Arochlor mg/l - < < < < < x x < x Arochlor mg/l - < < < < < x x < x Arochlor mg/l - < < < < < x x < x Arochlor mg/l - < < < < < x x < x Arochlor mg/l - < < < < < x x < x Arochlor mg/l - < < < < < x x < x Arochlor mg/l - < < < < < x x < x Other Pesticides and Herbicides 1 2,3,7,8-TCDD ng/l 0.03 < x x x x x x < x 2,4,5-T mg/l - < x x x x x x < x 2,4-Dichlorophenoxyacetic acid (2,4-D) mg/l - < x x x x x x < x Dimethoate mg/l - <0.01 x x x x x x <0.01 x Dinoseb mg/l - < x x x x x x < x Disulfoton mg/l - <0.01 x x x x x x <0.01 x Famphur mg/l - <0.005 x x x x x x <0.005 x Methyl parathion mg/l - <0.01 x x x x x x <0.01 x o,o,o-triethyl phosphorothioate mg/l - <0.01 x x x x x x <0.01 x Parathion (Ethyl) mg/l - <0.01 x x x x x x <0.01 x Phorate mg/l - <0.01 x x x x x x <0.01 x Silvex 1 (2,4,5-TP) mg/l - < x x x x x x < x o,o-diethyl o-2pyrazinyl phosphorothioate (Thionazin) mg/l - <0.01 x x x x x x <0.01 x * baseline averages and standard deviations are based on 1999 and 2000 data only as per requirements in EPA, Subpart 803., Ground Water Sampling and Analysis, hazardous x parameter not analyzed (#) Scanned for and not detected, breaks down almost immediately in water. JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
110 JSAI Appendix C. Copies of laboratory reports for the June 25 and 26, 2013, and December 19, 2013, sampling events JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
111 JSAI Laboratory Results Sample Date (Lab Report Date ) JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
112 Hall Environmental Analysis Laboratory 4901 Hawkins NE Albuquerque, NM TEL: FAX: Website: July 24, 2013 Joshua Rosenblatt City of Las Cruces PO Box Las Cruces, NM TEL: (575) FAX (575) RE: City of Las Cruces Foothills Landfill Monitoring Wells OrderNo.: 1306B08 Dear Joshua Rosenblatt: Hall Environmental Analysis Laboratory received 4 sample(s) on 6/26/2013 for the analyses presented in the following report. This report is a revised report and it replaces the original report issued July 15, These were analyzed according to EPA procedures or equivalent. To access our accredited tests please go to or the state specific web sites. See the sample checklist and/or the Chain of Custody for information regarding the sample receipt temperature and preservation. Data qualifiers or a narrative will be provided if the sample analysis or analytical quality control parameters require a flag. All samples are reported as received unless otherwise indicated. Please don't hesitate to contact HEAL for any additional information or clarifications. Sincerely, Andy Freeman Laboratory Manager 4901 Hawkins NE Albuquerque, NM 87109
113 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B08 Date Reported: 7/24/2013 Client Sample ID: MW-1 Collection Date: 6/25/ :17:00 AM Received Date: 6/26/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 µg/l 1 7/1/ :46:13 AM ,2-Dibromoethane µg/l 1 7/1/ :46:13 AM 8176 EPA METHOD 300.0: ANIONS Analyst: JRR Chloride mg/l 20 6/26/ :20:19 PM R11606 Nitrogen, Nitrate (As N) 0.10 mg/l 1 6/26/ :43:06 PM R11606 Sulfate mg/l 1 6/26/ :43:06 PM R11606 EPA METHOD 200.7: METALS Analyst: JLF Barium mg/l 1 7/9/ :44:52 PM R11805 Beryllium mg/l 1 7/9/ :44:52 PM R11805 Cadmium mg/l 1 7/9/ :44:52 PM R11805 Calcium mg/l 1 7/9/ :44:52 PM R11805 Chromium mg/l 1 7/9/ :44:52 PM R11805 Cobalt mg/l 1 7/9/ :44:52 PM R11805 Copper mg/l 1 7/9/ :44:52 PM R11805 Iron mg/l 1 7/9/ :44:52 PM R11805 Magnesium mg/l 1 7/9/ :44:52 PM R11805 Manganese mg/l 1 7/9/ :44:52 PM R11805 Nickel mg/l 1 7/9/ :44:52 PM R11805 Potassium mg/l 1 7/9/ :44:52 PM R11805 Silver mg/l 1 7/9/ :44:52 PM R11805 Sodium mg/l 1 7/9/ :44:52 PM R11805 Vanadium mg/l 1 7/9/ :44:52 PM R11805 Zinc mg/l 1 7/9/ :44:52 PM R11805 EPA 200.8: METALS Analyst: DBD Antimony mg/l 1 7/10/ :29:55 PM R11836 Arsenic mg/l 1 7/5/ :20:10 AM R11758 Lead mg/l 1 7/5/ :20:10 AM R11758 Selenium mg/l 1 7/5/ :20:10 AM R11758 Thallium mg/l 1 7/5/ :20:10 AM R11758 EPA METHOD 8260B: VOLATILES, TABLE I Analyst: CWS 1,2-Dibromo-3-chloropropane 2.0 µg/l 1 6/28/2013 3:10:19 PM R ,2-Dibromoethane (EDB) 1.0 µg/l 1 6/28/2013 3:10:19 PM R11660 Methyl tert-butyl ether (MTBE) 1.0 µg/l 1 6/28/2013 3:10:19 PM R11660 Acetone 10 µg/l 1 6/28/2013 3:10:19 PM R11660 Acrylonitrile 10 µg/l 1 6/28/2013 3:10:19 PM R11660 Benzene 1.0 µg/l 1 6/28/2013 3:10:19 PM R11660 Bromochloromethane 2.0 µg/l 1 6/28/2013 3:10:19 PM R11660 Bromodichloromethane 1.0 µg/l 1 6/28/2013 3:10:19 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 1 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
114 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B08 Date Reported: 7/24/2013 Client Sample ID: MW-1 Collection Date: 6/25/ :17:00 AM Received Date: 6/26/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichloroethane (EDC) 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane Ethylbenzene 2-Hexanone Iodomethane 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) Toluene trans-1,2-dce trans-1,3-dichloropropene trans-1,4-dichloro-2-butene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Analyst: CWS 1.0 µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R µg/l 1 6/28/2013 3:10:19 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 2 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
115 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B08 Date Reported: 7/24/2013 Client Sample ID: MW-1 Collection Date: 6/25/ :17:00 AM Received Date: 6/26/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Xylenes, Total Surr: 1,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d8 TOTAL PHENOLICS BY SW µg/l 1 6/28/2013 3:10:19 PM Analyst: CWS R %REC 1 6/28/2013 3:10:19 PM R %REC 1 6/28/2013 3:10:19 PM R %REC 1 6/28/2013 3:10:19 PM R %REC 1 6/28/2013 3:10:19 PM R11660 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 7/9/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH Analyst: LRW mg/l 1 7/8/2013 4:45:13 PM R11792 Analyst: JML µmhos/cm 1 6/26/2013 7:51:33 PM R mg/l 1 Analyst: TMG 6/27/ :30:00 PM R11604 Analyst: JML ph H ph units 1 6/26/2013 7:51:33 PM R11593 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: JML mg/l CaCO3 1 6/26/2013 7:51:33 PM R mg/l CaCO3 1 6/26/2013 7:51:33 PM R mg/l CaCO3 1 6/26/2013 7:51:33 PM R11593 Analyst: KS mg/l 1 6/30/2013 4:41:00 PM 8151 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 3 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
116 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B08 Date Reported: 7/24/2013 Client Sample ID: MW-2 Collection Date: 6/25/ :20:00 AM Received Date: 6/26/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 µg/l 1 7/1/ :00:01 PM ,2-Dibromoethane µg/l 1 7/1/ :00:01 PM 8176 EPA METHOD 300.0: ANIONS Analyst: JRR Chloride mg/l 1 6/26/ :32:44 PM R11606 Nitrogen, Nitrate (As N) mg/l 1 6/26/ :32:44 PM R11606 Sulfate mg/l 1 6/26/ :32:44 PM R11606 EPA METHOD 200.7: METALS Analyst: JLF Barium mg/l 1 7/9/2013 1:06:00 PM R11805 Beryllium mg/l 1 7/9/2013 1:06:00 PM R11805 Cadmium mg/l 1 7/9/2013 1:06:00 PM R11805 Calcium mg/l 1 7/9/2013 1:06:00 PM R11805 Chromium mg/l 1 7/9/2013 1:06:00 PM R11805 Cobalt mg/l 1 7/9/2013 1:06:00 PM R11805 Copper mg/l 1 7/9/2013 1:06:00 PM R11805 Iron mg/l 1 7/9/2013 1:06:00 PM R11805 Magnesium mg/l 1 7/9/2013 1:06:00 PM R11805 Manganese mg/l 1 7/9/2013 1:06:00 PM R11805 Nickel mg/l 1 7/9/2013 1:06:00 PM R11805 Potassium mg/l 1 7/9/2013 1:06:00 PM R11805 Silver mg/l 1 7/9/2013 1:06:00 PM R11805 Sodium mg/l 1 7/9/2013 1:06:00 PM R11805 Vanadium mg/l 1 7/9/2013 1:06:00 PM R11805 Zinc mg/l 1 7/9/2013 1:06:00 PM R11805 EPA 200.8: METALS Analyst: DBD Antimony mg/l 1 7/10/ :34:13 PM R11836 Arsenic mg/l 1 7/5/ :24:29 AM R11758 Lead mg/l 1 7/5/ :24:29 AM R11758 Selenium mg/l 1 7/5/ :24:29 AM R11758 Thallium mg/l 1 7/5/ :24:29 AM R11758 EPA METHOD 8260B: VOLATILES, TABLE I Analyst: CWS 1,2-Dibromo-3-chloropropane 2.0 µg/l 1 6/28/2013 4:37:17 PM R ,2-Dibromoethane (EDB) 1.0 µg/l 1 6/28/2013 4:37:17 PM R11660 Methyl tert-butyl ether (MTBE) 1.0 µg/l 1 6/28/2013 4:37:17 PM R11660 Acetone 10 µg/l 1 6/28/2013 4:37:17 PM R11660 Acrylonitrile 10 µg/l 1 6/28/2013 4:37:17 PM R11660 Benzene 1.0 µg/l 1 6/28/2013 4:37:17 PM R11660 Bromochloromethane 2.0 µg/l 1 6/28/2013 4:37:17 PM R11660 Bromodichloromethane 1.0 µg/l 1 6/28/2013 4:37:17 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 4 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
117 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B08 Date Reported: 7/24/2013 Client Sample ID: MW-2 Collection Date: 6/25/ :20:00 AM Received Date: 6/26/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichloroethane (EDC) 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane Ethylbenzene 2-Hexanone Iodomethane 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) Toluene trans-1,2-dce trans-1,3-dichloropropene trans-1,4-dichloro-2-butene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Analyst: CWS 1.0 µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R µg/l 1 6/28/2013 4:37:17 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 5 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
118 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B08 Date Reported: 7/24/2013 Client Sample ID: MW-2 Collection Date: 6/25/ :20:00 AM Received Date: 6/26/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Xylenes, Total Surr: 1,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d8 TOTAL PHENOLICS BY SW µg/l 1 6/28/2013 4:37:17 PM Analyst: CWS R %REC 1 6/28/2013 4:37:17 PM R %REC 1 6/28/2013 4:37:17 PM R %REC 1 6/28/2013 4:37:17 PM R %REC 1 6/28/2013 4:37:17 PM R11660 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 7/9/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH 1.0 mg/l 1 7/8/2013 5:03:04 PM Analyst: LRW R11792 Analyst: JML µmhos/cm 1 6/26/2013 7:59:48 PM R mg/l 1 Analyst: TMG 6/27/ :30:00 PM R11604 Analyst: JML ph H ph units 1 6/26/2013 7:59:48 PM R11593 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: JML mg/l CaCO3 1 6/26/2013 7:59:48 PM R mg/l CaCO3 1 6/26/2013 7:59:48 PM R mg/l CaCO3 1 6/26/2013 7:59:48 PM R11593 Analyst: KS mg/l 1 6/30/2013 4:41:00 PM 8151 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 6 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
119 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B08 Date Reported: 7/24/2013 Client Sample ID: MW-3 Collection Date: 6/25/ :43:00 AM Received Date: 6/26/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 µg/l 1 7/1/ :41:11 PM ,2-Dibromoethane µg/l 1 7/1/ :41:11 PM 8176 EPA METHOD 300.0: ANIONS Analyst: JRR Chloride mg/l 1 6/27/ :22:23 AM R11606 Nitrogen, Nitrate (As N) mg/l 1 6/27/ :22:23 AM R11606 Sulfate mg/l 1 6/27/ :22:23 AM R11606 EPA METHOD 200.7: METALS Analyst: JLF Barium mg/l 1 7/9/2013 1:08:26 PM R11805 Beryllium mg/l 1 7/9/2013 1:08:26 PM R11805 Cadmium mg/l 1 7/9/2013 1:08:26 PM R11805 Calcium mg/l 1 7/9/2013 1:08:26 PM R11805 Chromium mg/l 1 7/9/2013 1:08:26 PM R11805 Cobalt mg/l 1 7/9/2013 1:08:26 PM R11805 Copper mg/l 1 7/9/2013 1:08:26 PM R11805 Iron mg/l 1 7/9/2013 1:08:26 PM R11805 Magnesium mg/l 1 7/9/2013 1:08:26 PM R11805 Manganese mg/l 1 7/9/2013 1:08:26 PM R11805 Nickel mg/l 1 7/9/2013 1:08:26 PM R11805 Potassium mg/l 1 7/9/2013 1:08:26 PM R11805 Silver mg/l 1 7/9/2013 1:08:26 PM R11805 Sodium mg/l 1 7/9/2013 1:08:26 PM R11805 Vanadium mg/l 1 7/9/2013 1:08:26 PM R11805 Zinc mg/l 1 7/9/2013 1:08:26 PM R11805 EPA 200.8: METALS Analyst: DBD Antimony mg/l 1 7/10/ :38:32 PM R11836 Arsenic mg/l 1 7/5/ :28:47 AM R11758 Lead mg/l 1 7/5/ :28:47 AM R11758 Selenium mg/l 1 7/5/ :28:47 AM R11758 Thallium mg/l 1 7/5/ :28:47 AM R11758 EPA METHOD 8260B: VOLATILES, TABLE I Analyst: CWS 1,2-Dibromo-3-chloropropane 2.0 µg/l 1 6/28/2013 5:06:14 PM R ,2-Dibromoethane (EDB) 1.0 µg/l 1 6/28/2013 5:06:14 PM R11660 Methyl tert-butyl ether (MTBE) 1.0 µg/l 1 6/28/2013 5:06:14 PM R11660 Acetone 10 µg/l 1 6/28/2013 5:06:14 PM R11660 Acrylonitrile 10 µg/l 1 6/28/2013 5:06:14 PM R11660 Benzene 1.0 µg/l 1 6/28/2013 5:06:14 PM R11660 Bromochloromethane 2.0 µg/l 1 6/28/2013 5:06:14 PM R11660 Bromodichloromethane 1.0 µg/l 1 6/28/2013 5:06:14 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 7 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
120 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B08 Date Reported: 7/24/2013 Client Sample ID: MW-3 Collection Date: 6/25/ :43:00 AM Received Date: 6/26/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Analyst: CWS Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichloroethane (EDC) 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane Ethylbenzene 2-Hexanone Iodomethane 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) Toluene trans-1,2-dce trans-1,3-dichloropropene trans-1,4-dichloro-2-butene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride 1.0 µg/l µg/l 1 10 µg/l 1 10 µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l 1 10 µg/l 1 10 µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l µg/l 1 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM 6/28/2013 5:06:14 PM R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 8 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
121 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B08 Date Reported: 7/24/2013 Client Sample ID: MW-3 Collection Date: 6/25/ :43:00 AM Received Date: 6/26/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Xylenes, Total Surr: 1,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d8 TOTAL PHENOLICS BY SW µg/l 1 6/28/2013 5:06:14 PM Analyst: CWS R %REC 1 6/28/2013 5:06:14 PM R %REC 1 6/28/2013 5:06:14 PM R %REC 1 6/28/2013 5:06:14 PM R %REC 1 6/28/2013 5:06:14 PM R11660 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 7/9/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH 1.0 mg/l 1 7/8/2013 5:19:26 PM Analyst: LRW R11792 Analyst: JML µmhos/cm 1 6/26/2013 8:09:56 PM R mg/l 1 Analyst: TMG 6/27/ :30:00 PM R11604 Analyst: JML ph H ph units 1 6/26/2013 8:09:56 PM R11593 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: JML mg/l CaCO3 1 6/26/2013 8:09:56 PM R mg/l CaCO3 1 6/26/2013 8:09:56 PM R mg/l CaCO3 1 6/26/2013 8:09:56 PM R11593 Analyst: KS mg/l 1 6/30/2013 4:41:00 PM 8151 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 9 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
122 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B08 Date Reported: 7/24/2013 Client Sample ID: MW-4 Collection Date: 6/25/ :45:00 PM Received Date: 6/26/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 µg/l 1 7/1/2013 1:08:43 PM ,2-Dibromoethane µg/l 1 7/1/2013 1:08:43 PM 8176 EPA METHOD 300.0: ANIONS Analyst: JRR Chloride mg/l 1 6/27/ :47:12 AM R11606 Nitrogen, Nitrate (As N) mg/l 1 6/27/ :47:12 AM R11606 Sulfate mg/l 1 6/27/ :47:12 AM R11606 EPA METHOD 200.7: METALS Analyst: JLF Barium mg/l 1 7/9/2013 1:10:53 PM R11805 Beryllium mg/l 1 7/9/2013 1:10:53 PM R11805 Cadmium mg/l 1 7/9/2013 1:10:53 PM R11805 Calcium mg/l 5 7/9/2013 2:21:42 PM R11805 Chromium mg/l 1 7/9/2013 1:10:53 PM R11805 Cobalt mg/l 1 7/9/2013 1:10:53 PM R11805 Copper mg/l 1 7/9/2013 1:10:53 PM R11805 Iron mg/l 1 7/9/2013 1:10:53 PM R11805 Magnesium mg/l 1 7/9/2013 1:10:53 PM R11805 Manganese mg/l 1 7/9/2013 1:10:53 PM R11805 Nickel mg/l 1 7/9/2013 1:10:53 PM R11805 Potassium mg/l 1 7/9/2013 1:10:53 PM R11805 Silver mg/l 1 7/9/2013 1:10:53 PM R11805 Sodium mg/l 1 7/9/2013 1:10:53 PM R11805 Vanadium mg/l 1 7/9/2013 1:10:53 PM R11805 Zinc mg/l 1 7/9/2013 1:10:53 PM R11805 EPA 200.8: METALS Analyst: DBD Antimony mg/l 1 7/10/ :42:50 PM R11836 Arsenic mg/l 1 7/5/ :33:21 AM R11758 Lead mg/l 1 7/5/ :33:21 AM R11758 Selenium mg/l 1 7/5/ :33:21 AM R11758 Thallium mg/l 1 7/5/ :33:21 AM R11758 EPA METHOD 8260B: VOLATILES, TABLE I Analyst: CWS 1,2-Dibromo-3-chloropropane 2.0 µg/l 1 6/28/2013 5:35:11 PM R ,2-Dibromoethane (EDB) 1.0 µg/l 1 6/28/2013 5:35:11 PM R11660 Methyl tert-butyl ether (MTBE) 1.0 µg/l 1 6/28/2013 5:35:11 PM R11660 Acetone 10 µg/l 1 6/28/2013 5:35:11 PM R11660 Acrylonitrile 10 µg/l 1 6/28/2013 5:35:11 PM R11660 Benzene 1.0 µg/l 1 6/28/2013 5:35:11 PM R11660 Bromochloromethane 2.0 µg/l 1 6/28/2013 5:35:11 PM R11660 Bromodichloromethane 1.0 µg/l 1 6/28/2013 5:35:11 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 10 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
123 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B08 Date Reported: 7/24/2013 Client Sample ID: MW-4 Collection Date: 6/25/ :45:00 PM Received Date: 6/26/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichloroethane (EDC) 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane Ethylbenzene 2-Hexanone Iodomethane 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) Toluene trans-1,2-dce trans-1,3-dichloropropene trans-1,4-dichloro-2-butene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Analyst: CWS 1.0 µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R µg/l 1 6/28/2013 5:35:11 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 11 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
124 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B08 Date Reported: 7/24/2013 Client Sample ID: MW-4 Collection Date: 6/25/ :45:00 PM Received Date: 6/26/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Xylenes, Total Surr: 1,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d8 TOTAL PHENOLICS BY SW µg/l 1 6/28/2013 5:35:11 PM Analyst: CWS R %REC 1 6/28/2013 5:35:11 PM R %REC 1 6/28/2013 5:35:11 PM R %REC 1 6/28/2013 5:35:11 PM R %REC 1 6/28/2013 5:35:11 PM R11660 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 7/9/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH 1.0 mg/l 1 7/8/2013 5:35:42 PM Analyst: LRW R11792 Analyst: JML µmhos/cm 1 6/26/2013 8:18:58 PM R mg/l 1 Analyst: TMG 6/27/ :30:00 PM R11604 Analyst: JML ph H ph units 1 6/26/2013 8:18:58 PM R11593 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: JML mg/l CaCO3 1 6/26/2013 8:18:58 PM R mg/l CaCO3 1 6/26/2013 8:18:58 PM R mg/l CaCO3 1 6/26/2013 8:18:58 PM R11593 Analyst: KS mg/l 1 6/30/2013 4:41:00 PM 8151 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 12 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
125 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB Client ID: PBW Batch ID: R11805 RunNo: SampType: MBLK Analysis Date: 7/9/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium 1.0 Chromium Cobalt Copper Iron Magnesium 1.0 Manganese Nickel Potassium 1.0 Silver Sodium 1.0 Vanadium Zinc Sample ID LCS Client ID: LCSW Batch ID: R11805 RunNo: SampType: LCS Analysis Date: 7/9/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 13 of 28
126 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID 1306B08-001EMS Client ID: MW-1 Batch ID: R11805 RunNo: SampType: MS Analysis Date: 7/9/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc Sample ID 1306B08-001EMSD Client ID: MW-1 Batch ID: R11805 RunNo: SampType: MSD Analysis Date: 7/9/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 14 of 28
127 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB Client ID: PBW Batch ID: R11805 RunNo: SampType: MBLK Analysis Date: 7/9/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium 1.0 Chromium Cobalt Copper Iron Magnesium 1.0 Manganese Nickel Potassium 1.0 Silver Sodium 1.0 Vanadium Zinc Sample ID LCS Client ID: LCSW Batch ID: R11805 RunNo: SampType: LCS Analysis Date: 7/9/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 15 of 28
128 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB Client ID: PBW Batch ID: R11758 RunNo: SampType: MBLK Analysis Date: 7/5/2013 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Selenium Thallium Sample ID MB Client ID: PBW Batch ID: R11758 RunNo: SampType: MBLK Analysis Date: 7/5/2013 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Selenium Sample ID LCS Client ID: LCSW Batch ID: R11758 RunNo: SampType: LCS Analysis Date: 7/5/2013 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Selenium Thallium Sample ID LCS Client ID: LCSW Batch ID: R11758 RunNo: SampType: LCS Analysis Date: 7/5/2013 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Selenium Sample ID LCS Client ID: LCSW Batch ID: R11836 RunNo: SampType: LCS Analysis Date: 7/10/2013 TestCode: EPA 200.8: Metals SeqNo: Antimony Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 16 of 28
129 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB Client ID: PBW Batch ID: R11836 RunNo: SampType: MBLK Analysis Date: 7/10/2013 TestCode: EPA 200.8: Metals SeqNo: Antimony Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 17 of 28
130 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB Client ID: PBW Batch ID: R11606 RunNo: SampType: MBLK Analysis Date: 6/26/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride 0.50 Nitrogen, Nitrate (As N) 0.10 Sulfate 0.50 Sample ID LCS Client ID: LCSW Batch ID: R11606 RunNo: SampType: LCS Analysis Date: 6/26/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Nitrogen, Nitrate (As N) Sulfate Sample ID MB Client ID: PBW Batch ID: R11606 RunNo: SampType: MBLK Analysis Date: 6/26/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride 0.50 Nitrogen, Nitrate (As N) 0.10 Sulfate 0.50 Sample ID LCS Client ID: LCSW Batch ID: R11606 RunNo: SampType: LCS Analysis Date: 6/26/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Nitrogen, Nitrate (As N) Sulfate Sample ID 1306B08-001BMS Client ID: MW-1 Batch ID: R11606 RunNo: SampType: MS Analysis Date: 6/26/2013 TestCode: EPA Method 300.0: Anions SeqNo: Nitrogen, Nitrate (As N) Sulfate Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 18 of 28
131 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID 1306B08-001BMSD Client ID: MW-1 Batch ID: R11606 RunNo: SampType: MSD Analysis Date: 6/26/2013 TestCode: EPA Method 300.0: Anions SeqNo: Nitrogen, Nitrate (As N) Sulfate Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 19 of 28
132 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB-8176 Client ID: PBW Batch ID: 8176 RunNo: /1/2013 SampType: MBLK Analysis Date: 7/1/2013 TestCode: EPA Method 504.1: EDB/DBCP SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane ,2-Dibromoethane Sample ID LCS-8176 Client ID: LCSW Batch ID: 8176 RunNo: /1/2013 SampType: LCS Analysis Date: 7/1/2013 TestCode: EPA Method 504.1: EDB/DBCP SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane ,2-Dibromoethane Sample ID 1306B08-002AMS Client ID: MW-2 Batch ID: 8176 RunNo: /1/2013 SampType: MS Analysis Date: 7/1/2013 TestCode: EPA Method 504.1: EDB/DBCP SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane ,2-Dibromoethane Sample ID 1306B08-002AMSD Client ID: MW-2 Batch ID: 8176 RunNo: /1/2013 SampType: MSD Analysis Date: 7/1/2013 TestCode: EPA Method 504.1: EDB/DBCP SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane SR 1,2-Dibromoethane R Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 20 of 28
133 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID 5ml rb Client ID: PBW Batch ID: R11660 RunNo: SampType: MBLK Analysis Date: 6/28/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane 2.0 1,2-Dibromoethane (EDB) 1.0 Methyl tert-butyl ether (MTBE) 1.0 Acetone 10 Acrylonitrile 10 Benzene 1.0 Bromochloromethane 2.0 Bromodichloromethane 1.0 Bromoform 1.0 Bromomethane Butanone 10 Carbon disulfide 10 Carbon Tetrachloride 1.0 Chlorobenzene 1.0 Chloroethane 2.0 Chloroform 1.0 Chloromethane 1.0 cis-1,2-dce 1.0 cis-1,3-dichloropropene 1.0 Dibromochloromethane 1.0 Dibromomethane 1.0 1,2-Dichlorobenzene 1.0 1,4-Dichlorobenzene 1.0 1,2-Dichloroethane (EDC) 1.0 1,1-Dichloroethane 1.0 1,1-Dichloroethene 1.0 1,2-Dichloropropane 0.50 Ethylbenzene Hexanone 10 Iodomethane 10 4-Methyl-2-pentanone 10 Methylene Chloride 1.0 Styrene 1.0 1,1,1,2-Tetrachloroethane 1.0 1,1,2,2-Tetrachloroethane 1.0 Tetrachloroethene (PCE) 0.50 Toluene 1.0 trans-1,2-dce 1.0 trans-1,3-dichloropropene 1.0 trans-1,4-dichloro-2-butene 10 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 21 of 28
134 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID 5ml rb Client ID: PBW Batch ID: R11660 RunNo: SampType: MBLK Analysis Date: 6/28/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l 1,1,1-Trichloroethane 1.0 1,1,2-Trichloroethane 1.0 Trichloroethene (TCE) 1.0 Trichlorofluoromethane 1.0 1,2,3-Trichloropropane 1.0 Vinyl acetate 10 Vinyl chloride 0.40 Xylenes, Total 2.0 Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d Sample ID 100ng lcs Client ID: LCSW Batch ID: R11660 RunNo: SampType: LCS Analysis Date: 6/28/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l Benzene Chlorobenzene ,1-Dichloroethene Toluene Trichloroethene (TCE) Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d Sample ID 1306b08-001a ms Client ID: MW-1 Batch ID: R11660 RunNo: SampType: MS Analysis Date: 6/28/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l Benzene Chlorobenzene ,1-Dichloroethene Toluene Trichloroethene (TCE) S Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 22 of 28
135 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID 1306b08-001a ms Client ID: MW-1 Batch ID: R11660 RunNo: SampType: MS Analysis Date: 6/28/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l Surr: Dibromofluoromethane Surr: Toluene-d Sample ID 1306b08-001a msd Client ID: MW-1 Batch ID: R11660 RunNo: SampType: MSD Analysis Date: 6/28/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l Benzene Chlorobenzene ,1-Dichloroethene Toluene Trichloroethene (TCE) S Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 23 of 28
136 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB Client ID: PBW Batch ID: R11792 RunNo: SampType: MBLK Analysis Date: 7/8/2013 TestCode: EPA Method 9060 TOC SeqNo: Total Organic Carbon 1.0 Sample ID LCS ST Client ID: LCSW Batch ID: R11792 RunNo: SampType: LCS Analysis Date: 7/8/2013 TestCode: EPA Method 9060 TOC SeqNo: Total Organic Carbon Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 24 of 28
137 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB-8278 Client ID: PBW Batch ID: 8278 RunNo: /9/2013 SampType: MBLK TestCode: Total Phenolics by SW Analysis Date: 7/9/2013 SeqNo: Units: µg/l Phenolics, Total Recoverable 2.5 Sample ID LCS-8278 Client ID: LCSW Batch ID: 8278 RunNo: /9/2013 SampType: LCS TestCode: Total Phenolics by SW Analysis Date: 7/9/2013 SeqNo: Units: µg/l Phenolics, Total Recoverable Sample ID LCSD-8278 Client ID: LCSS02 Batch ID: 8278 RunNo: /9/2013 SampType: LCSD TestCode: Total Phenolics by SW Analysis Date: 7/9/2013 SeqNo: Units: µg/l Phenolics, Total Recoverable Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 25 of 28
138 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB Client ID: PBW Batch ID: R11604 RunNo: SampType: MBLK Analysis Date: 6/27/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia 1.0 Sample ID LCS Client ID: LCSW Batch ID: R11604 RunNo: SampType: LCS Analysis Date: 6/27/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia Sample ID 1306B08-001BMS Client ID: MW-1 Batch ID: R11604 RunNo: SampType: MS Analysis Date: 6/27/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia Sample ID 1306B08-001BMSD Client ID: MW-1 Batch ID: R11604 RunNo: SampType: MSD Analysis Date: 6/27/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 26 of 28
139 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID mb-1 Client ID: PBW Batch ID: R11593 RunNo: SampType: mblk Analysis Date: 6/26/2013 TestCode: SM2320B: Alkalinity SeqNo: CaCO3 Total Alkalinity (as CaCO3) 20 Sample ID lcs-1 Client ID: LCSW Batch ID: R11593 RunNo: SampType: lcs Analysis Date: 6/26/2013 TestCode: SM2320B: Alkalinity SeqNo: CaCO3 Total Alkalinity (as CaCO3) Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 27 of 28
140 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B08 24-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB-8151 Client ID: PBW Batch ID: 8151 RunNo: /28/2013 SampType: MBLK Analysis Date: 6/30/2013 TestCode: SM2540C MOD: Total Dissolved Solids SeqNo: Total Dissolved Solids 20.0 Sample ID LCS-8151 Client ID: LCSW Batch ID: 8151 RunNo: /28/2013 SampType: LCS Analysis Date: 6/30/2013 TestCode: SM2540C MOD: Total Dissolved Solids SeqNo: Total Dissolved Solids Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 28 of 28
141
142
143 JSAI Laboratory Results Sample Dates (Lab Report Date ) JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
144 Hall Environmental Analysis Laboratory 4901 Hawkins NE Albuquerque, NM TEL: FAX: Website: July 30, 2013 Joshua Rosenblatt City of Las Cruces PO Box Las Cruces, NM TEL: (575) FAX (575) RE: City of Las Cruces Foothills Landfill Monitoring Wells OrderNo.: 1306B57 Dear Joshua Rosenblatt: Hall Environmental Analysis Laboratory received 6 sample(s) on 6/27/2013 for the analyses presented in the following report. This report is a revised report and it replaces the original report issued July 19, These were analyzed according to EPA procedures or equivalent. To access our accredited tests please go to or the state specific web sites. See the sample checklist and/or the Chain of Custody for information regarding the sample receipt temperature and preservation. Data qualifiers or a narrative will be provided if the sample analysis or analytical quality control parameters require a flag. All samples are reported as received unless otherwise indicated. Please don't hesitate to contact HEAL for any additional information or clarifications. Sincerely, Andy Freeman Laboratory Manager 4901 Hawkins NE Albuquerque, NM 87109
145 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-8 Collection Date: 6/26/2013 8:30:00 AM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 µg/l 1 7/1/2013 1:22:28 PM ,2-Dibromoethane µg/l 1 7/1/2013 1:22:28 PM 8176 EPA METHOD 300.0: ANIONS Analyst: JRR Chloride mg/l 1 6/28/ :57:19 AM R11629 Nitrogen, Nitrate (As N) mg/l 1 6/28/ :57:19 AM R11629 Sulfate mg/l 1 6/28/ :57:19 AM R11629 EPA METHOD 200.7: METALS Analyst: JLF Barium mg/l 1 7/3/2013 5:41:18 PM 8170 Beryllium mg/l 1 7/3/2013 5:41:18 PM 8170 Cadmium mg/l 1 7/3/2013 5:41:18 PM 8170 Calcium mg/l 1 7/3/2013 5:41:18 PM 8170 Chromium mg/l 1 7/3/2013 5:41:18 PM 8170 Cobalt mg/l 1 7/3/2013 5:41:18 PM 8170 Copper mg/l 1 7/3/2013 5:41:18 PM 8170 Iron mg/l 1 7/3/2013 5:41:18 PM 8170 Magnesium mg/l 1 7/3/2013 5:41:18 PM 8170 Manganese mg/l 1 7/3/2013 5:41:18 PM 8170 Nickel mg/l 1 7/3/2013 5:41:18 PM 8170 Potassium mg/l 1 7/3/2013 5:41:18 PM 8170 Silver mg/l 1 7/3/2013 5:41:18 PM 8170 Sodium mg/l 1 7/3/2013 5:41:18 PM 8170 Vanadium mg/l 1 7/3/2013 5:41:18 PM 8170 Zinc mg/l 1 7/3/2013 5:41:18 PM 8170 EPA 200.8: METALS Analyst: DBD Antimony mg/l 1 7/17/ :36:37 AM 8170 Arsenic mg/l 1 7/10/2013 4:51:50 PM 8170 Lead mg/l 1 7/10/2013 4:51:50 PM 8170 Selenium mg/l 1 7/10/2013 4:51:50 PM 8170 Thallium mg/l 1 7/10/2013 4:51:50 PM 8170 EPA METHOD 8260B: VOLATILES, TABLE I Analyst: CWS 1,2-Dibromo-3-chloropropane 2.0 µg/l 1 6/28/2013 6:04:07 PM R ,2-Dibromoethane (EDB) 1.0 µg/l 1 6/28/2013 6:04:07 PM R11660 Methyl tert-butyl ether (MTBE) 1.0 µg/l 1 6/28/2013 6:04:07 PM R11660 Acetone 10 µg/l 1 6/28/2013 6:04:07 PM R11660 Acrylonitrile 10 µg/l 1 6/28/2013 6:04:07 PM R11660 Benzene 1.0 µg/l 1 6/28/2013 6:04:07 PM R11660 Bromochloromethane 2.0 µg/l 1 6/28/2013 6:04:07 PM R11660 Bromodichloromethane 1.0 µg/l 1 6/28/2013 6:04:07 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 1 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
146 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-8 Collection Date: 6/26/2013 8:30:00 AM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichloroethane (EDC) 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane Ethylbenzene 2-Hexanone Iodomethane 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) Toluene trans-1,2-dce trans-1,3-dichloropropene trans-1,4-dichloro-2-butene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Analyst: CWS 1.0 µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R µg/l 1 6/28/2013 6:04:07 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 2 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
147 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-8 Collection Date: 6/26/2013 8:30:00 AM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Xylenes, Total Surr: 1,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d8 TOTAL PHENOLICS BY SW µg/l 1 6/28/2013 6:04:07 PM Analyst: CWS R %REC 1 6/28/2013 6:04:07 PM R %REC 1 6/28/2013 6:04:07 PM R %REC 1 6/28/2013 6:04:07 PM R %REC 1 6/28/2013 6:04:07 PM R11660 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 7/9/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH Analyst: LRW mg/l 1 7/8/2013 8:03:05 PM R11792 Analyst: JML µmhos/cm 1 6/27/2013 3:14:18 PM R mg/l 1 7/11/2013 6:43:00 AM Analyst: TMG R11855 Analyst: JML ph H ph units 1 6/27/2013 3:14:18 PM R11633 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: JML mg/l CaCO3 1 6/27/2013 3:14:18 PM R mg/l CaCO3 1 6/27/2013 3:14:18 PM R mg/l CaCO3 1 6/27/2013 3:14:18 PM R11633 Analyst: KS mg/l 1 6/30/2013 4:41:00 PM 8151 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 3 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
148 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-7 Collection Date: 6/26/2013 9:20:00 AM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 µg/l 1 7/1/2013 1:36:20 PM ,2-Dibromoethane µg/l 1 7/1/2013 1:36:20 PM 8176 EPA METHOD 300.0: ANIONS Analyst: JRR Chloride mg/l 20 6/28/2013 1:34:33 AM R11629 Nitrogen, Nitrate (As N) mg/l 1 6/28/2013 1:22:08 AM R11629 Sulfate mg/l 20 6/28/2013 1:34:33 AM R11629 EPA METHOD 200.7: METALS Analyst: JLF Barium mg/l 1 7/9/2013 1:42:22 PM R11805 Beryllium mg/l 1 7/9/2013 1:42:22 PM R11805 Cadmium mg/l 1 7/9/2013 1:42:22 PM R11805 Calcium mg/l 1 7/9/2013 1:42:22 PM R11805 Chromium mg/l 1 7/9/2013 1:42:22 PM R11805 Cobalt mg/l 1 7/9/2013 1:42:22 PM R11805 Copper mg/l 1 7/9/2013 1:42:22 PM R11805 Iron mg/l 1 7/9/2013 1:42:22 PM R11805 Magnesium mg/l 1 7/9/2013 1:42:22 PM R11805 Manganese mg/l 1 7/9/2013 1:42:22 PM R11805 Nickel mg/l 1 7/9/2013 1:42:22 PM R11805 Potassium mg/l 1 7/9/2013 1:42:22 PM R11805 Silver mg/l 1 7/9/2013 1:42:22 PM R11805 Sodium mg/l 1 7/9/2013 1:42:22 PM R11805 Vanadium mg/l 1 7/9/2013 1:42:22 PM R11805 Zinc mg/l 1 7/9/2013 1:42:22 PM R11805 EPA 200.8: METALS Analyst: DBD Antimony mg/l 1 7/11/2013 6:23:09 PM R11882 Arsenic mg/l 1 7/16/2013 2:08:00 PM R11967 Lead mg/l 1 7/16/2013 2:08:00 PM R11967 Selenium mg/l 1 7/16/2013 2:08:00 PM R11967 Thallium mg/l 1 7/11/2013 6:23:09 PM R11882 EPA METHOD 8260B: VOLATILES, TABLE I Analyst: CWS 1,2-Dibromo-3-chloropropane 2.0 µg/l 1 6/28/2013 6:33:00 PM R ,2-Dibromoethane (EDB) 1.0 µg/l 1 6/28/2013 6:33:00 PM R11660 Methyl tert-butyl ether (MTBE) 1.0 µg/l 1 6/28/2013 6:33:00 PM R11660 Acetone 10 µg/l 1 6/28/2013 6:33:00 PM R11660 Acrylonitrile 10 µg/l 1 6/28/2013 6:33:00 PM R11660 Benzene 1.0 µg/l 1 6/28/2013 6:33:00 PM R11660 Bromochloromethane 2.0 µg/l 1 6/28/2013 6:33:00 PM R11660 Bromodichloromethane 1.0 µg/l 1 6/28/2013 6:33:00 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 4 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
149 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-7 Collection Date: 6/26/2013 9:20:00 AM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichloroethane (EDC) 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane Ethylbenzene 2-Hexanone Iodomethane 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) Toluene trans-1,2-dce trans-1,3-dichloropropene trans-1,4-dichloro-2-butene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Analyst: CWS 1.0 µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R µg/l 1 6/28/2013 6:33:00 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 5 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
150 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-7 Collection Date: 6/26/2013 9:20:00 AM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Xylenes, Total Surr: 1,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d8 TOTAL PHENOLICS BY SW µg/l 1 6/28/2013 6:33:00 PM Analyst: CWS R %REC 1 6/28/2013 6:33:00 PM R %REC 1 6/28/2013 6:33:00 PM R %REC 1 6/28/2013 6:33:00 PM R %REC 1 6/28/2013 6:33:00 PM R11660 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 7/9/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH 1.0 mg/l 1 7/8/2013 8:19:44 PM Analyst: LRW R11792 Analyst: JML µmhos/cm 1 6/27/2013 3:25:46 PM R mg/l 1 7/11/2013 6:43:00 AM Analyst: TMG R11855 Analyst: JML ph H ph units 1 6/27/2013 3:25:46 PM R11633 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: JML mg/l CaCO3 1 6/27/2013 3:25:46 PM R mg/l CaCO3 1 6/27/2013 3:25:46 PM R mg/l CaCO3 1 6/27/2013 3:25:46 PM R11633 Analyst: KS mg/l 1 6/30/2013 4:41:00 PM 8151 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 6 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
151 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-6 Collection Date: 6/26/ :00:00 AM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 µg/l 1 7/1/2013 1:50:05 PM ,2-Dibromoethane µg/l 1 7/1/2013 1:50:05 PM 8176 EPA METHOD 300.0: ANIONS Analyst: JRR Chloride mg/l 1 6/28/2013 1:46:58 AM R11629 Nitrogen, Nitrate (As N) mg/l 1 6/28/2013 1:46:58 AM R11629 Sulfate mg/l 1 6/28/2013 1:46:58 AM R11629 EPA METHOD 200.7: METALS Analyst: JLF Barium mg/l 1 7/9/2013 1:44:49 PM R11805 Beryllium mg/l 1 7/9/2013 1:44:49 PM R11805 Cadmium mg/l 1 7/9/2013 1:44:49 PM R11805 Calcium mg/l 1 7/9/2013 1:44:49 PM R11805 Chromium mg/l 1 7/9/2013 1:44:49 PM R11805 Cobalt mg/l 1 7/9/2013 1:44:49 PM R11805 Copper mg/l 1 7/9/2013 1:44:49 PM R11805 Iron mg/l 1 7/9/2013 1:44:49 PM R11805 Magnesium mg/l 1 7/9/2013 1:44:49 PM R11805 Manganese mg/l 1 7/9/2013 1:44:49 PM R11805 Nickel mg/l 1 7/9/2013 1:44:49 PM R11805 Potassium mg/l 1 7/9/2013 1:44:49 PM R11805 Silver mg/l 1 7/9/2013 1:44:49 PM R11805 Sodium mg/l 1 7/9/2013 1:44:49 PM R11805 Vanadium mg/l 1 7/9/2013 1:44:49 PM R11805 Zinc mg/l 1 7/9/2013 1:44:49 PM R11805 EPA 200.8: METALS Analyst: DBD Antimony mg/l 1 7/11/2013 6:27:28 PM R11882 Arsenic mg/l 1 7/16/2013 2:16:01 PM R11967 Lead mg/l 1 7/16/2013 2:16:01 PM R11967 Selenium mg/l 1 7/16/2013 2:16:01 PM R11967 Thallium mg/l 1 7/11/2013 6:27:28 PM R11882 EPA METHOD 8260B: VOLATILES, TABLE I Analyst: CWS 1,2-Dibromo-3-chloropropane 2.0 µg/l 1 6/28/2013 7:01:51 PM R ,2-Dibromoethane (EDB) 1.0 µg/l 1 6/28/2013 7:01:51 PM R11660 Methyl tert-butyl ether (MTBE) 1.0 µg/l 1 6/28/2013 7:01:51 PM R11660 Acetone 10 µg/l 1 6/28/2013 7:01:51 PM R11660 Acrylonitrile 10 µg/l 1 6/28/2013 7:01:51 PM R11660 Benzene 1.0 µg/l 1 6/28/2013 7:01:51 PM R11660 Bromochloromethane 2.0 µg/l 1 6/28/2013 7:01:51 PM R11660 Bromodichloromethane 1.0 µg/l 1 6/28/2013 7:01:51 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 7 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
152 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-6 Collection Date: 6/26/ :00:00 AM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichloroethane (EDC) 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane Ethylbenzene 2-Hexanone Iodomethane 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) Toluene trans-1,2-dce trans-1,3-dichloropropene trans-1,4-dichloro-2-butene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Analyst: CWS 1.0 µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R µg/l 1 6/28/2013 7:01:51 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 8 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
153 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-6 Collection Date: 6/26/ :00:00 AM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Xylenes, Total Surr: 1,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d8 TOTAL PHENOLICS BY SW µg/l 1 6/28/2013 7:01:51 PM Analyst: CWS R %REC 1 6/28/2013 7:01:51 PM R %REC 1 6/28/2013 7:01:51 PM R %REC 1 6/28/2013 7:01:51 PM R %REC 1 6/28/2013 7:01:51 PM R11660 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 7/9/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH Analyst: LRW mg/l 1 7/8/2013 8:36:23 PM R11792 Analyst: JML µmhos/cm 1 6/27/2013 3:35:55 PM R mg/l 1 7/11/2013 6:43:00 AM Analyst: TMG R11855 Analyst: JML ph H ph units 1 6/27/2013 3:35:55 PM R11633 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: JML mg/l CaCO3 1 6/27/2013 3:35:55 PM R mg/l CaCO3 1 6/27/2013 3:35:55 PM R mg/l CaCO3 1 6/27/2013 3:35:55 PM R11633 Analyst: KS mg/l 1 6/30/2013 4:41:00 PM 8151 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 9 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
154 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-5 Collection Date: 6/26/ :35:00 AM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 µg/l 1 7/1/2013 2:03:49 PM ,2-Dibromoethane µg/l 1 7/1/2013 2:03:49 PM 8176 EPA METHOD 300.0: ANIONS Analyst: JRR Chloride mg/l 20 6/28/2013 2:24:12 AM R11629 Nitrogen, Nitrate (As N) mg/l 1 6/28/2013 2:11:47 AM R11629 Sulfate mg/l 1 6/28/2013 2:11:47 AM R11629 EPA METHOD 200.7: METALS Analyst: JLF Barium mg/l 1 7/9/2013 1:47:15 PM R11805 Beryllium mg/l 1 7/9/2013 1:47:15 PM R11805 Cadmium mg/l 1 7/9/2013 1:47:15 PM R11805 Calcium mg/l 1 7/9/2013 1:47:15 PM R11805 Chromium mg/l 1 7/9/2013 1:47:15 PM R11805 Cobalt mg/l 1 7/9/2013 1:47:15 PM R11805 Copper mg/l 1 7/9/2013 1:47:15 PM R11805 Iron mg/l 1 7/9/2013 1:47:15 PM R11805 Magnesium mg/l 1 7/9/2013 1:47:15 PM R11805 Manganese mg/l 1 7/9/2013 1:47:15 PM R11805 Nickel mg/l 1 7/9/2013 1:47:15 PM R11805 Potassium mg/l 1 7/9/2013 1:47:15 PM R11805 Silver mg/l 1 7/9/2013 1:47:15 PM R11805 Sodium mg/l 1 7/9/2013 1:47:15 PM R11805 Vanadium mg/l 1 7/9/2013 1:47:15 PM R11805 Zinc mg/l 1 7/9/2013 1:47:15 PM R11805 EPA 200.8: METALS Analyst: DBD Antimony mg/l 1 7/11/2013 6:31:46 PM R11882 Arsenic mg/l 1 7/16/2013 2:18:41 PM R11967 Lead mg/l 1 7/16/2013 2:18:41 PM R11967 Selenium mg/l 1 7/16/2013 2:18:41 PM R11967 Thallium mg/l 1 7/11/2013 6:31:46 PM R11882 EPA METHOD 8260B: VOLATILES, TABLE I Analyst: CWS 1,2-Dibromo-3-chloropropane 2.0 µg/l 1 6/28/2013 7:30:39 PM R ,2-Dibromoethane (EDB) 1.0 µg/l 1 6/28/2013 7:30:39 PM R11660 Methyl tert-butyl ether (MTBE) 1.0 µg/l 1 6/28/2013 7:30:39 PM R11660 Acetone 10 µg/l 1 6/28/2013 7:30:39 PM R11660 Acrylonitrile 10 µg/l 1 6/28/2013 7:30:39 PM R11660 Benzene 1.0 µg/l 1 6/28/2013 7:30:39 PM R11660 Bromochloromethane 2.0 µg/l 1 6/28/2013 7:30:39 PM R11660 Bromodichloromethane 1.0 µg/l 1 6/28/2013 7:30:39 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 10 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
155 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-5 Collection Date: 6/26/ :35:00 AM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichloroethane (EDC) 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane Ethylbenzene 2-Hexanone Iodomethane 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) Toluene trans-1,2-dce trans-1,3-dichloropropene trans-1,4-dichloro-2-butene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Analyst: CWS 1.0 µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R µg/l 1 6/28/2013 7:30:39 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 11 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
156 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-5 Collection Date: 6/26/ :35:00 AM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Xylenes, Total Surr: 1,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d8 TOTAL PHENOLICS BY SW µg/l 1 6/28/2013 7:30:39 PM Analyst: CWS R %REC 1 6/28/2013 7:30:39 PM R %REC 1 6/28/2013 7:30:39 PM R %REC 1 6/28/2013 7:30:39 PM R %REC 1 6/28/2013 7:30:39 PM R11660 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 7/9/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH Analyst: LRW mg/l 1 7/8/2013 8:52:50 PM R11792 Analyst: JML µmhos/cm 1 6/27/2013 3:45:38 PM R mg/l 1 7/11/2013 6:43:00 AM Analyst: TMG R11855 Analyst: JML ph H ph units 1 6/27/2013 3:45:38 PM R11633 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: JML mg/l CaCO3 1 6/27/2013 3:45:38 PM R mg/l CaCO3 1 6/27/2013 3:45:38 PM R mg/l CaCO3 1 6/27/2013 3:45:38 PM R11633 Analyst: KS mg/l 1 6/30/2013 4:41:00 PM 8151 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 12 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
157 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-9 Collection Date: 6/26/2013 2:12:00 PM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane EPA METHOD 300.0: ANIONS Analyst: LRW 0.10 µg/l 1 7/1/2013 2:17:33 PM µg/l 1 7/1/2013 2:17:33 PM 8176 Analyst: JRR Chloride * mg/l 50 7/1/ :09:14 PM R11694 Nitrogen, Nitrate (As N) Sulfate EPA METHOD 200.7: METALS Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium 0.10 mg/l 1 6/28/2013 3:01:25 AM R mg/l 20 6/28/2013 3:13:50 AM R11629 Analyst: JLF mg/l 1 7/9/2013 1:49:41 PM R mg/l mg/l 1 7/9/2013 1:49:41 PM 7/9/2013 1:49:41 PM R11805 R mg/l 5 7/9/2013 2:24:09 PM R mg/l mg/l mg/l 1 7/9/2013 1:49:41 PM 7/9/2013 1:49:41 PM 7/9/2013 1:49:41 PM R11805 R11805 R mg/l 1 7/9/2013 1:49:41 PM R mg/l 1 7/9/2013 1:49:41 PM R11805 Manganese * mg/l 1 7/9/2013 1:49:41 PM R11805 Nickel * mg/l 1 7/9/2013 1:49:41 PM R11805 Potassium Silver Sodium Vanadium Zinc EPA 200.8: METALS Antimony Arsenic Lead Selenium Thallium EPA METHOD 8260B: VOLATILES, TABLE I 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) Methyl tert-butyl ether (MTBE) Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane mg/l 1 7/9/2013 1:49:41 PM R mg/l 5 7/9/2013 2:24:09 PM R mg/l 5 7/9/2013 2:24:09 PM R mg/l 1 7/9/2013 1:49:41 PM R mg/l 1 7/9/2013 1:49:41 PM R mg/l 1 7/17/2013 4:44:16 PM Analyst: DBD R mg/l 1 7/16/2013 2:21:20 PM R mg/l 1 7/16/2013 2:21:20 PM R mg/l 1 7/16/2013 2:21:20 PM R mg/l µg/l µg/l µg/l 1 10 µg/l 1 10 µg/l µg/l µg/l µg/l 1 7/17/2013 4:44:16 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM R12020 Analyst: CWS Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 13 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
158 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-9 Collection Date: 6/26/2013 2:12:00 PM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Analyst: CWS Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichloroethane (EDC) 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane Ethylbenzene 2-Hexanone Iodomethane 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) Toluene trans-1,2-dce trans-1,3-dichloropropene trans-1,4-dichloro-2-butene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride 1.0 µg/l µg/l 1 10 µg/l 1 10 µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l 1 10 µg/l 1 10 µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l µg/l 1 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM 6/28/2013 7:59:23 PM R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 14 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
159 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City of Las Cruces Foothills Landfill Mo Lab ID: 1306B Matrix: AQUEOUS Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 Client Sample ID: MW-9 Collection Date: 6/26/2013 2:12:00 PM Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Xylenes, Total Surr: 1,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d8 TOTAL PHENOLICS BY SW µg/l 1 6/28/2013 7:59:23 PM Analyst: CWS R %REC 1 6/28/2013 7:59:23 PM R %REC 1 6/28/2013 7:59:23 PM R %REC 1 6/28/2013 7:59:23 PM R %REC 1 6/28/2013 7:59:23 PM R11660 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 7/9/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH 1.0 mg/l 1 7/8/2013 9:09:35 PM Analyst: LRW R11792 Analyst: JML µmhos/cm 1 6/27/2013 3:59:26 PM R mg/l 1 7/11/2013 6:43:00 AM Analyst: TMG R11855 Analyst: JML ph H ph units 1 6/27/2013 3:59:26 PM R11633 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Analyst: JML mg/l CaCO3 1 6/27/2013 3:59:26 PM R mg/l CaCO3 1 6/27/2013 3:59:26 PM R mg/l CaCO3 1 6/27/2013 3:59:26 PM R11633 Analyst: KS Total Dissolved Solids * mg/l 1 6/30/2013 4:41:00 PM 8151 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 15 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
160 Hall Environmental Analysis Laboratory, Inc. Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 CLIENT: City of Las Cruces Client Sample ID: Trip Blank Project: City of Las Cruces Foothills Landfill Mo Collection Date: Lab ID: 1306B Matrix: TRIP BLANK Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane EPA METHOD 8260B: VOLATILES, TABLE I 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) Methyl tert-butyl ether (MTBE) Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichloroethane (EDC) 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane Ethylbenzene 2-Hexanone Iodomethane 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) Analyst: LRW 0.10 µg/l 1 7/1/2013 2:31:20 PM µg/l 1 7/1/2013 2:31:20 PM 8176 Analyst: CWS 2.0 µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 16 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
161 Hall Environmental Analysis Laboratory, Inc. Analytical Report Lab Order 1306B57 Date Reported: 7/30/2013 CLIENT: City of Las Cruces Client Sample ID: Trip Blank Project: City of Las Cruces Foothills Landfill Mo Collection Date: Lab ID: 1306B Matrix: TRIP BLANK Received Date: 6/27/2013 9:00:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Toluene trans-1,2-dce trans-1,3-dichloropropene trans-1,4-dichloro-2-butene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylenes, Total Surr: 1,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d8 Analyst: CWS 1.0 µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R µg/l 1 6/28/2013 8:28:04 PM R %REC 1 6/28/2013 8:28:04 PM R %REC 1 6/28/2013 8:28:04 PM R %REC 1 6/28/2013 8:28:04 PM R %REC 1 6/28/2013 8:28:04 PM R11660 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 17 of 38 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit
162 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB-8170 Client ID: PBW Batch ID: 8170 RunNo: /1/2013 SampType: MBLK Analysis Date: 7/2/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium 1.0 Chromium Cobalt Iron Magnesium 1.0 Manganese Nickel Potassium 1.0 Silver Sodium 1.0 Vanadium Zinc Sample ID LCS-8170 Client ID: LCSW Batch ID: 8170 RunNo: /1/2013 SampType: LCS Analysis Date: 7/2/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium Chromium Cobalt Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 18 of 38
163 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB-8170 Client ID: PBW Batch ID: 8170 RunNo: /1/2013 SampType: MBLK Analysis Date: 7/3/2013 TestCode: EPA Method 200.7: Metals SeqNo: Copper Sample ID LCS-8170 Client ID: LCSW Batch ID: 8170 RunNo: /1/2013 SampType: LCS Analysis Date: 7/3/2013 TestCode: EPA Method 200.7: Metals SeqNo: Copper Sample ID 1306B57-001CMS Client ID: MW-8 Batch ID: 8170 RunNo: /1/2013 SampType: MS Analysis Date: 7/3/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc Sample ID 1306B57-001CMSD Client ID: MW-8 Batch ID: 8170 RunNo: /1/2013 SampType: MSD Analysis Date: 7/3/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium Chromium Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 19 of 38
164 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID 1306B57-001CMSD Client ID: MW-8 Batch ID: 8170 RunNo: /1/2013 SampType: MSD Analysis Date: 7/3/2013 TestCode: EPA Method 200.7: Metals SeqNo: Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc Sample ID MB Client ID: PBW Batch ID: R11805 RunNo: SampType: MBLK Analysis Date: 7/9/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium 1.0 Chromium Cobalt Copper Iron Magnesium 1.0 Manganese Nickel Potassium 1.0 Silver Sodium 1.0 Vanadium Zinc Sample ID LCS Client ID: LCSW Batch ID: R11805 RunNo: SampType: LCS Analysis Date: 7/9/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 20 of 38
165 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID LCS Client ID: LCSW Batch ID: R11805 RunNo: SampType: LCS Analysis Date: 7/9/2013 TestCode: EPA Method 200.7: Metals SeqNo: Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc Sample ID MB Client ID: PBW Batch ID: R11805 RunNo: SampType: MBLK Analysis Date: 7/9/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium 1.0 Chromium Cobalt Copper Iron Magnesium 1.0 Manganese Nickel Potassium 1.0 Silver Sodium 1.0 Vanadium Zinc Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 21 of 38
166 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID LCS Client ID: LCSW Batch ID: R11805 RunNo: SampType: LCS Analysis Date: 7/9/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 22 of 38
167 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB-8170 Client ID: PBW Batch ID: 8170 RunNo: /1/2013 SampType: MBLK Analysis Date: 7/10/2013 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Selenium Thallium Sample ID LLLCS-8170 Client ID: BatchQC Batch ID: 8170 RunNo: /1/2013 SampType: LCSLL Analysis Date: 7/10/2013 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Selenium Thallium Sample ID LLLCS-8170 Client ID: BatchQC Batch ID: 8170 RunNo: /1/2013 SampType: LCSLL Analysis Date: 7/11/2013 TestCode: EPA 200.8: Metals SeqNo: Antimony S Sample ID MB-8170 Client ID: PBW Batch ID: 8170 RunNo: /1/2013 SampType: MBLK Analysis Date: 7/11/2013 TestCode: EPA 200.8: Metals SeqNo: Antimony Sample ID LCS Client ID: LCSW Batch ID: R11882 RunNo: SampType: LCS Analysis Date: 7/11/2013 TestCode: EPA 200.8: Metals SeqNo: Antimony Thallium Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 23 of 38
168 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB Client ID: PBW Batch ID: R11882 RunNo: SampType: MBLK Analysis Date: 7/11/2013 TestCode: EPA 200.8: Metals SeqNo: Antimony Thallium Sample ID LCS Client ID: LCSW Batch ID: R11967 RunNo: SampType: LCS Analysis Date: 7/16/2013 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Selenium Sample ID MB Client ID: PBW Batch ID: R11967 RunNo: SampType: MBLK Analysis Date: 7/16/2013 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Selenium Sample ID LCS Client ID: LCSW Batch ID: R11967 RunNo: SampType: LCS Analysis Date: 7/16/2013 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Selenium Sample ID LCS Client ID: LCSW Batch ID: R11967 RunNo: SampType: LCS Analysis Date: 7/16/2013 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Selenium Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 24 of 38
169 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID LCS Client ID: LCSW Batch ID: R11967 RunNo: SampType: LCS Analysis Date: 7/16/2013 TestCode: EPA 200.8: Metals SeqNo: Lead Sample ID MB Client ID: PBW Batch ID: R11967 RunNo: SampType: MBLK Analysis Date: 7/16/2013 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Selenium Sample ID MB Client ID: PBW Batch ID: R11967 RunNo: SampType: MBLK Analysis Date: 7/16/2013 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Selenium Sample ID MB Client ID: PBW Batch ID: R11967 RunNo: SampType: MBLK Analysis Date: 7/16/2013 TestCode: EPA 200.8: Metals SeqNo: Lead Sample ID LCS Client ID: LCSW Batch ID: R12020 RunNo: SampType: LCS Analysis Date: 7/17/2013 TestCode: EPA 200.8: Metals SeqNo: Antimony Thallium Sample ID MB Client ID: PBW Batch ID: R12020 RunNo: SampType: MBLK Analysis Date: 7/17/2013 TestCode: EPA 200.8: Metals SeqNo: Antimony Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 25 of 38
170 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB Client ID: PBW Batch ID: R12020 RunNo: SampType: MBLK Analysis Date: 7/17/2013 TestCode: EPA 200.8: Metals SeqNo: Thallium Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 26 of 38
171 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB Client ID: PBW Batch ID: R11629 RunNo: SampType: MBLK Analysis Date: 6/27/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride 0.50 Nitrogen, Nitrate (As N) 0.10 Sulfate 0.50 Sample ID LCS Client ID: LCSW Batch ID: R11629 RunNo: SampType: LCS Analysis Date: 6/27/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Nitrogen, Nitrate (As N) Sulfate Sample ID MB Client ID: PBW Batch ID: R11629 RunNo: SampType: MBLK Analysis Date: 6/27/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride 0.50 Nitrogen, Nitrate (As N) 0.10 Sulfate 0.50 Sample ID LCS Client ID: LCSW Batch ID: R11629 RunNo: SampType: LCS Analysis Date: 6/27/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Nitrogen, Nitrate (As N) Sulfate Sample ID MB Client ID: PBW Batch ID: R11694 RunNo: SampType: MBLK Analysis Date: 7/1/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride 0.50 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 27 of 38
172 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID LCS Client ID: LCSW Batch ID: R11694 RunNo: SampType: LCS Analysis Date: 7/1/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 28 of 38
173 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB-8176 Client ID: PBW Batch ID: 8176 RunNo: /1/2013 SampType: MBLK Analysis Date: 7/1/2013 TestCode: EPA Method 504.1: EDB/DBCP SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane ,2-Dibromoethane Sample ID LCS-8176 Client ID: LCSW Batch ID: 8176 RunNo: /1/2013 SampType: LCS Analysis Date: 7/1/2013 TestCode: EPA Method 504.1: EDB/DBCP SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane ,2-Dibromoethane Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 29 of 38
174 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID 5ml rb Client ID: PBW Batch ID: R11660 RunNo: SampType: MBLK Analysis Date: 6/28/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane 2.0 1,2-Dibromoethane (EDB) 1.0 Methyl tert-butyl ether (MTBE) 1.0 Acetone 10 Acrylonitrile 10 Benzene 1.0 Bromochloromethane 2.0 Bromodichloromethane 1.0 Bromoform 1.0 Bromomethane Butanone 10 Carbon disulfide 10 Carbon Tetrachloride 1.0 Chlorobenzene 1.0 Chloroethane 2.0 Chloroform 1.0 Chloromethane 1.0 cis-1,2-dce 1.0 cis-1,3-dichloropropene 1.0 Dibromochloromethane 1.0 Dibromomethane 1.0 1,2-Dichlorobenzene 1.0 1,4-Dichlorobenzene 1.0 1,2-Dichloroethane (EDC) 1.0 1,1-Dichloroethane 1.0 1,1-Dichloroethene 1.0 1,2-Dichloropropane 0.50 Ethylbenzene Hexanone 10 Iodomethane 10 4-Methyl-2-pentanone 10 Methylene Chloride 1.0 Styrene 1.0 1,1,1,2-Tetrachloroethane 1.0 1,1,2,2-Tetrachloroethane 1.0 Tetrachloroethene (PCE) 0.50 Toluene 1.0 trans-1,2-dce 1.0 trans-1,3-dichloropropene 1.0 trans-1,4-dichloro-2-butene 10 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 30 of 38
175 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID 5ml rb Client ID: PBW Batch ID: R11660 RunNo: SampType: MBLK Analysis Date: 6/28/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l 1,1,1-Trichloroethane 1.0 1,1,2-Trichloroethane 1.0 Trichloroethene (TCE) 1.0 Trichlorofluoromethane 1.0 1,2,3-Trichloropropane 1.0 Vinyl acetate 10 Vinyl chloride 0.40 Xylenes, Total 2.0 Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d Sample ID 100ng lcs Client ID: LCSW Batch ID: R11660 RunNo: SampType: LCS Analysis Date: 6/28/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l Benzene Chlorobenzene ,1-Dichloroethene Toluene Trichloroethene (TCE) Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 31 of 38
176 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB Client ID: PBW Batch ID: R11792 RunNo: SampType: MBLK Analysis Date: 7/8/2013 TestCode: EPA Method 9060 TOC SeqNo: Total Organic Carbon 1.0 Sample ID LCS ST Client ID: LCSW Batch ID: R11792 RunNo: SampType: LCS Analysis Date: 7/8/2013 TestCode: EPA Method 9060 TOC SeqNo: Total Organic Carbon Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 32 of 38
177 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB-8278 Client ID: PBW Batch ID: 8278 RunNo: /9/2013 SampType: MBLK TestCode: Total Phenolics by SW Analysis Date: 7/9/2013 SeqNo: Units: µg/l Phenolics, Total Recoverable 2.5 Sample ID LCS-8278 Client ID: LCSW Batch ID: 8278 RunNo: /9/2013 SampType: LCS TestCode: Total Phenolics by SW Analysis Date: 7/9/2013 SeqNo: Units: µg/l Phenolics, Total Recoverable Sample ID LCSD-8278 Client ID: LCSS02 Batch ID: 8278 RunNo: /9/2013 SampType: LCSD TestCode: Total Phenolics by SW Analysis Date: 7/9/2013 SeqNo: Units: µg/l Phenolics, Total Recoverable Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 33 of 38
178 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID 1306b57-004b dup Client ID: MW-5 Batch ID: R11633 RunNo: SampType: dup Analysis Date: 6/27/2013 TestCode: SM2510B: Specific Conductance SeqNo: Units: µmhos/cm Conductivity Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 34 of 38
179 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB Client ID: PBW Batch ID: R11855 RunNo: SampType: MBLK Analysis Date: 7/11/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia 1.0 Sample ID LCS Client ID: LCSW Batch ID: R11855 RunNo: SampType: LCS Analysis Date: 7/11/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia Sample ID 1306B57-001BMS Client ID: MW-8 Batch ID: R11855 RunNo: SampType: MS Analysis Date: 7/11/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia Sample ID 1306B57-001BMSD Client ID: MW-8 Batch ID: R11855 RunNo: SampType: MSD Analysis Date: 7/11/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 35 of 38
180 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID 1306b57-004b dup SampType: dup TestCode: SM4500-H+B: ph Client ID: MW-5 Batch ID: R11633 RunNo: Analysis Date: 6/27/2013 SeqNo: Units: ph units ph H Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 36 of 38
181 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID mb-1 Client ID: PBW Batch ID: R11633 RunNo: SampType: mblk Analysis Date: 6/27/2013 TestCode: SM2320B: Alkalinity SeqNo: CaCO3 Total Alkalinity (as CaCO3) 20 Sample ID lcs-1 Client ID: LCSW Batch ID: R11633 RunNo: SampType: lcs Analysis Date: 6/27/2013 TestCode: SM2320B: Alkalinity SeqNo: CaCO3 Total Alkalinity (as CaCO3) Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 37 of 38
182 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1306B57 30-Jul-13 Client: Project: City of Las Cruces City of Las Cruces Foothills Landfill Monitoring Sample ID MB-8151 Client ID: PBW Batch ID: 8151 RunNo: /28/2013 SampType: MBLK Analysis Date: 6/30/2013 TestCode: SM2540C MOD: Total Dissolved Solids SeqNo: Total Dissolved Solids 20.0 Sample ID LCS-8151 Client ID: LCSW Batch ID: 8151 RunNo: /28/2013 SampType: LCS Analysis Date: 6/30/2013 TestCode: SM2540C MOD: Total Dissolved Solids SeqNo: Total Dissolved Solids Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit Page 38 of 38
183
184
185
186 JSAI Laboratory Results Sample Date (Lab Report Date , Report 1 of 2) JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
187 Hall Environmental Analysis Laboratory 4901 Hawkins NE Albuquerque, NM TEL: FAX: Website: January 17, 2014 Joshua Rosenblatt City of Las Cruces PO Box Las Cruces, NM TEL: (575) FAX (575) RE: City Of Las Cruces Foothills Lanfdill Monitoring Wells OrderNo.: 1312A00 Dear Joshua Rosenblatt: Hall Environmental Analysis Laboratory received 2 sample(s) on 12/20/2013 for the analyses presented in the following report. This report is a revised report and it replaces the original report issued January 13, These were analyzed according to EPA procedures or equivalent. To access our accredited tests please go to or the state specific web sites. See the sample checklist and/or the Chain of Custody for information regarding the sample receipt temperature and preservation. Data qualifiers or a narrative will be provided if the sample analysis or analytical quality control parameters require a flag. All samples are reported as received unless otherwise indicated. Please don't hesitate to contact HEAL for any additional information or clarifications. Sincerely, Andy Freeman Laboratory Manager 4901 Hawkins NE Albuquerque, NM 87109
188 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A00 Date Reported: 1/17/2014 Client Sample ID: MW-1 Collection Date: 12/19/2013 9:43:00 AM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 H µg/l 1 1/16/ :06:12 AM ,2-Dibromoethane H µg/l 1 1/16/ :06:12 AM EPA METHOD 300.0: ANIONS Chloride Nitrogen, Nitrate (As N) Sulfate EPA METHOD 200.7: METALS Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc EPA 200.8: METALS Antimony Arsenic Lead Selenium Thallium EPA METHOD 8260B: VOLATILES, TABLE I Benzene Toluene Ethylbenzene Methyl tert-butyl ether (MTBE) 1,2-Dichloroethane (EDC) 1,2-Dibromoethane (EDB) Acetone Analyst: JRR mg/l 20 12/20/2013 5:19:46 PM R mg/l 1 12/20/2013 5:07:22 PM R mg/l 1 12/20/2013 5:07:22 PM R15728 Analyst: ELS mg/l 1 12/27/2013 1:24:27 PM R mg/l mg/l 1 12/27/2013 1:24:27 PM 12/27/2013 1:24:27 PM R15768 R mg/l 1 12/30/2013 1:53:19 PM R mg/l mg/l mg/l 1 12/27/2013 1:24:27 PM 12/27/2013 1:24:27 PM 12/27/2013 1:24:27 PM R15768 R15768 R mg/l 1 12/30/2013 1:53:19 PM R mg/l 1 12/30/2013 1:53:19 PM R mg/l 1 12/27/2013 1:24:27 PM R mg/l 1 12/27/2013 1:24:27 PM R mg/l 1 12/30/2013 1:53:19 PM R mg/l 1 12/27/2013 1:24:27 PM R mg/l 1 12/30/2013 1:53:19 PM R mg/l mg/l mg/l mg/l mg/l 1 12/27/2013 1:24:27 PM 12/27/2013 1:24:27 PM 1/6/2014 4:27:38 PM 1/6/2014 4:27:38 PM 1/6/2014 4:27:38 PM R15768 R15768 Analyst: DBD R15909 R15909 R mg/l 1 1/8/2014 3:05:52 PM R mg/l µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l 1 1/6/2014 4:27:38 PM R15909 Analyst: DJF 12/22/2013 8:07:30 PM 12/22/2013 8:07:30 PM 12/22/2013 8:07:30 PM 12/22/2013 8:07:30 PM 12/22/2013 8:07:30 PM 12/22/2013 8:07:30 PM 12/22/2013 8:07:30 PM Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. R15681 R15681 R15681 R15681 R15681 R15681 R15681 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 1 of 21 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
189 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A00 Date Reported: 1/17/2014 Client Sample ID: MW-1 Collection Date: 12/19/2013 9:43:00 AM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Bromodichloromethane Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene 1,2-Dibromo-3-chloropropane Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane 2-Hexanone 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) trans-1,2-dce trans-1,3-dichloropropene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl chloride Xylenes, Total Acrylonitrile Bromochloromethane Analyst: DJF 1.0 µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/23/ :17:20 AM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R µg/l 1 12/22/2013 8:07:30 PM R15681 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 2 of 21 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
190 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A00 Date Reported: 1/17/2014 Client Sample ID: MW-1 Collection Date: 12/19/2013 9:43:00 AM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Iodomethane trans-1,4-dichloro-2-butene Vinyl acetate Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d4 Surr: Toluene-d8 Surr: 4-Bromofluorobenzene TOTAL PHENOLICS BY SW µg/l 1 10 µg/l 1 10 µg/l 1 Analyst: DJF 12/22/2013 8:07:30 PM 12/22/2013 8:07:30 PM 12/22/2013 8:07:30 PM R15681 R15681 R %REC 1 12/22/2013 8:07:30 PM R %REC 1 12/22/2013 8:07:30 PM R %REC 1 12/22/2013 8:07:30 PM R %REC 1 12/22/2013 8:07:30 PM R15681 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 12/23/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH Analyst: JDC mg/l 1 12/23/ :47:21 PM R15700 Analyst: SRM µmhos/cm 1 12/23/2013 4:14:03 PM R mg/l 1 Analyst: TMG 12/27/ :30:00 AM R15765 Analyst: SRM ph H ph units 1 12/23/2013 4:14:03 PM R15709 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: SRM mg/l CaCO3 1 12/23/2013 4:14:03 PM R mg/l CaCO3 1 12/23/2013 4:14:03 PM R mg/l CaCO3 1 12/23/2013 4:14:03 PM R15709 Analyst: KS mg/l 1 12/27/ :29:00 AM Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 3 of 21 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
191 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A00 Date Reported: 1/17/2014 Client Sample ID: MW-2 Collection Date: 12/19/ :47:00 AM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 H µg/l 1 1/16/ :20:05 AM ,2-Dibromoethane H µg/l 1 1/16/ :20:05 AM EPA METHOD 300.0: ANIONS Chloride Nitrogen, Nitrate (As N) Sulfate EPA METHOD 200.7: METALS Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc EPA 200.8: METALS Antimony Arsenic Lead Selenium Thallium EPA METHOD 8260B: VOLATILES, TABLE I Benzene Toluene Ethylbenzene Methyl tert-butyl ether (MTBE) 1,2-Dichloroethane (EDC) 1,2-Dibromoethane (EDB) Acetone Analyst: JRR mg/l 1 12/20/2013 5:32:11 PM R mg/l 1 12/20/2013 5:32:11 PM R mg/l 1 12/20/2013 5:32:11 PM R15728 Analyst: ELS mg/l 1 12/27/2013 1:27:58 PM R mg/l mg/l 1 12/27/2013 1:27:58 PM 12/27/2013 1:27:58 PM R15768 R mg/l 1 12/30/2013 1:55:07 PM R mg/l mg/l mg/l mg/l 1 12/27/2013 1:27:58 PM 12/27/2013 1:27:58 PM 12/27/2013 1:27:58 PM 12/30/2013 1:55:07 PM R15768 R15768 R15768 R mg/l 1 12/30/2013 1:55:07 PM R mg/l mg/l 1 12/27/2013 1:27:58 PM 12/27/2013 1:27:58 PM R15768 R mg/l 1 12/30/2013 1:55:07 PM R mg/l 1 12/27/2013 1:27:58 PM R mg/l 1 12/30/2013 1:55:07 PM R mg/l mg/l mg/l 1 12/27/2013 1:27:58 PM 12/27/2013 1:27:58 PM 1/6/2014 4:32:09 PM R15768 R15768 Analyst: DBD R mg/l 1 1/6/2014 4:32:09 PM R mg/l mg/l mg/l µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l 1 1/6/2014 4:32:09 PM 1/8/2014 3:08:32 PM 1/6/2014 4:32:09 PM R15909 R15963 R15909 Analyst: DJF 12/22/2013 8:39:20 PM 12/22/2013 8:39:20 PM 12/22/2013 8:39:20 PM 12/22/2013 8:39:20 PM 12/22/2013 8:39:20 PM 12/22/2013 8:39:20 PM 12/22/2013 8:39:20 PM Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. R15681 R15681 R15681 R15681 R15681 R15681 R15681 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 4 of 21 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
192 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A00 Date Reported: 1/17/2014 Client Sample ID: MW-2 Collection Date: 12/19/ :47:00 AM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Bromodichloromethane Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene 1,2-Dibromo-3-chloropropane Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane 2-Hexanone 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) trans-1,2-dce trans-1,3-dichloropropene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl chloride Xylenes, Total Acrylonitrile Bromochloromethane Analyst: DJF 1.0 µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/23/ :45:56 AM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R µg/l 1 12/22/2013 8:39:20 PM R15681 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 5 of 21 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
193 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A00 Date Reported: 1/17/2014 Client Sample ID: MW-2 Collection Date: 12/19/ :47:00 AM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Iodomethane trans-1,4-dichloro-2-butene Vinyl acetate Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d4 Surr: Toluene-d8 Surr: 4-Bromofluorobenzene TOTAL PHENOLICS BY SW µg/l 1 10 µg/l 1 10 µg/l 1 Analyst: DJF 12/22/2013 8:39:20 PM 12/22/2013 8:39:20 PM 12/22/2013 8:39:20 PM R15681 R15681 R %REC 1 12/22/2013 8:39:20 PM R %REC 1 12/22/2013 8:39:20 PM R %REC 1 12/22/2013 8:39:20 PM R %REC 1 12/22/2013 8:39:20 PM R15681 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 12/23/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH Analyst: JDC mg/l 1 12/24/ :33:31 AM R15700 Analyst: SRM µmhos/cm 1 12/23/2013 4:22:16 PM R mg/l 1 Analyst: TMG 12/27/ :30:00 AM R15765 Analyst: SRM ph H ph units 1 12/23/2013 4:22:16 PM R15709 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: SRM mg/l CaCO3 1 12/23/2013 4:22:16 PM R mg/l CaCO3 1 12/23/2013 4:22:16 PM R mg/l CaCO3 1 12/23/2013 4:22:16 PM R15709 Analyst: KS mg/l 1 12/27/ :29:00 AM Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 6 of 21 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
194 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: R15768 RunNo: SampType: MBLK Analysis Date: 12/27/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Chromium Cobalt Copper Manganese Nickel Silver Vanadium Zinc Sample ID LCS Client ID: LCSW Batch ID: R15768 RunNo: SampType: LCS Analysis Date: 12/27/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Chromium Cobalt Copper Manganese Nickel Silver Vanadium Zinc Sample ID MB Client ID: PBW Batch ID: R15805 RunNo: SampType: MBLK Analysis Date: 12/30/2013 TestCode: EPA Method 200.7: Metals SeqNo: Calcium 1.0 Iron Magnesium 1.0 Potassium 1.0 Sodium 1.0 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 7 of 21
195 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID LCS Client ID: LCSW Batch ID: R15805 RunNo: SampType: LCS Analysis Date: 12/30/2013 TestCode: EPA Method 200.7: Metals SeqNo: Calcium Iron Magnesium Potassium Sodium Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 8 of 21
196 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID LCS Client ID: LCSW Batch ID: R15909 RunNo: SampType: LCS Analysis Date: 1/6/2014 TestCode: EPA 200.8: Metals SeqNo: Antimony Arsenic Lead Thallium Sample ID LCS Client ID: LCSW Batch ID: R15909 RunNo: SampType: LCS Analysis Date: 1/6/2014 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Sample ID MB Client ID: PBW Batch ID: R15909 RunNo: SampType: MBLK Analysis Date: 1/6/2014 TestCode: EPA 200.8: Metals SeqNo: Antimony Arsenic Lead Thallium Sample ID MB Client ID: PBW Batch ID: R15909 RunNo: SampType: MBLK Analysis Date: 1/6/2014 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Sample ID LCS Client ID: LCSW Batch ID: R15963 RunNo: SampType: LCS Analysis Date: 1/8/2014 TestCode: EPA 200.8: Metals SeqNo: Selenium Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 9 of 21
197 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: R15963 RunNo: SampType: MBLK Analysis Date: 1/8/2014 TestCode: EPA 200.8: Metals SeqNo: Selenium Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 10 of 21
198 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID A5 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_5 Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Nitrogen, Nitrate (As N) Sulfate Sample ID MB Client ID: PBW Batch ID: R15728 RunNo: SampType: MBLK Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride 0.50 Nitrogen, Nitrate (As N) 0.10 Sulfate 0.50 Sample ID LCS Client ID: LCSW Batch ID: R15728 RunNo: SampType: LCS Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Nitrogen, Nitrate (As N) Sulfate Sample ID A6 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_6 Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Nitrogen, Nitrate (As N) Sulfate Sample ID A4 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_4 Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Nitrogen, Nitrate (As N) Sulfate Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 11 of 21
199 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID A5 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_5 Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Nitrogen, Nitrate (As N) Sulfate Sample ID A6 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_6 Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Nitrogen, Nitrate (As N) S Sulfate Sample ID A4 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_4 Analysis Date: 12/21/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Nitrogen, Nitrate (As N) Sulfate Sample ID A5 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_5 Analysis Date: 12/21/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Nitrogen, Nitrate (As N) Sulfate Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 12 of 21
200 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: RunNo: /16/2014 SampType: MBLK Analysis Date: 1/16/2014 TestCode: EPA Method 504.1: EDB/DBCP SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane ,2-Dibromoethane Sample ID LCS Client ID: LCSW Batch ID: RunNo: /16/2014 SampType: LCS Analysis Date: 1/16/2014 TestCode: EPA Method 504.1: EDB/DBCP SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane ,2-Dibromoethane Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 13 of 21
201 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID 5ml rb Client ID: PBW Batch ID: R15681 RunNo: SampType: MBLK Analysis Date: 12/22/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l Benzene 1.0 Toluene 1.0 Ethylbenzene 1.0 Methyl tert-butyl ether (MTBE) 1.0 1,2-Dichloroethane (EDC) 1.0 1,2-Dibromoethane (EDB) 1.0 Acetone 10 Bromodichloromethane 1.0 Bromoform 1.0 Bromomethane Butanone 10 Carbon disulfide 10 Carbon Tetrachloride 1.0 Chlorobenzene 1.0 Chloroethane 2.0 Chloroform 1.0 Chloromethane 1.0 cis-1,2-dce 1.0 cis-1,3-dichloropropene 1.0 1,2-Dibromo-3-chloropropane 2.0 Dibromochloromethane 1.0 Dibromomethane 1.0 1,2-Dichlorobenzene 1.0 1,4-Dichlorobenzene 1.0 1,1-Dichloroethane 1.0 1,1-Dichloroethene 1.0 1,2-Dichloropropane Hexanone 10 4-Methyl-2-pentanone 10 Methylene Chloride 1.0 Styrene 1.0 1,1,1,2-Tetrachloroethane 1.0 1,1,2,2-Tetrachloroethane 1.0 Tetrachloroethene (PCE) 0.50 trans-1,2-dce 1.0 trans-1,3-dichloropropene 1.0 1,1,1-Trichloroethane 1.0 1,1,2-Trichloroethane 1.0 Trichloroethene (TCE) 1.0 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 14 of 21
202 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID 5ml rb Client ID: PBW Batch ID: R15681 RunNo: SampType: MBLK Analysis Date: 12/22/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l Trichlorofluoromethane 1.0 1,2,3-Trichloropropane 1.0 Vinyl chloride 0.40 Xylenes, Total 2.0 Acrylonitrile 10 Bromochloromethane 2.0 Iodomethane 10 trans-1,4-dichloro-2-butene 10 Vinyl acetate 10 Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d Surr: Toluene-d Surr: 4-Bromofluorobenzene Sample ID 100nglcs,200ngacac Client ID: LCSW Batch ID: R15681 RunNo: SampType: LCS Analysis Date: 12/22/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l Benzene Toluene Chlorobenzene ,1-Dichloroethene Trichloroethene (TCE) Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d Surr: Toluene-d Surr: 4-Bromofluorobenzene Sample ID 5mL rb Client ID: PBW Batch ID: R15701 RunNo: SampType: MBLK Analysis Date: 12/23/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: %REC Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d Surr: Toluene-d Surr: 4-Bromofluorobenzene Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 15 of 21
203 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID 100ng lcs Client ID: LCSW Batch ID: R15701 RunNo: SampType: LCS Analysis Date: 12/23/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: %REC Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d Surr: Toluene-d Surr: 4-Bromofluorobenzene Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 16 of 21
204 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID 1312A00-001FMS Client ID: MW-1 Batch ID: R15700 RunNo: SampType: MS Analysis Date: 12/24/2013 TestCode: EPA Method 9060 TOC SeqNo: Total Organic Carbon Sample ID 1312A00-001FMSD Client ID: MW-1 Batch ID: R15700 RunNo: SampType: MSD Analysis Date: 12/24/2013 TestCode: EPA Method 9060 TOC SeqNo: Total Organic Carbon Sample ID MB Client ID: PBW Batch ID: R15700 RunNo: SampType: MBLK Analysis Date: 12/23/2013 TestCode: EPA Method 9060 TOC SeqNo: Total Organic Carbon 1.0 Sample ID LCS ST Client ID: LCSW Batch ID: R15700 RunNo: SampType: LCS Analysis Date: 12/23/2013 TestCode: EPA Method 9060 TOC SeqNo: Total Organic Carbon Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 17 of 21
205 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: RunNo: /23/2013 SampType: MBLK TestCode: Total Phenolics by SW Analysis Date: 12/23/2013 SeqNo: Units: µg/l Phenolics, Total Recoverable 2.5 Sample ID LCS Client ID: LCSW Batch ID: RunNo: /23/2013 SampType: LCS TestCode: Total Phenolics by SW Analysis Date: 12/23/2013 SeqNo: Units: µg/l Phenolics, Total Recoverable Sample ID 1312A00-002BMS Client ID: MW-2 Batch ID: RunNo: /23/2013 SampType: MS TestCode: Total Phenolics by SW Analysis Date: 12/23/2013 SeqNo: Units: µg/l Phenolics, Total Recoverable Sample ID 1312A00-002BMSD Client ID: MW-2 Batch ID: RunNo: /23/2013 SampType: MSD TestCode: Total Phenolics by SW Analysis Date: 12/23/2013 SeqNo: Units: µg/l Phenolics, Total Recoverable Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 18 of 21
206 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: R15765 RunNo: SampType: MBLK Analysis Date: 12/27/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia 1.0 Sample ID LCS Client ID: LCSW Batch ID: R15765 RunNo: SampType: LCS Analysis Date: 12/27/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia Sample ID 1312A00-001DMS Client ID: MW-1 Batch ID: R15765 RunNo: SampType: MS Analysis Date: 12/27/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia Sample ID 1312A00-001DMSD Client ID: MW-1 Batch ID: R15765 RunNo: SampType: MSD Analysis Date: 12/27/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 19 of 21
207 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID mb-1 Client ID: PBW Batch ID: R15709 RunNo: SampType: MBLK Analysis Date: 12/23/2013 TestCode: SM2320B: Alkalinity SeqNo: CaCO3 Total Alkalinity (as CaCO3) 20 Sample ID lcs-1 Client ID: LCSW Batch ID: R15709 RunNo: SampType: LCS Analysis Date: 12/23/2013 TestCode: SM2320B: Alkalinity SeqNo: CaCO3 Total Alkalinity (as CaCO3) Sample ID mb-2 Client ID: PBW Batch ID: R15709 RunNo: SampType: MBLK Analysis Date: 12/23/2013 TestCode: SM2320B: Alkalinity SeqNo: CaCO3 Total Alkalinity (as CaCO3) 20 Sample ID lcs-2 Client ID: LCSW Batch ID: R15709 RunNo: SampType: LCS Analysis Date: 12/23/2013 TestCode: SM2320B: Alkalinity SeqNo: CaCO3 Total Alkalinity (as CaCO3) Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 20 of 21
208 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A00 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: RunNo: /25/2013 SampType: MBLK Analysis Date: 12/27/2013 TestCode: SM2540C MOD: Total Dissolved Solids SeqNo: Total Dissolved Solids 20.0 Sample ID LCS Client ID: LCSW Batch ID: RunNo: /25/2013 SampType: LCS Analysis Date: 12/27/2013 TestCode: SM2540C MOD: Total Dissolved Solids SeqNo: Total Dissolved Solids Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 21 of 21
209
210
211 JSAI Laboratory Results Sample Date (Lab Report Date , Report 2 of 2) JOHN SHOMAKER & ASSOCIATES, INC. WATER-RESOURCE A ENVIRONMENTAL CONSULTANTS
212 Hall Environmental Analysis Laboratory 4901 Hawkins NE Albuquerque, NM TEL: FAX: Website: January 17, 2014 Joshua Rosenblatt City of Las Cruces PO Box Las Cruces, NM TEL: (575) FAX (575) RE: City Of Las Cruces Foothills Lanfdill Monitoring Wells OrderNo.: 1312A22 Dear Joshua Rosenblatt: Hall Environmental Analysis Laboratory received 3 sample(s) on 12/20/2013 for the analyses presented in the following report. This report is a revised report and it replaces the original report issued January 13, These were analyzed according to EPA procedures or equivalent. To access our accredited tests please go to or the state specific web sites. See the sample checklist and/or the Chain of Custody for information regarding the sample receipt temperature and preservation. Data qualifiers or a narrative will be provided if the sample analysis or analytical quality control parameters require a flag. All samples are reported as received unless otherwise indicated. Please don't hesitate to contact HEAL for any additional information or clarifications. Sincerely, Andy Freeman Laboratory Manager 4901 Hawkins NE Albuquerque, NM 87109
213 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A22 Date Reported: 1/17/2014 Client Sample ID: MW-3 Collection Date: 12/19/ :19:00 AM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 H µg/l 1 1/16/ :34:00 AM ,2-Dibromoethane H µg/l 1 1/16/ :34:00 AM EPA METHOD 300.0: ANIONS Chloride Sulfate Nitrate+Nitrite as N EPA METHOD 200.7: METALS Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc EPA 200.8: METALS Antimony Arsenic Lead Selenium Thallium EPA METHOD 8260B: VOLATILES, TABLE I Benzene Toluene Ethylbenzene Methyl tert-butyl ether (MTBE) 1,2-Dichloroethane (EDC) 1,2-Dibromoethane (EDB) Acetone Analyst: JRR mg/l 1 12/20/2013 8:50:44 PM R mg/l 1 12/20/2013 8:50:44 PM R mg/l 5 12/28/2013 1:09:58 AM R15794 Analyst: ELS mg/l 1 12/27/2013 1:31:29 PM R mg/l mg/l 1 12/27/2013 1:31:29 PM 12/27/2013 1:31:29 PM R15768 R mg/l 1 12/30/2013 1:56:55 PM R mg/l mg/l 1 12/27/2013 1:31:29 PM 12/27/2013 1:31:29 PM R15768 R mg/l 1 12/27/2013 1:31:29 PM R mg/l 1 12/30/2013 1:56:55 PM R mg/l 1 12/30/2013 1:56:55 PM R mg/l mg/l 1 12/27/2013 1:31:29 PM 12/27/2013 1:31:29 PM R15768 R mg/l 1 12/30/2013 1:56:55 PM R mg/l 1 12/27/2013 1:31:29 PM R mg/l 1 12/30/2013 1:56:55 PM R mg/l 1 12/27/2013 1:31:29 PM R mg/l 1 12/27/2013 1:31:29 PM R mg/l 1 1/6/2014 4:36:40 PM Analyst: DBD R mg/l 1 1/6/2014 4:36:40 PM R mg/l 1 1/6/2014 4:36:40 PM R mg/l mg/l µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l 1 1/8/2014 3:11:11 PM 1/6/2014 4:36:40 PM R15963 R15909 Analyst: DJF 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. R15681 R15681 R15681 R15681 R15681 R15681 R15681 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 1 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
214 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A22 Date Reported: 1/17/2014 Client Sample ID: MW-3 Collection Date: 12/19/ :19:00 AM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Analyst: DJF Bromodichloromethane Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene 1,2-Dibromo-3-chloropropane Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane 2-Hexanone 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) trans-1,2-dce trans-1,3-dichloropropene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl chloride Xylenes, Total Acrylonitrile Bromochloromethane 1.0 µg/l µg/l µg/l 1 10 µg/l 1 10 µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l 1 10 µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l µg/l 1 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 R15681 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 2 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
215 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A22 Date Reported: 1/17/2014 Client Sample ID: MW-3 Collection Date: 12/19/ :19:00 AM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Iodomethane trans-1,4-dichloro-2-butene Vinyl acetate Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d4 Surr: Toluene-d8 Surr: 4-Bromofluorobenzene TOTAL PHENOLICS BY SW µg/l 1 10 µg/l 1 10 µg/l 1 Analyst: DJF 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM 12/22/2013 9:11:04 PM R15681 R15681 R %REC 1 12/22/2013 9:11:04 PM R %REC 1 12/22/2013 9:11:04 PM R %REC 1 12/22/2013 9:11:04 PM R %REC 1 12/22/2013 9:11:04 PM R15681 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 12/23/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH 1.0 mg/l 1 Analyst: JDC 12/24/2013 1:38:03 AM R15700 Analyst: SRM µmhos/cm 1 12/23/2013 4:31:58 PM R mg/l 1 Analyst: TMG 12/30/2013 8:45:00 AM R15792 Analyst: SRM ph H ph units 1 12/23/2013 4:31:58 PM R15709 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: SRM mg/l CaCO3 1 12/23/2013 4:31:58 PM R mg/l CaCO3 1 12/23/2013 4:31:58 PM R mg/l CaCO3 1 12/23/2013 4:31:58 PM R15709 Analyst: KS mg/l 1 12/27/ :29:00 AM Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 3 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
216 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A22 Date Reported: 1/17/2014 Client Sample ID: MW-4 Collection Date: 12/19/ :05:00 PM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 H µg/l 1 1/16/ :15:45 PM ,2-Dibromoethane H µg/l 1 1/16/ :15:45 PM EPA METHOD 300.0: ANIONS Chloride Sulfate Nitrate+Nitrite as N EPA METHOD 200.7: METALS Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc EPA 200.8: METALS Antimony Arsenic Lead Selenium Thallium EPA METHOD 8260B: VOLATILES, TABLE I Benzene Toluene Ethylbenzene Methyl tert-butyl ether (MTBE) 1,2-Dichloroethane (EDC) 1,2-Dibromoethane (EDB) Acetone Analyst: JRR mg/l 1 12/20/2013 9:15:32 PM R mg/l 1 12/20/2013 9:15:32 PM R mg/l 5 12/28/2013 1:22:22 AM R15794 Analyst: ELS mg/l 1 12/27/2013 1:34:57 PM R mg/l mg/l 1 12/27/2013 1:34:57 PM 12/27/2013 1:34:57 PM R15768 R mg/l 5 12/30/2013 2:00:32 PM R mg/l mg/l 1 12/27/2013 1:34:57 PM 12/27/2013 1:34:57 PM R15768 R mg/l 1 12/27/2013 1:34:57 PM R mg/l 1 12/30/2013 1:58:43 PM R mg/l 1 12/30/2013 1:58:43 PM R mg/l 1 12/27/2013 1:34:57 PM R mg/l 1 12/27/2013 1:34:57 PM R mg/l 1 12/30/2013 1:58:43 PM R mg/l 1 12/27/2013 1:34:57 PM R mg/l 1 12/30/2013 1:58:43 PM R mg/l 1 12/27/2013 1:34:57 PM R mg/l 1 12/27/2013 1:34:57 PM R mg/l mg/l 1 1/6/2014 4:41:11 PM 1/6/2014 4:41:11 PM Analyst: DBD R15909 R mg/l 1 1/6/2014 4:41:11 PM R mg/l mg/l µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l 1 1/8/2014 3:13:51 PM 1/6/2014 4:41:11 PM R15963 R15909 Analyst: DJF 12/22/2013 9:42:45 PM 12/22/2013 9:42:45 PM 12/22/2013 9:42:45 PM 12/22/2013 9:42:45 PM 12/22/2013 9:42:45 PM 12/22/2013 9:42:45 PM 12/22/2013 9:42:45 PM Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. R15681 R15681 R15681 R15681 R15681 R15681 R15681 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 4 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
217 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A22 Date Reported: 1/17/2014 Client Sample ID: MW-4 Collection Date: 12/19/ :05:00 PM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Bromodichloromethane Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene 1,2-Dibromo-3-chloropropane Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane 2-Hexanone 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) trans-1,2-dce trans-1,3-dichloropropene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl chloride Xylenes, Total Acrylonitrile Bromochloromethane Analyst: DJF 1.0 µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/23/ :14:35 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R µg/l 1 12/22/2013 9:42:45 PM R15681 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 5 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
218 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A22 Date Reported: 1/17/2014 Client Sample ID: MW-4 Collection Date: 12/19/ :05:00 PM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Iodomethane trans-1,4-dichloro-2-butene Vinyl acetate Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d4 Surr: Toluene-d8 Surr: 4-Bromofluorobenzene TOTAL PHENOLICS BY SW µg/l 1 10 µg/l 1 10 µg/l 1 Analyst: DJF 12/22/2013 9:42:45 PM 12/22/2013 9:42:45 PM 12/22/2013 9:42:45 PM R15681 R15681 R %REC 1 12/22/2013 9:42:45 PM R %REC 1 12/22/2013 9:42:45 PM R %REC 1 12/22/2013 9:42:45 PM R %REC 1 12/22/2013 9:42:45 PM R15681 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 12/23/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH 1.0 mg/l 1 Analyst: JDC 12/24/2013 1:54:20 AM R15700 Analyst: SRM µmhos/cm 1 12/23/2013 5:00:20 PM R mg/l 1 Analyst: TMG 12/30/2013 8:45:00 AM R15792 Analyst: SRM ph H ph units 1 12/23/2013 5:00:20 PM R15709 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: SRM mg/l CaCO3 1 12/23/2013 5:00:20 PM R mg/l CaCO3 1 12/23/2013 5:00:20 PM R mg/l CaCO3 1 12/23/2013 5:00:20 PM R15709 Analyst: KS mg/l 1 12/27/ :29:00 AM Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 6 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
219 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A22 Date Reported: 1/17/2014 Client Sample ID: MW-7 Collection Date: 12/19/2013 1:24:00 PM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 504.1: EDB/DBCP Analyst: LRW 1,2-Dibromo-3-chloropropane 0.10 H µg/l 1 1/16/ :29:40 PM ,2-Dibromoethane H µg/l 1 1/16/ :29:40 PM EPA METHOD 300.0: ANIONS Chloride Sulfate Nitrate+Nitrite as N EPA METHOD 200.7: METALS Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Potassium Silver Sodium Vanadium Zinc EPA 200.8: METALS Antimony Arsenic Lead Selenium Thallium EPA METHOD 8260B: VOLATILES, TABLE I Benzene Toluene Ethylbenzene Methyl tert-butyl ether (MTBE) 1,2-Dichloroethane (EDC) 1,2-Dibromoethane (EDB) Acetone Analyst: JRR mg/l 20 12/20/2013 9:52:46 PM R mg/l 20 12/20/2013 9:52:46 PM R mg/l 5 12/28/2013 1:34:46 AM R15794 Analyst: ELS mg/l 1 12/27/2013 1:45:11 PM R mg/l mg/l 1 12/27/2013 1:45:11 PM 12/27/2013 1:45:11 PM R15768 R mg/l 1 12/30/2013 2:02:19 PM R mg/l mg/l mg/l mg/l 1 12/27/2013 1:45:11 PM 12/27/2013 1:45:11 PM 12/27/2013 1:45:11 PM 12/30/2013 2:02:19 PM R15768 R15768 R15768 R mg/l 1 12/30/2013 2:02:19 PM R mg/l 1 12/27/2013 1:45:11 PM R mg/l 1 12/27/2013 1:45:11 PM R mg/l 1 12/30/2013 2:02:19 PM R mg/l 1 12/27/2013 1:45:11 PM R mg/l 1 12/30/2013 2:02:19 PM R mg/l mg/l mg/l mg/l mg/l 1 12/27/2013 1:45:11 PM 12/27/2013 1:45:11 PM 1/6/2014 4:45:41 PM 1/6/2014 4:45:41 PM 1/6/2014 4:45:41 PM R15768 R15768 Analyst: DBD R15909 R15909 R mg/l 1 1/8/2014 3:16:30 PM R mg/l µg/l µg/l µg/l µg/l µg/l µg/l 1 10 µg/l 1 1/6/2014 4:45:41 PM R15909 Analyst: DJF 12/22/ :14:23 PM R /22/ :14:23 PM R /22/ :14:23 PM R /22/ :14:23 PM R /22/ :14:23 PM R /22/ :14:23 PM R /22/ :14:23 PM R15681 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 7 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
220 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A22 Date Reported: 1/17/2014 Client Sample ID: MW-7 Collection Date: 12/19/2013 1:24:00 PM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Bromodichloromethane Bromoform Bromomethane 2-Butanone Carbon disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dce cis-1,3-dichloropropene 1,2-Dibromo-3-chloropropane Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane 2-Hexanone 4-Methyl-2-pentanone Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) trans-1,2-dce trans-1,3-dichloropropene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl chloride Xylenes, Total Acrylonitrile Bromochloromethane Analyst: DJF 1.0 µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/23/ :43:19 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R µg/l 1 12/22/ :14:23 PM R15681 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 8 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
221 Hall Environmental Analysis Laboratory, Inc. CLIENT: City of Las Cruces Project: City Of Las Cruces Foothills Lanfdill Mo Lab ID: 1312A Matrix: AQUEOUS Analytical Report Lab Order 1312A22 Date Reported: 1/17/2014 Client Sample ID: MW-7 Collection Date: 12/19/2013 1:24:00 PM Received Date: 12/20/ :30:00 AM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 8260B: VOLATILES, TABLE I Iodomethane trans-1,4-dichloro-2-butene Vinyl acetate Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d4 Surr: Toluene-d8 Surr: 4-Bromofluorobenzene TOTAL PHENOLICS BY SW µg/l 1 10 µg/l 1 10 µg/l 1 Analyst: DJF 12/22/ :14:23 PM R /22/ :14:23 PM R /22/ :14:23 PM R %REC 1 12/22/ :14:23 PM R %REC 1 12/22/ :14:23 PM R %REC 1 12/22/ :14:23 PM R %REC 1 12/22/ :14:23 PM R15681 Analyst: SCC Phenolics, Total Recoverable 2.5 µg/l 1 12/23/ EPA METHOD 9060 TOC Total Organic Carbon SM2510B: SPECIFIC COUCTANCE Conductivity SM 4500 NH3: AMMONIA Nitrogen, Ammonia SM4500-H+B: PH 1.0 mg/l 1 Analyst: JDC 12/24/2013 2:10:37 AM R15700 Analyst: SRM µmhos/cm 1 12/23/2013 5:17:28 PM R mg/l 1 Analyst: TMG 12/30/2013 8:45:00 AM R15792 Analyst: SRM ph H ph units 1 12/23/2013 5:17:28 PM R15709 SM2320B: ALKALINITY Bicarbonate (As CaCO3) Carbonate (As CaCO3) Total Alkalinity (as CaCO3) SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids Analyst: SRM mg/l CaCO3 1 12/23/2013 5:17:28 PM R mg/l CaCO3 1 12/23/2013 5:17:28 PM R mg/l CaCO3 1 12/23/2013 5:17:28 PM R15709 Analyst: KS mg/l 1 12/27/ :29:00 AM Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit Page 9 of 28 O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits
222 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: R15768 RunNo: SampType: MBLK Analysis Date: 12/27/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Chromium Cobalt Copper Manganese Nickel Silver Vanadium Zinc Sample ID LCS Client ID: LCSW Batch ID: R15768 RunNo: SampType: LCS Analysis Date: 12/27/2013 TestCode: EPA Method 200.7: Metals SeqNo: Barium Beryllium Cadmium Chromium Cobalt Copper Manganese Nickel Silver Vanadium Zinc Sample ID MB Client ID: PBW Batch ID: R15805 RunNo: SampType: MBLK Analysis Date: 12/30/2013 TestCode: EPA Method 200.7: Metals SeqNo: Calcium 1.0 Iron Magnesium 1.0 Potassium 1.0 Sodium 1.0 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 10 of 28
223 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID LCS Client ID: LCSW Batch ID: R15805 RunNo: SampType: LCS Analysis Date: 12/30/2013 TestCode: EPA Method 200.7: Metals SeqNo: Calcium Iron Magnesium Potassium Sodium Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 11 of 28
224 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID LCS Client ID: LCSW Batch ID: R15909 RunNo: SampType: LCS Analysis Date: 1/6/2014 TestCode: EPA 200.8: Metals SeqNo: Antimony Arsenic Lead Thallium Sample ID LCS Client ID: LCSW Batch ID: R15909 RunNo: SampType: LCS Analysis Date: 1/6/2014 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Sample ID MB Client ID: PBW Batch ID: R15909 RunNo: SampType: MBLK Analysis Date: 1/6/2014 TestCode: EPA 200.8: Metals SeqNo: Antimony Arsenic Lead Thallium Sample ID MB Client ID: PBW Batch ID: R15909 RunNo: SampType: MBLK Analysis Date: 1/6/2014 TestCode: EPA 200.8: Metals SeqNo: Arsenic Lead Sample ID LCS Client ID: LCSW Batch ID: R15963 RunNo: SampType: LCS Analysis Date: 1/8/2014 TestCode: EPA 200.8: Metals SeqNo: Selenium Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 12 of 28
225 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: R15963 RunNo: SampType: MBLK Analysis Date: 1/8/2014 TestCode: EPA 200.8: Metals SeqNo: Selenium Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 13 of 28
226 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID A5 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_5 Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Sulfate Sample ID MB Client ID: PBW Batch ID: R15728 RunNo: SampType: MBLK Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride 0.50 Sulfate 0.50 Sample ID LCS Client ID: LCSW Batch ID: R15728 RunNo: SampType: LCS Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Sulfate Sample ID A6 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_6 Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Sulfate Sample ID A4 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_4 Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Sulfate Sample ID A5 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_5 Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 14 of 28
227 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID A5 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_5 Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Sulfate Sample ID A6 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_6 Analysis Date: 12/20/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Sulfate Sample ID A4 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_4 Analysis Date: 12/21/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Sulfate Sample ID A5 Client ID: BatchQC Batch ID: R15728 RunNo: SampType: CCV_5 Analysis Date: 12/21/2013 TestCode: EPA Method 300.0: Anions SeqNo: Chloride Sulfate Sample ID A6 Client ID: BatchQC Batch ID: R15794 RunNo: SampType: CCV_6 Analysis Date: 12/27/2013 TestCode: EPA Method 300.0: Anions SeqNo: Nitrate+Nitrite as N Sample ID MB Client ID: PBW Batch ID: R15794 RunNo: SampType: MBLK Analysis Date: 12/27/2013 TestCode: EPA Method 300.0: Anions SeqNo: Nitrate+Nitrite as N 0.20 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 15 of 28
228 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID LCS Client ID: LCSW Batch ID: R15794 RunNo: SampType: LCS Analysis Date: 12/27/2013 TestCode: EPA Method 300.0: Anions SeqNo: Nitrate+Nitrite as N Sample ID A4 Client ID: BatchQC Batch ID: R15794 RunNo: SampType: CCV_4 Analysis Date: 12/27/2013 TestCode: EPA Method 300.0: Anions SeqNo: Nitrate+Nitrite as N Sample ID A5 Client ID: BatchQC Batch ID: R15794 RunNo: SampType: CCV_5 Analysis Date: 12/27/2013 TestCode: EPA Method 300.0: Anions SeqNo: Nitrate+Nitrite as N Sample ID A4 Client ID: BatchQC Batch ID: R15794 RunNo: SampType: CCV_4 Analysis Date: 12/27/2013 TestCode: EPA Method 300.0: Anions SeqNo: Nitrate+Nitrite as N Sample ID A5 Client ID: BatchQC Batch ID: R15794 RunNo: SampType: CCV_5 Analysis Date: 12/27/2013 TestCode: EPA Method 300.0: Anions SeqNo: Nitrate+Nitrite as N Sample ID A4 Client ID: BatchQC Batch ID: R15794 RunNo: SampType: CCV_4 Analysis Date: 12/28/2013 TestCode: EPA Method 300.0: Anions SeqNo: Nitrate+Nitrite as N Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 16 of 28
229 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID A5 Client ID: BatchQC Batch ID: R15794 RunNo: SampType: CCV_5 Analysis Date: 12/28/2013 TestCode: EPA Method 300.0: Anions SeqNo: Nitrate+Nitrite as N Sample ID A4 Client ID: BatchQC Batch ID: R15794 RunNo: SampType: CCV_4 Analysis Date: 12/28/2013 TestCode: EPA Method 300.0: Anions SeqNo: Nitrate+Nitrite as N Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 17 of 28
230 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: RunNo: /16/2014 SampType: MBLK Analysis Date: 1/16/2014 TestCode: EPA Method 504.1: EDB/DBCP SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane ,2-Dibromoethane Sample ID LCS Client ID: LCSW Batch ID: RunNo: /16/2014 SampType: LCS Analysis Date: 1/16/2014 TestCode: EPA Method 504.1: EDB/DBCP SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane ,2-Dibromoethane Sample ID 1312A22-001AMS Client ID: MW-3 Batch ID: RunNo: /16/2014 SampType: MS Analysis Date: 1/16/2014 TestCode: EPA Method 504.1: EDB/DBCP SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane ,2-Dibromoethane Sample ID 1312A22-001AMSD Client ID: MW-3 Batch ID: RunNo: /16/2014 SampType: MSD Analysis Date: 1/16/2014 TestCode: EPA Method 504.1: EDB/DBCP SeqNo: Units: µg/l 1,2-Dibromo-3-chloropropane ,2-Dibromoethane Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 18 of 28
231 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID 5ml rb Client ID: PBW Batch ID: R15681 RunNo: SampType: MBLK Analysis Date: 12/22/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l Benzene 1.0 Toluene 1.0 Ethylbenzene 1.0 Methyl tert-butyl ether (MTBE) 1.0 1,2-Dichloroethane (EDC) 1.0 1,2-Dibromoethane (EDB) 1.0 Acetone 10 Bromodichloromethane 1.0 Bromoform 1.0 Bromomethane Butanone 10 Carbon disulfide 10 Carbon Tetrachloride 1.0 Chlorobenzene 1.0 Chloroethane 2.0 Chloroform 1.0 Chloromethane 1.0 cis-1,2-dce 1.0 cis-1,3-dichloropropene 1.0 1,2-Dibromo-3-chloropropane 2.0 Dibromochloromethane 1.0 Dibromomethane 1.0 1,2-Dichlorobenzene 1.0 1,4-Dichlorobenzene 1.0 1,1-Dichloroethane 1.0 1,1-Dichloroethene 1.0 1,2-Dichloropropane Hexanone 10 4-Methyl-2-pentanone 10 Methylene Chloride 1.0 Styrene 1.0 1,1,1,2-Tetrachloroethane 1.0 1,1,2,2-Tetrachloroethane 1.0 Tetrachloroethene (PCE) 0.50 trans-1,2-dce 1.0 trans-1,3-dichloropropene 1.0 1,1,1-Trichloroethane 1.0 1,1,2-Trichloroethane 1.0 Trichloroethene (TCE) 1.0 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 19 of 28
232 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID 5ml rb Client ID: PBW Batch ID: R15681 RunNo: SampType: MBLK Analysis Date: 12/22/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l Trichlorofluoromethane 1.0 1,2,3-Trichloropropane 1.0 Vinyl chloride 0.40 Xylenes, Total 2.0 Acrylonitrile 10 Bromochloromethane 2.0 Iodomethane 10 trans-1,4-dichloro-2-butene 10 Vinyl acetate 10 Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d Surr: Toluene-d Surr: 4-Bromofluorobenzene Sample ID 100nglcs,200ngacac Client ID: LCSW Batch ID: R15681 RunNo: SampType: LCS Analysis Date: 12/22/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: µg/l Benzene Toluene Chlorobenzene ,1-Dichloroethene Trichloroethene (TCE) Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d Surr: Toluene-d Surr: 4-Bromofluorobenzene Sample ID 5mL rb Client ID: PBW Batch ID: R15701 RunNo: SampType: MBLK Analysis Date: 12/23/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: %REC Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d Surr: Toluene-d Surr: 4-Bromofluorobenzene Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 20 of 28
233 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID 100ng lcs Client ID: LCSW Batch ID: R15701 RunNo: SampType: LCS Analysis Date: 12/23/2013 TestCode: EPA Method 8260B: Volatiles, Table I SeqNo: Units: %REC Surr: Dibromofluoromethane Surr: 1,2-Dichloroethane-d Surr: Toluene-d Surr: 4-Bromofluorobenzene Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 21 of 28
234 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: R15700 RunNo: SampType: MBLK Analysis Date: 12/23/2013 TestCode: EPA Method 9060 TOC SeqNo: Total Organic Carbon 1.0 Sample ID LCS ST Client ID: LCSW Batch ID: R15700 RunNo: SampType: LCS Analysis Date: 12/23/2013 TestCode: EPA Method 9060 TOC SeqNo: Total Organic Carbon Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 22 of 28
235 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: RunNo: /23/2013 SampType: MBLK TestCode: Total Phenolics by SW Analysis Date: 12/23/2013 SeqNo: Units: µg/l Phenolics, Total Recoverable 2.5 Sample ID LCS Client ID: LCSW Batch ID: RunNo: /23/2013 SampType: LCS TestCode: Total Phenolics by SW Analysis Date: 12/23/2013 SeqNo: Units: µg/l Phenolics, Total Recoverable Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 23 of 28
236 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID 1312A22-001Ddup Client ID: MW-3 Batch ID: R15709 RunNo: SampType: DUP Analysis Date: 12/23/2013 TestCode: SM2510B: Specific Conductance SeqNo: Units: µmhos/cm Conductivity Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 24 of 28
237 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: R15792 RunNo: SampType: MBLK Analysis Date: 12/30/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia 1.0 Sample ID LCS Client ID: LCSW Batch ID: R15792 RunNo: SampType: LCS Analysis Date: 12/30/2013 TestCode: SM 4500 NH3: Ammonia SeqNo: Nitrogen, Ammonia Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 25 of 28
238 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID 1312A22-001Ddup SampType: DUP TestCode: SM4500-H+B: ph Client ID: MW-3 Batch ID: R15709 RunNo: Analysis Date: 12/23/2013 SeqNo: Units: ph units ph H Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 26 of 28
239 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID mb-1 Client ID: PBW Batch ID: R15709 RunNo: SampType: MBLK Analysis Date: 12/23/2013 TestCode: SM2320B: Alkalinity SeqNo: CaCO3 Total Alkalinity (as CaCO3) 20 Sample ID lcs-1 Client ID: LCSW Batch ID: R15709 RunNo: SampType: LCS Analysis Date: 12/23/2013 TestCode: SM2320B: Alkalinity SeqNo: CaCO3 Total Alkalinity (as CaCO3) Sample ID mb-2 Client ID: PBW Batch ID: R15709 RunNo: SampType: MBLK Analysis Date: 12/23/2013 TestCode: SM2320B: Alkalinity SeqNo: CaCO3 Total Alkalinity (as CaCO3) 20 Sample ID lcs-2 Client ID: LCSW Batch ID: R15709 RunNo: SampType: LCS Analysis Date: 12/23/2013 TestCode: SM2320B: Alkalinity SeqNo: CaCO3 Total Alkalinity (as CaCO3) Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 27 of 28
240 QC SUMMARY REPORT Hall Environmental Analysis Laboratory, Inc. WO#: 1312A22 17-Jan-14 Client: Project: City of Las Cruces City Of Las Cruces Foothills Lanfdill Monitorin Sample ID MB Client ID: PBW Batch ID: RunNo: /25/2013 SampType: MBLK Analysis Date: 12/27/2013 TestCode: SM2540C MOD: Total Dissolved Solids SeqNo: Total Dissolved Solids 20.0 Sample ID LCS Client ID: LCSW Batch ID: RunNo: /25/2013 SampType: LCS Analysis Date: 12/27/2013 TestCode: SM2540C MOD: Total Dissolved Solids SeqNo: Total Dissolved Solids Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits Not Detected at the Reporting Limit O RSD is greater than RSDlimit P Sample ph greater than 2 for VOA and TOC only. R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted recovery limits Page 28 of 28
241
242
Spring 2016 Summary Report Residential Drinking Water Well Sampling LRI Landfill
Spring 2016 Summary Report Residential Drinking Water Well Sampling LRI Landfill Contents 1. Summary 2. Table 1 Spring 2016 Water Quality Results 3. Table 2 Spring 2016 Water Quality VOC Results 4. Table
More informationSpring 2017 Summary Report Residential Drinking Water Well Sampling LRI Landfill
Spring 2017 Summary Report Residential Drinking Water Well Sampling LRI Landfill Contents 1. Summary 2. Table 1 Spring 2017 Water Quality Results 3. Table 2 Spring 2017 Water Quality VOC Results 4. Table
More informationINDUSTRIAL DRYCLEANER WOES, VERNON, CALIFORNIA Kevin Green R.G., SCS ENGINEERS Darren Ness, R.E.A., SCS ENGINEERS Thomas Dong, R.E.A.
BACKGROUND INDUSTRIAL DRYCLEANER WOES, VERNON, CALIFORNIA Kevin Green R.G., SCS ENGINEERS Darren Ness, R.E.A., SCS ENGINEERS Thomas Dong, R.E.A., SCS ENGINEERS A fire at a former industrial dry cleaning
More informationKaren O. Zwolak Tampa Electric Company 702 N. Franklin Street Tampa, FL
5012 W. Lemon Street Tampa, Florida 33609 Ph 813.944.3464 Fax 813.944.4959 December 31, 2015 (via email) Karen O. Zwolak Tampa Electric Company 702 N. Franklin Street Tampa, FL 33602 kozwolak@tecoenergy.com
More informationFALL 2017 SEMI-ANNUAL WATER QUALITY MONITORING REPORT FOR THE HALIFAX MUNICIPAL LANDFILL
FALL 207 SEMI-ANNUAL WATER QUALITY MONITORING REPORT FOR THE HALIFAX MUNICIPAL LAFILL December 2, 207 VTDEC Project NS95-065 Prepared for: Town of Halifax P.O. Box 45 Halifax, Vermont 05358 Prepared by:
More informationEngineering and Environmental Geophysics with terratem
Engineering and Environmental Geophysics with terratem (1) Geophysical Consultant Alpha Geosciences Pty. Ltd. Sydney NSW 2210 Australia Email: rhenderson@terratem.com Roger Henderson (1) ABSTRACT terratem
More informationWM2012 Conference, February 26 March 1, 2012, Phoenix, Arizona, USA. Groundwater Monitoring Report Generation Tools 12005
Groundwater Monitoring Report Generation Tools 12005 Natalie López Savannah River Nuclear Solutions LLC, Aiken, South Carolina, 29808 ABSTRACT Compliance with National and State environmental regulations
More informationGroundwater in Hydrologic Cycle
Groundwater in Hydrologic Cycle Types of Terrestrial Water Surface Water Soil Moisture Ground water Pores Full of Combination of Air and Water Unsaturated Zone / Zone of Aeration / Vadose (Soil Water)
More informationSILENCING THE NOISE: NEW TECHNOLOGY TO OBTAIN TIME- INTEGRATED AVERAGE GROUNDWATER CONCENTRATION OVER MONTHS
SILENCING THE NOISE: NEW TECHNOLOGY TO OBTAIN TIME- INTEGRATED AVERAGE GROUNDWATER CONCENTRATION OVER MONTHS GC 3 Thomas McHugh, Charles Newell, Lisa Molofsky, Julia Small, Kaitlin Moran GSI ENVIRONMENTAL
More informationCreating an Environmental Database to Facilitate Groundwater Contamination Analysis. Jimmy Bowden Daniel B. Stephens and Associates
Creating an Environmental Database to Facilitate Groundwater Contamination Analysis Jimmy Bowden Daniel B. Stephens and Associates Abstract Assigning responsibility for the cleanup of groundwater contamination
More informationState Water Survey Division
THE CLIMATE OF ILLINOIS Lying midway between the Continental Divide and the Atlantic Ocean, and 500 miles north of the Gulf of Mexico, Illinois has a climate labeled as continental. Cold winters, and warm,
More informationCity Of London Environmental & Engineering Services Department Wastewater Treatment Operations
City Of London Environmental & Engineering Services Department Wastewater Treatment Operations Greenway Pollution Control Centre 2014 Annual Report February 2015 Page 1 of 87 Summary This annual report
More informationBiosparging and SVE Using Vertical and Directionally-Drilled Wells to Address LNAPL and Petroleum Constituents in a Residential Development
Biosparging and SVE Using Vertical and Directionally-Drilled Wells to Address LNAPL and Petroleum Constituents in a Residential Development Mike Skeean, P.E. ADEM Groundwater Conference June 9, 2015 Agenda
More informationUTILITY REPORT FOR THORNTON SELF STORAGE THORNTON, COLORADO
UTILITY REPORT FOR THORNTON SELF STORAGE THORNTON, COLORADO Prepared by: Bowman Consulting 63 Park Point Dr. Suite 1 Golden, CO 841 (33)-81-29 June 29, 215 Revised August 14, 215 CERTIFICATE SHEET DCB
More informationSurveys and Maps for Drainage Design
Surveys and Maps for Drainage Design SURVEY TYPES BENCH LEVEL Survey Used to determine the elevation of a point (1-D) PROFILE Survey Used to determine the elevations of a line (2-D) TOPOGRAPHIC Survey
More information1.0 INTRODUCTION. Subject: Peaking Analysis
Memo Date: Friday, Project: NorthWestern Energy Operations Modeling of Hydros To: John Vandaveer, NorthWestern Energy From: Rick Miller, HDR Subject: Peaking Analysis 1.0 INTRODUCTION The goal of this
More informationBadger. United. Ammunition Plant. Prepared for: Badger Army
214 Monitoring Well Optimization lan Deterrent Burning Ground and Central lumes Badger rmy mmunition lant repared for: United tates Departmentt of the rmy Badger rmy mmunition lant 756 U.. Highway 12 North
More informationSPRING 2017 SEMI-ANNUAL WATER QUALITY MONITORING REPORT FOR THE HALIFAX MUNICIPAL LANDFILL
SPRING 207 SEMI-ANNUAL WATER QUALITY MONITORING REPORT FOR THE HALIFAX MUNICIPAL LAFILL July 3, 207 VTDEC Project NS95-065 Prepared for: Town of Halifax P.O. Box 45 Halifax, Vermont 05358 Prepared by:
More informationDEQ Guidance on Recordkeeping and Reporting
Regulatory Reference: OAC 252:515-19-40 Applicability. All solid waste disposal facilities. Purpose. To provide guidance on the records to be maintained in the facility operating record and submitted to
More information2. AREAL PHOTOGRAPHS, SATELLITE IMAGES, & TOPOGRAPHIC MAPS
LAST NAME (ALL IN CAPS): FIRST NAME: 2. AREAL PHOTOGRAPHS, SATELLITE IMAGES, & TOPOGRAPHIC MAPS Instructions: Refer to Exercise 3 in your Lab Manual on pages 47-64 to answer the questions in this work
More informationApplicant Type (Conditional Use Permit, Variance, Tract Map, etc.): Applicant: Address: Phone(s): Fax:
ENVIRONMENTAL QUESTIONNAIRE City of Twentynine Palms Community Development Department 6136 Adobe Road Twentynine Palms, CA 92277 (760) 367-6799 Fax (760) 367-5400 29palms.org : Please complete each statement
More informationv Prerequisite Tutorials Required Components Time
v. 10.0 GMS 10.0 Tutorial MODFLOW Stochastic Modeling, Parameter Randomization Run MODFLOW in Stochastic (Monte Carlo) Mode by Randomly Varying Parameters Objectives Learn how to develop a stochastic (Monte
More informationLocated at Located in the Traffic Signing Category.
Located at https://mdotjboss.state.mi.us/tssd/tssdhome.htm# Located in the Traffic Signing Category. August 29 th, 2018: The following updates were made to the web site. SIGN-100-G: Dated 05/24/18 - The
More informationPREMISES POLLUTION LIABILITY
Beacon Hill Associates, Inc PO Box 1532 Charlottesville, VA 22902 Toll Free: 800) 596-2156 Fax: 434) 979-8964 info@b-h-a.com PREMISES POLLUTION LIABILITY APPLICATION PREMISES POLLUTION LIABILITY COVERAGE
More informationv MODFLOW Stochastic Modeling, Parameter Randomization GMS 10.3 Tutorial
v. 10.3 GMS 10.3 Tutorial MODFLOW Stochastic Modeling, Parameter Randomization Run MODFLOW in Stochastic (Monte Carlo) Mode by Randomly Varying Parameters Objectives Learn how to develop a stochastic (Monte
More informationMGO Tutorial - Dewatering Scenario
MGO Tutorial - Dewatering Scenario Introduction 1.0.1 Background Pumping well optimization technology is used to determine the ideal pumping well locations, and ideal pumping rates at these locations,
More information2045 DEMOGRAPHIC FORECAST SURFACE TRANSPORTATION TECHNICAL COMMITTEE APRIL 28, 2017
2045 DEMOGRAPHIC FORECAST SURFACE TRANSPORTATION TECHNICAL COMMITTEE APRIL 28, 2017 BACKGROUND The demographic forecasts provide a common base for regional planning and resource allocations. The forecasts
More informationEBR Application for Review Request to Review Environmental Compliance Approval Cruickshank Construction Limited Elginburg Quarry, Kingston
EBR Application for Review Request to Review Environmental Compliance Approval Cruickshank Construction Limited Elginburg Quarry, Kingston Decision Summary EBRO File No.: 16EBR001.R Issue: The Ministry
More informationARLINGTON COUNTY, VIRGINIA
ARLINGTON COUNTY, VIRGINIA County Board Agenda Item Meeting of December 12, 2015 DATE: December 1, 2015 SUBJECT: SP-84-U-15-1 USE PERMIT ASSOCIATED WITH A SITE PLAN for a telecommunications facility; located
More informationScreen3 View. Contents. Page 1
Screen3 View Contents Introduction What is EPA's SCREEN3 Model? What is the Screen3 View Interface? Toollbar Buttons Preliminary Considerations Source Inputs Screen3 Options Running SCREEN3 Model Graphic
More informationOctober 2001 (June 2002 revision) Greenpoint Tittabawassee River Dioxin Study Area Phase I Sampling Study Report
October 2001 (June 2002 revision) Greenpoint Tittabawassee River Dioxin Study Area Phase I Sampling Study Report Summary Soil samples collected as part of a wetland mitigation project identified elevated
More informationKnight Piésold. Knight Piésold
Mount Polley Project Tailings Facility Summary February 26, 2007 Knight Piesold ref #: 101-01/18 1 Overview of Presentation General Information Project Background On-going Operations and Monitoring Test
More informationQuanta Resources Corporation Superfund Site, Operable Unit 1 (OU1) Edgewater, New Jersey Progress Report July 2015
CH2M BOS 18 Tremont Street Suite 700 Boston, MA 02108-2307 O +1 617.523.2002 F +1 617.723.9036 www.ch2m.com August 7, 2015 Mr. Richard Ho, RPM/OSC U.S. Environmental Protection Agency Region 2 Emergency
More informationMGO Tutorial - Dewatering Scenario
MGO Tutorial - Dewatering Scenario Introduction Pumping well optimization technology is used to determine the ideal pumping well locations, and ideal pumping rates at these locations, in order to minimize
More informationManage your environmental monitoring data with power, depth and ease
EQWin Software Inc. PO Box 75106 RPO White Rock Surrey BC V4A 0B1 Canada Tel: +1 (604) 669-5554 Fax: +1 (888) 620-7140 E-mail: support@eqwinsoftware.com www.eqwinsoftware.com EQWin 7 Manage your environmental
More informationSECTIONS II - VIII QUANTITY, FORM, AND FILING REQUIREMENTS APPLICATION FILING FEES NOTICE TO COMMUNITY ORGANIZATIONS NOTICE IN UTILITY BILLS
SECTIONS II - VIII QUANTITY, FORM, AND FILING REQUIREMENTS APPLICATION FILING FEES PROOF OF SERVICE NOTICE TO COMMUNITY ORGANIZATIONS PUBLIC NOTICE NOTICE IN UTILITY BILLS NOTICE OF OWNERS OF PROPERTY
More informationFebruary 11, Mr. Michael Cox Arkansas Egg, LLC Mill Road Summers, AR Compliance Inspection AFIN: , Permit No.
February 11, 2013 Mr. Michael Cox Arkansas Egg, LLC 24185 Mill Road Summers, AR 72769 Re: Compliance Inspection AFIN: 72-00198, Permit No.: 5164-W Dear Mr. Cox: On January 29, 2013, I performed a routine
More informationMapping Constituents Using FIELDS
Mapping Constituents Using FIELDS MAPPING CONSTITUENTS USING FIELDS FIELDS is a software system developed by the U.S. Environmental Protection Agency (EPA) to support sampling and remedial decision-making.
More informationINSTRUCTIONS FOR NJDEP ONLINE SITE INVESTIGATION REPORT SERVICE
New Jersey Department of Environmental Protection Site Remediation and Waste Management Program INSTRUCTIONS FOR NJDEP ONLINE SITE INVESTIGATION REPORT SERVICE Applicability Use these instructions when
More informationEnergy Engineering: Tools and Trends
Energy Engineering: Tools and Trends AEE Northeast Ohio Chapter Meeting March 27, 2008 1 Introduction Background and Experience Energy Engineer for Trane 20 years in HVAC Industry Equipment design and
More informationCITY OF VAUGHAN EXTRACT FROM COUNCIL MEETING MINUTES OF SEPTEMBER 25, 2012
CITY OF VAUGHAN EXTRACT FROM COUNCIL MEETING MINUTES OF SEPTEMBER 25, 2012 Item 23, Report No. 33, of the Committee of the Whole, which was adopted without amendment by the Council of the City of Vaughan
More informationNotice Basic Information Estimated Contract Value (USD) $400, (Not shown to suppliers) Reference Number Issuing Organization
Notice Basic Information Estimated Contract Value (USD) $400,000.00 (Not shown to suppliers) Reference Number 0000213543 Issuing Organization Colorado Mesa University Owner Organization Colorado Mesa University
More informationUnique Well Identifiers. General Description
Appendix 2 Unique Well Identifiers General Description The unique well identifier (UWI) is the standard well identification that was developed for the petroleum industry by the Geoscience Data Committee
More informationConsistent Measurement of Broadband Availability
Consistent Measurement of Broadband Availability By Advanced Analytical Consulting Group, Inc. September 2016 Abstract This paper provides several, consistent measures of broadband availability from 2009
More informationNew Jersey Department of Environmental Protection (NJDEP) Site Remediation Program INSTRUCTIONS FOR NJDEP ONLINE REMEDIAL INVESTIGATION REPORT SERVICE
New Jersey Department of Environmental Protection (NJDEP) Site Remediation Program INSTRUCTIONS FOR NJDEP ONLINE REMEDIAL INVESTIGATION REPORT SERVICE Applicability Use these instructions when submitting
More informationCDSN Universal Minimum Data Elements Physical/Chemical Data 2015
COLORADO WATER QUALITY MONITORING COUNCIL COLORADO DATA SHARING NETWORK P.O. Box 2058 Ridgway, CO 81432 970-258-0836 cdsn@coloradowater.org www.coloradowaterdata.org July 1, 2015 CDSN Universal Minimum
More informationENMAX Power Corporation
Decision 22769-D01-2017 Transmission Lines 138-1.80L and 138-1.81L September 15, 2017 Alberta Utilities Commission Decision 22769-D01-2017 Transmission Lines 138-1.80L and 138-1.81L Proceeding 22769 Application
More informationNATIONAL DEMOLITION ASSOCIATION PROJECT PRE-START SURVEY
NATIONAL DEMOLITION ASSOCIATION PROJECT PRE-START SURVEY PROJECT INFORMATION Project Name Project Number Project Location City Legal Description: Plat # State Zip Code County Client Client Address Contact(s)
More informationThe Agricultural Environmental Site Assessment (AgESA)
The Agricultural Environmental Site Assessment (AgESA) Guidance Document 14 The Minnesota Department of Agriculture (MDA) frequently receives questions about Phase I Environmental Site Assessments (ESAs)
More informationRe: April 24 to July 7, 2017 Dust Monitoring and Site Work Observations, Lots 12 and 13, Beverly Hills, California
October 12, 2017 Project No. 2016-158 Via Email David Yelton Deputy Building Official Department of Community Development - City of Beverly Hills 455 North Rexford Drive Beverly Hills, CA 90210 Re: April
More information10.1 BIBLIOGRAPHY Noise and Vibration Study Yard and
10 Bibliography 10.1 BIBLIOGRAPHY ATS Consulting, Noise and Vibration Study Yard and Shops Segment, March 31, 2006. ATS Consulting, Station Noise Mitigation and Acoustical Treatment Study, January 28,
More information8 Modeling Fractured Rock
8 Modeling Fractured Rock Groundwater flow and chemical transport models can help to characterize and remediate fractured rock sites at all scales. It is critical that any modeling be performed by modelers
More informationEmployee Job Title. APPENDIX H-5 Electronic Data
Employee Job Title APPENDIX H-5 Electronic Data : Electronic Data Page H-5.1 APPENDIX I-5: ELECTRONIC DATA The electronic content of the Annual Groundwater Report has been greatly expanded in the 2011/2012
More informationRAMES. FRAMES 1.X T u t o r i a l. tutorial BEGINNING OF TUTORIAL. Click to begin
RAMES tutorial BEGINNING OF TUTORIAL FRAMES 1.X T u t o r i a l Click to begin TABLE OF CONTENTS Tutorial overview FAMILIARIZES USERS WITH TUTORIAL FEATURES Tutorial introduction INTRODUCES THE STORY IN
More informationimag 4700 Series FLANGED MAGMETER
p r (Remote Display) RIGHT METER FOR Water & Wastewater Treatment Municipal Pump skids Pump stations Packaged plants Filtration systems Reclaimed water Hydraulic fracturing -300 Features Easy setup Minimal
More informationManagement of Mine Water Quality Data from Permitting to Compliance to Closure
Golden CO; USA Reliable Mine Water Technology IMWA 2013 Management of Mine Water Quality Data from Permitting to Compliance to Closure Susan Wyman¹, Makinsey Harmon² Whetstone Associates, 104 W. Ruby Avenue,
More informationSaving Energy with Free Cooling and How Well It Works
Saving Energy with Free Cooling and How Well It Works Brent Draney HPC Facility Integration Lead Data Center Efficiency Summit 2014-1 - NERSC is the primary computing facility for DOE Office of Science
More informationNON STRUCTURAL STORMWATER STRATEGIES (NJAC 7:8-5.3) - ATTACHMENT G
NON STRUCTURAL STORMWATER STRATEGIES (NJAC 7:8-5.3) - ATTACHMENT G 1. Has the applicant identified the Nonstructural Stormwater Strategies which are incorporated into Project and where they are located
More informationTechnical Report REVISION SHEET. STUDSVIK UK LIMITED ENSREG Stress Tests : Final Report NO PROTECTIVE MARKING NO PROTECTIVE MARKING.
STUDSVIK UK LIMITED ENSREG Stress Tests : Final Report REVISION SHEET Rev. Description Revised By Checked By Approved By A Original copy ER DS MM Studsvik Report Reference: TR_MRF021 Revision: Rev A Date:
More informationFormer DuPont Barksdale Works Project Update
Former DuPont Barksdale Works Project Update September 10, 2003 Presented by: DuPont Corporate Remediation Group Presenters and Topics Brad Nave - DuPont Corporate Remediation Group Tonight s Topics Update
More informationEXHIBIT A SCOPE OF SERVICES. Rapid City Landfill Permit 2018 Project No. SW / CIP No
EXHIBIT A SCOPE OF SERVICES Rapid City Landfill Permit 2018 Project No. SW18 2448 / CIP No. 51202 The Rapid City Landfill s current Solid Waste Operations Permit expires July 15, 2019. The City wishes
More informationMining Engineering Technician: Speciality Mine Exploitation
Mining Engineering Technician: Speciality Mine Exploitation FIRST YEAR PHYSICAL BASES OF ENGINEERING 9220001 Core 1st 1st semester 6 7.2 Mechanics. Electricity. Thermodynamics. Fluid mechanics. Classes
More informationMODFLOW UZF Package The MODFLOW Unsaturated-Zone Flow (UZF) Package Interface in GMS
v. 10.2 GMS 10.2 Tutorial The MODFLOW Unsaturated-Zone Flow (UZF) Package Interface in GMS Objectives This tutorial explains how to use the MODFLOW Unsaturated-Zone Flow (UZF) package and compares it to
More informationConsistent Measurement of Broadband Availability
Consistent Measurement of Broadband Availability FCC Data through 12/2015 By Advanced Analytical Consulting Group, Inc. December 2016 Abstract This paper provides several, consistent measures of broadband
More informationMGO Tutorial: Plume Management
MGO Tutorial: Plume Management Introduction Pumping well optimization technology is used to determine the ideal pumping well locations, and ideal pumping rates at these locations, in order to minimize
More informationDallas Municipal Archives Archives Collections Finding Guides and Inventories
Dallas Municipal Archives Archives Collections Finding Guides and Inventories Guide No. 29A City of Dallas Water Works, 1890 1993 (Collection 91060) Processed by: Cindy Smolovik City Archivist Office of
More informationGROUND FAULT CIRCUIT INTERUPTERS
Title: GFCI Effective Date: 11/14/2014 Control Number: THG_0031 Revision Number: 1 Date: 10/21/2015 Annual Review Completed: 5/13/2015 GROUND FAULT CIRCUIT INTERUPTERS CONTENTS I. PURPOSE II. GENERAL REQUIREMENTS
More informationVTA s BART Silicon Valley Phase II Extension Project San Jose Downtown Association
VTA s BART Silicon Valley Phase II Extension Project San Jose Downtown Association August 24, 2017 THANK YOU! San Jose Downtown Association for inviting us & San Jose First United Methodist Church for
More informationCuyama Valley Groundwater Basin Groundwater Sustainability Plan Data Management System Draft. Prepared by:
Cuyama Valley Groundwater Basin Groundwater Sustainability Plan Data Management System Draft Prepared by: November 2018 Chapter 6 Data Management System This chapter includes the Data Management System
More informationEXTRA TERRITORIAL ZONING COMMISSION CASE ANALYSIS
DOÑA ANA COUNTY COMMUNITY PLANNING AND ECONOMIC DEVELOPMENT DEPARTMENT Building Planning GIS 845 North Motel Boulevard Las Cruces, New Mexico 88007 (575) 647-7350 Fax: (575) 525-6131 Toll Free: 1 (877)
More informationMunicipal Setting Designations: A Guide for Cities
TCEQ GENERAL INFORMATION Remediation Division GI-326 Revised February 2013 Municipal Setting Designations: A Guide for Cities INTRODUCTION In 2003, the 78 th Texas Legislature passed a Municipal Setting
More informationAPPLICATION No. To the ALBERTA ENERGY AND UTILITIES BOARD RE:
APPLICATION No. To the ALBERTA ENERGY AND UTILITIES BOARD RE: New 240 kv Montana Alberta Tie Ltd. (MATL) Substation 120S and Reconfigure 240kV Transmission Line 923L AltaLink Management Ltd. 2611 3 rd
More informationTHE NEXUS OF LEAK DETECTION & ASSET MANAGEMENT
THE NEXUS OF LEAK DETECTION & ASSET MANAGEMENT AN INNOVATIVE AND EFFICIENT APPROACH IN SAN MARCOS, TX & SAN JUAN, PR Wayne Pratt WPratt@wachsws.com (847) 946-5907 Agenda Leak Detection Key Drivers Methodology
More informationAppendix H PCB Inspection and Sampling Information for Building G (500, Angel Shark) at Malibu High School
Appendix H PCB Inspection and Sampling Information for Building G (500, Angel Shark) at Malibu High School ENVIRON Tables ENVIRON Table H-4 Summary of Pre- and Post-BMP Annual Cleaning Air Sampling Results
More informationSENATE, No STATE OF NEW JERSEY. 217th LEGISLATURE INTRODUCED DECEMBER 12, 2016
SENATE, No. STATE OF NEW JERSEY th LEGISLATURE INTRODUCED DECEMBER, 0 Sponsored by: Senator STEPHEN M. SWEENEY District (Cumberland, Gloucester and Salem) Senator LINDA R. GREENSTEIN District (Mercer and
More informationimag 4700 Series FLANGED MAGMETER
r (Remote Display) RIGHT METER FOR Water & Wastewater Treatment Municipal Pump skids Pump stations Packaged plants Filtration systems Reclaimed water Hydraulic fracturing Features Easy setup Minimal straight
More informationGeologic Sequestration Data System (GSDS) Status of Development
Geologic Sequestration Data System (GSDS) Status of Development Joe Tiago, U.S. EPA Ground Water Protection Council (GWPC) Houston, TX January 24, 2012 Purpose Describe the process and status of GSDS development
More informationWater Distribution System Wireless Monitoring Solutions
Water Distribution System Wireless Monitoring Solutions Pump Station Aquifer Level Tank Level Reservoir Level Rainfall Mag Meter Flow Hydrant Pressure Water Meter Flow Water Quality Water Hammer Pressure
More informationRT3D Sequential Anaerobic Degradation: PCE TCE DCE VC
GMS 7.0 TUTORIALS RT3D Sequential Anaerobic Degradation: PCE TCE DCE VC This tutorial illustrates the steps involved in modeling sequential anaerobic degradation of PCE using the RT3D model. Since the
More informationENMAX Generation Portfolio Inc.
Decision 22192-D01-2017 ENMAX Generation Portfolio Inc. September 5, 2017 Alberta Utilities Commission Decision 22192-D01-2017 ENMAX Generation Portfolio Inc. Proceeding 22192 Application 22192-A002 September
More informationARLINGTON COUNTY, VIRGINIA
ARLINGTON COUNTY, VIRGINIA County Board Agenda Item Meeting of October 15, 2016 DATE: October 11, 2016 SUBJECT: Request to ratify advertisement of public hearings by the Planning Commission and the County
More informationUSE OF DATABASES IN CHARACTERIZATION AT MINE SITES 1
USE OF DATABASES IN CHARACTERIZATION AT MINE SITES 1 Virginia T. McLemore 2, Gretchen K. Hoffman, Maureen Wilks, J. Steven Raugust, and Glen R. Jones Abstract: Mining companies and their consultants generate
More informationimag-series Flanged Magmeter
s Flow Meters & Controls imag-series o M o vi n g P a r t N FEATURES Easy setup Minimal straight pipe Mounted or remote rate & total Tamper-evident seal NSF-61 approved (3 only) IP68 rated 9001:2008 ISO
More informationCOMBINING MULTIPLE GEOPHYSICAL DATA SETS INTO A SINGLE 3D IMAGE. Abstract
COMBINING MULTIPLE GEOPHYSICAL DATA SETS INTO A SINGLE 3D IMAGE Jeffrey J. Daniels*, Mark Vendl+, Jennifer Holt*, and Erich Guy* *OSU, Columbus, OH +USEPA, Chicago, IL Abstract Traditional geophysical
More informationProvider Monitoring Process
Provider Monitoring Process This statewide provider monitoring process is applicable for all providers including direct vendors, Agency with Choice (AWC) Financial Management Services (FMS) providers and
More informationComparison of MANE-VU SIP Template to EPA SIP Checklist. September 17, 2007
Comparison of MANE-VU SIP to EPA SIP Checklist 9/17/07: Draft 1 Comparison of MANE-VU SIP to EPA SIP Checklist September 17, 2007 Key to Color Codes action MANE-VU work product Class I states only (and
More informationAnnual Report for the Utility Savings Initiative
Report to the North Carolina General Assembly Annual Report for the Utility Savings Initiative July 1, 2016 June 30, 2017 NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY http://portal.ncdenr.org Page
More informationNORSOK M-501. Frequently asked questions
NORSOK M-501 Frequently asked questions Hempel NORSOK coating systems What is NORSOK M-501? NORSOK M-501 is a standard document developed by the Norwegian petroleum industry to ensure adequate safety,
More informationUpdate : CalFresh Elimination of Change Reporting in CalFresh
Santa Clara County Social Services Agency page 1 Date: 03/18/16 References: Cross-References: Clerical: Handbook Revision: ACL #15-90, ACL #15-90E None No Yes Elimination of Change Reporting in CalFresh
More informationGMS 9.1 Tutorial MODFLOW Conceptual Model Approach II Build a multi-layer MODFLOW model using advanced conceptual model techniques
v. 9.1 GMS 9.1 Tutorial Build a multi-layer MODFLOW model using advanced conceptual model techniques 00 Objectives The conceptual model approach involves using the GIS tools in the Map module to develop
More informationAppendix C.6. Best Management Practices for Construction Activities
Appendix C.6 Best Management Practices for Construction Activities In accordance with Section F.2 of San Diego Regional Water Quality Control Board (RWQCB) Order 2001-01 (Permit), the City of La Mesa has
More informationLone-StarS Electronic Emissions Reporting User Guide
Lone-StarS Electronic Emissions Reporting User Guide This is a step-by-step manual on how to work with the Lone-StarS program to report emissions electronically to TCEQ (Texas Commission in Environmental
More informationUnited Nations Environment Programme
UNITED NATIONS United Nations Environment Programme Distr. GENERAL UNEP/OzL.Pro/ExCom/81/41 21 May 2018 EP ORIGINAL: ENGLISH EXECUTIVE COMMITTEE OF THE MULTILATERAL FUND FOR THE IMPLEMENTATION OF THE MONTREAL
More informationIndirect Adiabatic and Evaporative Data Centre Cooling
Indirect Adiabatic and Evaporative Data Centre Cooling Developed in response to the broadening of the ASHRAE recommended server inlet temperature envelope in 2008, Excool represents the most advanced
More informationUtilityScan TM. Locate and Map Underground Utilities with GPR. Typical Uses. Designate Targets.
UtilityScan TM Locate and Map Underground Utilities with GPR UtilityScan is the industry standard ground penetrating radar solution for the designation of subsurface utilities. With UtilityScan, users
More informationDATA CENTER LIQUID COOLING
DATA CENTER LIQUID COOLING EFFICIENT, EFFECTIVE, SUSTAINABLE What is Liquid Cooling? Key Trends & Potential Inhibitors Why are Many Owner/Operators Making the Move? Types of Liquid Cooling Solutions Liquid
More informationUSER MANUAL
www.deq.state.mi.us/watertrack USER MANUAL Noncommunity Water Supply Program Noncommunity & Private Drinking Water Supplies Unit Environmental Health Section Office of Drinking Water & Municipal Assistance
More informationCHAPTER 82 WELL CONTRACTOR CERTIFICATION [Prior to 5/12/93, see also 567 Ch 37]
Ch 82, p.1 CHAPTER 82 WELL CONTRACTOR CERTIFICATION [Prior to 5/12/93, see also 567 Ch 37] 567 82.1(455B) Definitions. In addition to the definitions in Iowa Code sections 455B.171, 455B.190 and 455B.190A,
More informationMED-PROJECT REQUEST FOR APPROVAL OF MAIL-BACK PACKAGE DISPOSAL PROCESS
MED-PROJECT REQUEST FOR APPROVAL OF MAIL-BACK PACKAGE DISPOSAL PROCESS July 23, 2016 MED-PROJECT REQUEST FOR APPROVAL OF MAIL-BACK PACKAGE DISPOSAL PROCESS Pursuant to County of Santa Clara Safe Drug Disposal
More informationComparison of 1D and 2D Surface Water Models for Solid Waste Facilities. Garth R. Bowers, P.E., Carl E. Bueter, P.E., Larry Henk
Comparison of 1D and 2D Surface Water Models for Solid Waste Facilities Garth R. Bowers, P.E., Carl E. Bueter, P.E., Larry Henk Introduction Importance of Accurate Floodplain Delineation Required by Federal
More information