Nutrient loads and trends for several Florida Rivers
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1 Nutrient loads and trends for several Florida Rivers Chris Sedlacek Jay Silvanima and Gail Sloane Florida Department of Environmental Protection Division of Water Resource Management 1
2 Introduction Nutrients NO 2-3, NH 3, PO 4 Eutrophication Surface Water Trend stations 37 out of 75 stations State and EPA funded program 2
3 USGS gauging stations 3
4 Surface Water trend stations 4
5 Introduction Nutrients NO 2-3, NH 3, PO 4 Eutrophication Surface Water Trend stations 37 out of 75 stations State and EPA funded program Calculation of load based on average flow and average analyte concentration Trend determination 5
6 Trend analysis Nitrate and Nitrite total as N 3513 Ammonia and Organic Nitrogen (Total as N) 3522 Residual Residual Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q COLLECTION.DATE Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 COLLECTION.DATE median(senslope) "INCREASING TREND" P-value =.3714 Withlacoochee Record from Analysis is non-parametric median(senslope) "DECREASING TREND" P-value = Suwannee Seasonality corrected Flow adjusted Sen slope is very small 6
7 Selected rivers stations Escambia Apalachicola St. Marks Suwannee Withlacoochee Little Manatee Caloosahatchee 7
8 Selected rivers stations Escambia Apalachicola St. Marks Suwannee Withlacoochee Little Manatee Caloosahatchee 8
9 Escambia River Flow 3541 Ammonia, Total FLOW (cfs) Nitrate and Nitrite Ammonia Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 COLLECTION.DATE Nitrate and Nitrite Ammonia+Org.N, Total Ammonia and Org. N 2,168 9
10 Escambia River Flow 3541 Orthophosphate FLOW (cfs) Phosphorous, Total Orthophosphate Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 COLLECTION.DATE Phosphorous
11 Selected rivers stations Escambia Apalachicola St. Marks Suwannee Withlacoochee Little Manatee Caloosahatchee 11
12 Apalachicola River Flow 3524 Ammonia, Total FLOW (cfs) Nitrate and Nitrite Ammonia Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 COLLECTION.DATE Nitrate and Nitrite , Ammonia+Org.N, Total 12 1 Ammonia and Org. N 5,
13 Apalachicola River Flow 3524 Orthophosphate FLOW (cfs) Phosphorous, Total Orthophosphate Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 COLLECTION.DATE Phosphorous
14 Selected rivers stations Escambia Apalachicola St. Marks Suwannee Withlacoochee Little Manatee Caloosahatchee 14
15 St. Marks River Flow 3528 Ammonia, Total Ammonia FLOW (cfs) Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 COLLECTION.DATE Nitrate and Nitrite Nitrate and Nitrite Ammonia+Org.N, Total 35 3 Ammonia and Org. N
16 St. Marks River Flow 3528 Orthophosphate Orthophosphate FLOW (cfs) Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 COLLECTION.DATE Phosphorous, Total Phosphorous
17 Selected rivers stations Escambia Apalachicola St. Marks Suwannee Withlacoochee Little Manatee Caloosahatchee 17
18 Suwannee River Flow 3522 Ammonia, Total FLOW (cfs) Nitrate and Nitrite Ammonia Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 COLLECTION.DATE Nitrate and Nitrite , Ammonia+Org.N, Total Ammonia and Org. N 3,53 18
19 Suwannee River Flow 3522 Orthophosphate FLOW (cfs) Phosphorous, Total Orthophosphate Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 COLLECTION.DATE Phosphorous
20 Selected rivers stations Escambia Apalachicola St. Marks Suwannee Withlacoochee Little Manatee In 25 NO 3 loading was calculated to be 6,198 metric tons Caloosahatchee 2
21 Selected rivers stations Escambia Apalachicola St. Marks Suwannee Withlacoochee Little Manatee Caloosahatchee 21
22 Withlacoochee River Flow 3513 Ammonia, Total FLOW (cfs) Nitrate and Nitrite Ammonia Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q COLLECTION.DATE Nitrate and Nitrite Ammonia+Org.N, Total Ammonia and Org. N
23 Withlacoochee River Flow 3513 Orthophosphate FLOW (cfs) Phosphorous, Total Orthophosphate Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q COLLECTION.DATE Phosphorous
24 Selected rivers stations Escambia Apalachicola St. Marks Suwannee Withlacoochee Little Manatee Caloosahatchee 24
25 Little Manatee River Flow 3555 Ammonia, Total FLOW (cfs) Nitrate and Nitrite Ammonia Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q COLLECTION.DATE Nitrate and Nitrite Ammonia+Org.N, Total 25 2 Ammonia and Org. N
26 Little Manatee River Flow 3555 Orthophosphate FLOW (cfs) Phosphorous, Total Orthophosphate Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q COLLECTION.DATE Phosphorous
27 Selected rivers stations Escambia Apalachicola St. Marks Suwannee Withlacoochee Little Manatee Caloosahatchee 27
28 Caloosahatchee River Flow 3568 Ammonia, Total FLOW (cfs) Nitrate and Nitrite Ammonia Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q COLLECTION.DATE Nitrate and Nitrite Ammonia+Org.N, Total 6 Ammonia and Org. N 3,
29 Caloosahatchee River Flow 3568 Orthophosphate FLOW (cfs) Phosphorous, Total Orthophosphate Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q COLLECTION.DATE Phosphorous
30 Summary Large data set available Loading and trends are variable Enhancement of monitoring network Chris Sedlacek Watershed Monitoring Section Florida Department of Environmental Protection 26 Blair Stone Rd. Tallahassee, FL Phone: (85)
31 Web sites Water Resource Management Surface Water Quality Chris Sedlacek Watershed Monitoring Section Florida Department of Environmental Protection 26 Blair Stone Rd. Tallahassee, FL Phone: (85)
32 Questions Chris Sedlacek Watershed Monitoring Section Florida Department of Environmental Protection 26 Blair Stone Rd. Tallahassee, FL Phone: (85)
33 33
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